{"id":"https://openalex.org/W2021938690","doi":"https://doi.org/10.1021/ic991001z","title":"Ground-State Properties and Excited-State Reactivity of 8-Quinolate Complexes of Ruthenium(II)","display_name":"Ground-State Properties and Excited-State Reactivity of 8-Quinolate Complexes of Ruthenium(II)","publication_year":1999,"publication_date":"1999-12-01","ids":{"openalex":"https://openalex.org/W2021938690","doi":"https://doi.org/10.1021/ic991001z","mag":"2021938690","pmid":"https://pubmed.ncbi.nlm.nih.gov/11671331"},"language":"en","primary_location":{"id":"doi:10.1021/ic991001z","doi":"https://doi.org/10.1021/ic991001z","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic991001z","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://digitalcommons.otterbein.edu/chem_fac/8","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5060110088","display_name":"Jeremy T. Warren","orcid":"https://orcid.org/0000-0002-8191-7958","observed_orcids":["https://orcid.org/0000-0002-8191-7958"]},"institutions":[{"id":"https://openalex.org/I52357470","display_name":"The Ohio State University","ror":"https://ror.org/00rs6vg23","country_code":"US","type":"education","lineage":["https://openalex.org/I52357470"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jeremy T. Warren","raw_affiliation_strings":["Department of Chemistry, The Ohio State University, Columbus, Ohio 43210"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, The Ohio State University, Columbus, Ohio 43210","institution_ids":["https://openalex.org/I52357470"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100344414","display_name":"Wei Chen","orcid":"https://orcid.org/0000-0002-2909-3023","observed_orcids":["https://orcid.org/0000-0002-2909-3023"]},"institutions":[{"id":"https://openalex.org/I52357470","display_name":"The Ohio State University","ror":"https://ror.org/00rs6vg23","country_code":"US","type":"education","lineage":["https://openalex.org/I52357470"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Wei Chen","raw_affiliation_strings":["Department of Chemistry, The Ohio State University, Columbus, Ohio 43210"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, The Ohio State University, Columbus, Ohio 43210","institution_ids":["https://openalex.org/I52357470"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5044459355","display_name":"Dean H. Johnston","orcid":"https://orcid.org/0000-0001-7533-8178","observed_orcids":["https://orcid.org/0000-0001-7533-8178"]},"institutions":[{"id":"https://openalex.org/I52357470","display_name":"The Ohio State University","ror":"https://ror.org/00rs6vg23","country_code":"US","type":"education","lineage":["https://openalex.org/I52357470"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Dean H. Johnston","raw_affiliation_strings":["Department of Chemistry, The Ohio State University, Columbus, Ohio 43210"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, The Ohio State University, Columbus, Ohio 43210","institution_ids":["https://openalex.org/I52357470"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5038676358","display_name":"Claudia Turr\u00f3","orcid":"https://orcid.org/0000-0003-3202-5870","observed_orcids":["https://orcid.org/0000-0003-3202-5870"]},"institutions":[{"id":"https://openalex.org/I52357470","display_name":"The Ohio State University","ror":"https://ror.org/00rs6vg23","country_code":"US","type":"education","lineage":["https://openalex.org/I52357470"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Claudia Turro","raw_affiliation_strings":["Department of Chemistry, The Ohio State University, Columbus, Ohio 43210"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, The Ohio State University, Columbus, Ohio 43210","institution_ids":["https://openalex.org/I52357470"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I52357470"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.5409,"has_fulltext":false,"cited_by_count":59,"citation_normalized_percentile":{"value":0.8907347,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"38","issue":"26","first_page":"6187","last_page":"6192"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.989300012588501,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.989300012588501,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10611","display_name":"Organic Light-Emitting Diodes Research","score":0.0034000000450760126,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11240","display_name":"Luminescence and Fluorescent Materials","score":0.003000000026077032,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ruthenium-ii-complexes","display_name":"ruthenium(II) complexes","score":0.9480000138282776},{"id":"https://openalex.org/keywords/metal-to-ligand-charge-transfer","display_name":"metal-to-ligand charge transfer","score":0.7829999923706055},{"id":"https://openalex.org/keywords/excited-state-reactivity","display_name":"excited-state reactivity","score":0.8159999847412109},{"id":"https://openalex.org/keywords/photophysical-properties","display_name":"photophysical properties","score":0.7089999914169312},{"id":"https://openalex.org/keywords/redox-properties","display_name":"redox properties","score":0.8389999866485596},{"id":"https://openalex.org/keywords/emission-lifetime","display_name":"emission lifetime","score":0.7490000128746033},{"id":"https://openalex.org/keywords/methyl-viologen-reduction","display_name":"methyl viologen reduction","score":0.8109999895095825},{"id":"https://openalex.org/keywords/marcus-inverted-region","display_name":"Marcus inverted region","score":0.7730000019073486},{"id":"https://openalex.org/keywords/electron-transfer","display_name":"electron transfer","score":0.5849999785423279},{"id":"https://openalex.org/keywords/2-2-bipyridine","display_name":"2,2'-bipyridine","score":0.8240000009536743},{"id":"https://openalex.org/keywords/1-10-phenanthroline","display_name":"1,10-phenanthroline","score":0.984000027179718}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9129676222801208},{"id":"https://openalex.org/C181500209","wikidata":"https://www.wikidata.org/wiki/Q215328","display_name":"Excited state","level":2,"score":0.7149434089660645},{"id":"https://openalex.org/C555196967","wikidata":"https://www.wikidata.org/wiki/Q1086","display_name":"Ruthenium","level":3,"score":0.7049421072006226},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.6438901424407959},{"id":"https://openalex.org/C2777660389","wikidata":"https://www.wikidata.org/wiki/Q416005","display_name":"Phenanthroline","level":2,"score":0.6087444424629211},{"id":"https://openalex.org/C123669783","wikidata":"https://www.wikidata.org/wiki/Q902898","display_name":"Electron transfer","level":2,"score":0.5236254334449768},{"id":"https://openalex.org/C2777463227","wikidata":"https://www.wikidata.org/wiki/Q408047","display_name":"Acetonitrile","level":2,"score":0.5034062266349792},{"id":"https://openalex.org/C2779336533","wikidata":"https://www.wikidata.org/wiki/Q413658","display_name":"Bipyridine","level":3,"score":0.4490698575973511},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.4318045973777771},{"id":"https://openalex.org/C55904794","wikidata":"https://www.wikidata.org/wiki/Q82682","display_name":"Redox","level":2,"score":0.42644429206848145},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.27012813091278076},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.24400115013122559},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.22201663255691528},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.06974485516548157},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.06270474195480347},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1021/ic991001z","doi":"https://doi.org/10.1021/ic991001z","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic991001z","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmid:11671331","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/11671331","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"},{"id":"pmh:oai:digitalcommons.otterbein.edu:chem_fac-1003","doi":null,"is_oa":true,"landing_page_url":"https://digitalcommons.otterbein.edu/chem_fac/8","pdf_url":null,"source":{"id":"https://openalex.org/S4377196640","display_name":"Digital Commons - Otterbein (Otterbein University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I197312921","host_organization_name":"Otterbein University","host_organization_lineage":["https://openalex.org/I197312921"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Chemistry Faculty Scholarship","raw_type":"text"}],"best_oa_location":{"id":"pmh:oai:digitalcommons.otterbein.edu:chem_fac-1003","doi":null,"is_oa":true,"landing_page_url":"https://digitalcommons.otterbein.edu/chem_fac/8","pdf_url":null,"source":{"id":"https://openalex.org/S4377196640","display_name":"Digital Commons - Otterbein (Otterbein University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I197312921","host_organization_name":"Otterbein University","host_organization_lineage":["https://openalex.org/I197312921"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Chemistry Faculty Scholarship","raw_type":"text"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":104,"referenced_works":["https://openalex.org/W322962319","https://openalex.org/W349115113","https://openalex.org/W577968295","https://openalex.org/W602561496","https://openalex.org/W1520991451","https://openalex.org/W1542757333","https://openalex.org/W1595263782","https://openalex.org/W1601422968","https://openalex.org/W1963567221","https://openalex.org/W1964832483","https://openalex.org/W1966624508","https://openalex.org/W1967141977","https://openalex.org/W1967949014","https://openalex.org/W1969220374","https://openalex.org/W1969633552","https://openalex.org/W1970393749","https://openalex.org/W1970499578","https://openalex.org/W1971194813","https://openalex.org/W1971499243","https://openalex.org/W1974007281","https://openalex.org/W1978960411","https://openalex.org/W1981259826","https://openalex.org/W1981733988","https://openalex.org/W1983090954","https://openalex.org/W1983346782","https://openalex.org/W1985832381","https://openalex.org/W1987458497","https://openalex.org/W1989384815","https://openalex.org/W1991079436","https://openalex.org/W1991101882","https://openalex.org/W1994282950","https://openalex.org/W1994498465","https://openalex.org/W1997124391","https://openalex.org/W2000310790","https://openalex.org/W2001270915","https://openalex.org/W2001343833","https://openalex.org/W2001720465","https://openalex.org/W2006354060","https://openalex.org/W2007610946","https://openalex.org/W2007679907","https://openalex.org/W2010777497","https://openalex.org/W2015001981","https://openalex.org/W2015650425","https://openalex.org/W2015800274","https://openalex.org/W2015982828","https://openalex.org/W2016551879","https://openalex.org/W2019460193","https://openalex.org/W2020766322","https://openalex.org/W2022322814","https://openalex.org/W2022470147","https://openalex.org/W2024031811","https://openalex.org/W2024608500","https://openalex.org/W2025659773","https://openalex.org/W2028537742","https://openalex.org/W2030586728","https://openalex.org/W2031534123","https://openalex.org/W2031904472","https://openalex.org/W2033288176","https://openalex.org/W2035258209","https://openalex.org/W2036268565","https://openalex.org/W2039018983","https://openalex.org/W2039809473","https://openalex.org/W2043167078","https://openalex.org/W2046133238","https://openalex.org/W2047101741","https://openalex.org/W2047693884","https://openalex.org/W2048093472","https://openalex.org/W2048255320","https://openalex.org/W2050843981","https://openalex.org/W2052212603","https://openalex.org/W2057102736","https://openalex.org/W2059124354","https://openalex.org/W2062543269","https://openalex.org/W2064456720","https://openalex.org/W2065221274","https://openalex.org/W2065249226","https://openalex.org/W2077035508","https://openalex.org/W2082129620","https://openalex.org/W2082496720","https://openalex.org/W2083006416","https://openalex.org/W2084751208","https://openalex.org/W2087152379","https://openalex.org/W2089802780","https://openalex.org/W2091237955","https://openalex.org/W2092329486","https://openalex.org/W2093644325","https://openalex.org/W2098847938","https://openalex.org/W2105905161","https://openalex.org/W2113274671","https://openalex.org/W2121135334","https://openalex.org/W2122299909","https://openalex.org/W2123987607","https://openalex.org/W2150305089","https://openalex.org/W2158046987","https://openalex.org/W2224142370","https://openalex.org/W2321189164","https://openalex.org/W2614884730","https://openalex.org/W2952513104","https://openalex.org/W2952928519","https://openalex.org/W2952993615","https://openalex.org/W3004794190","https://openalex.org/W3005061667","https://openalex.org/W3005392207","https://openalex.org/W4391606224"],"related_works":["https://openalex.org/W1983463270","https://openalex.org/W2065862920","https://openalex.org/W2082496720","https://openalex.org/W2086886286","https://openalex.org/W2134954265","https://openalex.org/W4254917185","https://openalex.org/W1985434904","https://openalex.org/W1963537024","https://openalex.org/W2042131735","https://openalex.org/W2042454275"],"abstract_inverted_index":{"In":[0],"an":[1],"effort":[2],"to":[3,55,84,201],"explore":[4],"new":[5],"systems":[6,74],"with":[7,62,78,152,162,191,195],"highly":[8,184],"reducing":[9,113,185],"excited":[10,99,187],"states,":[11],"we":[12],"prepared":[13],"a":[14],"series":[15],"of":[16,19,48,57,107,119,126,155,169],"Ru(II)":[17],"complexes":[18,60,110],"the":[20,49,58,66,90,108,116,120,153,171,176,183],"type":[21],"Ru(L)(2)quo(+)":[22,50,73,109],"(L":[23],"=":[24,34],"bpy":[25],"(2,2'-bipyridine),":[26],"phen":[27,94],"(1,10-phenanthroline),":[28],"dmphen":[29],"(4,7-dimethyl-1,10-phenanthroline),":[30],"tmphen":[31],"(3,4,7,8-tetramethyl-1,10-phenanthroline);":[32],"quo(-)":[33],"8-quinolate)":[35],"and":[36,40,45,128,137,140],"investigated":[37],"their":[38],"photophysical":[39],"redox":[41],"properties.":[42],"The":[43,72,167],"absorption":[44,148],"emission":[46,63],"spectra":[47],"are":[51,75,150],"significantly":[52,111],"red-shifted":[53],"relative":[54],"those":[56],"parent":[59,121],"Ru(L)(3)(2+),":[61],"maxima":[64],"in":[65,70,105,135,145,165,175],"757-783":[67],"nm":[68],"range":[69],"water.":[71,146,166],"easily":[76],"oxidized":[77],"E(1/2)(Ru(III/II))":[79],"values":[80],"ranging":[81,198],"from":[82,182,199],"+0.62":[83],"+0.70":[85],"V":[86,203],"vs":[87,204],"NHE,":[88],"making":[89],"emissive":[91],"Ru":[92],"-->":[93],"MLCT":[95,117],"(metal-to-ligand":[96],"charge":[97],"transfer)":[98],"states":[100,118],"(E(00)":[101],"approximately":[102],"1.95":[103],"eV":[104],"CH(3)CN)":[106],"better":[112],"agents":[114],"than":[115],"Ru(L)(3)(2+)":[122],"complexes.":[123],"Emission":[124],"lifetimes":[125],"17.0":[127],"32.2":[129],"ns":[130,142],"were":[131],"measured":[132],"for":[133,143],"Ru(phen)(2)quo(+)":[134,160,186],"water":[136],"acetonitrile,":[138],"respectively,":[139],"11.4":[141],"Ru(bpy)(2)quo(+)":[144],"Transient":[147],"results":[149],"consistent":[151],"formation":[154],"reduced":[156],"methyl":[157],"viologen":[158],"upon":[159],"excitation":[161],"visible":[163],"light":[164],"possibility":[168],"observing":[170],"Marcus":[172],"inverted":[173],"region":[174],"forward":[177],"bimolecular":[178],"electron":[179,193],"transfer":[180],"reaction":[181],"state":[188],"was":[189],"explored":[190],"neutral":[192],"acceptors":[194],"reduction":[196],"potentials":[197],"+0.25":[200],"-1.15":[202],"NHE.":[205]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":4},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":2},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":3},{"year":2016,"cited_by_count":3},{"year":2014,"cited_by_count":2},{"year":2012,"cited_by_count":3}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}