{"id":"https://openalex.org/W2020712702","doi":"https://doi.org/10.1039/tf9706600397","title":"Studies by electron spin resonance of the reactions of alkylperoxy radicals. Part 2.\u2014Equilibrium between alkylperoxy radicals and tetroxide molecules","display_name":"Studies by electron spin resonance of the reactions of alkylperoxy radicals. Part 2.\u2014Equilibrium between alkylperoxy radicals and tetroxide molecules","publication_year":1970,"publication_date":"1970-01-01","ids":{"openalex":"https://openalex.org/W2020712702","doi":"https://doi.org/10.1039/tf9706600397","mag":"2020712702"},"language":"en","primary_location":{"id":"doi:10.1039/tf9706600397","doi":"https://doi.org/10.1039/tf9706600397","is_oa":false,"landing_page_url":"https://doi.org/10.1039/tf9706600397","pdf_url":null,"source":{"id":"https://openalex.org/S164507617","display_name":"Transactions of the Faraday Society","issn_l":"0014-7672","issn":["0014-7672","2050-5647"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Trans. Faraday Soc.","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5075884909","display_name":"John E. Bennett","orcid":"https://orcid.org/0009-0008-1257-098X","observed_orcids":["https://orcid.org/0009-0008-1257-098X"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"J. E. Bennett","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101979897","display_name":"David M. Brown","orcid":"https://orcid.org/0000-0001-8248-056X","observed_orcids":["https://orcid.org/0000-0001-8248-056X"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"D. M. Brown","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5110018017","display_name":"Bryn Mile","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"B. Mile","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.7298,"has_fulltext":false,"cited_by_count":47,"citation_normalized_percentile":{"value":0.65004462,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":96},"biblio":{"volume":"66","issue":"0","first_page":"397","last_page":"405"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13013","display_name":"Free Radicals and Antioxidants","score":0.6679999828338623,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13013","display_name":"Free Radicals and Antioxidants","score":0.6679999828338623,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12381","display_name":"Electron Spin Resonance Studies","score":0.16259999573230743,"subfield":{"id":"https://openalex.org/subfields/1304","display_name":"Biophysics"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T10117","display_name":"Advanced Combustion Engine Technologies","score":0.025800000876188278,"subfield":{"id":"https://openalex.org/subfields/1507","display_name":"Fluid Flow and Transfer Processes"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/alkylperoxy-radicals","display_name":"alkylperoxy radicals","score":0.9990000128746033},{"id":"https://openalex.org/keywords/radical-dimerization","display_name":"radical dimerization","score":0.6269999742507935},{"id":"https://openalex.org/keywords/photolysis","display_name":"photolysis","score":0.6779999732971191},{"id":"https://openalex.org/keywords/radical-decay-kinetics","display_name":"radical decay kinetics","score":0.6489999890327454},{"id":"https://openalex.org/keywords/termination-reactions","display_name":"termination reactions","score":0.49399998784065247},{"id":"https://openalex.org/keywords/radical-concentration-measurement","display_name":"radical concentration measurement","score":0.31700000166893005}],"concepts":[{"id":"https://openalex.org/C139066938","wikidata":"https://www.wikidata.org/wiki/Q185056","display_name":"Radical","level":2,"score":0.9116623997688293},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8404436111450195},{"id":"https://openalex.org/C3288061","wikidata":"https://www.wikidata.org/wiki/Q161064","display_name":"Enthalpy","level":2,"score":0.7005501985549927},{"id":"https://openalex.org/C187961010","wikidata":"https://www.wikidata.org/wiki/Q260463","display_name":"Electron paramagnetic resonance","level":2,"score":0.6201926469802856},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.5437548756599426},{"id":"https://openalex.org/C39353612","wikidata":"https://www.wikidata.org/wiki/Q5283759","display_name":"Atmospheric temperature range","level":2,"score":0.513594388961792},{"id":"https://openalex.org/C32891209","wikidata":"https://www.wikidata.org/wiki/Q483666","display_name":"Spectroscopy","level":2,"score":0.4215892553329468},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.4078906774520874},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.39142027497291565},{"id":"https://openalex.org/C46141821","wikidata":"https://www.wikidata.org/wiki/Q209402","display_name":"Nuclear magnetic resonance","level":1,"score":0.21117714047431946},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.12209761142730713},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.096343994140625},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/tf9706600397","doi":"https://doi.org/10.1039/tf9706600397","is_oa":false,"landing_page_url":"https://doi.org/10.1039/tf9706600397","pdf_url":null,"source":{"id":"https://openalex.org/S164507617","display_name":"Transactions of the Faraday Society","issn_l":"0014-7672","issn":["0014-7672","2050-5647"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Trans. Faraday Soc.","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2072244529","https://openalex.org/W1995987819","https://openalex.org/W2024723221","https://openalex.org/W2054196759","https://openalex.org/W1992026672","https://openalex.org/W1764598193","https://openalex.org/W2031886531","https://openalex.org/W2078580246","https://openalex.org/W4239163413","https://openalex.org/W1981437738"],"abstract_inverted_index":{"Photolytically":[0],"generated":[1],"alkylperoxy":[2,24,77,123],"radicals":[3,25,46,78],"have":[4,112],"been":[5,113],"detected":[6],"and":[7,79,92,102],"their":[8],"concentration":[9,44],"measured":[10,125],"by":[11],"electron":[12],"spin":[13],"resonance":[14],"spectroscopy.":[15],"The":[16,61],"rate":[17],"of":[18,22,45,72,118,122,138],"the":[19,32,43,70,86,116,119,139],"irreversible":[20,120],"decay":[21,121],"tertiary":[23],"is":[26,63,67],"negligible":[27],"below":[28],"\u2013115\u00b0C.":[29],"However,":[30],"within":[31],"temperature":[33,41],"range":[34],"\u2013160":[35],"to":[36,47,49,69,130,132],"\u2013115\u00b0C,":[37],"a":[38,50,80,134],"reduction":[39],"in":[40,89],"causes":[42],"decrease":[48],"new":[51],"value":[52],"which,":[53],"once":[54],"achieved":[55],"does":[56],"not":[57],"vary":[58],"with":[59,115],"time.":[60],"process":[62],"reversible.":[64],"This":[65],"behaviour":[66],"attributed":[68],"existence":[71],"an":[73],"equilibrium":[74],"between":[75],"two":[76],"tetroxide":[81],"molecule.":[82],"Average":[83],"values":[84],"for":[85],"associated":[87],"changes":[88],"entropy":[90],"\u0394S\u00b0":[91],"enthalpy":[93],"\u0394H\u00b0":[94],"are":[95],"\u201338":[96],"\u00b1":[97,104],"4":[98],"cal":[99],"deg\u20131":[100],"mol\u20131":[101,107],"\u20138.9":[103],"0.5":[105],"kcal":[106],"respectively.":[108],"These":[109],"thermodynamic":[110],"constants":[111],"combined":[114],"rates":[117],"radicals,":[124],"at":[126],"higher":[127],"temperatures":[128],"(\u201360":[129],"+20\u00b0C)":[131],"provide":[133],"more":[135],"complete":[136],"description":[137],"termination":[140],"process.":[141]},"counts_by_year":[{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":1},{"year":2012,"cited_by_count":2}],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}
