{"id":"https://openalex.org/W2020002343","doi":"https://doi.org/10.1021/ja00707a055","title":"Carbonium ion intermediates and neighboring group participation in the decomposition of azo compounds","display_name":"Carbonium ion intermediates and neighboring group participation in the decomposition of azo compounds","publication_year":1970,"publication_date":"1970-02-01","ids":{"openalex":"https://openalex.org/W2020002343","doi":"https://doi.org/10.1021/ja00707a055","mag":"2020002343"},"language":"en","primary_location":{"id":"doi:10.1021/ja00707a055","doi":"https://doi.org/10.1021/ja00707a055","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja00707a055","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5018213765","display_name":"Evan L. Allred","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Evan L. Allred","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5013979746","display_name":"Charles Robb Flynn","orcid":"https://orcid.org/0000-0002-3749-0598","observed_orcids":["https://orcid.org/0000-0002-3749-0598"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Charles R. Flynn","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.4595,"has_fulltext":false,"cited_by_count":5,"citation_normalized_percentile":{"value":0.7622692,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":93,"max":95},"biblio":{"volume":"92","issue":"4","first_page":"1064","last_page":"1066"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12191","display_name":"Chemical Reaction Mechanisms","score":0.8281000256538391,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12191","display_name":"Chemical Reaction Mechanisms","score":0.8281000256538391,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13253","display_name":"Chemical Reactions and Mechanisms","score":0.1298999935388565,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T14068","display_name":"Organic and Inorganic Chemical Reactions","score":0.012000000104308128,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/carbonium-ion-intermediate","display_name":"carbonium ion intermediate","score":0.902999997138977},{"id":"https://openalex.org/keywords/neighboring-group-participation","display_name":"neighboring group participation","score":0.9940000176429749},{"id":"https://openalex.org/keywords/azo-compounds","display_name":"azo compounds","score":0.9589999914169312},{"id":"https://openalex.org/keywords/thermal-decomposition","display_name":"thermal decomposition","score":0.7110000252723694},{"id":"https://openalex.org/keywords/azo-bond-cleavage","display_name":"azo bond cleavage","score":0.5509999990463257},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.40400001406669617}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9889885187149048},{"id":"https://openalex.org/C167681012","wikidata":"https://www.wikidata.org/wiki/Q900328","display_name":"Carbonium ion","level":3,"score":0.9781162738800049},{"id":"https://openalex.org/C124681953","wikidata":"https://www.wikidata.org/wiki/Q339062","display_name":"Decomposition","level":2,"score":0.7662700414657593},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.6905113458633423},{"id":"https://openalex.org/C2781311116","wikidata":"https://www.wikidata.org/wiki/Q83306","display_name":"Group (periodic table)","level":2,"score":0.6434476375579834},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.4379260838031769},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.39375489950180054},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.37124884128570557},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.33578866720199585},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3315808176994324}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/ja00707a055","doi":"https://doi.org/10.1021/ja00707a055","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja00707a055","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2010398740","https://openalex.org/W2057528382","https://openalex.org/W1972761774","https://openalex.org/W2065255100","https://openalex.org/W2044303308","https://openalex.org/W1968772816","https://openalex.org/W1975756174","https://openalex.org/W1974590474","https://openalex.org/W1982137068","https://openalex.org/W2950262590"],"abstract_inverted_index":{"ADVERTISEMENT":[0],"RETURN":[1],"TO":[2],"ISSUEPREVArticleNEXTCarbonium":[3],"ion":[4],"intermediates":[5],"and":[6,18,66,71,100,144,161,177,179],"neighboring":[7],"group":[8],"participation":[9],"in":[10],"the":[11,53,84,89,118,129,142,145,150,157,163],"decomposition":[12],"of":[13,56,91,117],"azo":[14],"compoundsEvan":[15],"L.":[16],"Allred":[17],"Charles":[19],"R.":[20],"FlynnCite":[21],"this:":[22],"J.":[23],"Am.":[24],"Chem.":[25],"Soc.":[26],"1970,":[27],"92,":[28],"4,":[29],"1064\u20131066Publication":[30],"Date":[31],"(Print):February":[32],"1,":[33],"1970Publication":[34],"History":[35],"Published":[36],"online1":[37],"May":[38],"2002Published":[39],"inissue":[40],"1":[41],"February":[42],"1970https://pubs.acs.org/doi/10.1021/ja00707a055https://doi.org/10.1021/ja00707a055research-articleACS":[43],"PublicationsRequest":[44],"reuse":[45],"permissionsArticle":[46],"Views50Altmetric-Citations5LEARN":[47],"ABOUT":[48],"THESE":[49],"METRICSArticle":[50],"Views":[51],"are":[52,75,88],"COUNTER-compliant":[54],"sum":[55],"full":[57],"text":[58],"article":[59,123],"downloads":[60],"since":[61],"November":[62],"2008":[63],"(both":[64],"PDF":[65],"HTML)":[67],"across":[68],"all":[69],"institutions":[70],"individuals.":[72],"These":[73],"metrics":[74],"regularly":[76],"updated":[77,101],"to":[78,83],"reflect":[79],"usage":[80],"leading":[81],"up":[82],"last":[85],"few":[86],"days.Citations":[87],"number":[90],"other":[92],"articles":[93],"citing":[94],"this":[95],"article,":[96],"calculated":[97],"by":[98],"Crossref":[99,107],"daily.":[102],"Find":[103,153],"more":[104,154],"information":[105,155],"about":[106,141],"citation":[108],"counts.The":[109],"Altmetric":[110,158],"Attention":[111,159],"Score":[112,160],"is":[113,165],"a":[114,121,134],"quantitative":[115],"measure":[116],"attention":[119],"that":[120],"research":[122],"has":[124],"received":[125],"online.":[126],"Clicking":[127],"on":[128,156],"donut":[130],"icon":[131],"will":[132],"load":[133],"page":[135],"at":[136],"altmetric.com":[137],"with":[138,173],"additional":[139],"details":[140],"score":[143,164],"social":[146],"media":[147],"presence":[148],"for":[149],"given":[151],"article.":[152],"how":[162],"calculated.":[166],"Share":[167,182],"Add":[168],"toView":[169],"InAdd":[170],"Full":[171],"Text":[172],"ReferenceAdd":[174],"Description":[175],"ExportRISCitationCitation":[176],"abstractCitation":[178],"referencesMore":[180],"Options":[181],"onFacebookTwitterWechatLinked":[183],"InRedditEmail":[184],"Other":[185],"access":[186],"optionsGet":[187],"e-Alertsclose":[188],"Get":[189],"e-Alerts":[190]},"counts_by_year":[{"year":2020,"cited_by_count":2}],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}