{"id":"https://openalex.org/W2019780289","doi":"https://doi.org/10.1002/cber.19691021117","title":"\u00dcber die asymmetrische Induktion bei der LiAlH4\u2010Hydrierung diastereomerer (\u00b1)\u20103\u2010Amino\u20102.3\u2010diphenyl\u2010propiophenone","display_name":"\u00dcber die asymmetrische Induktion bei der LiAlH4\u2010Hydrierung diastereomerer (\u00b1)\u20103\u2010Amino\u20102.3\u2010diphenyl\u2010propiophenone","publication_year":1969,"publication_date":"1969-11-01","ids":{"openalex":"https://openalex.org/W2019780289","doi":"https://doi.org/10.1002/cber.19691021117","mag":"2019780289"},"language":"de","primary_location":{"id":"doi:10.1002/cber.19691021117","doi":"https://doi.org/10.1002/cber.19691021117","is_oa":false,"landing_page_url":"https://doi.org/10.1002/cber.19691021117","pdf_url":null,"source":{"id":"https://openalex.org/S4210215837","display_name":"Chemische Berichte","issn_l":"0009-2940","issn":["0009-2940"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemische Berichte","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5059746918","display_name":"Maria J. Lyapova","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I24768866","display_name":"Bulgarian Academy of Sciences","ror":"https://ror.org/01x8hew03","country_code":"BG","type":"government","lineage":["https://openalex.org/I24768866"]}],"countries":["BG"],"is_corresponding":false,"raw_author_name":"Maria J. Lyapova","raw_affiliation_strings":["Institut fu\u0308r Organische Chemie der Bulgarischen Akademie der Wissenschaften, Sofia","Institut f\u00fcr Organische Chemie der Bulgarischen Akademie der Wissenschaften, Sofia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut fu\u0308r Organische Chemie der Bulgarischen Akademie der Wissenschaften, Sofia","institution_ids":["https://openalex.org/I24768866"]},{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie der Bulgarischen Akademie der Wissenschaften, Sofia","institution_ids":["https://openalex.org/I24768866"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5111736696","display_name":"Bogdan J. Kurtev","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I24768866","display_name":"Bulgarian Academy of Sciences","ror":"https://ror.org/01x8hew03","country_code":"BG","type":"government","lineage":["https://openalex.org/I24768866"]}],"countries":["BG"],"is_corresponding":false,"raw_author_name":"Bogdan J. Kurtev","raw_affiliation_strings":["Institut fu\u0308r Organische Chemie der Bulgarischen Akademie der Wissenschaften, Sofia","Institut f\u00fcr Organische Chemie der Bulgarischen Akademie der Wissenschaften, Sofia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut fu\u0308r Organische Chemie der Bulgarischen Akademie der Wissenschaften, Sofia","institution_ids":["https://openalex.org/I24768866"]},{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie der Bulgarischen Akademie der Wissenschaften, Sofia","institution_ids":["https://openalex.org/I24768866"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I24768866"],"apc_list":null,"apc_paid":null,"fwci":0.9452,"has_fulltext":false,"cited_by_count":8,"citation_normalized_percentile":{"value":0.64547194,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"102","issue":"11","first_page":"3739","last_page":"3746"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.37599998712539673,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.37599998712539673,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13649","display_name":"Advanced Synthetic Organic Chemistry","score":0.19429999589920044,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12527","display_name":"Chemistry and Stereochemistry Studies","score":0.14650000631809235,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/asymmetric-induction","display_name":"asymmetric induction","score":0.9070000052452087},{"id":"https://openalex.org/keywords/lithium-aluminium-hydride-reduction","display_name":"lithium aluminium hydride reduction","score":0.8579999804496765},{"id":"https://openalex.org/keywords/diastereomers","display_name":"diastereomers","score":0.8240000009536743},{"id":"https://openalex.org/keywords/stereoselectivity","display_name":"stereoselectivity","score":0.7279999852180481},{"id":"https://openalex.org/keywords/3-aminopropanol","display_name":"3-aminopropanol","score":0.8209999799728394},{"id":"https://openalex.org/keywords/steric-effects","display_name":"steric effects","score":0.5440000295639038},{"id":"https://openalex.org/keywords/carbonyl-reduction","display_name":"carbonyl reduction","score":0.6809999942779541},{"id":"https://openalex.org/keywords/phosphorus-ylides","display_name":"phosphorus ylides","score":0.6000000238418579}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9081893563270569},{"id":"https://openalex.org/C2778909068","wikidata":"https://www.wikidata.org/wiki/Q415446","display_name":"Propiophenone","level":3,"score":0.8413245677947998},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.4329327344894409},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.36719030141830444},{"id":"https://openalex.org/C2777738585","wikidata":"https://www.wikidata.org/wiki/Q170744","display_name":"Ketone","level":2,"score":0.08147668838500977},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.031682103872299194}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/cber.19691021117","doi":"https://doi.org/10.1002/cber.19691021117","is_oa":false,"landing_page_url":"https://doi.org/10.1002/cber.19691021117","pdf_url":null,"source":{"id":"https://openalex.org/S4210215837","display_name":"Chemische Berichte","issn_l":"0009-2940","issn":["0009-2940"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemische Berichte","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":10,"referenced_works":["https://openalex.org/W1993791812","https://openalex.org/W2004705115","https://openalex.org/W2042462404","https://openalex.org/W2084919637","https://openalex.org/W2088672982","https://openalex.org/W2127084936","https://openalex.org/W2161511882","https://openalex.org/W2325551646","https://openalex.org/W2327841955","https://openalex.org/W2329975334"],"related_works":["https://openalex.org/W2606829913","https://openalex.org/W1983762577","https://openalex.org/W4235320673","https://openalex.org/W1499896175","https://openalex.org/W2604672810","https://openalex.org/W2320890430","https://openalex.org/W1964478804","https://openalex.org/W2048269039","https://openalex.org/W4238377785","https://openalex.org/W2066224210"],"abstract_inverted_index":{"Abstract":[0],"Die":[1],"LiAlH4\u2010Reduktion":[2],"diastereomerer":[3],"(\u00b1)\u20103\u2010Amino\u2010,":[4],"(\u00b1)\u20103\u2010Benzamino\u2010":[5],"und":[6],"(\u00b1)\u20103\u2010Alkylamino\u20102.3\u2010diphenyl\u2010propiophenone":[7],"f\u00fchrt":[8],"stereoselektiv":[9],"zu":[10,37],"entsprechenden":[11,67],"3\u2010Aminopropanolen\u2010(1).":[12],"Modell\u2010Betrachtungen":[13],"lassen":[14],"eine":[15],"sterische":[16],"Beeinflussung":[17],"der":[18,20,40,50,56],"Reduktion":[19,41],"Carbonylgruppe":[21],"nur":[22],"vom":[23],"benachbarten":[24],"dissymmetrischen":[25],"Kohlenstoffatom":[26],"voraussagen;":[27],"demnach":[28],"sind":[29],"Produkte":[30],"mit":[31,64],"gleicher,":[32],"vermutlich":[33],"erythro\u2010Konfiguration":[34],"an":[35],"C\u20101,2":[36],"erwarten.":[38],"Bei":[39],"des":[42],"(\u00b1)\u2010erythro\u20103\u2010Benzylidenamino\u20102.3\u2010diphenyl\u2010propiophenons":[43],"ist":[44],"die":[45,66],"Stereoselektivit\u00e4t":[46],"viel":[47],"niedriger,":[48],"was":[49],"Abwesenheit":[51],"eines":[52],"aktiven":[53],"Wasserstoffatoms":[54],"in":[55],"Aminogruppe":[57],"zugeschrieben":[58],"wird.":[59],"Aus":[60],"den":[61],"Aminopropanolen":[62],"wurden":[63],"Phosgen":[65],"2\u2010Oxo\u20104.5.6\u2010triphenyl\u2010tetrahydro\u20101.3\u2010oxazine":[68],"gewonnen.":[69]},"counts_by_year":[],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2016-06-24T00:00:00"}