{"id":"https://openalex.org/W2019353602","doi":"https://doi.org/10.1063/1.450690","title":"Rotational energy level structure in the local mode limit","display_name":"Rotational energy level structure in the local mode limit","publication_year":1986,"publication_date":"1986-06-15","ids":{"openalex":"https://openalex.org/W2019353602","doi":"https://doi.org/10.1063/1.450690","mag":"2019353602"},"language":"en","primary_location":{"id":"doi:10.1063/1.450690","doi":"https://doi.org/10.1063/1.450690","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.450690","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5041562700","display_name":"Lauri Halonen","orcid":"https://orcid.org/0000-0003-4637-2689","observed_orcids":["https://orcid.org/0000-0003-4637-2689"]},"institutions":[{"id":"https://openalex.org/I35440088","display_name":"ETH Zurich","ror":"https://ror.org/05a28rw58","country_code":"CH","type":"education","lineage":["https://openalex.org/I2799323385","https://openalex.org/I35440088"]},{"id":"https://openalex.org/I4405253565","display_name":"Laboratory of Physical Chemistry","ror":"https://ror.org/00v171g37","country_code":"CH","type":"facility","lineage":["https://openalex.org/I2799323385","https://openalex.org/I35440088","https://openalex.org/I4405253565"]}],"countries":["CH"],"is_corresponding":false,"raw_author_name":"L. Halonen","raw_affiliation_strings":["Laboratorium f\u00fcr Physikalische Chemie, ETH-Zentrum, CH-8092 Z\u00fcrich, Switzerland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratorium f\u00fcr Physikalische Chemie, ETH-Zentrum, CH-8092 Z\u00fcrich, Switzerland","institution_ids":["https://openalex.org/I35440088","https://openalex.org/I4405253565"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5000622193","display_name":"Alan G. Robiette","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I40120149","display_name":"University of Oxford","ror":"https://ror.org/052gg0110","country_code":"GB","type":"education","lineage":["https://openalex.org/I40120149"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"A. G. Robiette","raw_affiliation_strings":["Oxford University Computing Service, 13 Banbury Road, Oxford OX2 6NN, England"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Oxford University Computing Service, 13 Banbury Road, Oxford OX2 6NN, England","institution_ids":["https://openalex.org/I40120149"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":3500,"currency":"USD","value_usd":3500},"apc_paid":null,"fwci":3.6037,"has_fulltext":false,"cited_by_count":106,"citation_normalized_percentile":{"value":0.93767275,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"84","issue":"12","first_page":"6861","last_page":"6871"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12967","display_name":"Molecular Spectroscopy and Structure","score":0.9545999765396118,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12967","display_name":"Molecular Spectroscopy and Structure","score":0.9545999765396118,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11111","display_name":"Spectroscopy and Laser Applications","score":0.030300000682473183,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.005200000014156103,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/xy2-molecules","display_name":"XY2 molecules","score":0.6340000033378601},{"id":"https://openalex.org/keywords/xy4-molecules","display_name":"XY4 molecules","score":0.9980000257492065},{"id":"https://openalex.org/keywords/c2v-symmetry","display_name":"C2v symmetry","score":0.7200000286102295},{"id":"https://openalex.org/keywords/c3v-symmetry","display_name":"C3v symmetry","score":0.9990000128746033},{"id":"https://openalex.org/keywords/td-symmetry","display_name":"Td symmetry","score":0.996999979019165},{"id":"https://openalex.org/keywords/coriolis-coupling","display_name":"Coriolis coupling","score":0.8450000286102295}],"concepts":[{"id":"https://openalex.org/C130367717","wikidata":"https://www.wikidata.org/wiki/Q189791","display_name":"Diagonal","level":2,"score":0.6704058051109314},{"id":"https://openalex.org/C135889238","wikidata":"https://www.wikidata.org/wiki/Q46276","display_name":"Kinetic energy","level":2,"score":0.6249334812164307},{"id":"https://openalex.org/C24123453","wikidata":"https://www.wikidata.org/wiki/Q900121","display_name":"Molecular vibration","level":3,"score":0.5831226706504822},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.5827807188034058},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.5761575102806091},{"id":"https://openalex.org/C169146920","wikidata":"https://www.wikidata.org/wiki/Q2140940","display_name":"Rotational energy","level":2,"score":0.5659852623939514},{"id":"https://openalex.org/C151201525","wikidata":"https://www.wikidata.org/wiki/Q177239","display_name":"Limit (mathematics)","level":2,"score":0.5180894732475281},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.47999307513237},{"id":"https://openalex.org/C188198153","wikidata":"https://www.wikidata.org/wiki/Q1613840","display_name":"Limiting","level":2,"score":0.4710065424442291},{"id":"https://openalex.org/C41999313","wikidata":"https://www.wikidata.org/wiki/Q489328","display_name":"Molecular physics","level":1,"score":0.46283650398254395},{"id":"https://openalex.org/C167812310","wikidata":"https://www.wikidata.org/wiki/Q3492913","display_name":"Rotational\u2013vibrational spectroscopy","level":3,"score":0.4454612135887146},{"id":"https://openalex.org/C32758168","wikidata":"https://www.wikidata.org/wiki/Q900488","display_name":"Normal mode","level":3,"score":0.440656840801239},{"id":"https://openalex.org/C87210426","wikidata":"https://www.wikidata.org/wiki/Q1072476","display_name":"Bending","level":2,"score":0.43702182173728943},{"id":"https://openalex.org/C84551667","wikidata":"https://www.wikidata.org/wiki/Q155640","display_name":"Potential energy","level":2,"score":0.43511962890625},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.3335604667663574},{"id":"https://openalex.org/C198394728","wikidata":"https://www.wikidata.org/wiki/Q3695508","display_name":"Vibration","level":2,"score":0.3083590567111969},{"id":"https://openalex.org/C181500209","wikidata":"https://www.wikidata.org/wiki/Q215328","display_name":"Excited state","level":2,"score":0.1941719651222229},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.16880610585212708},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.09952396154403687},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.05988892912864685},{"id":"https://openalex.org/C134306372","wikidata":"https://www.wikidata.org/wiki/Q7754","display_name":"Mathematical analysis","level":1,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C2524010","wikidata":"https://www.wikidata.org/wiki/Q8087","display_name":"Geometry","level":1,"score":0.0},{"id":"https://openalex.org/C78519656","wikidata":"https://www.wikidata.org/wiki/Q101333","display_name":"Mechanical engineering","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1063/1.450690","doi":"https://doi.org/10.1063/1.450690","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.450690","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":30,"referenced_works":["https://openalex.org/W643703923","https://openalex.org/W1530628942","https://openalex.org/W1625603345","https://openalex.org/W1965536208","https://openalex.org/W1976389500","https://openalex.org/W1984363655","https://openalex.org/W1993836539","https://openalex.org/W2019318938","https://openalex.org/W2025571634","https://openalex.org/W2026247207","https://openalex.org/W2026496857","https://openalex.org/W2028628785","https://openalex.org/W2037662666","https://openalex.org/W2044293847","https://openalex.org/W2046048568","https://openalex.org/W2050996021","https://openalex.org/W2053977656","https://openalex.org/W2059602736","https://openalex.org/W2071395489","https://openalex.org/W2073952805","https://openalex.org/W2076182132","https://openalex.org/W2080870336","https://openalex.org/W2081406975","https://openalex.org/W2111953398","https://openalex.org/W2114106656","https://openalex.org/W2136473475","https://openalex.org/W2143117645","https://openalex.org/W3096378285","https://openalex.org/W4250648937","https://openalex.org/W4285719527"],"related_works":["https://openalex.org/W2062289134","https://openalex.org/W2087125217","https://openalex.org/W1975561139","https://openalex.org/W2085860189","https://openalex.org/W2002158826","https://openalex.org/W104667078","https://openalex.org/W2054823176","https://openalex.org/W2073938431","https://openalex.org/W2044238028","https://openalex.org/W2033056957"],"abstract_inverted_index":{"The":[0,60,118],"nature":[1],"of":[2,8,100,112],"the":[3,9,21,45,50,57,64,68,78,89,98,101,110,131,138,142],"rotational":[4,65],"energy":[5,42],"level":[6],"structure":[7],"stretching":[10,52,69],"vibrational":[11,70,91],"states":[12,71],"in":[13,32,67,73,130],"XY2,":[14],"XY3,":[15],"and":[16,24,48,104,108,128],"XY4":[17],"molecules":[18,132],"(belonging":[19],"to":[20,84,88,141],"C2v,":[22],"C3v,":[23],"Td":[25],"point":[26],"groups,":[27],"respectively)":[28],"has":[29],"been":[30],"investigated":[31],"a":[33,134],"local":[34],"mode":[35],"limit":[36],"with":[37,49,122,133],"no":[38],"kinetic":[39],"or":[40],"potential":[41],"copling":[43],"between":[44,63,97],"bond":[46],"oscillators":[47],"fundamental":[51],"frequencies":[53],"much":[54],"larger":[55],"than":[56],"bending":[58],"frequencies.":[59],"Coriolis":[61],"effects":[62],"levels":[66],"disappear":[72],"this":[74],"limiting":[75],"case,":[76],"but":[77],"H22":[79,106,143],"resonance":[80],"terms":[81,107],"are":[82,95],"seen":[83],"be":[85],"important":[86],"owing":[87],"multiple":[90],"degeneracies.":[92],"Simple":[93],"relationships":[94],"obtained":[96],"coefficients":[99,144],"vibrationally":[102],"diagonal":[103],"off-diagonal":[105],"consequently":[109],"number":[111],"independent":[113],"molecular":[114],"parameters":[115],"is":[116,120,145],"reduced.":[117],"model":[119],"compared":[121],"experimental":[123],"data":[124],"for":[125],"XHn":[126],"hydrides,":[127],"particularly":[129],"heavy":[135],"central":[136],"mass":[137],"major":[139],"contribution":[140],"well":[146],"explained.":[147]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2022,"cited_by_count":4},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":3},{"year":2017,"cited_by_count":1},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}
