{"id":"https://openalex.org/W2018986597","doi":"https://doi.org/10.1002/1521-4109(200211)14:21<1464::aid-elan1464>3.0.co;2-o","title":"The Oxidation of Cysteine by Aqueous Ferricyanide: A Kinetic Study Using Boron Doped Diamond Electrode Voltammetry","display_name":"The Oxidation of Cysteine by Aqueous Ferricyanide: A Kinetic Study Using Boron Doped Diamond Electrode Voltammetry","publication_year":2002,"publication_date":"2002-11-01","ids":{"openalex":"https://openalex.org/W2018986597","doi":"https://doi.org/10.1002/1521-4109(200211)14:21<1464::aid-elan1464>3.0.co;2-o","mag":"2018986597"},"language":"en","primary_location":{"id":"doi:10.1002/1521-4109(200211)14:21<1464::aid-elan1464>3.0.co;2-o","doi":"https://doi.org/10.1002/1521-4109(200211)14:21<1464::aid-elan1464>3.0.co;2-o","is_oa":false,"landing_page_url":"https://doi.org/10.1002/1521-4109(200211)14:21<1464::aid-elan1464>3.0.co;2-o","pdf_url":null,"source":{"id":"https://openalex.org/S79832926","display_name":"Electroanalysis","issn_l":"1040-0397","issn":["1040-0397","1521-4109"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Electroanalysis","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5024570192","display_name":"Olga Nekrassova","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I40120149","display_name":"University of Oxford","ror":"https://ror.org/052gg0110","country_code":"GB","type":"education","lineage":["https://openalex.org/I40120149"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Olga Nekrassova","raw_affiliation_strings":["Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QZ, UK"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QZ, UK","institution_ids":["https://openalex.org/I40120149"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036603040","display_name":"Gary D. Allen","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I40120149","display_name":"University of Oxford","ror":"https://ror.org/052gg0110","country_code":"GB","type":"education","lineage":["https://openalex.org/I40120149"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Gary\u2005D. Allen","raw_affiliation_strings":["Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QZ, UK"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QZ, UK","institution_ids":["https://openalex.org/I40120149"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5023136543","display_name":"Nathan Scott Lawrence","orcid":"https://orcid.org/0000-0003-3290-4621","observed_orcids":["https://orcid.org/0000-0003-3290-4621"]},"institutions":[{"id":"https://openalex.org/I40120149","display_name":"University of Oxford","ror":"https://ror.org/052gg0110","country_code":"GB","type":"education","lineage":["https://openalex.org/I40120149"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Nathan\u2005S. Lawrence","raw_affiliation_strings":["Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QZ, UK"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QZ, UK","institution_ids":["https://openalex.org/I40120149"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5088147882","display_name":"Li Jiang","orcid":"https://orcid.org/0000-0002-3551-9430","observed_orcids":["https://orcid.org/0000-0002-3551-9430"]},"institutions":[{"id":"https://openalex.org/I4210133462","display_name":"Schlumberger (United Kingdom)","ror":"https://ror.org/03q6ms497","country_code":"GB","type":"company","lineage":["https://openalex.org/I4210092184","https://openalex.org/I4210133462"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Li Jiang","raw_affiliation_strings":["Schlumberger Cambridge Research, High Cross, Madingley Road, Cambridge, CB3 0EL, UK"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Schlumberger Cambridge Research, High Cross, Madingley Road, Cambridge, CB3 0EL, UK","institution_ids":["https://openalex.org/I4210133462"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110137822","display_name":"Timothy G. J. Jones","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210133462","display_name":"Schlumberger (United Kingdom)","ror":"https://ror.org/03q6ms497","country_code":"GB","type":"company","lineage":["https://openalex.org/I4210092184","https://openalex.org/I4210133462"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Timothy\u2005G.\u2005J. Jones","raw_affiliation_strings":["Schlumberger Cambridge Research, High Cross, Madingley Road, Cambridge, CB3 0EL, UK"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Schlumberger Cambridge Research, High Cross, Madingley Road, Cambridge, CB3 0EL, UK","institution_ids":["https://openalex.org/I4210133462"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5076368908","display_name":"Richard G. Compton","orcid":"https://orcid.org/0000-0001-9841-5041","observed_orcids":["https://orcid.org/0000-0001-9841-5041"]},"institutions":[{"id":"https://openalex.org/I40120149","display_name":"University of Oxford","ror":"https://ror.org/052gg0110","country_code":"GB","type":"education","lineage":["https://openalex.org/I40120149"]}],"countries":["GB"],"is_corresponding":true,"raw_author_name":"Richard\u2005G. Compton","raw_affiliation_strings":["Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QZ, UK"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Physical and Theoretical Chemistry Laboratory, University of Oxford, South Parks Road, Oxford, OX1 3QZ, UK","institution_ids":["https://openalex.org/I40120149"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5076368908"],"corresponding_institution_ids":["https://openalex.org/I40120149"],"apc_list":{"value":3800,"currency":"USD","value_usd":3800},"apc_paid":null,"fwci":3.7397,"has_fulltext":false,"cited_by_count":55,"citation_normalized_percentile":{"value":0.92356688,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":87,"max":98},"biblio":{"volume":"14","issue":"21","first_page":"1464","last_page":"1469"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11434","display_name":"Electrochemical Analysis and Applications","score":0.8525000214576721,"subfield":{"id":"https://openalex.org/subfields/1603","display_name":"Electrochemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11434","display_name":"Electrochemical Analysis and Applications","score":0.8525000214576721,"subfield":{"id":"https://openalex.org/subfields/1603","display_name":"Electrochemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10212","display_name":"Electrochemical sensors and biosensors","score":0.09350000321865082,"subfield":{"id":"https://openalex.org/subfields/1602","display_name":"Analytical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10030","display_name":"Electrocatalysts for Energy Conversion","score":0.02500000037252903,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/cysteine-oxidation","display_name":"cysteine oxidation","score":0.9950000047683716},{"id":"https://openalex.org/keywords/ferricyanide","display_name":"ferricyanide","score":0.9980000257492065},{"id":"https://openalex.org/keywords/boron-doped-diamond-electrode","display_name":"boron-doped diamond electrode","score":0.9100000262260437},{"id":"https://openalex.org/keywords/electrochemical-kinetics","display_name":"electrochemical kinetics","score":0.5490000247955322},{"id":"https://openalex.org/keywords/ec-mechanism","display_name":"EC mechanism","score":0.828000009059906},{"id":"https://openalex.org/keywords/rate-constants","display_name":"rate constants","score":0.6420000195503235},{"id":"https://openalex.org/keywords/ferrocyanide","display_name":"ferrocyanide","score":0.7609999775886536},{"id":"https://openalex.org/keywords/electrocatalysis","display_name":"electrocatalysis","score":0.8709999918937683}],"concepts":[{"id":"https://openalex.org/C2776043530","wikidata":"https://www.wikidata.org/wiki/Q1963663","display_name":"Ferrocyanide","level":3,"score":0.9198722243309021},{"id":"https://openalex.org/C2777411777","wikidata":"https://www.wikidata.org/wiki/Q2259447","display_name":"Ferricyanide","level":2,"score":0.876040518283844},{"id":"https://openalex.org/C2777869211","wikidata":"https://www.wikidata.org/wiki/Q1147647","display_name":"Cyclic voltammetry","level":4,"score":0.7797948122024536},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6558941602706909},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.6317376494407654},{"id":"https://openalex.org/C2779603750","wikidata":"https://www.wikidata.org/wiki/Q904093","display_name":"Voltammetry","level":4,"score":0.5972445607185364},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.5418177247047424},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.4828389286994934},{"id":"https://openalex.org/C30095370","wikidata":"https://www.wikidata.org/wiki/Q899488","display_name":"Protonation","level":3,"score":0.479899525642395},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.43478843569755554},{"id":"https://openalex.org/C2776422427","wikidata":"https://www.wikidata.org/wiki/Q419818","display_name":"Glassy carbon","level":5,"score":0.41855162382125854},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.3517104387283325},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.16083207726478577},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.11763042211532593},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.05014348030090332}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/1521-4109(200211)14:21<1464::aid-elan1464>3.0.co;2-o","doi":"https://doi.org/10.1002/1521-4109(200211)14:21<1464::aid-elan1464>3.0.co;2-o","is_oa":false,"landing_page_url":"https://doi.org/10.1002/1521-4109(200211)14:21<1464::aid-elan1464>3.0.co;2-o","pdf_url":null,"source":{"id":"https://openalex.org/S79832926","display_name":"Electroanalysis","issn_l":"1040-0397","issn":["1040-0397","1521-4109"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Electroanalysis","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W1966784335","https://openalex.org/W1979446724","https://openalex.org/W2059925750","https://openalex.org/W2054639015","https://openalex.org/W3160313778","https://openalex.org/W1977082795","https://openalex.org/W1989298477","https://openalex.org/W4247186256","https://openalex.org/W2035177616","https://openalex.org/W2138769750"],"abstract_inverted_index":{"The":[0,124],"oxidation":[1,28,83,121],"of":[2,12,24,30,56,77,80,114,133,149],"cysteine":[3,34,115],"by":[4,122,131],"ferricyanide":[5],"is":[6,40,95,129],"well":[7],"established.":[8],"However,":[9],"electrochemical":[10],"studies":[11],"the":[13,22,27,31,53,57,61,67,78,81,109,143,150],"mechanism":[14,102],"have":[15],"to":[16,21,74,97,119,159,164],"date":[17],"been":[18],"underdeveloped":[19],"due":[20],"lack":[23],"resolution":[25],"between":[26,142],"waves":[29],"ferrocyanide":[32,58],"and":[33,60,104,111],"on":[35,43],"most":[36],"electrode":[37,94],"materials.":[38],"It":[39],"shown":[41,118,141],"that":[42,99],"boron":[44],"doped":[45],"diamond":[46],"electrode,":[47],"unlike":[48],"for":[49,146],"example":[50],"platinum":[51],"electrodes,":[52],"voltammetric":[54,85],"responses":[55],"wave":[59],"targets":[62],"are":[63,117,157],"sufficiently":[64],"different,":[65],"with":[66,138],"former":[68],"at":[69,170],"a":[70,92,161],"lower":[71],"oxidizing":[72],"potential,":[73],"permit":[75],"examination":[76],"kinetics":[79],"homogeneous":[82,151],"via":[84],"methods.":[86],"Accordingly":[87],"conventional":[88],"cyclic":[89,125],"voltammetry":[90,126,169],"using":[91],"BDD":[93,171],"used":[96],"show":[98],"an":[100],"EC\u2032":[101],"occurs":[103],"rate":[105,153],"constants":[106],"deduced.":[107],"Both":[108],"protonated":[110],"de-protonated":[112],"forms":[113],"(pKa=10.5)":[116],"undergo":[120],"ferricyanide.":[123],"data":[127],"obtained":[128],"corroborated":[130],"use":[132],"channel":[134],"flow":[135],"cell":[136],"experiments":[137],"excellent":[139],"agreement":[140],"two":[144],"techniques":[145],"deduced":[147],"values":[148],"electrocatalytic":[152],"constants:":[154],"Channel":[155],"electrodes":[156],"seen":[158],"provide":[160],"convenient":[162],"means":[163],"allow":[165],"quantitative":[166],"mechanistic":[167],"hydrodynamic":[168],"electrodes.":[172]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":2},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":3},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":3},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":2},{"year":2014,"cited_by_count":1},{"year":2012,"cited_by_count":6}],"updated_date":"2026-10-12T09:40:04.860316","created_date":"2016-06-24T00:00:00"}