{"id":"https://openalex.org/W2018817852","doi":"https://doi.org/10.1039/dt9850001533","title":"Rhenium nitrosyl complexes with simple and with sterically demanding aromatic thiolate ligands: X-ray crystal structures of [PPh 4 ][Re 2 (SC 6 H 4 Me-4) 7 (NO) 2 ]\u00b7CH 2 Cl 2 and [Re(SC 6 H 3 Pr i 2 -2,6) 4 (NO)]","display_name":"Rhenium nitrosyl complexes with simple and with sterically demanding aromatic thiolate ligands: X-ray crystal structures of [PPh 4 ][Re 2 (SC 6 H 4 Me-4) 7 (NO) 2 ]\u00b7CH 2 Cl 2 and [Re(SC 6 H 3 Pr i 2 -2,6) 4 (NO)]","publication_year":1985,"publication_date":"1985-01-01","ids":{"openalex":"https://openalex.org/W2018817852","doi":"https://doi.org/10.1039/dt9850001533","mag":"2018817852"},"language":"en","primary_location":{"id":"doi:10.1039/dt9850001533","doi":"https://doi.org/10.1039/dt9850001533","is_oa":false,"landing_page_url":"https://doi.org/10.1039/dt9850001533","pdf_url":null,"source":{"id":"https://openalex.org/S4210210551","display_name":"Journal of the Chemical Society Dalton Transactions","issn_l":"1364-5447","issn":["1364-5447","1472-7773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"J. Chem. Soc., Dalton Trans.","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5049873829","display_name":"Philip J. Blower","orcid":"https://orcid.org/0000-0001-6290-1590","observed_orcids":["https://orcid.org/0000-0001-6290-1590"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Philip J. Blower","raw_affiliation_strings":["Imaging Chemistry & Biology"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Imaging Chemistry & Biology","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5002065251","display_name":"J.R. Dilworth","orcid":"https://orcid.org/0000-0002-2863-0616","observed_orcids":["https://orcid.org/0000-0002-2863-0616","https://orcid.org/0000-0001-6589-5990"]},"institutions":[{"id":"https://openalex.org/I162608824","display_name":"University of Sussex","ror":"https://ror.org/00ayhx656","country_code":"GB","type":"education","lineage":["https://openalex.org/I162608824"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Jonathan R. Dilworth","raw_affiliation_strings":["University of Sussex ,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of Sussex ,","institution_ids":["https://openalex.org/I162608824"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111762586","display_name":"John P. Hutchinson","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I392282","display_name":"University at Albany, State University of New York","ror":"https://ror.org/012zs8222","country_code":"US","type":"education","lineage":["https://openalex.org/I392282"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"John P. Hutchinson","raw_affiliation_strings":["SUNY Albany*"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"SUNY Albany*","institution_ids":["https://openalex.org/I392282"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5076995372","display_name":"Jon A. Zubieta","orcid":"https://orcid.org/0000-0003-2478-7867","observed_orcids":["https://orcid.org/0000-0003-2478-7867"]},"institutions":[{"id":"https://openalex.org/I392282","display_name":"University at Albany, State University of New York","ror":"https://ror.org/012zs8222","country_code":"US","type":"education","lineage":["https://openalex.org/I392282"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jon A. Zubieta","raw_affiliation_strings":["SUNY Albany*"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"SUNY Albany*","institution_ids":["https://openalex.org/I392282"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":1.7154,"has_fulltext":false,"cited_by_count":57,"citation_normalized_percentile":{"value":0.76436997,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":95},"biblio":{"volume":null,"issue":"8","first_page":"1533","last_page":"1541"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.5497999787330627,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.5497999787330627,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.19709999859333038,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.15209999680519104,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/rhenium-nitrosyl-complexes","display_name":"rhenium nitrosyl complexes","score":0.9959999918937683},{"id":"https://openalex.org/keywords/thiolate-ligands","display_name":"thiolate ligands","score":0.828000009059906},{"id":"https://openalex.org/keywords/thiophenol","display_name":"thiophenol","score":0.9670000076293945},{"id":"https://openalex.org/keywords/dinuclear-rhenium-complexes","display_name":"dinuclear rhenium complexes","score":0.8700000047683716},{"id":"https://openalex.org/keywords/trigonal-bipyramidal-coordination","display_name":"trigonal bipyramidal coordination","score":0.7570000290870667},{"id":"https://openalex.org/keywords/fluxional-behavior","display_name":"fluxional behavior","score":0.7630000114440918},{"id":"https://openalex.org/keywords/ligand-exchange","display_name":"ligand exchange","score":0.8190000057220459},{"id":"https://openalex.org/keywords/steric-effects","display_name":"steric effects","score":0.7239999771118164}],"concepts":[{"id":"https://openalex.org/C505216180","wikidata":"https://www.wikidata.org/wiki/Q737","display_name":"Rhenium","level":2,"score":0.9172555804252625},{"id":"https://openalex.org/C201194858","wikidata":"https://www.wikidata.org/wiki/Q898238","display_name":"Steric effects","level":2,"score":0.8294461369514465},{"id":"https://openalex.org/C75079739","wikidata":"https://www.wikidata.org/wiki/Q1571801","display_name":"Intramolecular force","level":2,"score":0.8101483583450317},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7387503981590271},{"id":"https://openalex.org/C104264131","wikidata":"https://www.wikidata.org/wiki/Q898637","display_name":"Isopropyl","level":2,"score":0.650981605052948},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.6400709748268127},{"id":"https://openalex.org/C111592845","wikidata":"https://www.wikidata.org/wiki/Q2867924","display_name":"Trigonal bipyramidal molecular geometry","level":3,"score":0.6229950189590454},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.547836184501648},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.44238901138305664},{"id":"https://openalex.org/C2781285689","wikidata":"https://www.wikidata.org/wiki/Q21921428","display_name":"Crystal (programming language)","level":2,"score":0.4351906478404999},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3816932439804077},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.15037724375724792},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0},{"id":"https://openalex.org/C199360897","wikidata":"https://www.wikidata.org/wiki/Q9143","display_name":"Programming language","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1039/dt9850001533","doi":"https://doi.org/10.1039/dt9850001533","is_oa":false,"landing_page_url":"https://doi.org/10.1039/dt9850001533","pdf_url":null,"source":{"id":"https://openalex.org/S4210210551","display_name":"Journal of the Chemical Society Dalton Transactions","issn_l":"1364-5447","issn":["1364-5447","1472-7773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"J. Chem. Soc., Dalton Trans.","raw_type":"journal-article"},{"id":"pmh:oai:kclpure.kcl.ac.uk:publications/751f8060-8fef-49ad-a848-fe264f24847b","doi":null,"is_oa":false,"landing_page_url":"https://kclpure.kcl.ac.uk/portal/en/publications/751f8060-8fef-49ad-a848-fe264f24847b","pdf_url":null,"source":{"id":"https://openalex.org/S4306400216","display_name":"Research Portal (King's College London)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I183935753","host_organization_name":"King's College London","host_organization_lineage":["https://openalex.org/I183935753"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Blower, P, Dilworth, J R, Hutchinson, J & Zubieta, J A 1985, 'Rhenium nitrosyl complexes with simple and with sterically demanding aromatic thiolate ligands: X-ray crystal structures of [PPh4][Re2(SC6H4Me-4)7(NO)2]\u00b7CH2Cl2 and [Re(SC6H3Pri2-2,6)4(NO)]', JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, no. 8, pp. 1533-41. https://doi.org/10.1039/DT9850001533","raw_type":"info:eu-repo/semantics/publishedVersion"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2604288103","https://openalex.org/W2168944581","https://openalex.org/W2025215430","https://openalex.org/W1970338367","https://openalex.org/W2319978776","https://openalex.org/W2107257621","https://openalex.org/W2009960973","https://openalex.org/W1994450151","https://openalex.org/W2020940650","https://openalex.org/W2055653064"],"abstract_inverted_index":{"Reaction":[0],"of":[1,6,13,16,23,29,104],"[ReCl2(OMe)(NO)(PPh3)2]":[2],"with":[3,43,68],"a":[4,87,99],"range":[5],"thiophenols":[7],"under":[8],"basic":[9],"conditions":[10],"gives":[11],"one":[12],"two":[14,92],"classes":[15],"products":[17],"depending":[18],"on":[19],"the":[20,24,53,77],"steric":[21],"requirements":[22],"thiols.":[25],"A":[26],"representative":[27],"member":[28],"each":[30],"class":[31],"has":[32],"been":[33],"characterised":[34],"by":[35],"an":[36,69],"X-":[37],"ray":[38],"crystal":[39],"structure":[40],"determination.":[41],"Thiophenols":[42,73],"methyl":[44],"or":[45,62,83],"isopropyl":[46],"groups":[47],"in":[48],"their":[49],"ortho":[50],"positions":[51],"give":[52,76],"mononuclear":[54],"complexes":[55],"[Re(SR)4(NO)](SR":[56],"=":[57,81],"SC6H2Pri3-2,4,6,":[58],"SC6H3Pri2-2,6,":[59],"SC6H2Pri2-2,6-4-":[60],"Br,":[61],"SC6H2Me3-2,4,6)":[63],"which":[64,85],"are":[65],"trigonal":[66],"bipyramidal":[67],"axial":[70],"NO":[71],"group.":[72],"without":[74],"ortho-substituents":[75],"dinuclear":[78],"anions":[79,97],"[Re2(SR)7(NO)2]\u2013(SR":[80],"SPh":[82],"SC6H4Me-4)":[84],"contain":[86],"triple":[88],"thiolate":[89],"bridge":[90],"between":[91],"equivalent":[93],"rhenium":[94],"atoms.":[95],"These":[96],"show":[98],"fluxionality":[100],"involving":[101],"intramolecular":[102],"exchange":[103],"six":[105],"thiolato-ligands.":[106]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-11-01T11:40:01.658920","created_date":"2016-06-24T00:00:00"}