{"id":"https://openalex.org/W2018083899","doi":"https://doi.org/10.1002/bbpc.19920961113","title":"Thermodynamics of Ammonium Halopallidates II. Heat Capacity and Thermodynamic Properties of (ND4)2PdCl6 at Temperatures from 5 K to 325 K","display_name":"Thermodynamics of Ammonium Halopallidates II. Heat Capacity and Thermodynamic Properties of (ND4)2PdCl6 at Temperatures from 5 K to 325 K","publication_year":1992,"publication_date":"1992-11-01","ids":{"openalex":"https://openalex.org/W2018083899","doi":"https://doi.org/10.1002/bbpc.19920961113","mag":"2018083899"},"language":"en","primary_location":{"id":"doi:10.1002/bbpc.19920961113","doi":"https://doi.org/10.1002/bbpc.19920961113","is_oa":false,"landing_page_url":"https://doi.org/10.1002/bbpc.19920961113","pdf_url":null,"source":{"id":"https://openalex.org/S4306504167","display_name":"Berichte der Bunsengesellschaft f\u00fcr physikalische Chemie","issn_l":"0005-9021","issn":["0005-9021"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Berichte der Bunsengesellschaft f\u00fcr physikalische Chemie","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5081068931","display_name":"Jane Edmund Callanan","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Jane E. Callanan","raw_affiliation_strings":["Callanan Associates, 2888 Bluff, Suite 429, Boulder, CO 80301, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Callanan Associates, 2888 Bluff, Suite 429, Boulder, CO 80301, USA","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110016924","display_name":"Ron D. Weir","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I51768193","display_name":"Royal Military College of Canada","ror":"https://ror.org/04yr71909","country_code":"CA","type":"education","lineage":["https://openalex.org/I51768193"]}],"countries":["CA"],"is_corresponding":true,"raw_author_name":"Ron D. Weir","raw_affiliation_strings":["Department of Chemistry and Chemical Engineering, Royal Military College of Canada, Kingston, Ontario K7K 5LO, Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Chemical Engineering, Royal Military College of Canada, Kingston, Ontario K7K 5LO, Canada","institution_ids":["https://openalex.org/I51768193"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5111553121","display_name":"EDGAR F. JUN. WESTRUM","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I27837315","display_name":"University of Michigan","ror":"https://ror.org/00jmfr291","country_code":"US","type":"education","lineage":["https://openalex.org/I27837315"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Edgar F. Westrum","raw_affiliation_strings":["Department of Chemistry, University of Michigan, Ann Arbor, MI 48109\u20131055, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Michigan, Ann Arbor, MI 48109\u20131055, USA","institution_ids":["https://openalex.org/I27837315"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5110016924"],"corresponding_institution_ids":["https://openalex.org/I51768193"],"apc_list":null,"apc_paid":null,"fwci":0.9579,"has_fulltext":false,"cited_by_count":17,"citation_normalized_percentile":{"value":0.6722903,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":94},"biblio":{"volume":"96","issue":"11","first_page":"1585","last_page":"1591"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12852","display_name":"Chemical Thermodynamics and Molecular Structure","score":0.9897000193595886,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12852","display_name":"Chemical Thermodynamics and Molecular Structure","score":0.9897000193595886,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11878","display_name":"Solid-state spectroscopy and crystallography","score":0.00279999990016222,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12358","display_name":"Thermal and Kinetic Analysis","score":0.0010999999940395355,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/deuterated-salts","display_name":"deuterated salts","score":0.847000002861023},{"id":"https://openalex.org/keywords/heat-capacity","display_name":"heat capacity","score":0.9449999928474426},{"id":"https://openalex.org/keywords/phase-transitions","display_name":"phase transitions","score":0.8109999895095825},{"id":"https://openalex.org/keywords/cubic-tetragonal-phase-transition","display_name":"cubic-tetragonal phase transition","score":0.7870000004768372},{"id":"https://openalex.org/keywords/debye-temperature","display_name":"Debye temperature","score":0.8679999709129333},{"id":"https://openalex.org/keywords/lattice-vibrations","display_name":"lattice vibrations","score":0.6620000004768372},{"id":"https://openalex.org/keywords/standard-entropy","display_name":"standard entropy","score":0.5320000052452087},{"id":"https://openalex.org/keywords/standard-enthalpy","display_name":"standard enthalpy","score":0.7940000295639038},{"id":"https://openalex.org/keywords/standard-gibbs-free-energy","display_name":"standard Gibbs free energy","score":0.8629999756813049},{"id":"https://openalex.org/keywords/palladium-chloride-complexes","display_name":"palladium chloride complexes","score":0.5490000247955322},{"id":"https://openalex.org/keywords/thermodynamic-properties","display_name":"thermodynamic properties","score":0.5889999866485596}],"concepts":[{"id":"https://openalex.org/C60205243","wikidata":"https://www.wikidata.org/wiki/Q179388","display_name":"Heat capacity","level":2,"score":0.921975314617157},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.6685755848884583},{"id":"https://openalex.org/C202270520","wikidata":"https://www.wikidata.org/wiki/Q634314","display_name":"Calorimetry","level":2,"score":0.6303732395172119},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5928199291229248},{"id":"https://openalex.org/C109663097","wikidata":"https://www.wikidata.org/wiki/Q182453","display_name":"Adiabatic process","level":2,"score":0.5402092933654785},{"id":"https://openalex.org/C25376523","wikidata":"https://www.wikidata.org/wiki/Q1151031","display_name":"Debye model","level":2,"score":0.46849140524864197},{"id":"https://openalex.org/C170751736","wikidata":"https://www.wikidata.org/wiki/Q503601","display_name":"Tetragonal crystal system","level":3,"score":0.45923763513565063},{"id":"https://openalex.org/C149288129","wikidata":"https://www.wikidata.org/wiki/Q185357","display_name":"Phase transition","level":2,"score":0.4118930995464325},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.21355843544006348},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.1882658302783966},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.09458848834037781}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/bbpc.19920961113","doi":"https://doi.org/10.1002/bbpc.19920961113","is_oa":false,"landing_page_url":"https://doi.org/10.1002/bbpc.19920961113","pdf_url":null,"source":{"id":"https://openalex.org/S4306504167","display_name":"Berichte der Bunsengesellschaft f\u00fcr physikalische Chemie","issn_l":"0005-9021","issn":["0005-9021"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Berichte der Bunsengesellschaft f\u00fcr physikalische Chemie","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":37,"referenced_works":["https://openalex.org/W1583985612","https://openalex.org/W1963836311","https://openalex.org/W1967239629","https://openalex.org/W1985367234","https://openalex.org/W1987006732","https://openalex.org/W1991471792","https://openalex.org/W1993790770","https://openalex.org/W1996462406","https://openalex.org/W2001640102","https://openalex.org/W2001883560","https://openalex.org/W2002664009","https://openalex.org/W2005356999","https://openalex.org/W2011855900","https://openalex.org/W2016205550","https://openalex.org/W2026285088","https://openalex.org/W2028532037","https://openalex.org/W2029611071","https://openalex.org/W2040332283","https://openalex.org/W2045390980","https://openalex.org/W2047222800","https://openalex.org/W2049053699","https://openalex.org/W2049174475","https://openalex.org/W2054082423","https://openalex.org/W2057876352","https://openalex.org/W2070293122","https://openalex.org/W2071813464","https://openalex.org/W2074157252","https://openalex.org/W2076503727","https://openalex.org/W2077638450","https://openalex.org/W2078372270","https://openalex.org/W2089885405","https://openalex.org/W2091652719","https://openalex.org/W2094342133","https://openalex.org/W2095068975","https://openalex.org/W2104804412","https://openalex.org/W4235990354","https://openalex.org/W4252133558"],"related_works":["https://openalex.org/W2001883560","https://openalex.org/W1583985612","https://openalex.org/W2040332283","https://openalex.org/W4256017414","https://openalex.org/W2075915501","https://openalex.org/W2006238706","https://openalex.org/W2011855900","https://openalex.org/W2052830681","https://openalex.org/W2016205550","https://openalex.org/W2031202395"],"abstract_inverted_index":{"Abstract":[0],"The":[1,86],"heat":[2,35,109],"capacity":[3,36],"of":[4,113],"deuterated":[5],"ammonium":[6],"hexachloropallidate":[7],"(ND4)2pDCl6":[8],"was":[9,29],"measured":[10],"from":[11,74],"5":[12],"K":[13,16,53,91,96,126],"to":[14,80,107,124],"325":[15],"by":[17],"adiabatic":[18],"calorimetry.":[19],"One":[20],"\u03bb\u2010shaped":[21],"phase":[22],"transition,":[23],"absent":[24],"in":[25,31],"the":[26,32,72,75,81,108,114,128],"protonated":[27],"salt,":[28],"found":[30],"curve":[33],"for":[34,118],"against":[37],"temperature.":[38],"This":[39],"transition":[40],"reaches":[41],"its":[42],"maximum":[43],"Cp.m":[44],"\u2243":[45],"150":[46],"\u00b7":[47,60,66,68,135],"R":[48,61],"at":[49,89],"(30.2":[50],"\u00b1":[51,58,94,133],"0.1)":[52],"with":[54],"\u0394trsSm0":[55],"=":[56,63,131],"(2.005":[57],"0.009)":[59],"(R":[62],"8.31451":[64],"J":[65],"K\u22121":[67],"mol\u22121)":[69],"and":[70,97,127],"marks":[71],"change":[73],"high":[76],"temperature":[77,83,88],"cubic":[78],"structure":[79],"low":[82],"tetragonal":[84],"structure.":[85],"Debye":[87],"0":[90],"equals":[92],"(96.5":[93],"2.4)":[95],"below":[98],"10":[99],"K,":[100],"only":[101],"lattice":[102],"vibrations":[103],"make":[104],"significant":[105],"contributions":[106],"capacity.":[110],"Smoothed":[111],"values":[112],"standard":[115],"thermodynamic":[116],"quantities":[117],"pure":[119],"(ND4)2PdCl6":[120],"are":[121],"tabulated":[122],"up":[123],"320":[125],"Sm0(273.15":[129],"K)":[130],"(49.80":[132],"0.05)":[134],"R.":[136]},"counts_by_year":[{"year":2017,"cited_by_count":1},{"year":2013,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}