{"id":"https://openalex.org/W2017728488","doi":"https://doi.org/10.1139/v70-102","title":"Thermolysis of some 2,3-diazabicyclo[3.3.0]octene systems","display_name":"Thermolysis of some 2,3-diazabicyclo[3.3.0]octene systems","publication_year":1970,"publication_date":"1970-02-15","ids":{"openalex":"https://openalex.org/W2017728488","doi":"https://doi.org/10.1139/v70-102","mag":"2017728488"},"language":"en","primary_location":{"id":"doi:10.1139/v70-102","doi":"https://doi.org/10.1139/v70-102","is_oa":false,"landing_page_url":"https://doi.org/10.1139/v70-102","pdf_url":null,"source":{"id":"https://openalex.org/S9189650","display_name":"Canadian Journal of Chemistry","issn_l":"0008-4042","issn":["0008-4042","1480-3291"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310312929","host_organization_name":"Canadian Science Publishing","host_organization_lineage":["https://openalex.org/P4310312929"],"host_organization_lineage_names":["Canadian Science Publishing"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Canadian Journal of Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5009264026","display_name":"Manfred P Schneider","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Manfred P. Schneider","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5109433537","display_name":"Robert J. Crawford","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Robert J. Crawford","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":1.4585,"has_fulltext":false,"cited_by_count":29,"citation_normalized_percentile":{"value":0.761213,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"48","issue":"4","first_page":"628","last_page":"632"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13876","display_name":"Chemical synthesis and pharmacological studies","score":0.6147000193595886,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13876","display_name":"Chemical synthesis and pharmacological studies","score":0.6147000193595886,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13253","display_name":"Chemical Reactions and Mechanisms","score":0.2337999939918518,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11611","display_name":"Cyclopropane Reaction Mechanisms","score":0.05119999870657921,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/thermal-decomposition","display_name":"thermal decomposition","score":0.9100000262260437},{"id":"https://openalex.org/keywords/pyrazolines","display_name":"pyrazolines","score":0.8529999852180481},{"id":"https://openalex.org/keywords/thermal-decomposition-kinetics","display_name":"thermal decomposition kinetics","score":0.5659999847412109},{"id":"https://openalex.org/keywords/thermal-decomposition-products","display_name":"thermal decomposition products","score":0.6370000243186951},{"id":"https://openalex.org/keywords/kinetic-isotope-effects","display_name":"kinetic isotope effects","score":0.8679999709129333},{"id":"https://openalex.org/keywords/deuterium-labeling","display_name":"deuterium labeling","score":0.6779999732971191}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9507790803909302},{"id":"https://openalex.org/C160434732","wikidata":"https://www.wikidata.org/wiki/Q2611095","display_name":"Thermal decomposition","level":2,"score":0.8445823192596436},{"id":"https://openalex.org/C2781230492","wikidata":"https://www.wikidata.org/wiki/Q151382","display_name":"Octene","level":4,"score":0.7500728368759155},{"id":"https://openalex.org/C2778733088","wikidata":"https://www.wikidata.org/wiki/Q192678","display_name":"Diene","level":3,"score":0.5742844939231873},{"id":"https://openalex.org/C124681953","wikidata":"https://www.wikidata.org/wiki/Q339062","display_name":"Decomposition","level":2,"score":0.5317749977111816},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.4329037070274353},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.42016878724098206},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.35553622245788574},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.08144408464431763},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C2778597550","wikidata":"https://www.wikidata.org/wiki/Q151313","display_name":"Ethylene","level":3,"score":0.0},{"id":"https://openalex.org/C176933379","wikidata":"https://www.wikidata.org/wiki/Q131877","display_name":"Natural rubber","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1139/v70-102","doi":"https://doi.org/10.1139/v70-102","is_oa":false,"landing_page_url":"https://doi.org/10.1139/v70-102","pdf_url":null,"source":{"id":"https://openalex.org/S9189650","display_name":"Canadian Journal of Chemistry","issn_l":"0008-4042","issn":["0008-4042","1480-3291"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310312929","host_organization_name":"Canadian Science Publishing","host_organization_lineage":["https://openalex.org/P4310312929"],"host_organization_lineage_names":["Canadian Science Publishing"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Canadian Journal of Chemistry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W1997155798","https://openalex.org/W2347085709","https://openalex.org/W2076843924","https://openalex.org/W2949735569","https://openalex.org/W1984514809","https://openalex.org/W2952843404","https://openalex.org/W2347079340","https://openalex.org/W2319509308","https://openalex.org/W2064883923","https://openalex.org/W2059622750"],"abstract_inverted_index":{"The":[0,22,34],"kinetics":[1],"and":[2,11,16,29,36,44],"products":[3,47],"of":[4,6,27,41],"thermolysis":[5,46],"2,3-diazabicyclo[3.3.0]oct-2-ene":[7],"(1),":[8],"2,3-diazabicyclo-[3.3.0]octa-2,7-diene":[9],"(2),":[10],"exo-4-methyl-2,3-diazabicyclo[3.3.0]octa-2,7-diene":[12],"(3)":[13],"are":[14,48],"described":[15],"compared":[17],"with":[18],"previously":[19],"studied":[20],"pyrazolines.":[21],"secondary":[23],"kinetic":[24],"isotope":[25],"effects":[26],"1-d2":[28],"2-d2":[30],"have":[31],"been":[32],"measured.":[33],"synthesis":[35],"nuclear":[37],"magnetic":[38],"resonance":[39],"spectra":[40],"these":[42],"compounds":[43],"their":[45],"discussed.":[49]},"counts_by_year":[],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}