{"id":"https://openalex.org/W2017680751","doi":"https://doi.org/10.1016/s1381-1169(99)00402-1","title":"Hydroxylation of alkanes catalysed by a chiral \u03bc-oxo diferric complex: a metal-based mechanism","display_name":"Hydroxylation of alkanes catalysed by a chiral \u03bc-oxo diferric complex: a metal-based mechanism","publication_year":2000,"publication_date":"2000-05-01","ids":{"openalex":"https://openalex.org/W2017680751","doi":"https://doi.org/10.1016/s1381-1169(99)00402-1","mag":"2017680751"},"language":"en","primary_location":{"id":"doi:10.1016/s1381-1169(99)00402-1","doi":"https://doi.org/10.1016/s1381-1169(99)00402-1","is_oa":false,"landing_page_url":"https://doi.org/10.1016/s1381-1169(99)00402-1","pdf_url":null,"source":{"id":"https://openalex.org/S52459750","display_name":"Journal of Molecular Catalysis A Chemical","issn_l":"1381-1169","issn":["1381-1169","1873-314X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Molecular Catalysis A: Chemical","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5049595299","display_name":"Yasmina Mekmouche","orcid":"https://orcid.org/0000-0002-5649-3110","observed_orcids":["https://orcid.org/0000-0002-5649-3110"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I177483745","display_name":"Universit\u00e9 Joseph Fourier","ror":"https://ror.org/02aj0kh94","country_code":"FR","type":"education","lineage":["https://openalex.org/I177483745","https://openalex.org/I899635006"]},{"id":"https://openalex.org/I2738703131","display_name":"Commissariat \u00e0 l'\u00c9nergie Atomique et aux \u00c9nergies Alternatives","ror":"https://ror.org/00jjx8s55","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131"]},{"id":"https://openalex.org/I3020098449","display_name":"CEA Grenoble","ror":"https://ror.org/02mg6n827","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131","https://openalex.org/I3020098449"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Yasmina Mekmouche","raw_affiliation_strings":["Laboratoire de Chimie et Biochimie des Centres Redox Biologiques, DBMS-CB/CEA-Grenoble/UMR U2F-CNRS-CEA 5047/Universit\u00e9 Joseph Fourier, 17 Avenue des Martyrs, 38054 Grenoble Cedex 9, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Chimie et Biochimie des Centres Redox Biologiques, DBMS-CB/CEA-Grenoble/UMR U2F-CNRS-CEA 5047/Universit\u00e9 Joseph Fourier, 17 Avenue des Martyrs, 38054 Grenoble Cedex 9, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I177483745","https://openalex.org/I2738703131","https://openalex.org/I3020098449"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5002581586","display_name":"Carole Duboc","orcid":"https://orcid.org/0000-0002-9415-198X","observed_orcids":["https://orcid.org/0000-0002-9415-198X"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I177483745","display_name":"Universit\u00e9 Joseph Fourier","ror":"https://ror.org/02aj0kh94","country_code":"FR","type":"education","lineage":["https://openalex.org/I177483745","https://openalex.org/I899635006"]},{"id":"https://openalex.org/I2738703131","display_name":"Commissariat \u00e0 l'\u00c9nergie Atomique et aux \u00c9nergies Alternatives","ror":"https://ror.org/00jjx8s55","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131"]},{"id":"https://openalex.org/I3020098449","display_name":"CEA Grenoble","ror":"https://ror.org/02mg6n827","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131","https://openalex.org/I3020098449"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Carole Duboc-Toia","raw_affiliation_strings":["Laboratoire de Chimie et Biochimie des Centres Redox Biologiques, DBMS-CB/CEA-Grenoble/UMR U2F-CNRS-CEA 5047/Universit\u00e9 Joseph Fourier, 17 Avenue des Martyrs, 38054 Grenoble Cedex 9, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Chimie et Biochimie des Centres Redox Biologiques, DBMS-CB/CEA-Grenoble/UMR U2F-CNRS-CEA 5047/Universit\u00e9 Joseph Fourier, 17 Avenue des Martyrs, 38054 Grenoble Cedex 9, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I177483745","https://openalex.org/I2738703131","https://openalex.org/I3020098449"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5089395161","display_name":"St\u00e9phane M\u00e9nage","orcid":"https://orcid.org/0000-0003-4512-8836","observed_orcids":["https://orcid.org/0000-0003-4512-8836"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I177483745","display_name":"Universit\u00e9 Joseph Fourier","ror":"https://ror.org/02aj0kh94","country_code":"FR","type":"education","lineage":["https://openalex.org/I177483745","https://openalex.org/I899635006"]},{"id":"https://openalex.org/I2738703131","display_name":"Commissariat \u00e0 l'\u00c9nergie Atomique et aux \u00c9nergies Alternatives","ror":"https://ror.org/00jjx8s55","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131"]},{"id":"https://openalex.org/I3020098449","display_name":"CEA Grenoble","ror":"https://ror.org/02mg6n827","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131","https://openalex.org/I3020098449"]}],"countries":["FR"],"is_corresponding":true,"raw_author_name":"St\u00e9phane M\u00e9nage","raw_affiliation_strings":["Laboratoire de Chimie et Biochimie des Centres Redox Biologiques, DBMS-CB/CEA-Grenoble/UMR U2F-CNRS-CEA 5047/Universit\u00e9 Joseph Fourier, 17 Avenue des Martyrs, 38054 Grenoble Cedex 9, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Chimie et Biochimie des Centres Redox Biologiques, DBMS-CB/CEA-Grenoble/UMR U2F-CNRS-CEA 5047/Universit\u00e9 Joseph Fourier, 17 Avenue des Martyrs, 38054 Grenoble Cedex 9, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I177483745","https://openalex.org/I2738703131","https://openalex.org/I3020098449"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5021612561","display_name":"Claude Lambeaux","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I177483745","display_name":"Universit\u00e9 Joseph Fourier","ror":"https://ror.org/02aj0kh94","country_code":"FR","type":"education","lineage":["https://openalex.org/I177483745","https://openalex.org/I899635006"]},{"id":"https://openalex.org/I2738703131","display_name":"Commissariat \u00e0 l'\u00c9nergie Atomique et aux \u00c9nergies Alternatives","ror":"https://ror.org/00jjx8s55","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131"]},{"id":"https://openalex.org/I3020098449","display_name":"CEA Grenoble","ror":"https://ror.org/02mg6n827","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131","https://openalex.org/I3020098449"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Claude Lambeaux","raw_affiliation_strings":["Laboratoire de Chimie et Biochimie des Centres Redox Biologiques, DBMS-CB/CEA-Grenoble/UMR U2F-CNRS-CEA 5047/Universit\u00e9 Joseph Fourier, 17 Avenue des Martyrs, 38054 Grenoble Cedex 9, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Chimie et Biochimie des Centres Redox Biologiques, DBMS-CB/CEA-Grenoble/UMR U2F-CNRS-CEA 5047/Universit\u00e9 Joseph Fourier, 17 Avenue des Martyrs, 38054 Grenoble Cedex 9, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I177483745","https://openalex.org/I2738703131","https://openalex.org/I3020098449"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5062221634","display_name":"Marc Fontecave","orcid":"https://orcid.org/0000-0002-8016-4747","observed_orcids":["https://orcid.org/0000-0002-8016-4747"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I177483745","display_name":"Universit\u00e9 Joseph Fourier","ror":"https://ror.org/02aj0kh94","country_code":"FR","type":"education","lineage":["https://openalex.org/I177483745","https://openalex.org/I899635006"]},{"id":"https://openalex.org/I2738703131","display_name":"Commissariat \u00e0 l'\u00c9nergie Atomique et aux \u00c9nergies Alternatives","ror":"https://ror.org/00jjx8s55","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131"]},{"id":"https://openalex.org/I3020098449","display_name":"CEA Grenoble","ror":"https://ror.org/02mg6n827","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131","https://openalex.org/I3020098449"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Marc Fontecave","raw_affiliation_strings":["Laboratoire de Chimie et Biochimie des Centres Redox Biologiques, DBMS-CB/CEA-Grenoble/UMR U2F-CNRS-CEA 5047/Universit\u00e9 Joseph Fourier, 17 Avenue des Martyrs, 38054 Grenoble Cedex 9, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Chimie et Biochimie des Centres Redox Biologiques, DBMS-CB/CEA-Grenoble/UMR U2F-CNRS-CEA 5047/Universit\u00e9 Joseph Fourier, 17 Avenue des Martyrs, 38054 Grenoble Cedex 9, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I177483745","https://openalex.org/I2738703131","https://openalex.org/I3020098449"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5089395161"],"corresponding_institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I177483745","https://openalex.org/I2738703131","https://openalex.org/I3020098449"],"apc_list":null,"apc_paid":null,"fwci":2.8559,"has_fulltext":false,"cited_by_count":41,"citation_normalized_percentile":{"value":0.89979142,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":97},"biblio":{"volume":"156","issue":"1-2","first_page":"85","last_page":"89"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.9839000105857849,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.9839000105857849,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.006000000052154064,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.002899999963119626,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/alkane-hydroxylation","display_name":"alkane hydroxylation","score":0.9660000205039978},{"id":"https://openalex.org/keywords/hydrogen-peroxide","display_name":"hydrogen peroxide","score":0.7580000162124634},{"id":"https://openalex.org/keywords/stereospecificity","display_name":"stereospecificity","score":0.8610000014305115},{"id":"https://openalex.org/keywords/enantioselectivity","display_name":"enantioselectivity","score":0.9670000076293945},{"id":"https://openalex.org/keywords/asymmetric-catalysis","display_name":"asymmetric catalysis","score":0.6769999861717224},{"id":"https://openalex.org/keywords/iron-complexes","display_name":"iron complexes","score":0.30300000309944153}],"concepts":[{"id":"https://openalex.org/C2781109383","wikidata":"https://www.wikidata.org/wiki/Q898497","display_name":"Hydroxylation","level":3,"score":0.865342378616333},{"id":"https://openalex.org/C89611455","wikidata":"https://www.wikidata.org/wiki/Q6804646","display_name":"Mechanism (biology)","level":2,"score":0.7765587568283081},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.610892653465271},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.5162343978881836},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.42623624205589294},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.3717251420021057},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.24565327167510986},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.10668212175369263},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C181199279","wikidata":"https://www.wikidata.org/wiki/Q8047","display_name":"Enzyme","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1016/s1381-1169(99)00402-1","doi":"https://doi.org/10.1016/s1381-1169(99)00402-1","is_oa":false,"landing_page_url":"https://doi.org/10.1016/s1381-1169(99)00402-1","pdf_url":null,"source":{"id":"https://openalex.org/S52459750","display_name":"Journal of Molecular Catalysis A Chemical","issn_l":"1381-1169","issn":["1381-1169","1873-314X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Molecular Catalysis A: Chemical","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":25,"referenced_works":["https://openalex.org/W1926950498","https://openalex.org/W1964906367","https://openalex.org/W1969026406","https://openalex.org/W1974089732","https://openalex.org/W1989269725","https://openalex.org/W1997412769","https://openalex.org/W2001740149","https://openalex.org/W2002343231","https://openalex.org/W2007708141","https://openalex.org/W2008705570","https://openalex.org/W2010486872","https://openalex.org/W2013393709","https://openalex.org/W2021302608","https://openalex.org/W2022301033","https://openalex.org/W2054262103","https://openalex.org/W2064185033","https://openalex.org/W2073356400","https://openalex.org/W2082642170","https://openalex.org/W2088488384","https://openalex.org/W2127163512","https://openalex.org/W2149325902","https://openalex.org/W2165811356","https://openalex.org/W2524458074","https://openalex.org/W2952716173","https://openalex.org/W4256127868"],"related_works":["https://openalex.org/W7047065972","https://openalex.org/W2039258689","https://openalex.org/W2063241469","https://openalex.org/W2950118279","https://openalex.org/W2034981651","https://openalex.org/W2024307327","https://openalex.org/W2149325902","https://openalex.org/W2101183114","https://openalex.org/W2170538198","https://openalex.org/W2006307256"],"abstract_inverted_index":null,"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":2},{"year":2013,"cited_by_count":4},{"year":2012,"cited_by_count":3}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}