{"id":"https://openalex.org/W2017113097","doi":"https://doi.org/10.1021/ja962676t","title":"Raman and Infrared Spectra of (2\u2018S)-[2\u2018-2H]Thymidine: Vibrational Coupling between Deoxyribosyl and Thymine Moieties and Structural Implications","display_name":"Raman and Infrared Spectra of (2\u2018S)-[2\u2018-2H]Thymidine: Vibrational Coupling between Deoxyribosyl and Thymine Moieties and Structural Implications","publication_year":1997,"publication_date":"1997-02-01","ids":{"openalex":"https://openalex.org/W2017113097","doi":"https://doi.org/10.1021/ja962676t","mag":"2017113097"},"language":"en","primary_location":{"id":"doi:10.1021/ja962676t","doi":"https://doi.org/10.1021/ja962676t","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja962676t","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5110172292","display_name":"Masamichi Tsuboi","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I149964584","display_name":"Tokyo University of Pharmacy and Life Sciences","ror":"https://ror.org/057jm7w82","country_code":"JP","type":"education","lineage":["https://openalex.org/I149964584"]},{"id":"https://openalex.org/I75421653","display_name":"University of Missouri\u2013Kansas City","ror":"https://ror.org/01w0d5g70","country_code":"US","type":"education","lineage":["https://openalex.org/I75421653"]},{"id":"https://openalex.org/I79746392","display_name":"IRYO Sosei University","ror":"https://ror.org/04v5axh10","country_code":"JP","type":"education","lineage":["https://openalex.org/I79746392"]}],"countries":["JP","US"],"is_corresponding":false,"raw_author_name":"Masamichi Tsuboi","raw_affiliation_strings":["Contribution from the Department of Fundamental Science, Iwaki\u2212Meisei University, Iwaki, Fukushima 970, Japan, Nicolet Japan Corporation, Hatsudai 2-5-8, Shibuya-ku, Tokyo 151, Japan, Laboratory of Pharmaceutical Chemistry, School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-03, Japan, and School of Biological Sciences, University of Missouri, Kansas City, Missouri 64110"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Fundamental Science, Iwaki\u2212Meisei University, Iwaki, Fukushima 970, Japan, Nicolet Japan Corporation, Hatsudai 2-5-8, Shibuya-ku, Tokyo 151, Japan, Laboratory of Pharmaceutical Chemistry, School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-03, Japan, and School of Biological Sciences, University of Missouri, Kansas City, Missouri 64110","institution_ids":["https://openalex.org/I149964584","https://openalex.org/I75421653","https://openalex.org/I79746392"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Mamoru Komatsu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I149964584","display_name":"Tokyo University of Pharmacy and Life Sciences","ror":"https://ror.org/057jm7w82","country_code":"JP","type":"education","lineage":["https://openalex.org/I149964584"]},{"id":"https://openalex.org/I75421653","display_name":"University of Missouri\u2013Kansas City","ror":"https://ror.org/01w0d5g70","country_code":"US","type":"education","lineage":["https://openalex.org/I75421653"]},{"id":"https://openalex.org/I79746392","display_name":"IRYO Sosei University","ror":"https://ror.org/04v5axh10","country_code":"JP","type":"education","lineage":["https://openalex.org/I79746392"]}],"countries":["JP","US"],"is_corresponding":false,"raw_author_name":"Mamoru Komatsu","raw_affiliation_strings":["Contribution from the Department of Fundamental Science, Iwaki\u2212Meisei University, Iwaki, Fukushima 970, Japan, Nicolet Japan Corporation, Hatsudai 2-5-8, Shibuya-ku, Tokyo 151, Japan, Laboratory of Pharmaceutical Chemistry, School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-03, Japan, and School of Biological Sciences, University of Missouri, Kansas City, Missouri 64110"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Fundamental Science, Iwaki\u2212Meisei University, Iwaki, Fukushima 970, Japan, Nicolet Japan Corporation, Hatsudai 2-5-8, Shibuya-ku, Tokyo 151, Japan, Laboratory of Pharmaceutical Chemistry, School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-03, Japan, and School of Biological Sciences, University of Missouri, Kansas City, Missouri 64110","institution_ids":["https://openalex.org/I149964584","https://openalex.org/I75421653","https://openalex.org/I79746392"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Junichi Hoshi","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I149964584","display_name":"Tokyo University of Pharmacy and Life Sciences","ror":"https://ror.org/057jm7w82","country_code":"JP","type":"education","lineage":["https://openalex.org/I149964584"]},{"id":"https://openalex.org/I75421653","display_name":"University of Missouri\u2013Kansas City","ror":"https://ror.org/01w0d5g70","country_code":"US","type":"education","lineage":["https://openalex.org/I75421653"]},{"id":"https://openalex.org/I79746392","display_name":"IRYO Sosei University","ror":"https://ror.org/04v5axh10","country_code":"JP","type":"education","lineage":["https://openalex.org/I79746392"]}],"countries":["JP","US"],"is_corresponding":false,"raw_author_name":"Junichi Hoshi","raw_affiliation_strings":["Contribution from the Department of Fundamental Science, Iwaki\u2212Meisei University, Iwaki, Fukushima 970, Japan, Nicolet Japan Corporation, Hatsudai 2-5-8, Shibuya-ku, Tokyo 151, Japan, Laboratory of Pharmaceutical Chemistry, School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-03, Japan, and School of Biological Sciences, University of Missouri, Kansas City, Missouri 64110"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Fundamental Science, Iwaki\u2212Meisei University, Iwaki, Fukushima 970, Japan, Nicolet Japan Corporation, Hatsudai 2-5-8, Shibuya-ku, Tokyo 151, Japan, Laboratory of Pharmaceutical Chemistry, School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-03, Japan, and School of Biological Sciences, University of Missouri, Kansas City, Missouri 64110","institution_ids":["https://openalex.org/I149964584","https://openalex.org/I75421653","https://openalex.org/I79746392"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5033349132","display_name":"Etsuko Kawashima","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I149964584","display_name":"Tokyo University of Pharmacy and Life Sciences","ror":"https://ror.org/057jm7w82","country_code":"JP","type":"education","lineage":["https://openalex.org/I149964584"]},{"id":"https://openalex.org/I75421653","display_name":"University of Missouri\u2013Kansas City","ror":"https://ror.org/01w0d5g70","country_code":"US","type":"education","lineage":["https://openalex.org/I75421653"]},{"id":"https://openalex.org/I79746392","display_name":"IRYO Sosei University","ror":"https://ror.org/04v5axh10","country_code":"JP","type":"education","lineage":["https://openalex.org/I79746392"]}],"countries":["JP","US"],"is_corresponding":false,"raw_author_name":"Etsuko Kawashima","raw_affiliation_strings":["Contribution from the Department of Fundamental Science, Iwaki\u2212Meisei University, Iwaki, Fukushima 970, Japan, Nicolet Japan Corporation, Hatsudai 2-5-8, Shibuya-ku, Tokyo 151, Japan, Laboratory of Pharmaceutical Chemistry, School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-03, Japan, and School of Biological Sciences, University of Missouri, Kansas City, Missouri 64110"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Fundamental Science, Iwaki\u2212Meisei University, Iwaki, Fukushima 970, Japan, Nicolet Japan Corporation, Hatsudai 2-5-8, Shibuya-ku, Tokyo 151, Japan, Laboratory of Pharmaceutical Chemistry, School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-03, Japan, and School of Biological Sciences, University of Missouri, Kansas City, Missouri 64110","institution_ids":["https://openalex.org/I149964584","https://openalex.org/I75421653","https://openalex.org/I79746392"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Takeshi Sekine","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I149964584","display_name":"Tokyo University of Pharmacy and Life Sciences","ror":"https://ror.org/057jm7w82","country_code":"JP","type":"education","lineage":["https://openalex.org/I149964584"]},{"id":"https://openalex.org/I75421653","display_name":"University of Missouri\u2013Kansas City","ror":"https://ror.org/01w0d5g70","country_code":"US","type":"education","lineage":["https://openalex.org/I75421653"]},{"id":"https://openalex.org/I79746392","display_name":"IRYO Sosei University","ror":"https://ror.org/04v5axh10","country_code":"JP","type":"education","lineage":["https://openalex.org/I79746392"]}],"countries":["JP","US"],"is_corresponding":false,"raw_author_name":"Takeshi Sekine","raw_affiliation_strings":["Contribution from the Department of Fundamental Science, Iwaki\u2212Meisei University, Iwaki, Fukushima 970, Japan, Nicolet Japan Corporation, Hatsudai 2-5-8, Shibuya-ku, Tokyo 151, Japan, Laboratory of Pharmaceutical Chemistry, School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-03, Japan, and School of Biological Sciences, University of Missouri, Kansas City, Missouri 64110"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Fundamental Science, Iwaki\u2212Meisei University, Iwaki, Fukushima 970, Japan, Nicolet Japan Corporation, Hatsudai 2-5-8, Shibuya-ku, Tokyo 151, Japan, Laboratory of Pharmaceutical Chemistry, School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-03, Japan, and School of Biological Sciences, University of Missouri, Kansas City, Missouri 64110","institution_ids":["https://openalex.org/I149964584","https://openalex.org/I75421653","https://openalex.org/I79746392"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5108762763","display_name":"Yoshiharu Ishido","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I149964584","display_name":"Tokyo University of Pharmacy and Life Sciences","ror":"https://ror.org/057jm7w82","country_code":"JP","type":"education","lineage":["https://openalex.org/I149964584"]},{"id":"https://openalex.org/I75421653","display_name":"University of Missouri\u2013Kansas City","ror":"https://ror.org/01w0d5g70","country_code":"US","type":"education","lineage":["https://openalex.org/I75421653"]},{"id":"https://openalex.org/I79746392","display_name":"IRYO Sosei University","ror":"https://ror.org/04v5axh10","country_code":"JP","type":"education","lineage":["https://openalex.org/I79746392"]}],"countries":["JP","US"],"is_corresponding":false,"raw_author_name":"Yoshiharu Ishido","raw_affiliation_strings":["Contribution from the Department of Fundamental Science, Iwaki\u2212Meisei University, Iwaki, Fukushima 970, Japan, Nicolet Japan Corporation, Hatsudai 2-5-8, Shibuya-ku, Tokyo 151, Japan, Laboratory of Pharmaceutical Chemistry, School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-03, Japan, and School of Biological Sciences, University of Missouri, Kansas City, Missouri 64110"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Fundamental Science, Iwaki\u2212Meisei University, Iwaki, Fukushima 970, Japan, Nicolet Japan Corporation, Hatsudai 2-5-8, Shibuya-ku, Tokyo 151, Japan, Laboratory of Pharmaceutical Chemistry, School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-03, Japan, and School of Biological Sciences, University of Missouri, Kansas City, Missouri 64110","institution_ids":["https://openalex.org/I149964584","https://openalex.org/I75421653","https://openalex.org/I79746392"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022617962","display_name":"Malcolm P. Russell","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I149964584","display_name":"Tokyo University of Pharmacy and Life Sciences","ror":"https://ror.org/057jm7w82","country_code":"JP","type":"education","lineage":["https://openalex.org/I149964584"]},{"id":"https://openalex.org/I75421653","display_name":"University of Missouri\u2013Kansas City","ror":"https://ror.org/01w0d5g70","country_code":"US","type":"education","lineage":["https://openalex.org/I75421653"]},{"id":"https://openalex.org/I79746392","display_name":"IRYO Sosei University","ror":"https://ror.org/04v5axh10","country_code":"JP","type":"education","lineage":["https://openalex.org/I79746392"]}],"countries":["JP","US"],"is_corresponding":false,"raw_author_name":"Malcolm P. Russell","raw_affiliation_strings":["Contribution from the Department of Fundamental Science, Iwaki\u2212Meisei University, Iwaki, Fukushima 970, Japan, Nicolet Japan Corporation, Hatsudai 2-5-8, Shibuya-ku, Tokyo 151, Japan, Laboratory of Pharmaceutical Chemistry, School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-03, Japan, and School of Biological Sciences, University of Missouri, Kansas City, Missouri 64110"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Fundamental Science, Iwaki\u2212Meisei University, Iwaki, Fukushima 970, Japan, Nicolet Japan Corporation, Hatsudai 2-5-8, Shibuya-ku, Tokyo 151, Japan, Laboratory of Pharmaceutical Chemistry, School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-03, Japan, and School of Biological Sciences, University of Missouri, Kansas City, Missouri 64110","institution_ids":["https://openalex.org/I149964584","https://openalex.org/I75421653","https://openalex.org/I79746392"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5023823920","display_name":"James M. Benevides","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I149964584","display_name":"Tokyo University of Pharmacy and Life Sciences","ror":"https://ror.org/057jm7w82","country_code":"JP","type":"education","lineage":["https://openalex.org/I149964584"]},{"id":"https://openalex.org/I75421653","display_name":"University of Missouri\u2013Kansas City","ror":"https://ror.org/01w0d5g70","country_code":"US","type":"education","lineage":["https://openalex.org/I75421653"]},{"id":"https://openalex.org/I79746392","display_name":"IRYO Sosei University","ror":"https://ror.org/04v5axh10","country_code":"JP","type":"education","lineage":["https://openalex.org/I79746392"]}],"countries":["JP","US"],"is_corresponding":false,"raw_author_name":"James M. Benevides","raw_affiliation_strings":["Contribution from the Department of Fundamental Science, Iwaki\u2212Meisei University, Iwaki, Fukushima 970, Japan, Nicolet Japan Corporation, Hatsudai 2-5-8, Shibuya-ku, Tokyo 151, Japan, Laboratory of Pharmaceutical Chemistry, School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-03, Japan, and School of Biological Sciences, University of Missouri, Kansas City, Missouri 64110"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Fundamental Science, Iwaki\u2212Meisei University, Iwaki, Fukushima 970, Japan, Nicolet Japan Corporation, Hatsudai 2-5-8, Shibuya-ku, Tokyo 151, Japan, Laboratory of Pharmaceutical Chemistry, School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-03, Japan, and School of Biological Sciences, University of Missouri, Kansas City, Missouri 64110","institution_ids":["https://openalex.org/I149964584","https://openalex.org/I75421653","https://openalex.org/I79746392"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5109136389","display_name":"George J. Thomas","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I149964584","display_name":"Tokyo University of Pharmacy and Life Sciences","ror":"https://ror.org/057jm7w82","country_code":"JP","type":"education","lineage":["https://openalex.org/I149964584"]},{"id":"https://openalex.org/I75421653","display_name":"University of Missouri\u2013Kansas City","ror":"https://ror.org/01w0d5g70","country_code":"US","type":"education","lineage":["https://openalex.org/I75421653"]},{"id":"https://openalex.org/I79746392","display_name":"IRYO Sosei University","ror":"https://ror.org/04v5axh10","country_code":"JP","type":"education","lineage":["https://openalex.org/I79746392"]}],"countries":["JP","US"],"is_corresponding":false,"raw_author_name":"George J. Thomas","raw_affiliation_strings":["Contribution from the Department of Fundamental Science, Iwaki\u2212Meisei University, Iwaki, Fukushima 970, Japan, Nicolet Japan Corporation, Hatsudai 2-5-8, Shibuya-ku, Tokyo 151, Japan, Laboratory of Pharmaceutical Chemistry, School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-03, Japan, and School of Biological Sciences, University of Missouri, Kansas City, Missouri 64110"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Contribution from the Department of Fundamental Science, Iwaki\u2212Meisei University, Iwaki, Fukushima 970, Japan, Nicolet Japan Corporation, Hatsudai 2-5-8, Shibuya-ku, Tokyo 151, Japan, Laboratory of Pharmaceutical Chemistry, School of Pharmacy, Tokyo University of Pharmacy and Life Science, 1432-1 Horinouchi, Hachioji, Tokyo 192-03, Japan, and School of Biological Sciences, University of Missouri, Kansas City, Missouri 64110","institution_ids":["https://openalex.org/I149964584","https://openalex.org/I75421653","https://openalex.org/I79746392"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":4.0317,"has_fulltext":false,"cited_by_count":76,"citation_normalized_percentile":{"value":0.94274538,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"119","issue":"8","first_page":"2025","last_page":"2032"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11324","display_name":"Spectroscopy Techniques in Biomedical and Chemical Research","score":0.8974999785423279,"subfield":{"id":"https://openalex.org/subfields/1304","display_name":"Biophysics"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},"topics":[{"id":"https://openalex.org/T11324","display_name":"Spectroscopy Techniques in Biomedical and Chemical Research","score":0.8974999785423279,"subfield":{"id":"https://openalex.org/subfields/1304","display_name":"Biophysics"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T10432","display_name":"DNA and Nucleic Acid Chemistry","score":0.07590000331401825,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.014299999922513962,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/thymidine","display_name":"thymidine","score":0.9240000247955322},{"id":"https://openalex.org/keywords/deuterium-labeling","display_name":"deuterium labeling","score":0.7910000085830688},{"id":"https://openalex.org/keywords/vibrational-coupling","display_name":"vibrational coupling","score":0.9350000023841858},{"id":"https://openalex.org/keywords/normal-mode-assignment","display_name":"normal mode assignment","score":0.7720000147819519},{"id":"https://openalex.org/keywords/nucleoside-structure","display_name":"nucleoside structure","score":0.5839999914169312},{"id":"https://openalex.org/keywords/sugar-conformation","display_name":"sugar conformation","score":0.6269999742507935}],"concepts":[{"id":"https://openalex.org/C2776858809","wikidata":"https://www.wikidata.org/wiki/Q171973","display_name":"Thymine","level":3,"score":0.914352536201477},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8871315717697144},{"id":"https://openalex.org/C2777108182","wikidata":"https://www.wikidata.org/wiki/Q422464","display_name":"Thymidine","level":3,"score":0.8087745904922485},{"id":"https://openalex.org/C2777709666","wikidata":"https://www.wikidata.org/wiki/Q192454","display_name":"Deoxyribose","level":3,"score":0.7962766885757446},{"id":"https://openalex.org/C40003534","wikidata":"https://www.wikidata.org/wiki/Q862228","display_name":"Raman spectroscopy","level":2,"score":0.7032655477523804},{"id":"https://openalex.org/C2777454769","wikidata":"https://www.wikidata.org/wiki/Q11172462","display_name":"Methylene","level":2,"score":0.5837749242782593},{"id":"https://openalex.org/C158355884","wikidata":"https://www.wikidata.org/wiki/Q11388","display_name":"Infrared","level":2,"score":0.46602675318717957},{"id":"https://openalex.org/C24107716","wikidata":"https://www.wikidata.org/wiki/Q123619","display_name":"Nucleic acid","level":2,"score":0.4128047823905945},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.4072031080722809},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.3742632567882538},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.3296152949333191},{"id":"https://openalex.org/C552990157","wikidata":"https://www.wikidata.org/wiki/Q7430","display_name":"DNA","level":2,"score":0.2534243166446686},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.12869149446487427},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.08740442991256714},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.08347150683403015},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/ja962676t","doi":"https://doi.org/10.1021/ja962676t","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja962676t","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":16,"referenced_works":["https://openalex.org/W653580821","https://openalex.org/W1968286102","https://openalex.org/W1978952197","https://openalex.org/W1988786731","https://openalex.org/W1994870432","https://openalex.org/W2017120330","https://openalex.org/W2036002146","https://openalex.org/W2036263076","https://openalex.org/W2061497347","https://openalex.org/W2075719295","https://openalex.org/W2081716248","https://openalex.org/W2087100981","https://openalex.org/W2094826490","https://openalex.org/W2949903807","https://openalex.org/W2950157376","https://openalex.org/W4213183351"],"related_works":["https://openalex.org/W2158192917","https://openalex.org/W1976049773","https://openalex.org/W1986152257","https://openalex.org/W2017120330","https://openalex.org/W2027989507","https://openalex.org/W2003808001","https://openalex.org/W2164174808","https://openalex.org/W2063705254","https://openalex.org/W2011234512","https://openalex.org/W4246864908"],"abstract_inverted_index":{"The":[0,64,192],"thymidine":[1,74,100,214],"stereoisotopomer,":[2],"(2\u2018":[3,102],"S":[4,13,103],")-[2\u2018-":[5,104],"2":[6,105,218,254],"H]thymidine,":[7],"which":[8],"incorporates":[9],"deuterium":[10],"in":[11,134,166,180],"the":[12,16,46,82,87,96,140,145,151,164,209,252],"configuration":[14],"at":[15],"furanosyl":[17],"2\u2018":[18],"carbon,":[19],"has":[20],"been":[21,28,108],"synthesized":[22],"and":[23,30,38,50,86,93,101,153,162,177,187,198,239,261],"its":[24],"vibrational":[25,79,206,278],"spectra":[26,40,55,182],"have":[27,107],"recorded":[29],"compared":[31],"with":[32,139],"those":[33],"of":[34,73,78,95,99,112,126,144,173,183,201,208,213,280],"normal":[35,71],"thymidine.":[36,281],"Infrared":[37],"Raman":[39,123,181],"were":[41,56],"collected":[42,57],"from":[43,58],"crystalline":[44],"powders,":[45],"latter":[47],"using":[48,61],"1063-":[49],"514.5-nm":[51],"excitations;":[52],"ultraviolet":[53],"resonance-Raman":[54],"aqueous":[59],"solutions":[60],"244-nm":[62],"excitation.":[63],"results":[65,194],"show,":[66],"remarkably,":[67],"that":[68,120],"virtually":[69],"all":[70],"modes":[72,207,263],"involve":[75,136],"some":[76],"degree":[77],"coupling":[80,138,149],"between":[81,150],"thymine":[83,131],"base":[84,152],"residue":[85],"deoxyribose":[88,174],"moiety.":[89],"Nevertheless,":[90],"systematic":[91],"assignments":[92,248,271],"correlation":[94],"spectral":[97,202],"frequencies":[98],"H]thymidine":[106],"accomplished.":[109],"A":[110],"finding":[111],"importance":[113],"for":[114,251,275],"nucleic":[115],"acid":[116],"structure":[117],"applications":[118],"is":[119],"many":[121,276],"prominent":[122],"marker":[124],"bands":[125,165,203,279],"thymidine,":[127],"assigned":[128],"previously":[129],"as":[130,171,215],"ring":[132,175],"vibrations,":[133],"fact":[135],"appreciable":[137],"C2\u2018":[141,210],"methylene":[142,211],"group":[143,212],"attached":[146],"sugar.":[147],"Vibrational":[148],"sugar":[154,160],"groups":[155],"implies":[156],"frequency":[157],"dependence":[158],"upon":[159],"conformation":[161],"allows":[163],"question":[167],"to":[168,204],"be":[169],"exploited":[170],"markers":[172],"pucker":[176],"glycosyl":[178],"orientation":[179],"DNA,":[184],"antiviral":[185],"drugs,":[186],"other":[188,277],"thymine-containing":[189],"nucleoside":[190],"analogues.":[191],"present":[193],"also":[195,273],"enable":[196],"unambiguous":[197],"novel":[199],"assignment":[200],"specific":[205],"follows:":[216],"C2\u2018H":[217,253],"antisymmetric":[219],"stretching":[220,227],"(2995":[221],"cm":[222,229,235,242,257,265],"-":[223,230,236,243,258,266],"1":[224,231,237,244,259,267],"),":[225,232,238],"symmetric":[226],"(2956":[228],"scissoring":[233],"(1404":[234],"wagging":[240],"(1174":[241],").":[245,268],"Additionally,":[246],"probable":[247],"are":[249,272],"deduced":[250],"twisting":[255],"(1103":[256],")":[260],"rocking":[262],"(898":[264],"Normal":[269],"mode":[270],"proposed":[274]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":4},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":3},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":5},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":3},{"year":2017,"cited_by_count":3},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":3},{"year":2013,"cited_by_count":3}],"updated_date":"2026-09-29T14:09:16.559479","created_date":"2016-06-24T00:00:00"}