{"id":"https://openalex.org/W2016947411","doi":"https://doi.org/10.1149/1.2221112","title":"Electrochemical Study of Autocatalytic Bismuth(III) Reduction with Ti(III)\u2010Complexes","display_name":"Electrochemical Study of Autocatalytic Bismuth(III) Reduction with Ti(III)\u2010Complexes","publication_year":1993,"publication_date":"1993-12-01","ids":{"openalex":"https://openalex.org/W2016947411","doi":"https://doi.org/10.1149/1.2221112","mag":"2016947411"},"language":"en","primary_location":{"id":"doi:10.1149/1.2221112","doi":"https://doi.org/10.1149/1.2221112","is_oa":true,"landing_page_url":"https://doi.org/10.1149/1.2221112","pdf_url":"https://iopscience.iop.org/article/10.1149/1.2221112/pdf","source":{"id":"https://openalex.org/S138759888","display_name":"Journal of The Electrochemical Society","issn_l":"0013-4651","issn":["0013-4651","1945-7111"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-2","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310311669","host_organization_name":"Institute of Physics","host_organization_lineage":["https://openalex.org/P4310311669"],"host_organization_lineage_names":["Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of The Electrochemical Society","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"bronze","oa_url":"https://iopscience.iop.org/article/10.1149/1.2221112/pdf","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5091627095","display_name":"D. L. Rutkevich","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I291386647","display_name":"Belarusian State University","ror":"https://ror.org/021036w13","country_code":"BY","type":"education","lineage":["https://openalex.org/I291386647"]}],"countries":["BY"],"is_corresponding":false,"raw_author_name":"D. L. Rutkevich","raw_affiliation_strings":["Physico\u2010Chemical Problems Research Institute of the Belorussian State University, 220080 Minsk, Republic of Belarus, CIS"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Physico\u2010Chemical Problems Research Institute of the Belorussian State University, 220080 Minsk, Republic of Belarus, CIS","institution_ids":["https://openalex.org/I291386647"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5062468331","display_name":"\u0413. \u041f. \u0428\u0435\u0432\u0447\u0435\u043d\u043a\u043e","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I291386647","display_name":"Belarusian State University","ror":"https://ror.org/021036w13","country_code":"BY","type":"education","lineage":["https://openalex.org/I291386647"]}],"countries":["BY"],"is_corresponding":false,"raw_author_name":"G. P. Shevchenko","raw_affiliation_strings":["Physico\u2010Chemical Problems Research Institute of the Belorussian State University, 220080 Minsk, Republic of Belarus, CIS"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Physico\u2010Chemical Problems Research Institute of the Belorussian State University, 220080 Minsk, Republic of Belarus, CIS","institution_ids":["https://openalex.org/I291386647"]}]},{"author_position":"middle","author":{"id":null,"display_name":"V. V. Sviridov","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I291386647","display_name":"Belarusian State University","ror":"https://ror.org/021036w13","country_code":"BY","type":"education","lineage":["https://openalex.org/I291386647"]}],"countries":["BY"],"is_corresponding":false,"raw_author_name":"V. V. Sviridov","raw_affiliation_strings":["Physico\u2010Chemical Problems Research Institute of the Belorussian State University, 220080 Minsk, Republic of Belarus, CIS"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Physico\u2010Chemical Problems Research Institute of the Belorussian State University, 220080 Minsk, Republic of Belarus, CIS","institution_ids":["https://openalex.org/I291386647"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5009042654","display_name":"Nikolai P. Osipovich","orcid":"https://orcid.org/0000-0001-6354-5292","observed_orcids":["https://orcid.org/0000-0001-6354-5292"]},"institutions":[{"id":"https://openalex.org/I291386647","display_name":"Belarusian State University","ror":"https://ror.org/021036w13","country_code":"BY","type":"education","lineage":["https://openalex.org/I291386647"]}],"countries":["BY"],"is_corresponding":false,"raw_author_name":"N. P. Osipovich","raw_affiliation_strings":["Physico\u2010Chemical Problems Research Institute of the Belorussian State University, 220080 Minsk, Republic of Belarus, CIS"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Physico\u2010Chemical Problems Research Institute of the Belorussian State University, 220080 Minsk, Republic of Belarus, CIS","institution_ids":["https://openalex.org/I291386647"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I291386647"],"apc_list":{"value":1950,"currency":"USD","value_usd":1950},"apc_paid":null,"fwci":0.3761,"has_fulltext":true,"cited_by_count":8,"citation_normalized_percentile":{"value":0.48059701,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":95},"biblio":{"volume":"140","issue":"12","first_page":"3473","last_page":"3478"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11200","display_name":"Electrodeposition and Electroless Coatings","score":0.8823000192642212,"subfield":{"id":"https://openalex.org/subfields/2508","display_name":"Surfaces, Coatings and Films"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11200","display_name":"Electrodeposition and Electroless Coatings","score":0.8823000192642212,"subfield":{"id":"https://openalex.org/subfields/2508","display_name":"Surfaces, Coatings and Films"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11434","display_name":"Electrochemical Analysis and Applications","score":0.11089999973773956,"subfield":{"id":"https://openalex.org/subfields/1603","display_name":"Electrochemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10030","display_name":"Electrocatalysts for Energy Conversion","score":0.0008999999845400453,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/titanium-iii-complexes","display_name":"titanium(III) complexes","score":0.9369999766349792},{"id":"https://openalex.org/keywords/autocatalysis","display_name":"autocatalysis","score":0.9039999842643738},{"id":"https://openalex.org/keywords/electrochemical-reduction-mechanism","display_name":"electrochemical reduction mechanism","score":0.5740000009536743},{"id":"https://openalex.org/keywords/bismuth-deposition","display_name":"bismuth deposition","score":0.7799999713897705},{"id":"https://openalex.org/keywords/solution-stability","display_name":"solution stability","score":0.6800000071525574},{"id":"https://openalex.org/keywords/acid-medium","display_name":"acid medium","score":0.33500000834465027},{"id":"https://openalex.org/keywords/electroactive-species","display_name":"electroactive species","score":0.32199999690055847}],"concepts":[{"id":"https://openalex.org/C37263863","wikidata":"https://www.wikidata.org/wiki/Q786897","display_name":"Autocatalysis","level":3,"score":0.9187363386154175},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.8092663884162903},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6425362825393677},{"id":"https://openalex.org/C533668322","wikidata":"https://www.wikidata.org/wiki/Q942","display_name":"Bismuth","level":2,"score":0.5890976190567017},{"id":"https://openalex.org/C95514000","wikidata":"https://www.wikidata.org/wiki/Q786897","display_name":"Autocatalytic reaction","level":2,"score":0.5457060933113098},{"id":"https://openalex.org/C30095370","wikidata":"https://www.wikidata.org/wiki/Q899488","display_name":"Protonation","level":3,"score":0.5178127884864807},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.48181620240211487},{"id":"https://openalex.org/C55904794","wikidata":"https://www.wikidata.org/wiki/Q82682","display_name":"Redox","level":2,"score":0.45492830872535706},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.4398183226585388},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.37320542335510254},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.2908380627632141},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.12777981162071228},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0866040587425232},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C121864883","wikidata":"https://www.wikidata.org/wiki/Q677916","display_name":"Statistical physics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1149/1.2221112","doi":"https://doi.org/10.1149/1.2221112","is_oa":true,"landing_page_url":"https://doi.org/10.1149/1.2221112","pdf_url":"https://iopscience.iop.org/article/10.1149/1.2221112/pdf","source":{"id":"https://openalex.org/S138759888","display_name":"Journal of The Electrochemical Society","issn_l":"0013-4651","issn":["0013-4651","1945-7111"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-2","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310311669","host_organization_name":"Institute of Physics","host_organization_lineage":["https://openalex.org/P4310311669"],"host_organization_lineage_names":["Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of The Electrochemical Society","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1149/1.2221112","doi":"https://doi.org/10.1149/1.2221112","is_oa":true,"landing_page_url":"https://doi.org/10.1149/1.2221112","pdf_url":"https://iopscience.iop.org/article/10.1149/1.2221112/pdf","source":{"id":"https://openalex.org/S138759888","display_name":"Journal of The Electrochemical Society","issn_l":"0013-4651","issn":["0013-4651","1945-7111"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-2","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310311669","host_organization_name":"Institute of Physics","host_organization_lineage":["https://openalex.org/P4310311669"],"host_organization_lineage_names":["Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of The Electrochemical Society","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320322015","display_name":"University of Toronto","ror":"https://ror.org/03dbr7087"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2016947411.pdf","grobid_xml":"https://content.openalex.org/works/W2016947411.grobid-xml"},"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2050128289","https://openalex.org/W2021182519","https://openalex.org/W3175523928","https://openalex.org/W1984980671","https://openalex.org/W2004328483","https://openalex.org/W7213190782","https://openalex.org/W2037119628","https://openalex.org/W2785521474","https://openalex.org/W2968052658","https://openalex.org/W2045861236"],"abstract_inverted_index":{"It":[0],"was":[1],"first":[2],"established":[3],"that":[4,17,85,94],"Bi(III)":[5,49],"can":[6,24],"be":[7,25,42,91,102],"reduced":[8],"by":[9,45,130],"Ti(III)":[10,51,111],"complexes":[11],"in":[12,27,124],"an":[13],"autocatalytic":[14],"mode":[15],"and":[16,50,65,104,136,149],"the":[18,22,48,55,58,66,69,78,88,95,99,121,125,131,142,148],"main":[19],"features":[20],"of":[21,29,36,47,57,68,117,139,152],"process":[23,59,79],"interpreted":[26],"terms":[28],"pure":[30],"electrochemical":[31,34],"mechanisms.":[32],"The":[33,115],"parameters":[35],"partial":[37,132],"reaction":[38,133],"coupling,":[39],"which":[40],"could":[41],"easily":[43],"changed":[44],"means":[46],"ions":[52],"complexation,":[53],"govern":[54],"possibility":[56],"as":[60,62],"well":[61],"its":[63],"rate":[64,116],"nature":[67],"product":[70],"formed":[71],"(continuous":[72],"film":[73],"or":[74],"stable":[75],"sol).":[76],"For":[77],"to":[80],"proceed":[81],"it":[82],"is":[83,128,137,150],"necessary":[84],"not":[86],"only":[87],"thermodynamic":[89],"condition":[90],"met,":[92],"but":[93],"kinetic":[96],"hindrances":[97],"for":[98],"reductant":[100],"oxidation":[101],"eliminated":[103],"these":[105],"are":[106,113],"realized":[107],"when":[108],"electroactive":[109],"protonated":[110],"complexonates":[112],"formed.":[114],"Bi":[118],"deposition":[119],"onto":[120],"conductive":[122],"surface":[123],"acid":[126],"medium":[127],"controlled":[129],"mixed":[134],"current":[135],"independent":[138,151],",":[140],"while":[141],"solution":[143],"stability":[144],"depends":[145],"mainly":[146],"on":[147],".":[153]},"counts_by_year":[{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2012,"cited_by_count":2}],"updated_date":"2026-10-01T08:54:57.152042","created_date":"2016-06-24T00:00:00"}