{"id":"https://openalex.org/W2016917261","doi":"https://doi.org/10.1063/1.463732","title":"Vibrationally induced rotational axis switching: A novel mechanism for vibrational mode coupling","display_name":"Vibrationally induced rotational axis switching: A novel mechanism for vibrational mode coupling","publication_year":1992,"publication_date":"1992-11-01","ids":{"openalex":"https://openalex.org/W2016917261","doi":"https://doi.org/10.1063/1.463732","mag":"2016917261"},"language":"en","primary_location":{"id":"doi:10.1063/1.463732","doi":"https://doi.org/10.1063/1.463732","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.463732","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5039106243","display_name":"H. Li","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I205783295","display_name":"Cornell University","ror":"https://ror.org/05bnh6r87","country_code":"US","type":"education","lineage":["https://openalex.org/I205783295"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"H. Li","raw_affiliation_strings":["Department of Chemistry, Cornell University, Ithaca, New York 14853-1301"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Cornell University, Ithaca, New York 14853-1301","institution_ids":["https://openalex.org/I205783295"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5001972509","display_name":"Gregory S. Ezra","orcid":"https://orcid.org/0000-0001-9959-810X","observed_orcids":["https://orcid.org/0000-0001-9959-810X"]},"institutions":[{"id":"https://openalex.org/I205783295","display_name":"Cornell University","ror":"https://ror.org/05bnh6r87","country_code":"US","type":"education","lineage":["https://openalex.org/I205783295"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Gregory S. Ezra","raw_affiliation_strings":["Department of Chemistry, Cornell University, Ithaca, New York 14853-1301"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Cornell University, Ithaca, New York 14853-1301","institution_ids":["https://openalex.org/I205783295"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5022181590","display_name":"Laura A. Philips","orcid":"https://orcid.org/0000-0001-6121-4131","observed_orcids":["https://orcid.org/0000-0001-6121-4131"]},"institutions":[{"id":"https://openalex.org/I205783295","display_name":"Cornell University","ror":"https://ror.org/05bnh6r87","country_code":"US","type":"education","lineage":["https://openalex.org/I205783295"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Laura A. Philips","raw_affiliation_strings":["Department of Chemistry, Cornell University, Ithaca, New York 14853-1301"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Cornell University, Ithaca, New York 14853-1301","institution_ids":["https://openalex.org/I205783295"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I205783295"],"apc_list":{"value":3500,"currency":"USD","value_usd":3500},"apc_paid":null,"fwci":3.0688,"has_fulltext":false,"cited_by_count":27,"citation_normalized_percentile":{"value":0.92082111,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":94},"biblio":{"volume":"97","issue":"9","first_page":"5956","last_page":"5963"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12967","display_name":"Molecular Spectroscopy and Structure","score":0.9077000021934509,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12967","display_name":"Molecular Spectroscopy and Structure","score":0.9077000021934509,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.05939999967813492,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11111","display_name":"Spectroscopy and Laser Applications","score":0.02930000051856041,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/vibrational-coupling","display_name":"vibrational coupling","score":0.8679999709129333},{"id":"https://openalex.org/keywords/vibration-rotation-interaction","display_name":"vibration-rotation interaction","score":0.8840000033378601},{"id":"https://openalex.org/keywords/2-fluoroethanol","display_name":"2-fluoroethanol","score":0.9290000200271606},{"id":"https://openalex.org/keywords/centrifugal-distortion","display_name":"centrifugal distortion","score":0.8009999990463257},{"id":"https://openalex.org/keywords/internal-rotation","display_name":"internal rotation","score":0.7350000143051147},{"id":"https://openalex.org/keywords/torsional-vibration","display_name":"torsional vibration","score":0.5170000195503235},{"id":"https://openalex.org/keywords/c-h-stretching-vibrations","display_name":"C-H stretching vibrations","score":0.6389999985694885},{"id":"https://openalex.org/keywords/coriolis-coupling","display_name":"Coriolis coupling","score":0.6700000166893005}],"concepts":[{"id":"https://openalex.org/C77461463","wikidata":"https://www.wikidata.org/wiki/Q7827201","display_name":"Torsion (gastropod)","level":2,"score":0.6471467018127441},{"id":"https://openalex.org/C74050887","wikidata":"https://www.wikidata.org/wiki/Q848368","display_name":"Rotation (mathematics)","level":2,"score":0.5896658301353455},{"id":"https://openalex.org/C131584629","wikidata":"https://www.wikidata.org/wiki/Q4308705","display_name":"Coupling (piping)","level":2,"score":0.5688322186470032},{"id":"https://openalex.org/C180205008","wikidata":"https://www.wikidata.org/wiki/Q159190","display_name":"Amplitude","level":2,"score":0.5498299598693848},{"id":"https://openalex.org/C198394728","wikidata":"https://www.wikidata.org/wiki/Q3695508","display_name":"Vibration","level":2,"score":0.5339281558990479},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.5031391978263855},{"id":"https://openalex.org/C126780896","wikidata":"https://www.wikidata.org/wiki/Q899871","display_name":"Distortion (music)","level":4,"score":0.46693697571754456},{"id":"https://openalex.org/C41999313","wikidata":"https://www.wikidata.org/wiki/Q489328","display_name":"Molecular physics","level":1,"score":0.4461277723312378},{"id":"https://openalex.org/C2994254730","wikidata":"https://www.wikidata.org/wiki/Q264251","display_name":"Internal rotation","level":2,"score":0.4306979477405548},{"id":"https://openalex.org/C71515424","wikidata":"https://www.wikidata.org/wiki/Q7370329","display_name":"Rotational\u2013vibrational coupling","level":3,"score":0.4193592965602875},{"id":"https://openalex.org/C4839761","wikidata":"https://www.wikidata.org/wiki/Q212111","display_name":"Spectral line","level":2,"score":0.37582167983055115},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.3745920658111572},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.19193291664123535},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.16233333945274353},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.11676657199859619},{"id":"https://openalex.org/C2524010","wikidata":"https://www.wikidata.org/wiki/Q8087","display_name":"Geometry","level":1,"score":0.09810975193977356},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C194257627","wikidata":"https://www.wikidata.org/wiki/Q211554","display_name":"Amplifier","level":3,"score":0.0},{"id":"https://openalex.org/C141071460","wikidata":"https://www.wikidata.org/wiki/Q40821","display_name":"Surgery","level":1,"score":0.0},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.0},{"id":"https://openalex.org/C49040817","wikidata":"https://www.wikidata.org/wiki/Q193091","display_name":"Optoelectronics","level":1,"score":0.0},{"id":"https://openalex.org/C46362747","wikidata":"https://www.wikidata.org/wiki/Q173431","display_name":"CMOS","level":2,"score":0.0},{"id":"https://openalex.org/C78519656","wikidata":"https://www.wikidata.org/wiki/Q101333","display_name":"Mechanical engineering","level":1,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1063/1.463732","doi":"https://doi.org/10.1063/1.463732","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.463732","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"},{"id":"pmh:ADA251085","doi":null,"is_oa":false,"landing_page_url":"http://oai.dtic.mil/oai/oai?&amp;verb=getRecord&amp;metadataPrefix=html&amp;identifier=ADA251085","pdf_url":null,"source":{"id":"https://openalex.org/S4406923043","display_name":"Defense Technical Information Center (DTIC)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"DTIC AND NTIS","raw_type":"Text"},{"id":"mag:3116359460","doi":null,"is_oa":false,"landing_page_url":"http://ui.adsabs.harvard.edu/abs/1992vira.rept.....L/abstract","pdf_url":null,"source":{"id":"https://openalex.org/S4306482006","display_name":"Unknown eBooks","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"ebook platform"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":"Unknown eBooks","raw_type":null}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":34,"referenced_works":["https://openalex.org/W148647367","https://openalex.org/W1517467250","https://openalex.org/W1964092882","https://openalex.org/W1967907709","https://openalex.org/W1973299685","https://openalex.org/W1974345852","https://openalex.org/W1976106600","https://openalex.org/W1977138440","https://openalex.org/W1978452420","https://openalex.org/W1979978894","https://openalex.org/W1986257482","https://openalex.org/W1988751373","https://openalex.org/W1990766352","https://openalex.org/W1996659001","https://openalex.org/W2000202053","https://openalex.org/W2001642380","https://openalex.org/W2004294314","https://openalex.org/W2007264108","https://openalex.org/W2011805684","https://openalex.org/W2019461491","https://openalex.org/W2026496857","https://openalex.org/W2036300230","https://openalex.org/W2038848365","https://openalex.org/W2040439797","https://openalex.org/W2046865256","https://openalex.org/W2063133760","https://openalex.org/W2079708446","https://openalex.org/W2091589872","https://openalex.org/W2092131542","https://openalex.org/W2101966964","https://openalex.org/W2157423271","https://openalex.org/W2169192827","https://openalex.org/W2178042910","https://openalex.org/W2377283066"],"related_works":["https://openalex.org/W3016662423","https://openalex.org/W1969184041","https://openalex.org/W2088843566","https://openalex.org/W2000202053","https://openalex.org/W4321261848","https://openalex.org/W95221309","https://openalex.org/W2130859127","https://openalex.org/W1978452420","https://openalex.org/W1989848416","https://openalex.org/W1987077737"],"abstract_inverted_index":{"High":[0],"resolution":[1],"IR":[2],"spectra":[3],"of":[4,18,31,72,79,94,107],"small-":[5],"to":[6,99],"medium-sized":[7],"molecules":[8],"such":[9],"as":[10,48],"2-fluoroethanol":[11],"(2FE)":[12],"show":[13],"that":[14,25,114],"the":[15,70,77,87,100,117],"effective":[16],"density":[17,106],"coupled":[19,108],"states":[20,98,109],"is":[21,46,63],"often":[22],"greater":[23],"than":[24],"obtained":[26],"by":[27],"a":[28,49,91,105],"direct":[29],"count":[30],"vibrational":[32],"states.":[33],"A":[34],"novel":[35],"mechanism":[36],"for":[37,52],"rotation\u2013vibration":[38],"interaction,":[39],"vibrationally":[40],"induced":[41],"rotational":[42],"axis":[43],"switching":[44],"(VIRAS),":[45],"proposed":[47],"possible":[50],"explanation":[51],"these":[53],"discrepancies.":[54],"VIRAS":[55],"has":[56],"its":[57],"origin":[58],"in":[59,110,116],"centrifugal":[60],"distortion,":[61],"and":[62],"physically":[64],"distinct":[65],"from":[66],"Coriolis":[67],"coupling.":[68],"In":[69],"case":[71],"2FE,":[73],"we":[74,103],"explicitly":[75],"treat":[76],"coupling":[78,93],"overall":[80],"rotation":[81,85],"with":[82,113],"large-amplitude":[83],"internal":[84],"about":[86],"C\u2013C":[88],"bond.":[89],"Assuming":[90],"uniform":[92],"all":[95],"dark":[96],"vibration\u2013torsion":[97],"bright":[101],"state,":[102],"predict":[104],"good":[111],"agreement":[112],"observed":[115],"C\u2013H":[118],"stretching":[119],"region":[120],"at":[121],"2980":[122],"cm\u22121.":[123]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2015,"cited_by_count":1}],"updated_date":"2026-09-26T08:19:03.415552","created_date":"2016-06-24T00:00:00"}
