{"id":"https://openalex.org/W2016876828","doi":"https://doi.org/10.1021/jp0482013","title":"Solvent-Assisted One-Pot Synthesis and Self-Assembly of 4-Aminothiophenol-Capped Gold Nanoparticles","display_name":"Solvent-Assisted One-Pot Synthesis and Self-Assembly of 4-Aminothiophenol-Capped Gold Nanoparticles","publication_year":2004,"publication_date":"2004-08-10","ids":{"openalex":"https://openalex.org/W2016876828","doi":"https://doi.org/10.1021/jp0482013","mag":"2016876828"},"language":"en","primary_location":{"id":"doi:10.1021/jp0482013","doi":"https://doi.org/10.1021/jp0482013","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp0482013","pdf_url":null,"source":{"id":"https://openalex.org/S185621672","display_name":"The Journal of Physical Chemistry B","issn_l":"1520-5207","issn":["1520-5207","1520-6106"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry B","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5071179911","display_name":"Jadab Sharma","orcid":"https://orcid.org/0000-0003-3138-8530","observed_orcids":["https://orcid.org/0000-0003-3138-8530"]},"institutions":[{"id":"https://openalex.org/I3125981224","display_name":"National Chemical Laboratory","ror":"https://ror.org/057mn3690","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I3125981224","https://openalex.org/I4210134808","https://openalex.org/I66760702"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Jadab Sharma","raw_affiliation_strings":["Physical and Materials Chemistry Division and Centre for Materials Characterization, National Chemical Laboratory, Dr. Homi Bhaba Road, Pune-411008, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Physical and Materials Chemistry Division and Centre for Materials Characterization, National Chemical Laboratory, Dr. Homi Bhaba Road, Pune-411008, India","institution_ids":["https://openalex.org/I3125981224"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5109101741","display_name":"Subhramannia Mahima","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I3125981224","display_name":"National Chemical Laboratory","ror":"https://ror.org/057mn3690","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I3125981224","https://openalex.org/I4210134808","https://openalex.org/I66760702"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"S. Mahima","raw_affiliation_strings":["Physical and Materials Chemistry Division and Centre for Materials Characterization, National Chemical Laboratory, Dr. Homi Bhaba Road, Pune-411008, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Physical and Materials Chemistry Division and Centre for Materials Characterization, National Chemical Laboratory, Dr. Homi Bhaba Road, Pune-411008, India","institution_ids":["https://openalex.org/I3125981224"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5028900072","display_name":"Bhalchandra\u2005A. Kakade","orcid":"https://orcid.org/0000-0002-2353-5476","observed_orcids":["https://orcid.org/0000-0002-2353-5476"]},"institutions":[{"id":"https://openalex.org/I3125981224","display_name":"National Chemical Laboratory","ror":"https://ror.org/057mn3690","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I3125981224","https://openalex.org/I4210134808","https://openalex.org/I66760702"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Bhalchandra A. Kakade","raw_affiliation_strings":["Physical and Materials Chemistry Division and Centre for Materials Characterization, National Chemical Laboratory, Dr. Homi Bhaba Road, Pune-411008, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Physical and Materials Chemistry Division and Centre for Materials Characterization, National Chemical Laboratory, Dr. Homi Bhaba Road, Pune-411008, India","institution_ids":["https://openalex.org/I3125981224"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5021049466","display_name":"Renu Pasricha","orcid":"https://orcid.org/0000-0002-9659-1225","observed_orcids":["https://orcid.org/0000-0002-9659-1225"]},"institutions":[{"id":"https://openalex.org/I3125981224","display_name":"National Chemical Laboratory","ror":"https://ror.org/057mn3690","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I3125981224","https://openalex.org/I4210134808","https://openalex.org/I66760702"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"Renu Pasricha","raw_affiliation_strings":["Physical and Materials Chemistry Division and Centre for Materials Characterization, National Chemical Laboratory, Dr. Homi Bhaba Road, Pune-411008, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Physical and Materials Chemistry Division and Centre for Materials Characterization, National Chemical Laboratory, Dr. Homi Bhaba Road, Pune-411008, India","institution_ids":["https://openalex.org/I3125981224"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111763063","display_name":"A.B. Mandale","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I3125981224","display_name":"National Chemical Laboratory","ror":"https://ror.org/057mn3690","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I3125981224","https://openalex.org/I4210134808","https://openalex.org/I66760702"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"A. B. Mandale","raw_affiliation_strings":["Physical and Materials Chemistry Division and Centre for Materials Characterization, National Chemical Laboratory, Dr. Homi Bhaba Road, Pune-411008, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Physical and Materials Chemistry Division and Centre for Materials Characterization, National Chemical Laboratory, Dr. Homi Bhaba Road, Pune-411008, India","institution_ids":["https://openalex.org/I3125981224"]}]},{"author_position":"last","author":{"id":null,"display_name":"K. Vijayamohanan","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I3125981224","display_name":"National Chemical Laboratory","ror":"https://ror.org/057mn3690","country_code":"IN","type":"facility","lineage":["https://openalex.org/I2799351866","https://openalex.org/I3125981224","https://openalex.org/I4210134808","https://openalex.org/I66760702"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"K. Vijayamohanan","raw_affiliation_strings":["Physical and Materials Chemistry Division and Centre for Materials Characterization, National Chemical Laboratory, Dr. Homi Bhaba Road, Pune-411008, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Physical and Materials Chemistry Division and Centre for Materials Characterization, National Chemical Laboratory, Dr. Homi Bhaba Road, Pune-411008, India","institution_ids":["https://openalex.org/I3125981224"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I3125981224"],"apc_list":null,"apc_paid":null,"fwci":1.1945,"has_fulltext":false,"cited_by_count":85,"citation_normalized_percentile":{"value":0.75155039,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":93,"max":99},"biblio":{"volume":"108","issue":"35","first_page":"13280","last_page":"13286"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10131","display_name":"Gold and Silver Nanoparticles Synthesis and Applications","score":0.9839000105857849,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10131","display_name":"Gold and Silver Nanoparticles Synthesis and Applications","score":0.9839000105857849,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12149","display_name":"Nanocluster Synthesis and Applications","score":0.012799999676644802,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13232","display_name":"Laser-Ablation Synthesis of Nanoparticles","score":0.0010999999940395355,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/gold-nanoparticles","display_name":"gold nanoparticles","score":0.9340000152587891},{"id":"https://openalex.org/keywords/4-aminothiophenol","display_name":"4-aminothiophenol","score":0.9760000109672546},{"id":"https://openalex.org/keywords/solvent-assisted-synthesis","display_name":"solvent-assisted synthesis","score":0.796999990940094},{"id":"https://openalex.org/keywords/one-pot-synthesis","display_name":"one-pot synthesis","score":0.9509999752044678},{"id":"https://openalex.org/keywords/self-assembly","display_name":"self-assembly","score":0.8859999775886536},{"id":"https://openalex.org/keywords/nanoparticle-aggregation","display_name":"nanoparticle aggregation","score":0.6470000147819519},{"id":"https://openalex.org/keywords/ph-dependent-morphology","display_name":"pH-dependent morphology","score":0.7239999771118164},{"id":"https://openalex.org/keywords/thiol-reduction","display_name":"thiol reduction","score":0.39399999380111694},{"id":"https://openalex.org/keywords/monolayer-protected-nanoparticles","display_name":"monolayer-protected nanoparticles","score":0.722000002861023},{"id":"https://openalex.org/keywords/electrochemical-redox-behavior","display_name":"electrochemical redox behavior","score":0.8009999990463257}],"concepts":[{"id":"https://openalex.org/C104819515","wikidata":"https://www.wikidata.org/wiki/Q900961","display_name":"Colloidal gold","level":3,"score":0.6543805003166199},{"id":"https://openalex.org/C155672457","wikidata":"https://www.wikidata.org/wiki/Q61231","display_name":"Nanoparticle","level":2,"score":0.6513255834579468},{"id":"https://openalex.org/C7070889","wikidata":"https://www.wikidata.org/wiki/Q902488","display_name":"Monolayer","level":2,"score":0.58966463804245},{"id":"https://openalex.org/C175708663","wikidata":"https://www.wikidata.org/wiki/Q899559","display_name":"X-ray photoelectron spectroscopy","level":2,"score":0.5249281525611877},{"id":"https://openalex.org/C119824511","wikidata":"https://www.wikidata.org/wiki/Q13553575","display_name":"Absorption spectroscopy","level":2,"score":0.5071547031402588},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.48751041293144226},{"id":"https://openalex.org/C160892712","wikidata":"https://www.wikidata.org/wiki/Q901559","display_name":"Fourier transform infrared spectroscopy","level":2,"score":0.4499533772468567},{"id":"https://openalex.org/C26856880","wikidata":"https://www.wikidata.org/wiki/Q910150","display_name":"Self-assembly","level":2,"score":0.44449788331985474},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.4370708465576172},{"id":"https://openalex.org/C60100273","wikidata":"https://www.wikidata.org/wiki/Q902806","display_name":"Thermogravimetric analysis","level":2,"score":0.4201151132583618},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.3560980558395386},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.3447529673576355},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.31915414333343506},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.30897974967956543},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.17766550183296204},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/jp0482013","doi":"https://doi.org/10.1021/jp0482013","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp0482013","pdf_url":null,"source":{"id":"https://openalex.org/S185621672","display_name":"The Journal of Physical Chemistry B","issn_l":"1520-5207","issn":["1520-5207","1520-6106"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry B","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":62,"referenced_works":["https://openalex.org/W1909553649","https://openalex.org/W1964377594","https://openalex.org/W1968044889","https://openalex.org/W1969422588","https://openalex.org/W1969645755","https://openalex.org/W1971785003","https://openalex.org/W1971971466","https://openalex.org/W1972195348","https://openalex.org/W1976826454","https://openalex.org/W1976846505","https://openalex.org/W1980545891","https://openalex.org/W1980864016","https://openalex.org/W1989860007","https://openalex.org/W1996979900","https://openalex.org/W1999198229","https://openalex.org/W2001809903","https://openalex.org/W2002385994","https://openalex.org/W2009518527","https://openalex.org/W2011995061","https://openalex.org/W2012134936","https://openalex.org/W2013072950","https://openalex.org/W2013442516","https://openalex.org/W2017117354","https://openalex.org/W2018908522","https://openalex.org/W2019026331","https://openalex.org/W2020148612","https://openalex.org/W2020679021","https://openalex.org/W2020858655","https://openalex.org/W2024583168","https://openalex.org/W2029082620","https://openalex.org/W2030025464","https://openalex.org/W2033096857","https://openalex.org/W2034124623","https://openalex.org/W2044030326","https://openalex.org/W2044667167","https://openalex.org/W2049021801","https://openalex.org/W2051458871","https://openalex.org/W2054717918","https://openalex.org/W2054801773","https://openalex.org/W2062470136","https://openalex.org/W2063800669","https://openalex.org/W2065457784","https://openalex.org/W2067765423","https://openalex.org/W2071969859","https://openalex.org/W2072152305","https://openalex.org/W2075997629","https://openalex.org/W2076913594","https://openalex.org/W2077228161","https://openalex.org/W2079343824","https://openalex.org/W2085225256","https://openalex.org/W2087812087","https://openalex.org/W2089079251","https://openalex.org/W2089276776","https://openalex.org/W2092997037","https://openalex.org/W2093850126","https://openalex.org/W2093913522","https://openalex.org/W2099189002","https://openalex.org/W2103179372","https://openalex.org/W2106853492","https://openalex.org/W2497302180","https://openalex.org/W2950415445","https://openalex.org/W4237036272"],"related_works":["https://openalex.org/W2388083339","https://openalex.org/W2076913594","https://openalex.org/W1990568676","https://openalex.org/W925473326","https://openalex.org/W2333908613","https://openalex.org/W1987697848","https://openalex.org/W1963352272","https://openalex.org/W2064014823","https://openalex.org/W2054107622","https://openalex.org/W2786066217"],"abstract_inverted_index":{"Single-step":[0],"preparation":[1],"of":[2,65,77,101,107,111,137,144,175,181,195,206,211,219,236,241],"smaller":[3],"sized":[4],"(ca.":[5],"3":[6],"nm,":[7,92],"approximate":[8],"composition":[9],"Au":[10,222],"923":[11],"ATP":[12,242],"241":[13],")":[14],"gold":[15,113,138,185,245],"nanoparticles":[16,49,114,139,186,223],"(AuNPs)":[17],"followed":[18],"by":[19,121,141,187],"their":[20],"self-assembly":[21],"is":[22,68,115],"demonstrated":[23],"using":[24],"4-aminothiophenol":[25],"(ATP)":[26],"as":[27,183],"a":[28,41,86,95,123,244],"reducing":[29],"agent":[30],"in":[31,53,56,117],"water/":[32],"N,":[33],"N":[34],"-dimethylformamide":[35],"(DMF).":[36],"Water":[37],"and":[38,162],"DMF":[39,57],"play":[40],"crucial":[42],"role":[43],"during":[44,208],"the":[45,63,66,75,78,105,112,118,142,151,173,182,193,204,209,220,229,237],"reduction":[46,210],"process,":[47],"since":[48],"are":[50,232],"formed":[51],"neither":[52],"water":[54],"nor":[55],"alone":[58],"at":[59,90],"room":[60],"temperature.":[61],"Moreover,":[62],"morphology":[64],"particles":[67],"found":[69],"to":[70,104],"be":[71],"strongly":[72],"dependent":[73],"on":[74,172,243],"pH":[76],"medium.":[79],"The":[80,109,177,216],"instantaneous":[81],"UV\u2212visible":[82],"absorption":[83],"spectrum":[84,191],"shows":[85,168,192],"relatively":[87],"sharp":[88],"peak":[89],"550":[91],"which":[93],"becomes":[94],"broad":[96],"band":[97],"after":[98],"1":[99],"h":[100],"mixing,":[102],"due":[103],"formation":[106],"aggregates.":[108],"size":[110],"controlled":[116],"stipulated":[119],"range":[120],"maintaining":[122],"critical":[124],"AuCl":[125,212],"4":[126,213],"-":[127,214],"/ATP":[128],"ratio.":[129],"Transmission":[130],"electron":[131],"microscopic":[132],"images":[133],"reveal":[134],"close-packed":[135],"assembly":[136],"induced":[140],"bifunctionality":[143],"ATP.":[145],"Powder":[146],"X-ray":[147,198],"diffraction":[148],"patterns":[149],"confirm":[150,203],"metallic":[152],"face-centered":[153],"cubic":[154],"(fcc)":[155],"lattice":[156],"structure":[157],"with":[158],"(111),":[159],"(200),":[160],"(220),":[161],"(311)":[163],"crystal":[164],"planes.":[165],"Thermogravimetric":[166],"analysis":[167,180],"22%":[169],"organic":[170],"molecules":[171],"surface":[174],"AuNPs.":[176],"molecular":[178],"level":[179],"prepared":[184],"Fourier":[188],"transform":[189],"infrared":[190],"presence":[194],"\u2212SO":[196],"stretching.":[197],"photoelectron":[199],"spectroscopic":[200],"results":[201],"also":[202],"oxidation":[205],"\u2212SH":[207],"ions.":[215],"cyclic":[217],"voltammograms":[218],"monolayer-protected":[221],"show":[224],"quasi-reversible":[225],"redox":[226],"behavior,":[227],"though":[228],"electrochemical":[230],"features":[231],"different":[233],"from":[234],"those":[235],"self-assembled":[238],"monolayer":[239],"(SAM)":[240],"electrode.":[246]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":5},{"year":2024,"cited_by_count":5},{"year":2022,"cited_by_count":4},{"year":2021,"cited_by_count":3},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":5},{"year":2017,"cited_by_count":4},{"year":2016,"cited_by_count":4},{"year":2015,"cited_by_count":4},{"year":2014,"cited_by_count":8},{"year":2013,"cited_by_count":3},{"year":2012,"cited_by_count":6}],"updated_date":"2026-10-04T09:36:47.201465","created_date":"2016-06-24T00:00:00"}