{"id":"https://openalex.org/W2016830934","doi":"https://doi.org/10.1021/jp801869c","title":"Thermodynamics of the Hydroxyl Radical Addition to Isoprene","display_name":"Thermodynamics of the Hydroxyl Radical Addition to Isoprene","publication_year":2008,"publication_date":"2008-07-01","ids":{"openalex":"https://openalex.org/W2016830934","doi":"https://doi.org/10.1021/jp801869c","mag":"2016830934","pmid":"https://pubmed.ncbi.nlm.nih.gov/18598012","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/2488963"},"language":"en","primary_location":{"id":"doi:10.1021/jp801869c","doi":"https://doi.org/10.1021/jp801869c","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp801869c","pdf_url":null,"source":{"id":"https://openalex.org/S146709414","display_name":"The Journal of Physical Chemistry A","issn_l":"1089-5639","issn":["1089-5639","1520-5215"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry A","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/2488963","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5020678429","display_name":"Marco A. Allodi","orcid":"https://orcid.org/0000-0002-3289-1659","observed_orcids":["https://orcid.org/0000-0002-3289-1659"]},"institutions":[{"id":"https://openalex.org/I188592606","display_name":"Hamilton College","ror":"https://ror.org/05709zb94","country_code":"US","type":"education","lineage":["https://openalex.org/I188592606"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Marco A. Allodi","raw_affiliation_strings":["Department of Chemistry, Center for Molecular Design, Hamilton College, 198 College Hill Road, Clinton, NY 13323","Department of Chemistry, Center for Molecular Design, Hamilton College, 198 College Hill Road, Clinton, NY 13323, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Center for Molecular Design, Hamilton College, 198 College Hill Road, Clinton, NY 13323","institution_ids":["https://openalex.org/I188592606"]},{"raw_affiliation_string":"Department of Chemistry, Center for Molecular Design, Hamilton College, 198 College Hill Road, Clinton, NY 13323, USA","institution_ids":["https://openalex.org/I188592606"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5000728064","display_name":"Karl N. Kirschner","orcid":"https://orcid.org/0000-0002-4581-920X","observed_orcids":["https://orcid.org/0000-0002-4581-920X"]},"institutions":[{"id":"https://openalex.org/I188592606","display_name":"Hamilton College","ror":"https://ror.org/05709zb94","country_code":"US","type":"education","lineage":["https://openalex.org/I188592606"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Karl N. Kirschner","raw_affiliation_strings":["Department of Chemistry, Center for Molecular Design, Hamilton College, 198 College Hill Road, Clinton, NY 13323"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Center for Molecular Design, Hamilton College, 198 College Hill Road, Clinton, NY 13323","institution_ids":["https://openalex.org/I188592606"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5052474010","display_name":"George C. Shields","orcid":"https://orcid.org/0000-0003-1287-8585","observed_orcids":["https://orcid.org/0000-0003-1287-8585"]},"institutions":[{"id":"https://openalex.org/I188592606","display_name":"Hamilton College","ror":"https://ror.org/05709zb94","country_code":"US","type":"education","lineage":["https://openalex.org/I188592606"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"George C. Shields","raw_affiliation_strings":["Department of Chemistry, Center for Molecular Design, Hamilton College, 198 College Hill Road, Clinton, NY 13323"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Center for Molecular Design, Hamilton College, 198 College Hill Road, Clinton, NY 13323","institution_ids":["https://openalex.org/I188592606"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5000728064","https://openalex.org/A5052474010"],"corresponding_institution_ids":["https://openalex.org/I188592606"],"apc_list":null,"apc_paid":null,"fwci":1.0532,"has_fulltext":false,"cited_by_count":35,"citation_normalized_percentile":{"value":0.74884055,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"112","issue":"30","first_page":"7064","last_page":"7071"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10075","display_name":"Atmospheric chemistry and aerosols","score":0.7773000001907349,"subfield":{"id":"https://openalex.org/subfields/1902","display_name":"Atmospheric Science"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10075","display_name":"Atmospheric chemistry and aerosols","score":0.7773000001907349,"subfield":{"id":"https://openalex.org/subfields/1902","display_name":"Atmospheric Science"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10002","display_name":"Advanced Chemical Physics Studies","score":0.07970000058412552,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10117","display_name":"Advanced Combustion Engine Technologies","score":0.05999999865889549,"subfield":{"id":"https://openalex.org/subfields/1507","display_name":"Fluid Flow and Transfer Processes"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/isoprene","display_name":"isoprene","score":0.7760000228881836},{"id":"https://openalex.org/keywords/hydroxyl-radicals","display_name":"hydroxyl radicals","score":0.9470000267028809},{"id":"https://openalex.org/keywords/radical-addition","display_name":"radical addition","score":0.765999972820282},{"id":"https://openalex.org/keywords/isoprene-oxidation","display_name":"isoprene oxidation","score":0.8090000152587891},{"id":"https://openalex.org/keywords/tropospheric-ozone","display_name":"tropospheric ozone","score":0.8410000205039978},{"id":"https://openalex.org/keywords/pre-reactive-complexes","display_name":"pre-reactive complexes","score":0.6460000276565552},{"id":"https://openalex.org/keywords/negative-temperature-dependence","display_name":"negative temperature dependence","score":0.7419999837875366},{"id":"https://openalex.org/keywords/reaction-kinetics","display_name":"reaction kinetics","score":0.5230000019073486},{"id":"https://openalex.org/keywords/free-energy-landscape","display_name":"free energy landscape","score":0.746999979019165},{"id":"https://openalex.org/keywords/reaction-energy-barrier","display_name":"reaction barriers","score":0.5400000214576721},{"id":"https://openalex.org/keywords/reaction-pathways","display_name":"reaction pathways","score":0.6079999804496765},{"id":"https://openalex.org/keywords/atmospheric-chemistry","display_name":"atmospheric chemistry","score":0.43799999356269836}],"concepts":[{"id":"https://openalex.org/C2780959689","wikidata":"https://www.wikidata.org/wiki/Q271943","display_name":"Isoprene","level":4,"score":0.9847187995910645},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8434052467346191},{"id":"https://openalex.org/C108204754","wikidata":"https://www.wikidata.org/wiki/Q353392","display_name":"Adduct","level":2,"score":0.7097019553184509},{"id":"https://openalex.org/C2776778087","wikidata":"https://www.wikidata.org/wiki/Q427071","display_name":"Hydroxyl radical","level":3,"score":0.6632698774337769},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.6594372987747192},{"id":"https://openalex.org/C139066938","wikidata":"https://www.wikidata.org/wiki/Q185056","display_name":"Radical","level":2,"score":0.5591769814491272},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.5082899928092957},{"id":"https://openalex.org/C95121573","wikidata":"https://www.wikidata.org/wiki/Q190474","display_name":"Activation energy","level":2,"score":0.45854026079177856},{"id":"https://openalex.org/C36663273","wikidata":"https://www.wikidata.org/wiki/Q209082","display_name":"Chemical kinetics","level":3,"score":0.45768821239471436},{"id":"https://openalex.org/C508106653","wikidata":"https://www.wikidata.org/wiki/Q36933","display_name":"Ozone","level":2,"score":0.42079228162765503},{"id":"https://openalex.org/C29563950","wikidata":"https://www.wikidata.org/wiki/Q183410","display_name":"Thermochemistry","level":2,"score":0.4168645739555359},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.33459433913230896},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.2631547749042511},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2573804557323456},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.0}],"mesh":[{"descriptor_ui":"D002070","descriptor_name":"Butadienes","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D008958","descriptor_name":"Models, Molecular","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D010420","descriptor_name":"Pentanes","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D013816","descriptor_name":"Thermodynamics","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D015394","descriptor_name":"Molecular Structure","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D045782","descriptor_name":"Hemiterpenes","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true}],"locations_count":9,"locations":[{"id":"doi:10.1021/jp801869c","doi":"https://doi.org/10.1021/jp801869c","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp801869c","pdf_url":null,"source":{"id":"https://openalex.org/S146709414","display_name":"The Journal of Physical Chemistry A","issn_l":"1089-5639","issn":["1089-5639","1520-5215"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry A","raw_type":"journal-article"},{"id":"pmid:18598012","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/18598012","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The journal of physical chemistry. A","raw_type":"Journal Article"},{"id":"pmh:oai:europepmc.org:1931473","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/2488963","pdf_url":null,"source":{"id":"https://openalex.org/S4306400806","display_name":"Europe PMC (PubMed Central)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1303153112","host_organization_name":"European Bioinformatics Institute","host_organization_lineage":["https://openalex.org/I1303153112"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"Text"},{"id":"pmh:oai:pubmedcentral.nih.gov:2488963","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/2488963","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"J Phys Chem A","raw_type":"Text"},{"id":"pmh:oai:CiteSeerX.psu:10.1.1.599.3798","doi":null,"is_oa":false,"landing_page_url":"http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.599.3798","pdf_url":null,"source":null,"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"http://www.armstrong.edu/images/science_technology/AllodiKS2008.pdf","raw_type":"text"},{"id":"pmh:oai:fraunhofer.de:N-95777","doi":null,"is_oa":false,"landing_page_url":"http://publica.fraunhofer.de/documents/N-95777.html","pdf_url":null,"source":{"id":"https://openalex.org/S4306400801","display_name":"Publikationsdatenbank der Fraunhofer-Gesellschaft (Fraunhofer-Gesellschaft)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4923324","host_organization_name":"Fraunhofer-Gesellschaft","host_organization_lineage":["https://openalex.org/I4923324"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Fraunhofer SCAI","raw_type":"Journal Article"},{"id":"pmh:oai:pub.h-brs.de:5479","doi":null,"is_oa":false,"landing_page_url":"https://pub.h-brs.de/frontdoor/index/index/docId/5479","pdf_url":null,"source":{"id":"https://openalex.org/S4306400385","display_name":"Publication Server of Bonn-Rhein-Sieg University of Applied Sciences (Bonn-Rhein-Sieg University of Applied Sciences)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I135140700","host_organization_name":"University of Bonn","host_organization_lineage":["https://openalex.org/I135140700"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"ISSN 1089-5639","raw_type":"article"},{"id":"pmh:oai:publica.fraunhofer.de:publica/217455","doi":null,"is_oa":false,"landing_page_url":"https://publica.fraunhofer.de/handle/publica/217455","pdf_url":null,"source":{"id":"https://openalex.org/S4306400318","display_name":"Fraunhofer-Publica (Fraunhofer-Gesellschaft)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4923324","host_organization_name":"Fraunhofer-Gesellschaft","host_organization_lineage":["https://openalex.org/I4923324"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"journal article"},{"id":"pmh:oai:scholarexchange.furman.edu:chm-citations-1391","doi":null,"is_oa":false,"landing_page_url":"https://scholar.google.com/scholar?q=10.1021/jp801869c","pdf_url":null,"source":{"id":"https://openalex.org/S4377196656","display_name":"Furman University Scholar Exchange (Furman University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I86115722","host_organization_name":"Furman University","host_organization_lineage":["https://openalex.org/I86115722"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Chemistry Department Faculty Citations","raw_type":"text"}],"best_oa_location":{"id":"pmh:oai:europepmc.org:1931473","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/2488963","pdf_url":null,"source":{"id":"https://openalex.org/S4306400806","display_name":"Europe PMC (PubMed Central)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1303153112","host_organization_name":"European Bioinformatics Institute","host_organization_lineage":["https://openalex.org/I1303153112"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"Text"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G5875773773","display_name":"Reactivity and Dynamics of Enediyne Natural Products","funder_award_id":"R15CA115524","funder_id":"https://openalex.org/F4320337351","funder_display_name":"National Cancer Institute"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320337351","display_name":"National Cancer Institute","ror":"https://ror.org/040gcmg81"},{"id":"https://openalex.org/F4320337367","display_name":"Division of Materials Research","ror":"https://ror.org/01pc7k308"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":109,"referenced_works":["https://openalex.org/W74713129","https://openalex.org/W1520276096","https://openalex.org/W1527894967","https://openalex.org/W1601753125","https://openalex.org/W1656321397","https://openalex.org/W1965768882","https://openalex.org/W1965936818","https://openalex.org/W1967791981","https://openalex.org/W1969508481","https://openalex.org/W1971063822","https://openalex.org/W1971735045","https://openalex.org/W1976172735","https://openalex.org/W1976353559","https://openalex.org/W1979486514","https://openalex.org/W1980381744","https://openalex.org/W1983805579","https://openalex.org/W1984845762","https://openalex.org/W1985864193","https://openalex.org/W1987235921","https://openalex.org/W1987552244","https://openalex.org/W1988634321","https://openalex.org/W1989771929","https://openalex.org/W1990299444","https://openalex.org/W1993127487","https://openalex.org/W1994727574","https://openalex.org/W1996140793","https://openalex.org/W1998250932","https://openalex.org/W2000699497","https://openalex.org/W2006921624","https://openalex.org/W2007575234","https://openalex.org/W2011587710","https://openalex.org/W2012999742","https://openalex.org/W2019369344","https://openalex.org/W2020729558","https://openalex.org/W2022718673","https://openalex.org/W2023265554","https://openalex.org/W2023905356","https://openalex.org/W2025035498","https://openalex.org/W2025355544","https://openalex.org/W2025396755","https://openalex.org/W2026903975","https://openalex.org/W2027744048","https://openalex.org/W2030712382","https://openalex.org/W2031778913","https://openalex.org/W2034770496","https://openalex.org/W2034812398","https://openalex.org/W2037902225","https://openalex.org/W2040650644","https://openalex.org/W2041589675","https://openalex.org/W2045951474","https://openalex.org/W2046577164","https://openalex.org/W2046616803","https://openalex.org/W2046680750","https://openalex.org/W2047844922","https://openalex.org/W2048756141","https://openalex.org/W2050891247","https://openalex.org/W2051215171","https://openalex.org/W2054656562","https://openalex.org/W2055117363","https://openalex.org/W2057533280","https://openalex.org/W2059887248","https://openalex.org/W2061658629","https://openalex.org/W2062021379","https://openalex.org/W2062606596","https://openalex.org/W2064262385","https://openalex.org/W2065424037","https://openalex.org/W2065894625","https://openalex.org/W2066491323","https://openalex.org/W2067321720","https://openalex.org/W2069006374","https://openalex.org/W2074166633","https://openalex.org/W2075093534","https://openalex.org/W2076702827","https://openalex.org/W2079686197","https://openalex.org/W2081107108","https://openalex.org/W2081751046","https://openalex.org/W2083835773","https://openalex.org/W2084596271","https://openalex.org/W2084878147","https://openalex.org/W2087841849","https://openalex.org/W2088030800","https://openalex.org/W2088765243","https://openalex.org/W2089850009","https://openalex.org/W2090078068","https://openalex.org/W2090937383","https://openalex.org/W2092930273","https://openalex.org/W2093016259","https://openalex.org/W2093204787","https://openalex.org/W2094797643","https://openalex.org/W2098500355","https://openalex.org/W2099629334","https://openalex.org/W2105456697","https://openalex.org/W2106686258","https://openalex.org/W2109652387","https://openalex.org/W2117302902","https://openalex.org/W2131880613","https://openalex.org/W2143632544","https://openalex.org/W2149854110","https://openalex.org/W2151950831","https://openalex.org/W2157517023","https://openalex.org/W2161776543","https://openalex.org/W2168225205","https://openalex.org/W2168424313","https://openalex.org/W2171765687","https://openalex.org/W2558874786","https://openalex.org/W2950397444","https://openalex.org/W2984501823","https://openalex.org/W4206211367","https://openalex.org/W4240035468"],"related_works":["https://openalex.org/W1973004262","https://openalex.org/W2143632544","https://openalex.org/W2013046345","https://openalex.org/W2055117363","https://openalex.org/W2743868048","https://openalex.org/W2087841849","https://openalex.org/W2040650644","https://openalex.org/W2116372664","https://openalex.org/W2002118999","https://openalex.org/W2888201297"],"abstract_inverted_index":{"Oxidation":[0],"of":[1,17,25,32,39,52,57,67,83,98,116],"isoprene":[2,53],"by":[3],"the":[4,50,55,61,80,89,96,112,126,141,178],"hydroxyl":[5,62],"radical":[6,63],"leads":[7],"to":[8,22,65,91,110,170,192,204],"tropospheric":[9],"ozone":[10],"formation.":[11,93],"Consequently,":[12],"a":[13,29,36,132],"more":[14],"complete":[15],"understanding":[16,31,38],"this":[18,75,117],"reaction":[19,40,146,161,164,186,198],"could":[20],"lead":[21],"better":[23,30,37],"models":[24],"regional":[26],"air":[27],"quality,":[28],"aerosol":[33],"formation,":[34],"and":[35,42,86,103,163,197],"kinetics":[41],"dynamics.":[43],"The":[44,148],"most":[45],"common":[46],"first":[47],"step":[48],"in":[49,72,177],"oxidation":[51],"is":[54,135],"formation":[56,97],"an":[58],"adduct,":[59],"with":[60],"adding":[64],"one":[66],"four":[68],"unsaturated":[69],"carbon":[70],"atoms":[71],"isoprene.":[73],"In":[74],"paper,":[76],"we":[77],"discuss":[78],"how":[79],"initial":[81],"conformations":[82],"isoprene,":[84],"s-trans":[85],"s-gauche,":[87],"influences":[88],"pathways":[90,158,183],"adduct":[92],"We":[94,120],"explore":[95],"pre-reactive":[99,133],"complexes":[100],"at":[101,123,138,153],"low":[102,139,154],"high":[104],"temperatures,":[105],"which":[106],"are":[107],"often":[108],"invoked":[109],"explain":[111],"negative":[113,160],"temperature":[114],"dependence":[115],"reaction's":[118],"kinetics.":[119],"show":[121,151],"that":[122,131,152,166,188,200],"higher":[124],"temperatures":[125,140,155,176],"free":[127],"energy":[128],"surface":[129],"indicates":[130],"complex":[134,142],"unlikely,":[136],"while":[137],"exists":[143],"on":[144],"two":[145],"pathways.":[147],"theoretical":[149],"results":[150],"all":[156,181],"eight":[157,182],"possess":[159,184],"barriers,":[162],"energies":[165,199],"range":[167,189,201],"from":[168,190,202],"-36.7":[169],"-23.0":[171],"kcal":[172,194,206],"x":[173,195,207],"mol(-1).":[174,208],"At":[175],"lower":[179],"atmosphere,":[180],"positive":[185],"barriers":[187],"3.8":[191],"6.0":[193],"mol(-1)":[196],"-28.8":[203],"-14.4":[205]},"counts_by_year":[{"year":2024,"cited_by_count":3},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":3},{"year":2014,"cited_by_count":4},{"year":2013,"cited_by_count":2},{"year":2012,"cited_by_count":7}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}
