{"id":"https://openalex.org/W2016803216","doi":"https://doi.org/10.1002/jrs.1250260110","title":"The Raman spectrum of brookite, TiO2 (Pbca, Z = 8)","display_name":"The Raman spectrum of brookite, TiO2 (Pbca, Z = 8)","publication_year":1995,"publication_date":"1995-01-01","ids":{"openalex":"https://openalex.org/W2016803216","doi":"https://doi.org/10.1002/jrs.1250260110","mag":"2016803216"},"language":"en","primary_location":{"id":"doi:10.1002/jrs.1250260110","doi":"https://doi.org/10.1002/jrs.1250260110","is_oa":false,"landing_page_url":"https://doi.org/10.1002/jrs.1250260110","pdf_url":null,"source":{"id":"https://openalex.org/S4206644","display_name":"Journal of Raman Spectroscopy","issn_l":"0377-0486","issn":["0377-0486","1097-4555"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-b","jufo-1","norway-1","poland-70","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Raman Spectroscopy","raw_type":"journal-article"},"parent_works":[],"lineage":["https://openalex.org/W2016803216"],"child_works_count":0,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5028948927","display_name":"Geoffrey A. Tompsett","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I154130895","display_name":"University of Auckland","ror":"https://ror.org/03b94tp07","country_code":"NZ","type":"education","lineage":["https://openalex.org/I154130895"]}],"countries":["NZ"],"is_corresponding":false,"raw_author_name":"G. A. Tompsett","raw_affiliation_strings":["Departments of Chemistry and Geology, University of Auckland, Private Bag, Auckland, New Zealand"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departments of Chemistry and Geology, University of Auckland, Private Bag, Auckland, New Zealand","institution_ids":["https://openalex.org/I154130895"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111098320","display_name":"Graham A. Bowmaker","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I154130895","display_name":"University of Auckland","ror":"https://ror.org/03b94tp07","country_code":"NZ","type":"education","lineage":["https://openalex.org/I154130895"]}],"countries":["NZ"],"is_corresponding":false,"raw_author_name":"G. A. Bowmaker","raw_affiliation_strings":["Departments of Chemistry and Geology, University of Auckland, Private Bag, Auckland, New Zealand"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departments of Chemistry and Geology, University of Auckland, Private Bag, Auckland, New Zealand","institution_ids":["https://openalex.org/I154130895"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110430165","display_name":"RPJ Cooney","orcid":"https://orcid.org/0000-0003-3347-6040","observed_orcids":["https://orcid.org/0000-0003-3347-6040"]},"institutions":[{"id":"https://openalex.org/I154130895","display_name":"University of Auckland","ror":"https://ror.org/03b94tp07","country_code":"NZ","type":"education","lineage":["https://openalex.org/I154130895"]}],"countries":["NZ"],"is_corresponding":true,"raw_author_name":"R. P. Cooney","raw_affiliation_strings":["Departments of Chemistry and Geology, University of Auckland, Private Bag, Auckland, New Zealand"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departments of Chemistry and Geology, University of Auckland, Private Bag, Auckland, New Zealand","institution_ids":["https://openalex.org/I154130895"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5055248856","display_name":"James B. Metson","orcid":"https://orcid.org/0000-0002-8781-9187","observed_orcids":["https://orcid.org/0000-0002-8781-9187"]},"institutions":[{"id":"https://openalex.org/I154130895","display_name":"University of Auckland","ror":"https://ror.org/03b94tp07","country_code":"NZ","type":"education","lineage":["https://openalex.org/I154130895"]}],"countries":["NZ"],"is_corresponding":false,"raw_author_name":"J. B. Metson","raw_affiliation_strings":["Departments of Chemistry and Geology, University of Auckland, Private Bag, Auckland, New Zealand"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departments of Chemistry and Geology, University of Auckland, Private Bag, Auckland, New Zealand","institution_ids":["https://openalex.org/I154130895"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5108506488","display_name":"Kerry A. Rodgers","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I154130895","display_name":"University of Auckland","ror":"https://ror.org/03b94tp07","country_code":"NZ","type":"education","lineage":["https://openalex.org/I154130895"]}],"countries":["NZ"],"is_corresponding":false,"raw_author_name":"K. A. Rodgers","raw_affiliation_strings":["Departments of Chemistry and Geology, University of Auckland, Private Bag, Auckland, New Zealand"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departments of Chemistry and Geology, University of Auckland, Private Bag, Auckland, New Zealand","institution_ids":["https://openalex.org/I154130895"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5084648689","display_name":"John M. Seakins","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I154130895","display_name":"University of Auckland","ror":"https://ror.org/03b94tp07","country_code":"NZ","type":"education","lineage":["https://openalex.org/I154130895"]}],"countries":["NZ"],"is_corresponding":false,"raw_author_name":"J. M. Seakins","raw_affiliation_strings":["Departments of Chemistry and Geology, University of Auckland, Private Bag, Auckland, New Zealand"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departments of Chemistry and Geology, University of Auckland, Private Bag, Auckland, New Zealand","institution_ids":["https://openalex.org/I154130895"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5110430165"],"corresponding_institution_ids":["https://openalex.org/I154130895"],"apc_list":{"value":4020,"currency":"USD","value_usd":4020},"apc_paid":null,"fwci":5.5439,"has_fulltext":false,"cited_by_count":542,"citation_normalized_percentile":{"value":0.94918444,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":99,"max":100},"biblio":{"volume":"26","issue":"1","first_page":"57","last_page":"62"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10024","display_name":"TiO2 Photocatalysis and Solar Cells","score":0.35499998927116394,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10024","display_name":"TiO2 Photocatalysis and Solar Cells","score":0.35499998927116394,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13443","display_name":"Mineralogy and Gemology Studies","score":0.32710000872612,"subfield":{"id":"https://openalex.org/subfields/1906","display_name":"Geochemistry and Petrology"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11324","display_name":"Spectroscopy Techniques in Biomedical and Chemical Research","score":0.061500001698732376,"subfield":{"id":"https://openalex.org/subfields/1304","display_name":"Biophysics"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/brookite","display_name":"brookite","score":0.9990000128746033},{"id":"https://openalex.org/keywords/titanium-dioxide","display_name":"titanium dioxide","score":0.7260000109672546},{"id":"https://openalex.org/keywords/raman-spectra","display_name":"Raman spectra","score":0.8109999895095825},{"id":"https://openalex.org/keywords/vibrational-assignment","display_name":"vibrational assignment","score":0.7870000004768372},{"id":"https://openalex.org/keywords/anatase","display_name":"anatase","score":0.7670000195503235},{"id":"https://openalex.org/keywords/rutile","display_name":"rutile","score":0.996999979019165},{"id":"https://openalex.org/keywords/fe-substitution","display_name":"iron substitution","score":0.49799999594688416},{"id":"https://openalex.org/keywords/ferric-iron","display_name":"iron(III)","score":0.6430000066757202},{"id":"https://openalex.org/keywords/hydroxyl-groups","display_name":"hydroxyl groups","score":0.6800000071525574},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.4320000112056732}],"concepts":[{"id":"https://openalex.org/C2779299574","wikidata":"https://www.wikidata.org/wiki/Q410609","display_name":"Brookite","level":5,"score":0.8297687768936157},{"id":"https://openalex.org/C40003534","wikidata":"https://www.wikidata.org/wiki/Q862228","display_name":"Raman spectroscopy","level":2,"score":0.7367140650749207},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6657454967498779},{"id":"https://openalex.org/C138411078","wikidata":"https://www.wikidata.org/wiki/Q911272","display_name":"Electron microprobe","level":2,"score":0.6555559039115906},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.6332481503486633},{"id":"https://openalex.org/C2777402863","wikidata":"https://www.wikidata.org/wiki/Q413357","display_name":"Anatase","level":4,"score":0.5694091320037842},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.5183947682380676},{"id":"https://openalex.org/C2777889555","wikidata":"https://www.wikidata.org/wiki/Q320603","display_name":"Rutile","level":2,"score":0.4948357939720154},{"id":"https://openalex.org/C2781285689","wikidata":"https://www.wikidata.org/wiki/Q21921428","display_name":"Crystal (programming language)","level":2,"score":0.4788113236427307},{"id":"https://openalex.org/C4839761","wikidata":"https://www.wikidata.org/wiki/Q212111","display_name":"Spectral line","level":2,"score":0.4316246509552002},{"id":"https://openalex.org/C199289684","wikidata":"https://www.wikidata.org/wiki/Q83353","display_name":"Mineralogy","level":1,"score":0.23541122674942017},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.08332893252372742},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.0780850350856781},{"id":"https://openalex.org/C1276947","wikidata":"https://www.wikidata.org/wiki/Q333","display_name":"Astronomy","level":1,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.0},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0},{"id":"https://openalex.org/C199360897","wikidata":"https://www.wikidata.org/wiki/Q9143","display_name":"Programming language","level":1,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C65165184","wikidata":"https://www.wikidata.org/wiki/Q218831","display_name":"Photocatalysis","level":3,"score":0.0},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/jrs.1250260110","doi":"https://doi.org/10.1002/jrs.1250260110","is_oa":false,"landing_page_url":"https://doi.org/10.1002/jrs.1250260110","pdf_url":null,"source":{"id":"https://openalex.org/S4206644","display_name":"Journal of Raman Spectroscopy","issn_l":"0377-0486","issn":["0377-0486","1097-4555"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-b","jufo-1","norway-1","poland-70","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Raman Spectroscopy","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":17,"referenced_works":["https://openalex.org/W30782643","https://openalex.org/W223266329","https://openalex.org/W573813488","https://openalex.org/W1557681670","https://openalex.org/W1621980802","https://openalex.org/W1778532170","https://openalex.org/W1966261254","https://openalex.org/W1971787089","https://openalex.org/W1994654175","https://openalex.org/W2014738995","https://openalex.org/W2066365289","https://openalex.org/W2083901759","https://openalex.org/W2088149984","https://openalex.org/W2185670775","https://openalex.org/W2317782838","https://openalex.org/W2334063268","https://openalex.org/W2598183321"],"related_works":["https://openalex.org/W2887501166","https://openalex.org/W2051035824","https://openalex.org/W2088149984","https://openalex.org/W2029988217","https://openalex.org/W2894208856","https://openalex.org/W4220673770","https://openalex.org/W2538022235","https://openalex.org/W2073624034","https://openalex.org/W1981960831","https://openalex.org/W2036519967"],"abstract_inverted_index":{"Abstract":[0],"The":[1],"Raman":[2],"microprobe":[3,147],"spectra":[4,152],"of":[5,32,56,124,156,167],"natural":[6],"brookite":[7,16],"crystals":[8,206],"from":[9],"Switzerland":[10],"and":[11,13,38,89,96,110,119,126,132,136,188],"Brazil":[12],"a":[14,19,30,41,57],"synthetic":[15],"powder":[17],"exhibit":[18],"characteristic":[20],"intense":[21],"band":[22,31,43],"at":[23,35,100],"153":[24],"cm\u22121.":[25],"In":[26],"contrast,":[27],"anatase":[28],"has":[29],"similar":[33],"intensity":[34],"144":[36],"cm\u22121":[37,109,112,190],"rutile":[39],"lacks":[40],"strong":[42],"in":[44,128,138,162,191,204],"this":[45],"region.":[46],"Polarization":[47],"experiments":[48],"with":[49],"the":[50,129,139,163,192],"Brazilian":[51,130],"crystal":[52,131],"permit":[53],"17":[54],"out":[55],"predicted":[58],"36":[59],"vibrational":[60],"bands":[61,95,184],"to":[62,116,169,179],"be":[63],"readily":[64],"assigned":[65,115],"as":[66],"A1g":[67,120],"(127,":[68],"154,":[69],"194,":[70],"247,":[71],"412,":[72],"640":[73],"cm\u22121),":[74,82],"B1g":[75],"(133,":[76],"159,":[77],"215,":[78],"320,":[79],"415,":[80],"502":[81],"B2g":[83,118],"(366,":[84],"395,":[85],"463,":[86],"584":[87],"cm\u22121)":[88],"B3g":[90],"(452":[91],"cm\u22121).":[92],"Eight":[93],"weaker":[94],"component":[97],"sub\u2010bands":[98],"resolved":[99],"172,":[101],"287,":[102],"545,":[103],"618":[104],"cm\u22121,":[105],"254,":[106],"329,":[107],"476":[108],"497":[111],"are":[113,142,158],"tentatively":[114],"B3g,":[117],"modes":[121],"respectively.":[122],"Traces":[123],"Si":[125],"Fe":[127],"Si,":[133],"Fe,":[134],"Al":[135],"S":[137],"Swiss":[140],"sample":[141],"indicated":[143],"by":[144],"spot":[145],"electron":[146],"analysis.":[148],"Electron":[149],"spin":[150],"resonance":[151],"suggest":[153],"small":[154],"amounts":[155],"Fe3+":[157],"substituting":[159],"for":[160],"Ti4+":[161],"structure.":[164],"Concomitant":[165],"protonation":[166],"oxygens":[168],"maintain":[170],"charge":[171],"balance":[172],"yields":[173],"OH":[174],"groups":[175],"which":[176],"give":[177],"rise":[178],"three":[180],"sharp,":[181],"low\u2010intensity":[182],"absorption":[183],"near":[185],"3360,":[186],"3380":[187],"3404":[189],"infrared":[193],"spectra.":[194],"X\u2010ray":[195],"photoelectron":[196],"spectroscopy":[197],"shows":[198],"that":[199],"surface\u2010bound":[200],"OH/H2O":[201],"species":[202],"exist":[203],"both":[205],"but":[207],"no":[208],"detectable":[209],"Ti3+.":[210]},"counts_by_year":[{"year":2026,"cited_by_count":20},{"year":2025,"cited_by_count":25},{"year":2024,"cited_by_count":26},{"year":2023,"cited_by_count":26},{"year":2022,"cited_by_count":32},{"year":2021,"cited_by_count":25},{"year":2020,"cited_by_count":34},{"year":2019,"cited_by_count":26},{"year":2018,"cited_by_count":25},{"year":2017,"cited_by_count":20},{"year":2016,"cited_by_count":30},{"year":2015,"cited_by_count":24},{"year":2014,"cited_by_count":29},{"year":2013,"cited_by_count":30},{"year":2012,"cited_by_count":21}],"updated_date":"2026-11-11T12:16:26.678958","created_date":"2016-06-24T00:00:00"}