{"id":"https://openalex.org/W2016757099","doi":"https://doi.org/10.1080/15421406808082921","title":"On the Correlations Between Constitution and Scintillation Properties in the p-Oligophenylene Series","display_name":"On the Correlations Between Constitution and Scintillation Properties in the p-Oligophenylene Series","publication_year":1968,"publication_date":"1968-06-01","ids":{"openalex":"https://openalex.org/W2016757099","doi":"https://doi.org/10.1080/15421406808082921","mag":"2016757099"},"language":"en","primary_location":{"id":"doi:10.1080/15421406808082921","doi":"https://doi.org/10.1080/15421406808082921","is_oa":false,"landing_page_url":"https://doi.org/10.1080/15421406808082921","pdf_url":null,"source":{"id":"https://openalex.org/S4210195761","display_name":"Molecular Crystals","issn_l":"0369-1152","issn":["0369-1152"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Molecular Crystals","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5066875274","display_name":"Hermann Otto Wirth","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]},{"id":"https://openalex.org/I197323543","display_name":"Johannes Gutenberg University Mainz","ror":"https://ror.org/023b0x485","country_code":"DE","type":"education","lineage":["https://openalex.org/I197323543"]}],"countries":["DE","US"],"is_corresponding":false,"raw_author_name":"H. O. Wirth","raw_affiliation_strings":["University of Mainz, Germany ; Argonne National Laboratory, Argonne, Illinois","Argonne National Laboratory , Argonne, Illinois","University of Mainz ,  Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of Mainz, Germany ; Argonne National Laboratory, Argonne, Illinois","institution_ids":["https://openalex.org/I1282105669"]},{"raw_affiliation_string":"Argonne National Laboratory , Argonne, Illinois","institution_ids":["https://openalex.org/I1282105669"]},{"raw_affiliation_string":"University of Mainz ,  Germany","institution_ids":["https://openalex.org/I197323543"]}]},{"author_position":"middle","author":{"id":null,"display_name":"F. U. Herrmann","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I197323543","display_name":"Johannes Gutenberg University Mainz","ror":"https://ror.org/023b0x485","country_code":"DE","type":"education","lineage":["https://openalex.org/I197323543"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"F. U. Herrmann","raw_affiliation_strings":["University of Mainz, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of Mainz, Germany","institution_ids":["https://openalex.org/I197323543"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113589729","display_name":"Georg S. Herrmann","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I197323543","display_name":"Johannes Gutenberg University Mainz","ror":"https://ror.org/023b0x485","country_code":"DE","type":"education","lineage":["https://openalex.org/I197323543"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"G. Herrmann","raw_affiliation_strings":["University of Mainz, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of Mainz, Germany","institution_ids":["https://openalex.org/I197323543"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5035051099","display_name":"Werner Kern","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I197323543","display_name":"Johannes Gutenberg University Mainz","ror":"https://ror.org/023b0x485","country_code":"DE","type":"education","lineage":["https://openalex.org/I197323543"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"W. Kern","raw_affiliation_strings":["University of Mainz, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University of Mainz, Germany","institution_ids":["https://openalex.org/I197323543"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":3.2669,"has_fulltext":false,"cited_by_count":28,"citation_normalized_percentile":{"value":0.91255659,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":null,"biblio":{"volume":"4","issue":"1-4","first_page":"321","last_page":"342"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11216","display_name":"Radiation Detection and Scintillator Technologies","score":0.9907000064849854,"subfield":{"id":"https://openalex.org/subfields/3108","display_name":"Radiation"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11216","display_name":"Radiation Detection and Scintillator Technologies","score":0.9907000064849854,"subfield":{"id":"https://openalex.org/subfields/3108","display_name":"Radiation"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11240","display_name":"Luminescence and Fluorescent Materials","score":0.005900000222027302,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10045","display_name":"Organic Electronics and Photovoltaics","score":0.00039999998989515007,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/organic-scintillators","display_name":"organic scintillators","score":0.8980000019073486},{"id":"https://openalex.org/keywords/structure-property-relationships","display_name":"structure-property relationships","score":0.6159999966621399},{"id":"https://openalex.org/keywords/solubility","display_name":"solubility","score":0.7080000042915344},{"id":"https://openalex.org/keywords/light-yield","display_name":"light yield","score":0.7279999852180481},{"id":"https://openalex.org/keywords/degree-of-condensation","display_name":"degree of condensation","score":0.878000020980835},{"id":"https://openalex.org/keywords/decay-time","display_name":"decay time","score":0.8539999723434448},{"id":"https://openalex.org/keywords/stokes-shift","display_name":"Stokes shift","score":0.9539999961853027},{"id":"https://openalex.org/keywords/optical-transparency","display_name":"optical transparency","score":0.6600000262260437},{"id":"https://openalex.org/keywords/pyrene","display_name":"pyrene","score":0.6169999837875366},{"id":"https://openalex.org/keywords/fluoranthene","display_name":"fluoranthene","score":0.9980000257492065},{"id":"https://openalex.org/keywords/photomultiplier-response","display_name":"photomultiplier response","score":0.49799999594688416}],"concepts":[{"id":"https://openalex.org/C155574463","wikidata":"https://www.wikidata.org/wiki/Q170731","display_name":"Solubility","level":2,"score":0.7862879633903503},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.7547078132629395},{"id":"https://openalex.org/C161694136","wikidata":"https://www.wikidata.org/wiki/Q910990","display_name":"Scintillator","level":3,"score":0.6780601143836975},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5652879476547241},{"id":"https://openalex.org/C2776482079","wikidata":"https://www.wikidata.org/wiki/Q741844","display_name":"Homologous series","level":2,"score":0.5511656403541565},{"id":"https://openalex.org/C20625954","wikidata":"https://www.wikidata.org/wiki/Q543533","display_name":"Coplanarity","level":2,"score":0.43437764048576355},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.3465683162212372},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.27177006006240845},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.17559602856636047},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.13893011212348938},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.08569914102554321},{"id":"https://openalex.org/C94915269","wikidata":"https://www.wikidata.org/wiki/Q1834857","display_name":"Detector","level":2,"score":0.0},{"id":"https://openalex.org/C2524010","wikidata":"https://www.wikidata.org/wiki/Q8087","display_name":"Geometry","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1080/15421406808082921","doi":"https://doi.org/10.1080/15421406808082921","is_oa":false,"landing_page_url":"https://doi.org/10.1080/15421406808082921","pdf_url":null,"source":{"id":"https://openalex.org/S4210195761","display_name":"Molecular Crystals","issn_l":"0369-1152","issn":["0369-1152"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Molecular Crystals","raw_type":"journal-article"},{"id":"pmh:oai:CiteSeerX.psu:10.1.1.504.4112","doi":null,"is_oa":false,"landing_page_url":"http://citeseerx.ist.psu.edu/viewdoc/summary?doi=10.1.1.504.4112","pdf_url":null,"source":null,"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"http://www.lsc-international.org/conf/pfiles/lsc1966_321.pdf","raw_type":"text"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":10,"referenced_works":["https://openalex.org/W51972368","https://openalex.org/W641589660","https://openalex.org/W1514401155","https://openalex.org/W1563819617","https://openalex.org/W2063716714","https://openalex.org/W2082768166","https://openalex.org/W2110676221","https://openalex.org/W2171120672","https://openalex.org/W2332813060","https://openalex.org/W6861729373"],"related_works":["https://openalex.org/W7096839236","https://openalex.org/W2089653355","https://openalex.org/W2073918677","https://openalex.org/W2037896135","https://openalex.org/W192906380","https://openalex.org/W1982244079","https://openalex.org/W2038186914","https://openalex.org/W435692866","https://openalex.org/W201641272","https://openalex.org/W1632975111"],"abstract_inverted_index":{"The":[0,221,428],"paper":[1],"deals":[2],"with":[3,148,186,195,245,270],"the":[4,33,53,130,179,182,187,196,212,234,237,242,250,255,265,271,275,283,323,326,331,346,349,373,398,425,434,437,445,449],"problem:":[5],"What":[6],"properties":[7],"are":[8,19,258],"requested":[9],"from":[10,136],"an":[11],"organic":[12,58,161],"scintillator":[13,59,403],"solute":[14,60],"and":[15,40,252,362],"what":[16],"structural":[17],"principles":[18],"given":[20],"to":[21,26,37,44,113,232,281,342,390,395,410,423],"realize,":[22],"or":[23,46,296,441],"at":[24,32],"least":[25],"influence":[27],"them":[28],"especially":[29,309],"by":[30],"looking":[31],"p-oligophenylene":[34,243,324,374],"series?":[35],"According":[36],"their":[38],"importance":[39],"also":[41,141,254],"in":[42,66,116,142,158,217,226,230,268,310,345,381],"respect":[43],"more":[45],"less":[47],"special":[48],"purposes":[49],"one":[50,435],"can":[51,110,163,302,337],"distinguish":[52],"following":[54],"sequence:":[55],"1)":[56],"An":[57],"must":[61],"have":[62,406],"a":[63,77,92,170,215,227,314,368,392,407],"sufficient":[64],"solubility":[65,140,156,439],"all":[67,155,411],"types":[68,151,412],"of":[69,79,84,96,100,121,132,152,175,189,192,236,248,264,274,285,319,333,386,413],"solvents":[70],"used":[71,239],"for":[72,127],"this":[73],"counting":[74],"method.":[75],"As":[76],"result":[78],"extensive":[80],"systematic":[81],"studies":[82],"substitution":[83,120],"larger":[85],"alkyl":[86,122,387],"groups":[87,123,134,388],"has":[88],"been":[89],"recognized":[90],"as":[91,294,330],"very":[93,298],"effective":[94,126],"principle":[95],"solubilization.":[97],"By":[98,288],"use":[99,131],"branched,":[101],"particularly":[102],"long-chain":[103],"branched":[104],"groups,":[105,430],"even":[106,442],"extremely":[107],"insoluble":[108],"substances":[109],"be":[111,164,202,225,303,338,391],"solubilized":[112],"any":[114,168],"extent":[115],"homopolar":[117],"solvents.":[118,144],"While":[119],"is":[124,174,279,318,377,419],"only":[125,420],"nonpolar":[128],"solvents,":[129],"oxa-alkyl":[133],"(derived":[135],"ethylene":[137],"oxide)":[138],"affords":[139],"polar":[143],"It":[145],"seems":[146,389],"that":[147],"these":[149,382],"two":[150,383],"substituents":[153],"almost":[154,378],"problems":[157],"low":[159,408],"molecular":[160],"chemistry":[162],"solved.":[165],"2)":[166],"In":[167,178,241,372],"case":[169],"high":[171,311,369],"light":[172,199,218],"output":[173],"greatest":[176,320],"importance.":[177],"p-coligo-phenylene":[180],"series":[181,244,325,375],"scintillation":[183],"efficiency":[184],"increases":[185],"degree":[188,247,332],"condensation":[190,334],"(number":[191],"rings).":[193],"Thus,":[194],"higher":[197,276],"homologs":[198,277],"yields":[200],"could":[201],"obtained":[203],"which":[204],"were":[205],"unknown":[206],"up":[207],"until":[208],"now.":[209],"Substituents":[210],"disturbing":[211],"coplanarity":[213],"cause":[214],"decrease":[216],"output.":[219],"3)":[220],"fluorescence":[222,256,300,363],"wavelengths":[223,301],"should":[224,405],"favorable":[228],"range":[229,284],"order":[231],"match":[233],"response":[235],"commonly":[238],"phototubes.":[240],"increasing":[246],"condensations":[249],"absorption":[251,361],"therefore":[253],"bands":[257],"shifted":[259],"into":[260],"longer":[261],"wavelengths.":[262],"Because":[263],"convergency":[266],"phenomena":[267],"connection":[269],"lower":[272],"accessibility":[273],"it":[278,418],"difficult":[280],"reach":[282],"400":[286],"mp.":[287],"introducing":[289],"other":[290,450],"chromophoric":[291],"systems,":[292],"such":[293],"pyrene":[295],"fluoranthene,":[297],"long":[299],"established.":[304],"4)":[305],"For":[306,322],"many":[307],"measurements,":[308],"energy":[312],"physics,":[313],"short":[315],"decay":[316,327],"time":[317,328],"interest.":[321],"decreases":[329],"increases.":[335,353],"This":[336],"easily":[339],"understood,":[340],"according":[341],"Forster,":[343],"since":[344],"same":[347],"direction":[348],"molar":[350],"extinction":[351],"coefficient":[352],"5)":[354],"A":[355],"large":[356],"mean":[357],"free":[358],"path":[359],"between":[360],"band":[364],"(Stokes":[365],"shift)":[366],"guarantees":[367],"optical":[370],"transparency.":[371],"there":[376],"no":[379],"overlap":[380],"bands.":[384],"Substitution":[385],"generalizable":[393],"provision":[394],"further":[396],"enhance":[397],"Stokes":[399],"shift.":[400],"6)":[401],"Organic":[402],"solutes":[404],"sensitivity":[409],"quenching":[414,447],"processes.":[415],"So":[416],"far,":[417],"known":[421],"how":[422],"eliminate":[424],"self":[426,446],"quenching.":[427],"solubilization":[429],"namely,":[431],"affording":[432],"on":[433,448],"hand":[436],"necessary":[438],"seduce,":[440],"completely":[443],"exclude,":[444],"hand.":[451]},"counts_by_year":[],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}