{"id":"https://openalex.org/W2016558696","doi":"https://doi.org/10.1134/s1990793113040088","title":"On the equilibrium of peroxy radicals in the oxidation of 2-propanol by molecular oxygen","display_name":"On the equilibrium of peroxy radicals in the oxidation of 2-propanol by molecular oxygen","publication_year":2013,"publication_date":"2013-07-01","ids":{"openalex":"https://openalex.org/W2016558696","doi":"https://doi.org/10.1134/s1990793113040088","mag":"2016558696"},"language":"en","primary_location":{"id":"doi:10.1134/s1990793113040088","doi":"https://doi.org/10.1134/s1990793113040088","is_oa":false,"landing_page_url":"https://doi.org/10.1134/s1990793113040088","pdf_url":null,"source":{"id":"https://openalex.org/S42965947","display_name":"Russian Journal of Physical Chemistry B","issn_l":"1990-7923","issn":["1990-7923","1990-7931"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":["dongbi-c","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320267","host_organization_name":"Pleiades Publishing","host_organization_lineage":["https://openalex.org/P4310320267","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Pleiades Publishing","Springer Nature"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Russian Journal of Physical Chemistry B","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5043906026","display_name":"E. G. Moskvitina","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I45791419","display_name":"Kuzbass State Technical University","ror":"https://ror.org/02hfhf494","country_code":"RU","type":"education","lineage":["https://openalex.org/I45791419"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"E. G. Moskvitina","raw_affiliation_strings":["Gorbachev Kuzbass State Technical University, Kemerovo, Russia","Gorbachev Kuzbass State Technical University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Gorbachev Kuzbass State Technical University, Kemerovo, Russia","institution_ids":["https://openalex.org/I45791419"]},{"raw_affiliation_string":"Gorbachev Kuzbass State Technical University","institution_ids":["https://openalex.org/I45791419"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5018595107","display_name":"\u0418. \u041c. \u0411\u043e\u0440\u0438\u0441\u043e\u0432","orcid":"https://orcid.org/0000-0003-2347-7306","observed_orcids":["https://orcid.org/0000-0003-2347-7306"]},"institutions":[{"id":"https://openalex.org/I4210154985","display_name":"M. Akmullah Bashkir State Pedagogical University","ror":"https://ror.org/05qcjpk30","country_code":"RU","type":"education","lineage":["https://openalex.org/I4210154985"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"I. M. Borisov","raw_affiliation_strings":["Akmullah Bashkir State Pedagogical University, Ufa, Russia","Akmullah Bashkir State Pedagogical University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Akmullah Bashkir State Pedagogical University, Ufa, Russia","institution_ids":["https://openalex.org/I4210154985"]},{"raw_affiliation_string":"Akmullah Bashkir State Pedagogical University","institution_ids":["https://openalex.org/I4210154985"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5006970118","display_name":"Sergey V. Puchkov","orcid":"https://orcid.org/0000-0001-8699-5448","observed_orcids":["https://orcid.org/0000-0001-8699-5448"]},"institutions":[{"id":"https://openalex.org/I45791419","display_name":"Kuzbass State Technical University","ror":"https://ror.org/02hfhf494","country_code":"RU","type":"education","lineage":["https://openalex.org/I45791419"]}],"countries":["RU"],"is_corresponding":true,"raw_author_name":"S. V. Puchkov","raw_affiliation_strings":["Gorbachev Kuzbass State Technical University, Kemerovo, Russia","Gorbachev Kuzbass State Technical University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Gorbachev Kuzbass State Technical University, Kemerovo, Russia","institution_ids":["https://openalex.org/I45791419"]},{"raw_affiliation_string":"Gorbachev Kuzbass State Technical University","institution_ids":["https://openalex.org/I45791419"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5068373066","display_name":"\u0410. \u041b. \u041f\u0435\u0440\u043a\u0435\u043b\u044c","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I45791419","display_name":"Kuzbass State Technical University","ror":"https://ror.org/02hfhf494","country_code":"RU","type":"education","lineage":["https://openalex.org/I45791419"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"A. L. Perkel\u2019","raw_affiliation_strings":["Gorbachev Kuzbass State Technical University, Kemerovo, Russia","Gorbachev Kuzbass State Technical University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Gorbachev Kuzbass State Technical University, Kemerovo, Russia","institution_ids":["https://openalex.org/I45791419"]},{"raw_affiliation_string":"Gorbachev Kuzbass State Technical University","institution_ids":["https://openalex.org/I45791419"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5006970118"],"corresponding_institution_ids":["https://openalex.org/I45791419"],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":2,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":93},"biblio":{"volume":"7","issue":"4","first_page":"407","last_page":"409"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10117","display_name":"Advanced Combustion Engine Technologies","score":0.5814999938011169,"subfield":{"id":"https://openalex.org/subfields/1507","display_name":"Fluid Flow and Transfer Processes"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10117","display_name":"Advanced Combustion Engine Technologies","score":0.5814999938011169,"subfield":{"id":"https://openalex.org/subfields/1507","display_name":"Fluid Flow and Transfer Processes"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13013","display_name":"Free Radicals and Antioxidants","score":0.27250000834465027,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.02969999983906746,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/peroxyl-radicals","display_name":"peroxy radicals","score":0.9369999766349792},{"id":"https://openalex.org/keywords/2-propanol-oxidation","display_name":"2-propanol oxidation","score":0.9670000076293945},{"id":"https://openalex.org/keywords/molecular-oxygen","display_name":"molecular oxygen","score":0.6940000057220459},{"id":"https://openalex.org/keywords/hydroperoxyl-radical","display_name":"hydroperoxyl radical","score":0.7570000290870667},{"id":"https://openalex.org/keywords/rate-constants","display_name":"rate constants","score":0.5130000114440918}],"concepts":[{"id":"https://openalex.org/C139066938","wikidata":"https://www.wikidata.org/wiki/Q185056","display_name":"Radical","level":2,"score":0.9224367141723633},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8494781255722046},{"id":"https://openalex.org/C2779887276","wikidata":"https://www.wikidata.org/wiki/Q423679","display_name":"Azobisisobutyronitrile","level":4,"score":0.7290917634963989},{"id":"https://openalex.org/C10710636","wikidata":"https://www.wikidata.org/wiki/Q857809","display_name":"Equilibrium constant","level":2,"score":0.5989996194839478},{"id":"https://openalex.org/C2778292535","wikidata":"https://www.wikidata.org/wiki/Q3407542","display_name":"Propanol","level":3,"score":0.5643024444580078},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.5491318106651306},{"id":"https://openalex.org/C540031477","wikidata":"https://www.wikidata.org/wiki/Q629","display_name":"Oxygen","level":2,"score":0.5196384191513062},{"id":"https://openalex.org/C93391505","wikidata":"https://www.wikidata.org/wiki/Q658700","display_name":"Reaction rate constant","level":3,"score":0.4760284721851349},{"id":"https://openalex.org/C2781066024","wikidata":"https://www.wikidata.org/wiki/Q156","display_name":"Alcohol","level":2,"score":0.45026659965515137},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.27256160974502563},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.2598860263824463},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.23457562923431396},{"id":"https://openalex.org/C2779607525","wikidata":"https://www.wikidata.org/wiki/Q14982","display_name":"Methanol","level":2,"score":0.1938088834285736},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1134/s1990793113040088","doi":"https://doi.org/10.1134/s1990793113040088","is_oa":false,"landing_page_url":"https://doi.org/10.1134/s1990793113040088","pdf_url":null,"source":{"id":"https://openalex.org/S42965947","display_name":"Russian Journal of Physical Chemistry B","issn_l":"1990-7923","issn":["1990-7923","1990-7931"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":["dongbi-c","poland-40","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320267","host_organization_name":"Pleiades Publishing","host_organization_lineage":["https://openalex.org/P4310320267","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Pleiades Publishing","Springer Nature"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Russian Journal of Physical Chemistry B","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":4,"referenced_works":["https://openalex.org/W86314487","https://openalex.org/W184442239","https://openalex.org/W2129885650","https://openalex.org/W2322867583"],"related_works":["https://openalex.org/W2325715377","https://openalex.org/W2080762195","https://openalex.org/W2093011723","https://openalex.org/W1985172792","https://openalex.org/W2059240246","https://openalex.org/W2129885650","https://openalex.org/W2090730679","https://openalex.org/W1975470382","https://openalex.org/W2353495781","https://openalex.org/W2122593145"],"abstract_inverted_index":{"Based":[0],"on":[1],"kinetic":[2],"data,":[3],"it":[4],"is":[5,27,37,59],"demonstrated":[6],"that":[7,29],"the":[8,17,30,34,41,51,54],"1-hydroxy-1-methylethylperoxyl":[9],"and":[10],"hydroperoxy":[11,55],"radicals":[12,36],"are":[13],"at":[14,21],"equilibrium":[15,31],"in":[16],"oxidation":[18],"of":[19,32,44,50,53],"2-propanol":[20,58],"323\u00b0C":[22],"initiated":[23],"by":[24],"azobisisobutyronitrile.":[25],"It":[26],"shown":[28],"between":[33],"peroxy":[35],"not":[38],"disturbed":[39],"within":[40],"covered":[42],"range":[43],"alcohol":[45],"concentrations.":[46],"The":[47],"rate":[48],"constants":[49],"reaction":[52],"radical":[56],"with":[57],"determined:":[60],"k":[61],"2.2":[62],"=":[63],"(0.13":[64],"\u00b1":[65],"0.04)":[66],"L":[67],"mol\u22121":[68],"s\u22121.":[69]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2019,"cited_by_count":1}],"updated_date":"2026-10-02T10:15:12.560889","created_date":"2016-06-24T00:00:00"}