{"id":"https://openalex.org/W2016498484","doi":"https://doi.org/10.1002/elan.200603719","title":"Electrocatalytic Reduction of HNO2 by a Silicomolybdate Polyanion: A Differential Electrochemical Mass Spectrometry Study","display_name":"Electrocatalytic Reduction of HNO2 by a Silicomolybdate Polyanion: A Differential Electrochemical Mass Spectrometry Study","publication_year":2007,"publication_date":"2007-01-01","ids":{"openalex":"https://openalex.org/W2016498484","doi":"https://doi.org/10.1002/elan.200603719","mag":"2016498484"},"language":"en","primary_location":{"id":"doi:10.1002/elan.200603719","doi":"https://doi.org/10.1002/elan.200603719","is_oa":false,"landing_page_url":"https://doi.org/10.1002/elan.200603719","pdf_url":null,"source":{"id":"https://openalex.org/S79832926","display_name":"Electroanalysis","issn_l":"1040-0397","issn":["1040-0397","1521-4109"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Electroanalysis","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5013981529","display_name":"Catherine Debiemme\u2010Chouvy","orcid":"https://orcid.org/0000-0001-7171-6039","observed_orcids":["https://orcid.org/0000-0001-7171-6039"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210092467","display_name":"Laboratoire Interfaces et Syst\u00e8mes \u00c9lectrochimiques","ror":"https://ror.org/00jb20a14","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I39804081","https://openalex.org/I4210092467","https://openalex.org/I4210128300"]},{"id":"https://openalex.org/I4405264447","display_name":"Universit\u00e9 Pierre-et-Marie-Curie","ror":"https://ror.org/01yvrd251","country_code":"FR","type":"education","lineage":["https://openalex.org/I39804081","https://openalex.org/I4405264447"]}],"countries":["FR"],"is_corresponding":true,"raw_author_name":"Catherine Debiemme\u2010Chouvy","raw_affiliation_strings":["Laboratoire Interfaces et Syste\u0300mes Electrochimiques, UPR15 du CNRS, Universite\u0301 Pierre et Marie Curie, Case courrier 133, 4, place Jussieu, 75252 Paris cedex 05, France","Laboratoire Interfaces et Syst\u00e8mes Electrochimiques, UPR15 du CNRS, Universit\u00e9 Pierre et Marie Curie, Case courrier 133, 4, place Jussieu, 75252\u2005Paris cedex 05, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire Interfaces et Syste\u0300mes Electrochimiques, UPR15 du CNRS, Universite\u0301 Pierre et Marie Curie, Case courrier 133, 4, place Jussieu, 75252 Paris cedex 05, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210092467","https://openalex.org/I4405264447"]},{"raw_affiliation_string":"Laboratoire Interfaces et Syst\u00e8mes Electrochimiques, UPR15 du CNRS, Universit\u00e9 Pierre et Marie Curie, Case courrier 133, 4, place Jussieu, 75252\u2005Paris cedex 05, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210092467","https://openalex.org/I4405264447"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5003208252","display_name":"Hubert Cachet","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210092467","display_name":"Laboratoire Interfaces et Syst\u00e8mes \u00c9lectrochimiques","ror":"https://ror.org/00jb20a14","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I39804081","https://openalex.org/I4210092467","https://openalex.org/I4210128300"]},{"id":"https://openalex.org/I4405264447","display_name":"Universit\u00e9 Pierre-et-Marie-Curie","ror":"https://ror.org/01yvrd251","country_code":"FR","type":"education","lineage":["https://openalex.org/I39804081","https://openalex.org/I4405264447"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Hubert Cachet","raw_affiliation_strings":["Laboratoire Interfaces et Syste\u0300mes Electrochimiques, UPR15 du CNRS, Universite\u0301 Pierre et Marie Curie, Case courrier 133, 4, place Jussieu, 75252 Paris cedex 05, France","Laboratoire Interfaces et Syst\u00e8mes Electrochimiques, UPR15 du CNRS, Universit\u00e9 Pierre et Marie Curie, Case courrier 133, 4, place Jussieu, 75252\u2005Paris cedex 05, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire Interfaces et Syste\u0300mes Electrochimiques, UPR15 du CNRS, Universite\u0301 Pierre et Marie Curie, Case courrier 133, 4, place Jussieu, 75252 Paris cedex 05, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210092467","https://openalex.org/I4405264447"]},{"raw_affiliation_string":"Laboratoire Interfaces et Syst\u00e8mes Electrochimiques, UPR15 du CNRS, Universit\u00e9 Pierre et Marie Curie, Case courrier 133, 4, place Jussieu, 75252\u2005Paris cedex 05, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210092467","https://openalex.org/I4405264447"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5034237360","display_name":"Guy Folcher","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210092467","display_name":"Laboratoire Interfaces et Syst\u00e8mes \u00c9lectrochimiques","ror":"https://ror.org/00jb20a14","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I39804081","https://openalex.org/I4210092467","https://openalex.org/I4210128300"]},{"id":"https://openalex.org/I4405264447","display_name":"Universit\u00e9 Pierre-et-Marie-Curie","ror":"https://ror.org/01yvrd251","country_code":"FR","type":"education","lineage":["https://openalex.org/I39804081","https://openalex.org/I4405264447"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Guy Folcher","raw_affiliation_strings":["Laboratoire Interfaces et Syste\u0300mes Electrochimiques, UPR15 du CNRS, Universite\u0301 Pierre et Marie Curie, Case courrier 133, 4, place Jussieu, 75252 Paris cedex 05, France","Laboratoire Interfaces et Syst\u00e8mes Electrochimiques, UPR15 du CNRS, Universit\u00e9 Pierre et Marie Curie, Case courrier 133, 4, place Jussieu, 75252\u2005Paris cedex 05, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire Interfaces et Syste\u0300mes Electrochimiques, UPR15 du CNRS, Universite\u0301 Pierre et Marie Curie, Case courrier 133, 4, place Jussieu, 75252 Paris cedex 05, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210092467","https://openalex.org/I4405264447"]},{"raw_affiliation_string":"Laboratoire Interfaces et Syst\u00e8mes Electrochimiques, UPR15 du CNRS, Universit\u00e9 Pierre et Marie Curie, Case courrier 133, 4, place Jussieu, 75252\u2005Paris cedex 05, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210092467","https://openalex.org/I4405264447"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5106082495","display_name":"C. Deslouis","orcid":"https://orcid.org/0000-0002-4174-6146","observed_orcids":["https://orcid.org/0000-0002-4174-6146"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210092467","display_name":"Laboratoire Interfaces et Syst\u00e8mes \u00c9lectrochimiques","ror":"https://ror.org/00jb20a14","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I39804081","https://openalex.org/I4210092467","https://openalex.org/I4210128300"]},{"id":"https://openalex.org/I4405264447","display_name":"Universit\u00e9 Pierre-et-Marie-Curie","ror":"https://ror.org/01yvrd251","country_code":"FR","type":"education","lineage":["https://openalex.org/I39804081","https://openalex.org/I4405264447"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Claude Deslouis","raw_affiliation_strings":["Laboratoire Interfaces et Syste\u0300mes Electrochimiques, UPR15 du CNRS, Universite\u0301 Pierre et Marie Curie, Case courrier 133, 4, place Jussieu, 75252 Paris cedex 05, France","Laboratoire Interfaces et Syst\u00e8mes Electrochimiques, UPR15 du CNRS, Universit\u00e9 Pierre et Marie Curie, Case courrier 133, 4, place Jussieu, 75252\u2005Paris cedex 05, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire Interfaces et Syste\u0300mes Electrochimiques, UPR15 du CNRS, Universite\u0301 Pierre et Marie Curie, Case courrier 133, 4, place Jussieu, 75252 Paris cedex 05, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210092467","https://openalex.org/I4405264447"]},{"raw_affiliation_string":"Laboratoire Interfaces et Syst\u00e8mes Electrochimiques, UPR15 du CNRS, Universit\u00e9 Pierre et Marie Curie, Case courrier 133, 4, place Jussieu, 75252\u2005Paris cedex 05, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210092467","https://openalex.org/I4405264447"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5013981529"],"corresponding_institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210092467","https://openalex.org/I4405264447"],"apc_list":{"value":3800,"currency":"USD","value_usd":3800},"apc_paid":null,"fwci":0.5155,"has_fulltext":false,"cited_by_count":11,"citation_normalized_percentile":{"value":0.58780233,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":95},"biblio":{"volume":"19","issue":"2-3","first_page":"259","last_page":"262"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11286","display_name":"Polyoxometalates: Synthesis and Applications","score":0.8496000170707703,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11286","display_name":"Polyoxometalates: Synthesis and Applications","score":0.8496000170707703,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10660","display_name":"Conducting polymers and applications","score":0.08669999986886978,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10212","display_name":"Electrochemical sensors and biosensors","score":0.02539999969303608,"subfield":{"id":"https://openalex.org/subfields/1602","display_name":"Analytical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/silicomolybdate","display_name":"silicomolybdate","score":0.7179999947547913},{"id":"https://openalex.org/keywords/keggin-heteropolyanions","display_name":"Keggin heteropolyanions","score":0.8059999942779541},{"id":"https://openalex.org/keywords/polypyrrole-films","display_name":"polypyrrole films","score":0.8659999966621399},{"id":"https://openalex.org/keywords/conducting-polymer-electrodes","display_name":"conducting polymer electrodes","score":0.7049999833106995},{"id":"https://openalex.org/keywords/amperometric-sensor","display_name":"amperometric sensor","score":0.7689999938011169},{"id":"https://openalex.org/keywords/electrocatalysis","display_name":"electrocatalysis","score":0.7739999890327454},{"id":"https://openalex.org/keywords/differential-electrochemical-mass-spectrometry","display_name":"differential electrochemical mass spectrometry","score":0.7950000166893005}],"concepts":[{"id":"https://openalex.org/C2777232022","wikidata":"https://www.wikidata.org/wiki/Q146230","display_name":"Polypyrrole","level":4,"score":0.8316765427589417},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7209985256195068},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.6522279977798462},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.5593671202659607},{"id":"https://openalex.org/C533411734","wikidata":"https://www.wikidata.org/wiki/Q171877","display_name":"Hydrogen peroxide","level":2,"score":0.5332068800926208},{"id":"https://openalex.org/C17365422","wikidata":"https://www.wikidata.org/wiki/Q664231","display_name":"Disproportionation","level":3,"score":0.5152723789215088},{"id":"https://openalex.org/C162356407","wikidata":"https://www.wikidata.org/wiki/Q180809","display_name":"Mass spectrometry","level":2,"score":0.4929237365722656},{"id":"https://openalex.org/C2776419827","wikidata":"https://www.wikidata.org/wiki/Q211891","display_name":"Nitrous acid","level":2,"score":0.4861564338207245},{"id":"https://openalex.org/C33989665","wikidata":"https://www.wikidata.org/wiki/Q5357962","display_name":"Electrocatalyst","level":4,"score":0.47295114398002625},{"id":"https://openalex.org/C139369640","wikidata":"https://www.wikidata.org/wiki/Q474536","display_name":"Amperometry","level":4,"score":0.4274919629096985},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.19164496660232544},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.14600062370300293},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.14161357283592224},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.11401775479316711},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.07398083806037903}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1002/elan.200603719","doi":"https://doi.org/10.1002/elan.200603719","is_oa":false,"landing_page_url":"https://doi.org/10.1002/elan.200603719","pdf_url":null,"source":{"id":"https://openalex.org/S79832926","display_name":"Electroanalysis","issn_l":"1040-0397","issn":["1040-0397","1521-4109"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Electroanalysis","raw_type":"journal-article"},{"id":"pmh:oai:HAL:hal-04144658v1","doi":null,"is_oa":false,"landing_page_url":"https://cnrs.hal.science/hal-04144658","pdf_url":null,"source":{"id":"https://openalex.org/S4306402512","display_name":"HAL","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4405252976","host_organization_name":"Centre pour la Communication Scientifique Directe","host_organization_lineage":["https://openalex.org/I4405252976"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Electroanalysis, 2007, 19 (2-3), pp.259-262. ⟨10.1002/elan.200603719⟩","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G2539733795","display_name":"D\u00e9veloppement d'un capteur simple et \u00e9conomique pour la mesure en continu et in situ de la teneur en nitrate dans les eaux","funder_award_id":"ANR-06-ECOT-0014","funder_id":"https://openalex.org/F4320320883","funder_display_name":"Agence Nationale de la Recherche"}],"funders":[{"id":"https://openalex.org/F4320320883","display_name":"Agence Nationale de la Recherche","ror":"https://ror.org/00rbzpz17"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":28,"referenced_works":["https://openalex.org/W195922216","https://openalex.org/W598559683","https://openalex.org/W1967309570","https://openalex.org/W1983187344","https://openalex.org/W1986080499","https://openalex.org/W1986657101","https://openalex.org/W1995562839","https://openalex.org/W1997543870","https://openalex.org/W1997728221","https://openalex.org/W2000299071","https://openalex.org/W2001117026","https://openalex.org/W2007319287","https://openalex.org/W2008224594","https://openalex.org/W2021518564","https://openalex.org/W2025515829","https://openalex.org/W2026506384","https://openalex.org/W2030896351","https://openalex.org/W2053131937","https://openalex.org/W2057664733","https://openalex.org/W2058205960","https://openalex.org/W2062664090","https://openalex.org/W2063432034","https://openalex.org/W2067836547","https://openalex.org/W2087079549","https://openalex.org/W2094182825","https://openalex.org/W2095179230","https://openalex.org/W2119259348","https://openalex.org/W2159192786"],"related_works":["https://openalex.org/W4200253169","https://openalex.org/W4392820422","https://openalex.org/W2000299071","https://openalex.org/W2606479339","https://openalex.org/W2024816099","https://openalex.org/W2375881170","https://openalex.org/W1981608655","https://openalex.org/W2035486812","https://openalex.org/W2161262616","https://openalex.org/W1987892272"],"abstract_inverted_index":{"Abstract":[0],"Electrocatalytic":[1],"activities":[2],"towards":[3],"the":[4,27,36,43,54,66,87,95,107,130,149,155],"reduction":[5,113],"of":[6,29,56,81,157],"important":[7],"analytes":[8],"such":[9],"as":[10,78],"nitrite,":[11],"bromate,":[12],"chlorate":[13],"and":[14,41,72,125,148],"hydrogen":[15],"peroxide":[16],"have":[17],"been":[18],"demonstrated":[19],"for":[20],"numerous":[21],"heteropolyanions":[22],"(HPAs).":[23],"In":[24],"this":[25],"paper,":[26],"behavior":[28],"a":[30,48,143],"Keggin\u2010type":[31],"HPA,":[32],"SiMo12O":[33,71,126,138],",":[34],"on":[35,42],"one":[37],"hand":[38,45],"in":[39,47,53,129,142],"solution":[40],"other":[44],"immobilized":[46,141],"conducting":[49],"polymer,":[50],"polypyrrole":[51],"(PPy),":[52],"presence":[55],"nitrous":[57,111],"acid":[58,112],"(HNO2)":[59],"is":[60,63,89,134],"examined.":[61],"It":[62],"shown":[64],"that":[65],"PPy":[67,96,144],"films":[68],"codoped":[69],"with":[70],"HSO":[73],"ions":[74,139],"could":[75],"be":[76],"used":[77,104],"sensitive":[79],"part":[80],"an":[82,118],"amperometric":[83],"sensor":[84],"even":[85],"if":[86],"response":[88],"limited":[90],"by":[91,114],"HNO2":[92,124],"diffusion":[93],"into":[94],"film.":[97],"Differential":[98],"electrochemical":[99],"mass":[100],"spectrometry":[101],"(DEMS)":[102],"was":[103],"to":[105,154],"determine":[106],"gas":[108,133],"formed":[109],"during":[110],"H2SiMo12O":[115],".":[116],"Under":[117],"applied":[119],"cathodic":[120],"potential,":[121],"when":[122,137],"both":[123],"are":[127,140],"present":[128],"medium,":[131],"NO":[132,150],"produced":[135],"whereas,":[136],"film,":[145],"N2O":[146],"evolves":[147],"concentration,":[151],"notably":[152],"due":[153],"disproportionation":[156],"HNO2,":[158],"decreases.":[159]},"counts_by_year":[{"year":2024,"cited_by_count":2},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":1},{"year":2016,"cited_by_count":1},{"year":2013,"cited_by_count":1}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}