{"id":"https://openalex.org/W2016335125","doi":"https://doi.org/10.1039/b612580h","title":"Ring-opening polymerization of 3,6-dimethyl-2,5-morpholinedione with discrete amino-alkoxy-bis(phenolate) yttrium initiators: mechanistic insights","display_name":"Ring-opening polymerization of 3,6-dimethyl-2,5-morpholinedione with discrete amino-alkoxy-bis(phenolate) yttrium initiators: mechanistic insights","publication_year":2006,"publication_date":"2006-01-01","ids":{"openalex":"https://openalex.org/W2016335125","doi":"https://doi.org/10.1039/b612580h","mag":"2016335125","pmid":"https://pubmed.ncbi.nlm.nih.gov/17283801"},"language":"en","primary_location":{"id":"doi:10.1039/b612580h","doi":"https://doi.org/10.1039/b612580h","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b612580h","pdf_url":null,"source":{"id":"https://openalex.org/S152760256","display_name":"Chemical Communications","issn_l":"1359-7345","issn":["1359-7345","1364-548X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemical Communications","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5083948720","display_name":"Pascal M. Castro","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210090783","display_name":"Institut des Sciences Chimiques de Rennes","ror":"https://ror.org/00adwkx90","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I28221208","https://openalex.org/I4210090783","https://openalex.org/I4210115835","https://openalex.org/I4210128300","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I4405258264","display_name":"Universit\u00e9 Rennes 1","ror":"https://ror.org/00crteh33","country_code":"FR","type":"education","lineage":["https://openalex.org/I4405258264","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I56067802","display_name":"Universit\u00e9 de Rennes","ror":"https://ror.org/015m7wh34","country_code":"FR","type":"education","lineage":["https://openalex.org/I56067802"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Pascal M. Castro","raw_affiliation_strings":["Laboratoire Organom\u00e9talliques et Catalyse, UMR 6226 Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex. jean-francois.carpentier@univ-rennes1.fr","Laboratoire Organom\u00e9talliques et Catalyse, UMR 6226 Universit\u00e9 de Rennes 1, Campus de Beaulieu,35042 Rennes Cedex,"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire Organom\u00e9talliques et Catalyse, UMR 6226 Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex. jean-francois.carpentier@univ-rennes1.fr","institution_ids":["https://openalex.org/I4210090783","https://openalex.org/I4405258264","https://openalex.org/I56067802"]},{"raw_affiliation_string":"Laboratoire Organom\u00e9talliques et Catalyse, UMR 6226 Universit\u00e9 de Rennes 1, Campus de Beaulieu,35042 Rennes Cedex,","institution_ids":["https://openalex.org/I4210090783","https://openalex.org/I4405258264","https://openalex.org/I56067802"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Gang Zhao","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210090783","display_name":"Institut des Sciences Chimiques de Rennes","ror":"https://ror.org/00adwkx90","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I28221208","https://openalex.org/I4210090783","https://openalex.org/I4210115835","https://openalex.org/I4210128300","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I4405258264","display_name":"Universit\u00e9 Rennes 1","ror":"https://ror.org/00crteh33","country_code":"FR","type":"education","lineage":["https://openalex.org/I4405258264","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I56067802","display_name":"Universit\u00e9 de Rennes","ror":"https://ror.org/015m7wh34","country_code":"FR","type":"education","lineage":["https://openalex.org/I56067802"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Gang Zhao","raw_affiliation_strings":["Laboratoire Organom\u00e9talliques et Catalyse, UMR 6226 Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire Organom\u00e9talliques et Catalyse, UMR 6226 Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex","institution_ids":["https://openalex.org/I4210090783","https://openalex.org/I4405258264","https://openalex.org/I56067802"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5049801841","display_name":"Abderrahmane Amgoune","orcid":"https://orcid.org/0000-0002-6195-1411","observed_orcids":["https://orcid.org/0000-0002-6195-1411"]},"institutions":[{"id":"https://openalex.org/I4210090783","display_name":"Institut des Sciences Chimiques de Rennes","ror":"https://ror.org/00adwkx90","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I28221208","https://openalex.org/I4210090783","https://openalex.org/I4210115835","https://openalex.org/I4210128300","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I4405258264","display_name":"Universit\u00e9 Rennes 1","ror":"https://ror.org/00crteh33","country_code":"FR","type":"education","lineage":["https://openalex.org/I4405258264","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I56067802","display_name":"Universit\u00e9 de Rennes","ror":"https://ror.org/015m7wh34","country_code":"FR","type":"education","lineage":["https://openalex.org/I56067802"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Abderramane Amgoune","raw_affiliation_strings":["Laboratoire Organom\u00e9talliques et Catalyse, UMR 6226 Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire Organom\u00e9talliques et Catalyse, UMR 6226 Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex","institution_ids":["https://openalex.org/I4210090783","https://openalex.org/I4405258264","https://openalex.org/I56067802"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5076564450","display_name":"C.M. Thomas","orcid":"https://orcid.org/0000-0001-8014-4255","observed_orcids":["https://orcid.org/0000-0001-8014-4255"]},"institutions":[{"id":"https://openalex.org/I4210090783","display_name":"Institut des Sciences Chimiques de Rennes","ror":"https://ror.org/00adwkx90","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I28221208","https://openalex.org/I4210090783","https://openalex.org/I4210115835","https://openalex.org/I4210128300","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I4405258264","display_name":"Universit\u00e9 Rennes 1","ror":"https://ror.org/00crteh33","country_code":"FR","type":"education","lineage":["https://openalex.org/I4405258264","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I56067802","display_name":"Universit\u00e9 de Rennes","ror":"https://ror.org/015m7wh34","country_code":"FR","type":"education","lineage":["https://openalex.org/I56067802"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Christophe M. Thomas","raw_affiliation_strings":["Laboratoire Organom\u00e9talliques et Catalyse, UMR 6226 Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire Organom\u00e9talliques et Catalyse, UMR 6226 Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex","institution_ids":["https://openalex.org/I4210090783","https://openalex.org/I4405258264","https://openalex.org/I56067802"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5064611725","display_name":"Jean\u2010Fran\u00e7ois Carpentier","orcid":"https://orcid.org/0000-0002-9160-7662","observed_orcids":["https://orcid.org/0000-0002-9160-7662","https://orcid.org/0000-0001-8961-900X"]},"institutions":[{"id":"https://openalex.org/I4210090783","display_name":"Institut des Sciences Chimiques de Rennes","ror":"https://ror.org/00adwkx90","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I28221208","https://openalex.org/I4210090783","https://openalex.org/I4210115835","https://openalex.org/I4210128300","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I4405258264","display_name":"Universit\u00e9 Rennes 1","ror":"https://ror.org/00crteh33","country_code":"FR","type":"education","lineage":["https://openalex.org/I4405258264","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I56067802","display_name":"Universit\u00e9 de Rennes","ror":"https://ror.org/015m7wh34","country_code":"FR","type":"education","lineage":["https://openalex.org/I56067802"]}],"countries":["FR"],"is_corresponding":true,"raw_author_name":"Jean-Fran?ois Carpentier","raw_affiliation_strings":["Laboratoire Organom\u00e9talliques et Catalyse, UMR 6226 Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire Organom\u00e9talliques et Catalyse, UMR 6226 Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex","institution_ids":["https://openalex.org/I4210090783","https://openalex.org/I4405258264","https://openalex.org/I56067802"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5064611725"],"corresponding_institution_ids":["https://openalex.org/I4210090783","https://openalex.org/I4405258264","https://openalex.org/I56067802"],"apc_list":null,"apc_paid":null,"fwci":1.4227,"has_fulltext":false,"cited_by_count":27,"citation_normalized_percentile":{"value":0.77254943,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":96},"biblio":{"volume":null,"issue":"43","first_page":"4509","last_page":"4509"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10661","display_name":"biodegradable polymer synthesis and properties","score":0.9702000021934509,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10661","display_name":"biodegradable polymer synthesis and properties","score":0.9702000021934509,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.013399999588727951,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.004999999888241291,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ring-opening-polymerization","display_name":"ring-opening polymerization","score":0.9959999918937683},{"id":"https://openalex.org/keywords/coordination-insertion-mechanism","display_name":"coordination-insertion mechanism","score":0.9390000104904175},{"id":"https://openalex.org/keywords/polymerization-mechanism","display_name":"polymerization mechanism","score":0.6209999918937683},{"id":"https://openalex.org/keywords/organolithium-initiators","display_name":"organolithium initiators","score":0.4620000123977661}],"concepts":[{"id":"https://openalex.org/C531131001","wikidata":"https://www.wikidata.org/wiki/Q941","display_name":"Yttrium","level":3,"score":0.8980493545532227},{"id":"https://openalex.org/C90150868","wikidata":"https://www.wikidata.org/wiki/Q39513","display_name":"Alkoxy group","level":3,"score":0.8648501634597778},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.727303147315979},{"id":"https://openalex.org/C2780378348","wikidata":"https://www.wikidata.org/wiki/Q25351438","display_name":"Ring (chemistry)","level":2,"score":0.651387095451355},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5897165536880493},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.4187389314174652},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.3979068994522095},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.26077479124069214},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.1662478744983673},{"id":"https://openalex.org/C2779851234","wikidata":"https://www.wikidata.org/wiki/Q50690","display_name":"Oxide","level":2,"score":0.0},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.0}],"mesh":[{"descriptor_ui":"D009025","descriptor_name":"Morpholines","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D011108","descriptor_name":"Polymers","qualifier_ui":"Q000138","qualifier_name":"chemical synthesis","is_major_topic":true},{"descriptor_ui":"D013696","descriptor_name":"Temperature","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D015019","descriptor_name":"Yttrium","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false}],"locations_count":3,"locations":[{"id":"doi:10.1039/b612580h","doi":"https://doi.org/10.1039/b612580h","is_oa":false,"landing_page_url":"https://doi.org/10.1039/b612580h","pdf_url":null,"source":{"id":"https://openalex.org/S152760256","display_name":"Chemical Communications","issn_l":"1359-7345","issn":["1359-7345","1364-548X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemical Communications","raw_type":"journal-article"},{"id":"pmid:17283801","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/17283801","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemical communications (Cambridge, England)","raw_type":"Journal Article"},{"id":"pmh:oai:HAL:hal-00323959v1","doi":null,"is_oa":false,"landing_page_url":"https://hal.science/hal-00323959","pdf_url":null,"source":{"id":"https://openalex.org/S4306402512","display_name":"HAL","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4405252976","host_organization_name":"Centre pour la Communication Scientifique Directe","host_organization_lineage":["https://openalex.org/I4405252976"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Chemical Communications, 2006, pp.4509-4511","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":20,"referenced_works":["https://openalex.org/W1974517910","https://openalex.org/W1980463426","https://openalex.org/W1985570466","https://openalex.org/W1999519347","https://openalex.org/W2006134956","https://openalex.org/W2012951595","https://openalex.org/W2015711678","https://openalex.org/W2025650969","https://openalex.org/W2027424784","https://openalex.org/W2034222578","https://openalex.org/W2045613923","https://openalex.org/W2046107812","https://openalex.org/W2046443789","https://openalex.org/W2053990051","https://openalex.org/W2080646078","https://openalex.org/W2086107432","https://openalex.org/W2090084294","https://openalex.org/W2096247312","https://openalex.org/W2141860146","https://openalex.org/W2170498612"],"related_works":["https://openalex.org/W4299511663","https://openalex.org/W6889076088","https://openalex.org/W1995032890","https://openalex.org/W2023703725","https://openalex.org/W2012737819","https://openalex.org/W1985442516","https://openalex.org/W2014675750","https://openalex.org/W2123037693","https://openalex.org/W2078532611","https://openalex.org/W2318785109"],"abstract_inverted_index":{"Alkoxy-amino-bis(phenolate)":[0],"yttrium":[1],"amide":[2],"and":[3],"alkoxide":[4],"complexes":[5],"promote":[6],"the":[7],"ring-opening":[8],"polymerization":[9,19],"of":[10],"(3S,6S)-dimethyl-2,5-morpholinedione":[11],"at":[12],"60-100":[13],"degrees":[14],"C":[15],"via":[16],"a":[17],"coordination-insertion":[18],"mechanism.":[20]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2020,"cited_by_count":3},{"year":2019,"cited_by_count":1},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}