{"id":"https://openalex.org/W2016001085","doi":"https://doi.org/10.1021/ac9011528","title":"Improved Measurement of Ozone and Carbonyls Using a Dual-Bed Sampling Cartridge Containing trans -1,2-Bis(2-pyridyl)ethylene and 2,4-Dinitrophenylhydrazine-Impregnated Silica","display_name":"Improved Measurement of Ozone and Carbonyls Using a Dual-Bed Sampling Cartridge Containing trans -1,2-Bis(2-pyridyl)ethylene and 2,4-Dinitrophenylhydrazine-Impregnated Silica","publication_year":2009,"publication_date":"2009-07-10","ids":{"openalex":"https://openalex.org/W2016001085","doi":"https://doi.org/10.1021/ac9011528","mag":"2016001085","pmid":"https://pubmed.ncbi.nlm.nih.gov/19591433"},"language":"en","primary_location":{"id":"doi:10.1021/ac9011528","doi":"https://doi.org/10.1021/ac9011528","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ac9011528","pdf_url":null,"source":{"id":"https://openalex.org/S191963794","display_name":"Analytical Chemistry","issn_l":"0003-2700","issn":["0003-2700","1520-6882"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-a","doyens","jufo-3","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Analytical Chemistry","raw_type":"journal-article"},"parent_works":[],"lineage":["https://openalex.org/W2016001085"],"child_works_count":0,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5090052031","display_name":"Shigehisa Uchiyama","orcid":"https://orcid.org/0000-0001-9312-4827","observed_orcids":["https://orcid.org/0000-0001-9312-4827"]},"institutions":[{"id":"https://openalex.org/I4210087842","display_name":"National Institute of Public Health","ror":"https://ror.org/0024aa414","country_code":"JP","type":"government","lineage":["https://openalex.org/I4210087842"]},{"id":"https://openalex.org/I4405257258","display_name":"Chiba Prefectural Environmental Research Center","ror":"https://ror.org/052pz1t61","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4405257258"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Shigehisa Uchiyama","raw_affiliation_strings":["Department of Environmental Health, National Institute of Public Health 2-3-6, Minami, Wako City, Saitama 351-0197, Japan, and Chiba Prefectural Environmental Research Center 1-88, Iwasaki-nishi, Ichihara City, Chiba 290-0046, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Environmental Health, National Institute of Public Health 2-3-6, Minami, Wako City, Saitama 351-0197, Japan, and Chiba Prefectural Environmental Research Center 1-88, Iwasaki-nishi, Ichihara City, Chiba 290-0046, Japan","institution_ids":["https://openalex.org/I4210087842","https://openalex.org/I4405257258"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110749018","display_name":"Suekazu Naito","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210087842","display_name":"National Institute of Public Health","ror":"https://ror.org/0024aa414","country_code":"JP","type":"government","lineage":["https://openalex.org/I4210087842"]},{"id":"https://openalex.org/I4405257258","display_name":"Chiba Prefectural Environmental Research Center","ror":"https://ror.org/052pz1t61","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4405257258"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Suekazu Naito","raw_affiliation_strings":["Department of Environmental Health, National Institute of Public Health 2-3-6, Minami, Wako City, Saitama 351-0197, Japan, and Chiba Prefectural Environmental Research Center 1-88, Iwasaki-nishi, Ichihara City, Chiba 290-0046, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Environmental Health, National Institute of Public Health 2-3-6, Minami, Wako City, Saitama 351-0197, Japan, and Chiba Prefectural Environmental Research Center 1-88, Iwasaki-nishi, Ichihara City, Chiba 290-0046, Japan","institution_ids":["https://openalex.org/I4210087842","https://openalex.org/I4405257258"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Mariko Matsumoto","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210087842","display_name":"National Institute of Public Health","ror":"https://ror.org/0024aa414","country_code":"JP","type":"government","lineage":["https://openalex.org/I4210087842"]},{"id":"https://openalex.org/I4405257258","display_name":"Chiba Prefectural Environmental Research Center","ror":"https://ror.org/052pz1t61","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4405257258"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Mariko Matsumoto","raw_affiliation_strings":["Department of Environmental Health, National Institute of Public Health 2-3-6, Minami, Wako City, Saitama 351-0197, Japan, and Chiba Prefectural Environmental Research Center 1-88, Iwasaki-nishi, Ichihara City, Chiba 290-0046, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Environmental Health, National Institute of Public Health 2-3-6, Minami, Wako City, Saitama 351-0197, Japan, and Chiba Prefectural Environmental Research Center 1-88, Iwasaki-nishi, Ichihara City, Chiba 290-0046, Japan","institution_ids":["https://openalex.org/I4210087842","https://openalex.org/I4405257258"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5102772123","display_name":"Yohei Inaba","orcid":"https://orcid.org/0000-0001-6890-2244","observed_orcids":["https://orcid.org/0000-0001-6890-2244"]},"institutions":[{"id":"https://openalex.org/I4210087842","display_name":"National Institute of Public Health","ror":"https://ror.org/0024aa414","country_code":"JP","type":"government","lineage":["https://openalex.org/I4210087842"]},{"id":"https://openalex.org/I4405257258","display_name":"Chiba Prefectural Environmental Research Center","ror":"https://ror.org/052pz1t61","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4405257258"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Yohei Inaba","raw_affiliation_strings":["Department of Environmental Health, National Institute of Public Health 2-3-6, Minami, Wako City, Saitama 351-0197, Japan, and Chiba Prefectural Environmental Research Center 1-88, Iwasaki-nishi, Ichihara City, Chiba 290-0046, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Environmental Health, National Institute of Public Health 2-3-6, Minami, Wako City, Saitama 351-0197, Japan, and Chiba Prefectural Environmental Research Center 1-88, Iwasaki-nishi, Ichihara City, Chiba 290-0046, Japan","institution_ids":["https://openalex.org/I4210087842","https://openalex.org/I4405257258"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5038381848","display_name":"Naoki Kunugita","orcid":"https://orcid.org/0000-0002-6516-8379","observed_orcids":["https://orcid.org/0000-0002-6516-8379"]},"institutions":[{"id":"https://openalex.org/I4210087842","display_name":"National Institute of Public Health","ror":"https://ror.org/0024aa414","country_code":"JP","type":"government","lineage":["https://openalex.org/I4210087842"]},{"id":"https://openalex.org/I4405257258","display_name":"Chiba Prefectural Environmental Research Center","ror":"https://ror.org/052pz1t61","country_code":"JP","type":"facility","lineage":["https://openalex.org/I4405257258"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Naoki Kunugita","raw_affiliation_strings":["Department of Environmental Health, National Institute of Public Health 2-3-6, Minami, Wako City, Saitama 351-0197, Japan, and Chiba Prefectural Environmental Research Center 1-88, Iwasaki-nishi, Ichihara City, Chiba 290-0046, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Environmental Health, National Institute of Public Health 2-3-6, Minami, Wako City, Saitama 351-0197, Japan, and Chiba Prefectural Environmental Research Center 1-88, Iwasaki-nishi, Ichihara City, Chiba 290-0046, Japan","institution_ids":["https://openalex.org/I4210087842","https://openalex.org/I4405257258"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5090052031"],"corresponding_institution_ids":["https://openalex.org/I4210087842","https://openalex.org/I4405257258"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.2828,"has_fulltext":false,"cited_by_count":32,"citation_normalized_percentile":{"value":0.76991007,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":97},"biblio":{"volume":"81","issue":"15","first_page":"6552","last_page":"6557"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10075","display_name":"Atmospheric chemistry and aerosols","score":0.8270999789237976,"subfield":{"id":"https://openalex.org/subfields/1902","display_name":"Atmospheric Science"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10075","display_name":"Atmospheric chemistry and aerosols","score":0.8270999789237976,"subfield":{"id":"https://openalex.org/subfields/1902","display_name":"Atmospheric Science"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10180","display_name":"Analytical chemistry methods development","score":0.06530000269412994,"subfield":{"id":"https://openalex.org/subfields/1602","display_name":"Analytical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12120","display_name":"Air Quality Monitoring and Forecasting","score":0.05510000139474869,"subfield":{"id":"https://openalex.org/subfields/2305","display_name":"Environmental Engineering"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ozone-measurement","display_name":"ozone measurement","score":0.8859999775886536},{"id":"https://openalex.org/keywords/carbonyl-compounds","display_name":"carbonyl compounds","score":0.9380000233650208},{"id":"https://openalex.org/keywords/trans-1-2-bis-4-pyridyl-ethylene","display_name":"trans-1,2-bis(4-pyridyl)ethylene","score":0.9470000267028809},{"id":"https://openalex.org/keywords/2-4-dinitrophenylhydrazine","display_name":"2,4-dinitrophenylhydrazine","score":0.9900000095367432},{"id":"https://openalex.org/keywords/pyridine-2-aldehyde","display_name":"pyridine-2-aldehyde","score":0.9160000085830688},{"id":"https://openalex.org/keywords/humidity-dependence","display_name":"humidity dependence","score":0.5339999794960022},{"id":"https://openalex.org/keywords/reaction-efficiency","display_name":"reaction efficiency","score":0.7770000100135803},{"id":"https://openalex.org/keywords/air-quality-monitoring","display_name":"air quality monitoring","score":0.5680000185966492}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9481297731399536},{"id":"https://openalex.org/C508106653","wikidata":"https://www.wikidata.org/wiki/Q36933","display_name":"Ozone","level":2,"score":0.8505169153213501},{"id":"https://openalex.org/C73826308","wikidata":"https://www.wikidata.org/wiki/Q684907","display_name":"Elution","level":2,"score":0.6166934967041016},{"id":"https://openalex.org/C34381374","wikidata":"https://www.wikidata.org/wiki/Q37144","display_name":"Cartridge","level":2,"score":0.5930312275886536},{"id":"https://openalex.org/C2778597550","wikidata":"https://www.wikidata.org/wiki/Q151313","display_name":"Ethylene","level":3,"score":0.5925760865211487},{"id":"https://openalex.org/C2779825165","wikidata":"https://www.wikidata.org/wiki/Q101497","display_name":"Aldehyde","level":3,"score":0.5627038478851318},{"id":"https://openalex.org/C158960510","wikidata":"https://www.wikidata.org/wiki/Q180600","display_name":"Relative humidity","level":2,"score":0.5194330215454102},{"id":"https://openalex.org/C2775930285","wikidata":"https://www.wikidata.org/wiki/Q161210","display_name":"Formaldehyde","level":2,"score":0.5170500874519348},{"id":"https://openalex.org/C40875361","wikidata":"https://www.wikidata.org/wiki/Q2356542","display_name":"Reagent","level":2,"score":0.4753396511077881},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.4646083414554596},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.23420783877372742},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.23396554589271545},{"id":"https://openalex.org/C153294291","wikidata":"https://www.wikidata.org/wiki/Q25261","display_name":"Meteorology","level":1,"score":0.08518853783607483},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C78519656","wikidata":"https://www.wikidata.org/wiki/Q101333","display_name":"Mechanical engineering","level":1,"score":0.0}],"mesh":[{"descriptor_ui":"D000393","descriptor_name":"Air Pollutants","qualifier_ui":"Q000032","qualifier_name":"analysis","is_major_topic":true},{"descriptor_ui":"D002244","descriptor_name":"Carbon","qualifier_ui":"Q000032","qualifier_name":"analysis","is_major_topic":true},{"descriptor_ui":"D002244","descriptor_name":"Carbon","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D002851","descriptor_name":"Chromatography, High Pressure Liquid","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D004784","descriptor_name":"Environmental Monitoring","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D005030","descriptor_name":"Ethylenes","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D010126","descriptor_name":"Ozone","qualifier_ui":"Q000032","qualifier_name":"analysis","is_major_topic":true},{"descriptor_ui":"D010659","descriptor_name":"Phenylhydrazines","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D011725","descriptor_name":"Pyridines","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D012822","descriptor_name":"Silicon Dioxide","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true}],"locations_count":2,"locations":[{"id":"doi:10.1021/ac9011528","doi":"https://doi.org/10.1021/ac9011528","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ac9011528","pdf_url":null,"source":{"id":"https://openalex.org/S191963794","display_name":"Analytical Chemistry","issn_l":"0003-2700","issn":["0003-2700","1520-6882"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-a","doyens","jufo-3","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Analytical Chemistry","raw_type":"journal-article"},{"id":"pmid:19591433","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/19591433","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Analytical chemistry","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":10,"referenced_works":["https://openalex.org/W1972150519","https://openalex.org/W1995348754","https://openalex.org/W2003035804","https://openalex.org/W2008869562","https://openalex.org/W2078248930","https://openalex.org/W2078502578","https://openalex.org/W2086860246","https://openalex.org/W2089177428","https://openalex.org/W2090107895","https://openalex.org/W2609596308"],"related_works":["https://openalex.org/W2008869562","https://openalex.org/W1974488749","https://openalex.org/W2767345883","https://openalex.org/W2026047573","https://openalex.org/W2162032331","https://openalex.org/W2521344865","https://openalex.org/W2061427958","https://openalex.org/W3170000429","https://openalex.org/W2075160435","https://openalex.org/W2014313337"],"abstract_inverted_index":{"We":[0],"have":[1],"previously":[2],"developed":[3],"a":[4,24,55,153,167,240,245],"new":[5],"method":[6,39,223],"using":[7,23,67],"trans-1,2-bis-(4-pyridyl)ethylene":[8],"(4-BPE)":[9],"and":[10,19,54,105,112,127,217,239],"2,4-dinitrophenylhydrazine":[11],"(DNPH)":[12],"for":[13,210],"the":[14,38,46,51,77,90,96,100,117,120,134,148,182,191,200,206,220,226],"simultaneous":[15],"determination":[16],"of":[17,50,72,76,79,103,140,157,171,184,194,215],"ozone":[18,80,128,145,197,211,216,231],"carbonyls":[20,218],"in":[21,45,70,133,144,199,234],"air":[22,236],"two-bed":[25],"cartridge":[26,242],"system.":[27],"In":[28,116],"this":[29],"method,":[30],"4-BPE":[31,165],"was":[32,142],"used":[33],"to":[34,83,131],"capture":[35],"ozone.":[36,187],"However,":[37],"suffered":[40],"from":[41,119,125],"long":[42],"reaction":[43,78,92,101,155,169,183,192],"times":[44,102],"eluate,":[47],"low":[48],"solubility":[49],"DNPH":[52,108,241],"derivative,":[53],"strong":[56],"dependence":[57],"on":[58,181],"atmospheric":[59],"moisture.":[60],"These":[61],"problems":[62],"could":[63],"be":[64],"overcome":[65],"by":[66,147,219,229],"trans-1,2-bis-(2-pyridyl)ethylene":[68],"(2-BPE)":[69],"place":[71],"4-BPE.":[73,94],"The":[74,213],"efficiency":[75,156,170,193],"with":[81,93,107,186,196,225,244],"2-BPE":[82,126,151,185,195,204],"form":[84],"pyridine-2-aldehyde":[85],"(2PA)":[86],"is":[87,129,198,205],"higher":[88],"than":[89],"corresponding":[91],"Under":[95],"optimized":[97],"elution":[98,118,135],"conditions,":[99],"2PA":[104,123],"4PA":[106],"are":[109],"within":[110],"15":[111],"120":[113],"min,":[114],"respectively.":[115],"sampling":[121],"cartridge,":[122],"formed":[124],"easier":[130],"dissolve":[132],"solvent.":[136],"A":[137],"stronger":[138],"influence":[139,180],"humidity":[141,162],"observed":[143],"recovery":[146],"4-BPE/DNPH":[149],"method.":[150],"exhibits":[152],"maximum":[154,168],"84%":[158],"at":[159,173],"32%":[160],"relative":[161],"(RH),":[163],"while":[164],"attains":[166],"82%":[172],"49%":[174],"RH.":[175],"Humidity":[176],"has":[177],"much":[178],"less":[179],"Above":[188],"18%":[189],"RH,":[190],"range":[201],"80-84%.":[202],"Thus,":[203],"more":[207],"useful":[208],"reagent":[209],"analysis.":[212],"concentrations":[214],"improved":[221],"2-BPE/DNPH":[222],"corresponded":[224],"mean":[227],"value":[228],"an":[230,235],"auto":[232],"analyzer":[233],"monitoring":[237],"station":[238],"coupled":[243],"KI-ozone":[246],"scrubbing":[247],"cartridge.":[248]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":2},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":3},{"year":2015,"cited_by_count":3},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":3},{"year":2012,"cited_by_count":3}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}