{"id":"https://openalex.org/W2015457129","doi":"https://doi.org/10.1039/j29710001957","title":"Adsorption effects in the polarographic behaviour of \u03c9-diazoacetophenones in aqueous buffer solutions","display_name":"Adsorption effects in the polarographic behaviour of \u03c9-diazoacetophenones in aqueous buffer solutions","publication_year":1971,"publication_date":"1971-01-01","ids":{"openalex":"https://openalex.org/W2015457129","doi":"https://doi.org/10.1039/j29710001957","mag":"2015457129"},"language":"en","primary_location":{"id":"doi:10.1039/j29710001957","doi":"https://doi.org/10.1039/j29710001957","is_oa":false,"landing_page_url":"https://doi.org/10.1039/j29710001957","pdf_url":null,"source":{"id":"https://openalex.org/S4210172504","display_name":"Journal of the Chemical Society B Physical Organic","issn_l":"0045-6470","issn":["0045-6470","2050-5590"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"J. Chem. Soc. B","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5060669765","display_name":"Michael Bailes","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"M. Bailes","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5013936548","display_name":"L. L. Leveson","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"L. L. Leveson","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.5991,"has_fulltext":false,"cited_by_count":1,"citation_normalized_percentile":{"value":0.5842235,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"0","issue":"0","first_page":"1957","last_page":"1961"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11434","display_name":"Electrochemical Analysis and Applications","score":0.98580002784729,"subfield":{"id":"https://openalex.org/subfields/1603","display_name":"Electrochemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11434","display_name":"Electrochemical Analysis and Applications","score":0.98580002784729,"subfield":{"id":"https://openalex.org/subfields/1603","display_name":"Electrochemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.003800000064074993,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11611","display_name":"Cyclopropane Reaction Mechanisms","score":0.0010999999940395355,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/diazoketones","display_name":"diazoketones","score":0.9269999861717224},{"id":"https://openalex.org/keywords/adsorption","display_name":"adsorption","score":0.7910000085830688},{"id":"https://openalex.org/keywords/polarographic-behavior","display_name":"polarographic behavior","score":0.824999988079071},{"id":"https://openalex.org/keywords/electrocapillary-curves","display_name":"electrocapillary curves","score":0.9480000138282776},{"id":"https://openalex.org/keywords/concentration-effects","display_name":"concentration effects","score":0.703000009059906},{"id":"https://openalex.org/keywords/autocatalytic-reduction","display_name":"autocatalytic reduction","score":0.9070000052452087},{"id":"https://openalex.org/keywords/electrolytic-reduction","display_name":"electrolytic reduction","score":0.7979999780654907},{"id":"https://openalex.org/keywords/reduction-rate-constant","display_name":"reduction rate constant","score":0.8230000138282776},{"id":"https://openalex.org/keywords/aqueous-buffer","display_name":"aqueous buffer","score":0.953000009059906}],"concepts":[{"id":"https://openalex.org/C37263863","wikidata":"https://www.wikidata.org/wiki/Q786897","display_name":"Autocatalysis","level":3,"score":0.924142599105835},{"id":"https://openalex.org/C188518856","wikidata":"https://www.wikidata.org/wiki/Q899397","display_name":"Polarography","level":2,"score":0.9005939960479736},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8558548092842102},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.8254008293151855},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.7427529692649841},{"id":"https://openalex.org/C68801617","wikidata":"https://www.wikidata.org/wiki/Q162908","display_name":"Electrolyte","level":3,"score":0.5826060771942139},{"id":"https://openalex.org/C145018004","wikidata":"https://www.wikidata.org/wiki/Q4985944","display_name":"Buffer (optical fiber)","level":2,"score":0.5632665157318115},{"id":"https://openalex.org/C2778117296","wikidata":"https://www.wikidata.org/wiki/Q208465","display_name":"Buffer solution","level":2,"score":0.5294280648231506},{"id":"https://openalex.org/C93391505","wikidata":"https://www.wikidata.org/wiki/Q658700","display_name":"Reaction rate constant","level":3,"score":0.4535074234008789},{"id":"https://openalex.org/C95514000","wikidata":"https://www.wikidata.org/wiki/Q786897","display_name":"Autocatalytic reaction","level":2,"score":0.44474703073501587},{"id":"https://openalex.org/C2779896888","wikidata":"https://www.wikidata.org/wiki/Q11498818","display_name":"Supporting electrolyte","level":4,"score":0.43237045407295227},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.4237060248851776},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.39050036668777466},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.2575923502445221},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.2424842119216919},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.23827609419822693},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.11014130711555481},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.0971827507019043},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C76155785","wikidata":"https://www.wikidata.org/wiki/Q418","display_name":"Telecommunications","level":1,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C121864883","wikidata":"https://www.wikidata.org/wiki/Q677916","display_name":"Statistical physics","level":1,"score":0.0},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/j29710001957","doi":"https://doi.org/10.1039/j29710001957","is_oa":false,"landing_page_url":"https://doi.org/10.1039/j29710001957","pdf_url":null,"source":{"id":"https://openalex.org/S4210172504","display_name":"Journal of the Chemical Society B Physical Organic","issn_l":"0045-6470","issn":["0045-6470","2050-5590"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"J. Chem. Soc. B","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2070340811","https://openalex.org/W2134456812","https://openalex.org/W2321723313","https://openalex.org/W2002221655","https://openalex.org/W2028489002","https://openalex.org/W2027565731","https://openalex.org/W1975917719","https://openalex.org/W2050565216","https://openalex.org/W2039158520","https://openalex.org/W1526285055"],"abstract_inverted_index":{"Electrocapillary":[0],"curves,":[1],"concentration":[2],"effects,":[3],"and":[4],"instantaneous":[5],"current":[6],"measurements":[7],"indicate":[8],"the":[9,14,19,22,34,47],"importance":[10],"of":[11,13,21,24,37,50],"adsorption":[12],"electroactive":[15],"substance":[16],"in":[17,26],"determining":[18],"shape":[20],"polarograms":[23],"\u03c9-diazoacetophenones":[25],"aqueous":[27],"buffer":[28],"solutions.":[29],"Potential-step":[30],"transients":[31],"show":[32],"that":[33],"electrolytic":[35],"reduction":[36,49],"adsorbed":[38,52],"diazoketone":[39],"is":[40],"autocatalytic.":[41],"Rate":[42],"constants":[43],"are":[44],"reported":[45],"for":[46],"autocatalytic":[48],"some":[51],"diazoketones.":[53]},"counts_by_year":[],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}