{"id":"https://openalex.org/W2015366237","doi":"https://doi.org/10.1002/pola.10348","title":"Polyolefin graft copolymers via living polymerization techniques: Preparation of poly(n\u2010butyl acrylate)\u2010graft\u2010polyethylene through the combination of Pd\u2010mediated living olefin polymerization and atom transfer radical polymerization","display_name":"Polyolefin graft copolymers via living polymerization techniques: Preparation of poly(n\u2010butyl acrylate)\u2010graft\u2010polyethylene through the combination of Pd\u2010mediated living olefin polymerization and atom transfer radical polymerization","publication_year":2002,"publication_date":"2002-06-21","ids":{"openalex":"https://openalex.org/W2015366237","doi":"https://doi.org/10.1002/pola.10348","mag":"2015366237"},"language":"en","primary_location":{"id":"doi:10.1002/pola.10348","doi":"https://doi.org/10.1002/pola.10348","is_oa":false,"landing_page_url":"https://doi.org/10.1002/pola.10348","pdf_url":null,"source":{"id":"https://openalex.org/S92465984","display_name":"Journal of Polymer Science Part A Polymer Chemistry","issn_l":"0887-624X","issn":["0887-624X","1099-0518"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Polymer Science Part A: Polymer Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5037911101","display_name":"Sung Chul Hong","orcid":"https://orcid.org/0000-0003-0961-7245","observed_orcids":["https://orcid.org/0000-0003-0961-7245"]},"institutions":[{"id":"https://openalex.org/I74973139","display_name":"Carnegie Mellon University","ror":"https://ror.org/05x2bcf33","country_code":"US","type":"education","lineage":["https://openalex.org/I74973139"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Sung Chul Hong","raw_affiliation_strings":["Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213","institution_ids":["https://openalex.org/I74973139"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100830267","display_name":"Shijun Jia","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I74973139","display_name":"Carnegie Mellon University","ror":"https://ror.org/05x2bcf33","country_code":"US","type":"education","lineage":["https://openalex.org/I74973139"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Shijun Jia","raw_affiliation_strings":["Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213","institution_ids":["https://openalex.org/I74973139"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5066916935","display_name":"Mircea Teodorescu","orcid":"https://orcid.org/0000-0002-0333-911X","observed_orcids":["https://orcid.org/0000-0002-0333-911X"]},"institutions":[{"id":"https://openalex.org/I74973139","display_name":"Carnegie Mellon University","ror":"https://ror.org/05x2bcf33","country_code":"US","type":"education","lineage":["https://openalex.org/I74973139"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Mircea Teodorescu","raw_affiliation_strings":["Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213","institution_ids":["https://openalex.org/I74973139"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5090408781","display_name":"Tomasz Kowalewski","orcid":"https://orcid.org/0000-0002-3544-554X","observed_orcids":["https://orcid.org/0000-0002-3544-554X"]},"institutions":[{"id":"https://openalex.org/I74973139","display_name":"Carnegie Mellon University","ror":"https://ror.org/05x2bcf33","country_code":"US","type":"education","lineage":["https://openalex.org/I74973139"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Tomasz Kowalewski","raw_affiliation_strings":["Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213","institution_ids":["https://openalex.org/I74973139"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5056539244","display_name":"Krzysztof Aleksander Matyjaszewski","orcid":"https://orcid.org/0000-0003-1960-3402","observed_orcids":["https://orcid.org/0000-0003-1960-3402"]},"institutions":[{"id":"https://openalex.org/I74973139","display_name":"Carnegie Mellon University","ror":"https://ror.org/05x2bcf33","country_code":"US","type":"education","lineage":["https://openalex.org/I74973139"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Krzysztof Matyjaszewski","raw_affiliation_strings":["Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Macromolecular Engineering, Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213","institution_ids":["https://openalex.org/I74973139"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5057102573","display_name":"Amy C. Gottfried","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Amy C. Gottfried","raw_affiliation_strings":["Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina 27599-3290","Department of Chemistry University of North Carolina Chapel Hill North Carolina 27599-3290"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina 27599-3290","institution_ids":["https://openalex.org/I114027177"]},{"raw_affiliation_string":"Department of Chemistry University of North Carolina Chapel Hill North Carolina 27599-3290","institution_ids":["https://openalex.org/I114027177"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5057551801","display_name":"Maurice Brookhart","orcid":"https://orcid.org/0000-0001-5401-8458","observed_orcids":["https://orcid.org/0000-0001-5401-8458"]},"institutions":[{"id":"https://openalex.org/I114027177","display_name":"University of North Carolina at Chapel Hill","ror":"https://ror.org/0130frc33","country_code":"US","type":"education","lineage":["https://openalex.org/I114027177"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Maurice Brookhart","raw_affiliation_strings":["Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina 27599-3290","Department of Chemistry University of North Carolina Chapel Hill North Carolina 27599-3290"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina 27599-3290","institution_ids":["https://openalex.org/I114027177"]},{"raw_affiliation_string":"Department of Chemistry University of North Carolina Chapel Hill North Carolina 27599-3290","institution_ids":["https://openalex.org/I114027177"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5056539244"],"corresponding_institution_ids":["https://openalex.org/I74973139"],"apc_list":{"value":3200,"currency":"USD","value_usd":3200},"apc_paid":null,"fwci":5.6509,"has_fulltext":false,"cited_by_count":112,"citation_normalized_percentile":{"value":0.97038749,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"40","issue":"16","first_page":"2736","last_page":"2749"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.9961000084877014,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.9961000084877014,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10389","display_name":"Polymer crystallization and properties","score":0.0017999999690800905,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.0005000000237487257,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/graft-copolymers","display_name":"graft copolymers","score":0.9110000133514404},{"id":"https://openalex.org/keywords/atom-transfer-radical-polymerization","display_name":"atom transfer radical polymerization","score":0.9599999785423279},{"id":"https://openalex.org/keywords/macromers","display_name":"macromonomers","score":0.8270000219345093},{"id":"https://openalex.org/keywords/branched-polyethylene","display_name":"branched polyethylene","score":0.7850000262260437},{"id":"https://openalex.org/keywords/reactivity-ratios","display_name":"reactivity ratios","score":0.7110000252723694},{"id":"https://openalex.org/keywords/polymer-incompatibility","display_name":"polymer incompatibility","score":0.7179999947547913},{"id":"https://openalex.org/keywords/microphase-separation","display_name":"microphase separation","score":0.949999988079071},{"id":"https://openalex.org/keywords/nanoscale-morphology","display_name":"nanoscale morphology","score":0.8330000042915344},{"id":"https://openalex.org/keywords/controlled-polymerization","display_name":"controlled polymerization","score":0.4449999928474426}],"concepts":[{"id":"https://openalex.org/C2777686893","wikidata":"https://www.wikidata.org/wiki/Q424370","display_name":"Polyolefin","level":3,"score":0.9014370441436768},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.7328054904937744},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.7079947590827942},{"id":"https://openalex.org/C2779751980","wikidata":"https://www.wikidata.org/wiki/Q143429","display_name":"Polyethylene","level":2,"score":0.6346887946128845},{"id":"https://openalex.org/C150539798","wikidata":"https://www.wikidata.org/wiki/Q757561","display_name":"Atom-transfer radical-polymerization","level":4,"score":0.6327277421951294},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.626004695892334},{"id":"https://openalex.org/C48396125","wikidata":"https://www.wikidata.org/wiki/Q903447","display_name":"Living polymerization","level":5,"score":0.5534119606018066},{"id":"https://openalex.org/C89760097","wikidata":"https://www.wikidata.org/wiki/Q304519","display_name":"Living free-radical polymerization","level":5,"score":0.5507352352142334},{"id":"https://openalex.org/C2779989194","wikidata":"https://www.wikidata.org/wiki/Q343016","display_name":"Acrylate","level":4,"score":0.5458354353904724},{"id":"https://openalex.org/C121120078","wikidata":"https://www.wikidata.org/wiki/Q3737603","display_name":"Chain transfer","level":5,"score":0.5133346915245056},{"id":"https://openalex.org/C2994428872","wikidata":"https://www.wikidata.org/wiki/Q81406","display_name":"Olefin polymerization","level":4,"score":0.5080042481422424},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.4938536286354065},{"id":"https://openalex.org/C51886252","wikidata":"https://www.wikidata.org/wiki/Q4118667","display_name":"Olefin fiber","level":3,"score":0.4714684784412384},{"id":"https://openalex.org/C111998727","wikidata":"https://www.wikidata.org/wiki/Q2620998","display_name":"Radical polymerization","level":4,"score":0.4517858922481537},{"id":"https://openalex.org/C206707181","wikidata":"https://www.wikidata.org/wiki/Q5051386","display_name":"Catalytic chain transfer","level":5,"score":0.4390207529067993},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.3355000913143158},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.32965195178985596},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.21203294396400452},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.20678108930587769},{"id":"https://openalex.org/C2779227376","wikidata":"https://www.wikidata.org/wiki/Q6505497","display_name":"Layer (electronics)","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/pola.10348","doi":"https://doi.org/10.1002/pola.10348","is_oa":false,"landing_page_url":"https://doi.org/10.1002/pola.10348","pdf_url":null,"source":{"id":"https://openalex.org/S92465984","display_name":"Journal of Polymer Science Part A Polymer Chemistry","issn_l":"0887-624X","issn":["0887-624X","1099-0518"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Polymer Science Part A: Polymer Chemistry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":49,"referenced_works":["https://openalex.org/W1572470728","https://openalex.org/W1966863664","https://openalex.org/W1971216193","https://openalex.org/W1982638481","https://openalex.org/W1984349413","https://openalex.org/W1986119632","https://openalex.org/W1991534816","https://openalex.org/W1995856926","https://openalex.org/W1997474277","https://openalex.org/W2004182290","https://openalex.org/W2009202574","https://openalex.org/W2013464543","https://openalex.org/W2015253591","https://openalex.org/W2016689740","https://openalex.org/W2021158547","https://openalex.org/W2033801096","https://openalex.org/W2038047390","https://openalex.org/W2042592947","https://openalex.org/W2045055557","https://openalex.org/W2046289304","https://openalex.org/W2046653307","https://openalex.org/W2055393399","https://openalex.org/W2059312570","https://openalex.org/W2059744460","https://openalex.org/W2062664418","https://openalex.org/W2062910181","https://openalex.org/W2069546742","https://openalex.org/W2071364972","https://openalex.org/W2074554162","https://openalex.org/W2075164508","https://openalex.org/W2079220901","https://openalex.org/W2080121118","https://openalex.org/W2081361953","https://openalex.org/W2083402372","https://openalex.org/W2088890545","https://openalex.org/W2090583316","https://openalex.org/W2091953468","https://openalex.org/W2092214586","https://openalex.org/W2093722068","https://openalex.org/W2140379963","https://openalex.org/W2144122182","https://openalex.org/W2150184000","https://openalex.org/W2153375279","https://openalex.org/W2485991064","https://openalex.org/W2487832401","https://openalex.org/W2608385810","https://openalex.org/W2949122505","https://openalex.org/W4231952765","https://openalex.org/W4240578940"],"related_works":["https://openalex.org/W2497865396","https://openalex.org/W2138451775","https://openalex.org/W1993917676","https://openalex.org/W1971995165","https://openalex.org/W2370674581","https://openalex.org/W4248260599","https://openalex.org/W921751473","https://openalex.org/W2183307880","https://openalex.org/W2373719591","https://openalex.org/W2967375218"],"abstract_inverted_index":{"Abstract":[0],"Poly(n\u2010butyl":[1],"acrylate)\u2010graft\u2010branched":[2],"polyethylene":[3,18,122],"was":[4,25,34,132],"successfully":[5],"prepared":[6,26],"by":[7,27,40,151],"the":[8,50,71,75,91,95,107,112,136],"combination":[9],"of":[10,49,59,74,94,106,111,146],"two":[11],"living":[12,29],"polymerization":[13],"techniques.":[14],"First,":[15],"a":[16,21,60,104,125,144],"branched":[17],"macromonomer":[19,33,65,76,101,113],"with":[20,37],"methacrylate\u2010functionalized":[22],"end":[23],"group":[24],"Pd\u2010mediated":[28],"olefin":[30],"polymerization.":[31,44],"The":[32,130],"then":[35],"copolymerized":[36],"n\u2010butyl":[38,78,88,115],"acrylate":[39,79],"atom":[41],"transfer":[42],"radical":[43],"Gel":[45],"permeation":[46],"chromatography":[47],"traces":[48],"graft":[51],"copolymers":[52],"showed":[53],"narrow":[54],"molecular":[55],"weight":[56],"distributions":[57],"indicative":[58],"controlled":[61],"reaction.":[62],"At":[63],"low":[64,69],"concentrations":[66,102],"corresponding":[67],"to":[68,77,82,87,114],"viscosities,":[70],"reactivity":[72,109],"ratios":[73],"were":[80],"similar":[81],"those":[83],"for":[84],"methyl":[85],"methacrylate":[86],"acrylate.":[89],"However,":[90],"increased":[92,100],"viscosity":[93],"reaction":[96],"solution":[97],"resulting":[98],"from":[99],"caused":[103],"lowering":[105],"apparent":[108],"ratio":[110],"acrylate,":[116],"indicating":[117],"an":[118],"incompatibility":[119,131],"between":[120],"nonpolar":[121],"segments":[123],"and":[124],"polar":[126],"poly(n\u2010butyl":[127],"acrylate)":[128],"backbone.":[129],"more":[133],"pronounced":[134],"in":[135],"solid":[137],"state,":[138],"exhibiting":[139],"cylindrical":[140],"nanoscale":[141],"morphology":[142],"as":[143,149],"result":[145],"microphase":[147],"separation,":[148],"observed":[150],"atomic":[152],"force":[153],"microscopy.":[154],"\u00a9":[155],"2002":[156,169],"Wiley":[157],"Periodicals,":[158],"Inc.":[159],"J":[160],"Polym":[161,165],"Sci":[162],"Part":[163],"A:":[164],"Chem":[166],"40:":[167],"2736\u20132749,":[168]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":3},{"year":2022,"cited_by_count":5},{"year":2021,"cited_by_count":3},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":3},{"year":2016,"cited_by_count":4},{"year":2015,"cited_by_count":4},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":6},{"year":2012,"cited_by_count":6}],"updated_date":"2026-10-07T09:51:55.459714","created_date":"2025-10-10T00:00:00"}