{"id":"https://openalex.org/W2014986915","doi":"https://doi.org/10.1002/jlac.198719870333","title":"Chelatkontrollierte Grignard\u2010Reaktionen mit \u03b1\u2010(1H\u20101,2,4\u2010Triazol\u20101\u2010yl)ketonen","display_name":"Chelatkontrollierte Grignard\u2010Reaktionen mit \u03b1\u2010(1H\u20101,2,4\u2010Triazol\u20101\u2010yl)ketonen","publication_year":1987,"publication_date":"1987-04-27","ids":{"openalex":"https://openalex.org/W2014986915","doi":"https://doi.org/10.1002/jlac.198719870333","mag":"2014986915"},"language":"de","primary_location":{"id":"doi:10.1002/jlac.198719870333","doi":"https://doi.org/10.1002/jlac.198719870333","is_oa":false,"landing_page_url":"https://doi.org/10.1002/jlac.198719870333","pdf_url":null,"source":{"id":"https://openalex.org/S117292697","display_name":"Liebigs Annalen der Chemie","issn_l":"0170-2041","issn":["0170-2041"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Liebigs Annalen der Chemie","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5020895608","display_name":"Ernst Buschmann","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210107087","display_name":"BASF (Germany)","ror":"https://ror.org/01q8f6705","country_code":"DE","type":"company","lineage":["https://openalex.org/I4210107087"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Ernst Buschmann","raw_affiliation_strings":["BASF Aktiengesellschaft, Hauptlaboratorium, D-6700 Ludwigshafen"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"BASF Aktiengesellschaft, Hauptlaboratorium, D-6700 Ludwigshafen","institution_ids":["https://openalex.org/I4210107087"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5040000627","display_name":"Bernd Zeeh","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210107087","display_name":"BASF (Germany)","ror":"https://ror.org/01q8f6705","country_code":"DE","type":"company","lineage":["https://openalex.org/I4210107087"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Bernd Zeeh","raw_affiliation_strings":["BASF Aktiengesellschaft, Hauptlaboratorium, D-6700 Ludwigshafen"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"BASF Aktiengesellschaft, Hauptlaboratorium, D-6700 Ludwigshafen","institution_ids":["https://openalex.org/I4210107087"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5058286893","display_name":"Norbert G\u00f6tz","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210107087","display_name":"BASF (Germany)","ror":"https://ror.org/01q8f6705","country_code":"DE","type":"company","lineage":["https://openalex.org/I4210107087"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Norbert G\u00f6tz","raw_affiliation_strings":["BASF Aktiengesellschaft, Hauptlaboratorium, D-6700 Ludwigshafen"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"BASF Aktiengesellschaft, Hauptlaboratorium, D-6700 Ludwigshafen","institution_ids":["https://openalex.org/I4210107087"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5077480853","display_name":"Linhard Sproesser","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210107087","display_name":"BASF (Germany)","ror":"https://ror.org/01q8f6705","country_code":"DE","type":"company","lineage":["https://openalex.org/I4210107087"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Linhard Sproesser","raw_affiliation_strings":["BASF Aktiengesellschaft, Hauptlaboratorium, D-6700 Ludwigshafen"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"BASF Aktiengesellschaft, Hauptlaboratorium, D-6700 Ludwigshafen","institution_ids":["https://openalex.org/I4210107087"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5019210873","display_name":"Nigel P.C. Walker","orcid":"https://orcid.org/0009-0002-5838-8311","observed_orcids":["https://orcid.org/0009-0002-5838-8311"]},"institutions":[{"id":"https://openalex.org/I4210107087","display_name":"BASF (Germany)","ror":"https://ror.org/01q8f6705","country_code":"DE","type":"company","lineage":["https://openalex.org/I4210107087"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Nigel Walker","raw_affiliation_strings":["BASF Aktiengesellschaft, Hauptlaboratorium, D-6700 Ludwigshafen"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"BASF Aktiengesellschaft, Hauptlaboratorium, D-6700 Ludwigshafen","institution_ids":["https://openalex.org/I4210107087"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5020895608"],"corresponding_institution_ids":["https://openalex.org/I4210107087"],"apc_list":null,"apc_paid":null,"fwci":0.5404,"has_fulltext":false,"cited_by_count":2,"citation_normalized_percentile":{"value":0.59662824,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"1987","issue":"4","first_page":"349","last_page":"355"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12228","display_name":"Coordination Chemistry and Organometallics","score":0.4672999978065491,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12228","display_name":"Coordination Chemistry and Organometallics","score":0.4672999978065491,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.25780001282691956,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.049800001084804535,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/grignard-reaction","display_name":"Grignard reaction","score":0.8169999718666077},{"id":"https://openalex.org/keywords/metal-chelates","display_name":"metal chelates","score":0.6600000262260437},{"id":"https://openalex.org/keywords/1-2-4-triazole","display_name":"1,2,4-triazole","score":0.8360000252723694},{"id":"https://openalex.org/keywords/imidazole","display_name":"imidazole","score":0.7059999704360962},{"id":"https://openalex.org/keywords/diastereoselectivity","display_name":"diastereoselectivity","score":0.949999988079071},{"id":"https://openalex.org/keywords/azole-ligands","display_name":"azole ligands","score":0.8159999847412109},{"id":"https://openalex.org/keywords/x-ray-crystal-structure","display_name":"X-ray crystal structure","score":0.6029999852180481},{"id":"https://openalex.org/keywords/organometallic-intermediates","display_name":"organometallic intermediates","score":0.5929999947547913}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9011216759681702},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.6366156339645386}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/jlac.198719870333","doi":"https://doi.org/10.1002/jlac.198719870333","is_oa":false,"landing_page_url":"https://doi.org/10.1002/jlac.198719870333","pdf_url":null,"source":{"id":"https://openalex.org/S117292697","display_name":"Liebigs Annalen der Chemie","issn_l":"0170-2041","issn":["0170-2041"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Liebigs Annalen der Chemie","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":7,"referenced_works":["https://openalex.org/W1993791812","https://openalex.org/W2060390716","https://openalex.org/W2077155651","https://openalex.org/W2097594464","https://openalex.org/W2123439629","https://openalex.org/W2148662566","https://openalex.org/W4230721663"],"related_works":["https://openalex.org/W2406833069","https://openalex.org/W2054189915","https://openalex.org/W2333987631","https://openalex.org/W1981754680","https://openalex.org/W4246150425","https://openalex.org/W2164207333","https://openalex.org/W2005066410","https://openalex.org/W2005237684","https://openalex.org/W2006637806","https://openalex.org/W2323318060"],"abstract_inverted_index":{"Abstract":[0],"Die":[1],"hohe":[2],"Diastereoselektivit\u00e4t":[3],"der":[4,37],"Umsetzung":[5],"von":[6,24],"\u03b1\u2010(1H\u20101,2,4\u2010Triazol\u20101\u2010yl)ketonen":[7],"(1,":[8],"4),":[9],"\u03b1\u2010Alkoxy\u2010\u03b1\u2010(1H\u20101,2,4\u2010triazol\u20101\u2010yl)ketonen":[10],"(7,":[11],"13)":[12],"und":[13,44],"entsprechender":[14],"Imidazolderivate":[15],"(10)":[16],"mit":[17],"Grignard\u2010Reagenzien":[18],"wird":[19],"auf":[20],"die":[21,33],"intermedi\u00e4re":[22],"Ausbildung":[23],"postulierten":[25],"Chelatkomplexen":[26],"3,":[27],"9":[28],"zur\u00fcckgef\u00fchrt.":[29],"Dabei":[30],"k\u00f6nnen":[31],"sowohl":[32],"Alkoxygruppe":[34],"als":[35,39],"auch":[36],"Azolsubstituent":[38],"Ligand":[40],"fungieren.":[41],"Von":[42],"2d":[43],"8d":[45],"wurde":[46],"eine":[47],"R\u00f6ntgenstrukturanalyse":[48],"ausgef\u00fchrt.":[49]},"counts_by_year":[],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}