{"id":"https://openalex.org/W2014924315","doi":"https://doi.org/10.1021/jp025860b","title":"Blackbody Infrared Radiative Dissociation of Partially Solvated Tris(2,2\u2018-bipyridine)ruthenium(II) Complex Ions","display_name":"Blackbody Infrared Radiative Dissociation of Partially Solvated Tris(2,2\u2018-bipyridine)ruthenium(II) Complex Ions","publication_year":2002,"publication_date":"2002-09-06","ids":{"openalex":"https://openalex.org/W2014924315","doi":"https://doi.org/10.1021/jp025860b","mag":"2014924315"},"language":"en","primary_location":{"id":"doi:10.1021/jp025860b","doi":"https://doi.org/10.1021/jp025860b","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp025860b","pdf_url":null,"source":{"id":"https://openalex.org/S146709414","display_name":"The Journal of Physical Chemistry A","issn_l":"1089-5639","issn":["1089-5639","1520-5215"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry A","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5066755414","display_name":"Stanley M. Stevens","orcid":"https://orcid.org/0000-0002-1399-0256","observed_orcids":["https://orcid.org/0000-0002-1399-0256"]},"institutions":[{"id":"https://openalex.org/I17974374","display_name":"Universidade de S\u00e3o Paulo","ror":"https://ror.org/036rp1748","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374"]},{"id":"https://openalex.org/I33213144","display_name":"University of Florida","ror":"https://ror.org/02y3ad647","country_code":"US","type":"education","lineage":["https://openalex.org/I33213144"]},{"id":"https://openalex.org/I58956616","display_name":"Case Western Reserve University","ror":"https://ror.org/051fd9666","country_code":"US","type":"education","lineage":["https://openalex.org/I58956616"]},{"id":"https://openalex.org/I88694374","display_name":"Marshall University","ror":"https://ror.org/02erqft81","country_code":"US","type":"education","lineage":["https://openalex.org/I88694374"]}],"countries":["BR","US"],"is_corresponding":false,"raw_author_name":"Stanley M. Stevens","raw_affiliation_strings":["Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, Chemistry Department, Case Western Reserve University, Cleveland, Ohio 44106, Department of Chemistry, Marshall University, Huntington, West Virginia 25755, and Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP, Brazil, Caixa Postal 26077, CEP 05599-970"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, Chemistry Department, Case Western Reserve University, Cleveland, Ohio 44106, Department of Chemistry, Marshall University, Huntington, West Virginia 25755, and Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP, Brazil, Caixa Postal 26077, CEP 05599-970","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I33213144","https://openalex.org/I58956616","https://openalex.org/I88694374"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5002455482","display_name":"Robert C. Dunbar","orcid":"https://orcid.org/0000-0002-5459-5527","observed_orcids":["https://orcid.org/0000-0002-5459-5527"]},"institutions":[{"id":"https://openalex.org/I17974374","display_name":"Universidade de S\u00e3o Paulo","ror":"https://ror.org/036rp1748","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374"]},{"id":"https://openalex.org/I33213144","display_name":"University of Florida","ror":"https://ror.org/02y3ad647","country_code":"US","type":"education","lineage":["https://openalex.org/I33213144"]},{"id":"https://openalex.org/I58956616","display_name":"Case Western Reserve University","ror":"https://ror.org/051fd9666","country_code":"US","type":"education","lineage":["https://openalex.org/I58956616"]},{"id":"https://openalex.org/I88694374","display_name":"Marshall University","ror":"https://ror.org/02erqft81","country_code":"US","type":"education","lineage":["https://openalex.org/I88694374"]}],"countries":["BR","US"],"is_corresponding":false,"raw_author_name":"Robert C. Dunbar","raw_affiliation_strings":["Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, Chemistry Department, Case Western Reserve University, Cleveland, Ohio 44106, Department of Chemistry, Marshall University, Huntington, West Virginia 25755, and Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP, Brazil, Caixa Postal 26077, CEP 05599-970"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, Chemistry Department, Case Western Reserve University, Cleveland, Ohio 44106, Department of Chemistry, Marshall University, Huntington, West Virginia 25755, and Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP, Brazil, Caixa Postal 26077, CEP 05599-970","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I33213144","https://openalex.org/I58956616","https://openalex.org/I88694374"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5006274420","display_name":"William D. Price","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I17974374","display_name":"Universidade de S\u00e3o Paulo","ror":"https://ror.org/036rp1748","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374"]},{"id":"https://openalex.org/I33213144","display_name":"University of Florida","ror":"https://ror.org/02y3ad647","country_code":"US","type":"education","lineage":["https://openalex.org/I33213144"]},{"id":"https://openalex.org/I58956616","display_name":"Case Western Reserve University","ror":"https://ror.org/051fd9666","country_code":"US","type":"education","lineage":["https://openalex.org/I58956616"]},{"id":"https://openalex.org/I88694374","display_name":"Marshall University","ror":"https://ror.org/02erqft81","country_code":"US","type":"education","lineage":["https://openalex.org/I88694374"]}],"countries":["BR","US"],"is_corresponding":false,"raw_author_name":"William D. Price","raw_affiliation_strings":["Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, Chemistry Department, Case Western Reserve University, Cleveland, Ohio 44106, Department of Chemistry, Marshall University, Huntington, West Virginia 25755, and Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP, Brazil, Caixa Postal 26077, CEP 05599-970"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, Chemistry Department, Case Western Reserve University, Cleveland, Ohio 44106, Department of Chemistry, Marshall University, Huntington, West Virginia 25755, and Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP, Brazil, Caixa Postal 26077, CEP 05599-970","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I33213144","https://openalex.org/I58956616","https://openalex.org/I88694374"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5069079201","display_name":"Marcelo  Martins Sena","orcid":"https://orcid.org/0000-0001-5693-9015","observed_orcids":["https://orcid.org/0000-0001-5693-9015"]},"institutions":[{"id":"https://openalex.org/I17974374","display_name":"Universidade de S\u00e3o Paulo","ror":"https://ror.org/036rp1748","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374"]},{"id":"https://openalex.org/I33213144","display_name":"University of Florida","ror":"https://ror.org/02y3ad647","country_code":"US","type":"education","lineage":["https://openalex.org/I33213144"]},{"id":"https://openalex.org/I58956616","display_name":"Case Western Reserve University","ror":"https://ror.org/051fd9666","country_code":"US","type":"education","lineage":["https://openalex.org/I58956616"]},{"id":"https://openalex.org/I88694374","display_name":"Marshall University","ror":"https://ror.org/02erqft81","country_code":"US","type":"education","lineage":["https://openalex.org/I88694374"]}],"countries":["BR","US"],"is_corresponding":false,"raw_author_name":"Marcelo Sena","raw_affiliation_strings":["Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, Chemistry Department, Case Western Reserve University, Cleveland, Ohio 44106, Department of Chemistry, Marshall University, Huntington, West Virginia 25755, and Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP, Brazil, Caixa Postal 26077, CEP 05599-970"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, Chemistry Department, Case Western Reserve University, Cleveland, Ohio 44106, Department of Chemistry, Marshall University, Huntington, West Virginia 25755, and Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP, Brazil, Caixa Postal 26077, CEP 05599-970","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I33213144","https://openalex.org/I58956616","https://openalex.org/I88694374"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5025702872","display_name":"Clifford H. Watson","orcid":"https://orcid.org/0000-0003-0480-4092","observed_orcids":["https://orcid.org/0000-0003-0480-4092"]},"institutions":[{"id":"https://openalex.org/I17974374","display_name":"Universidade de S\u00e3o Paulo","ror":"https://ror.org/036rp1748","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374"]},{"id":"https://openalex.org/I33213144","display_name":"University of Florida","ror":"https://ror.org/02y3ad647","country_code":"US","type":"education","lineage":["https://openalex.org/I33213144"]},{"id":"https://openalex.org/I58956616","display_name":"Case Western Reserve University","ror":"https://ror.org/051fd9666","country_code":"US","type":"education","lineage":["https://openalex.org/I58956616"]},{"id":"https://openalex.org/I88694374","display_name":"Marshall University","ror":"https://ror.org/02erqft81","country_code":"US","type":"education","lineage":["https://openalex.org/I88694374"]}],"countries":["BR","US"],"is_corresponding":false,"raw_author_name":"Clifford H. Watson","raw_affiliation_strings":["Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, Chemistry Department, Case Western Reserve University, Cleveland, Ohio 44106, Department of Chemistry, Marshall University, Huntington, West Virginia 25755, and Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP, Brazil, Caixa Postal 26077, CEP 05599-970"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, Chemistry Department, Case Western Reserve University, Cleveland, Ohio 44106, Department of Chemistry, Marshall University, Huntington, West Virginia 25755, and Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP, Brazil, Caixa Postal 26077, CEP 05599-970","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I33213144","https://openalex.org/I58956616","https://openalex.org/I88694374"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036245855","display_name":"Linda S. Nichols","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I17974374","display_name":"Universidade de S\u00e3o Paulo","ror":"https://ror.org/036rp1748","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374"]},{"id":"https://openalex.org/I33213144","display_name":"University of Florida","ror":"https://ror.org/02y3ad647","country_code":"US","type":"education","lineage":["https://openalex.org/I33213144"]},{"id":"https://openalex.org/I58956616","display_name":"Case Western Reserve University","ror":"https://ror.org/051fd9666","country_code":"US","type":"education","lineage":["https://openalex.org/I58956616"]},{"id":"https://openalex.org/I88694374","display_name":"Marshall University","ror":"https://ror.org/02erqft81","country_code":"US","type":"education","lineage":["https://openalex.org/I88694374"]}],"countries":["BR","US"],"is_corresponding":false,"raw_author_name":"Linda S. Nichols","raw_affiliation_strings":["Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, Chemistry Department, Case Western Reserve University, Cleveland, Ohio 44106, Department of Chemistry, Marshall University, Huntington, West Virginia 25755, and Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP, Brazil, Caixa Postal 26077, CEP 05599-970"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, Chemistry Department, Case Western Reserve University, Cleveland, Ohio 44106, Department of Chemistry, Marshall University, Huntington, West Virginia 25755, and Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP, Brazil, Caixa Postal 26077, CEP 05599-970","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I33213144","https://openalex.org/I58956616","https://openalex.org/I88694374"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5103436973","display_name":"Jos\u00e9 Manuel Riveros","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I17974374","display_name":"Universidade de S\u00e3o Paulo","ror":"https://ror.org/036rp1748","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374"]},{"id":"https://openalex.org/I33213144","display_name":"University of Florida","ror":"https://ror.org/02y3ad647","country_code":"US","type":"education","lineage":["https://openalex.org/I33213144"]},{"id":"https://openalex.org/I58956616","display_name":"Case Western Reserve University","ror":"https://ror.org/051fd9666","country_code":"US","type":"education","lineage":["https://openalex.org/I58956616"]},{"id":"https://openalex.org/I88694374","display_name":"Marshall University","ror":"https://ror.org/02erqft81","country_code":"US","type":"education","lineage":["https://openalex.org/I88694374"]}],"countries":["BR","US"],"is_corresponding":false,"raw_author_name":"Jose M. Riveros","raw_affiliation_strings":["Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, Chemistry Department, Case Western Reserve University, Cleveland, Ohio 44106, Department of Chemistry, Marshall University, Huntington, West Virginia 25755, and Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP, Brazil, Caixa Postal 26077, CEP 05599-970"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, Chemistry Department, Case Western Reserve University, Cleveland, Ohio 44106, Department of Chemistry, Marshall University, Huntington, West Virginia 25755, and Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP, Brazil, Caixa Postal 26077, CEP 05599-970","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I33213144","https://openalex.org/I58956616","https://openalex.org/I88694374"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110119618","display_name":"David E. Richardson","orcid":"https://orcid.org/0009-0005-6453-9173","observed_orcids":["https://orcid.org/0009-0005-6453-9173"]},"institutions":[{"id":"https://openalex.org/I17974374","display_name":"Universidade de S\u00e3o Paulo","ror":"https://ror.org/036rp1748","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374"]},{"id":"https://openalex.org/I33213144","display_name":"University of Florida","ror":"https://ror.org/02y3ad647","country_code":"US","type":"education","lineage":["https://openalex.org/I33213144"]},{"id":"https://openalex.org/I58956616","display_name":"Case Western Reserve University","ror":"https://ror.org/051fd9666","country_code":"US","type":"education","lineage":["https://openalex.org/I58956616"]},{"id":"https://openalex.org/I88694374","display_name":"Marshall University","ror":"https://ror.org/02erqft81","country_code":"US","type":"education","lineage":["https://openalex.org/I88694374"]}],"countries":["BR","US"],"is_corresponding":false,"raw_author_name":"David E. Richardson","raw_affiliation_strings":["Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, Chemistry Department, Case Western Reserve University, Cleveland, Ohio 44106, Department of Chemistry, Marshall University, Huntington, West Virginia 25755, and Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP, Brazil, Caixa Postal 26077, CEP 05599-970"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, Chemistry Department, Case Western Reserve University, Cleveland, Ohio 44106, Department of Chemistry, Marshall University, Huntington, West Virginia 25755, and Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP, Brazil, Caixa Postal 26077, CEP 05599-970","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I33213144","https://openalex.org/I58956616","https://openalex.org/I88694374"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5013414360","display_name":"John R. Eyler","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I17974374","display_name":"Universidade de S\u00e3o Paulo","ror":"https://ror.org/036rp1748","country_code":"BR","type":"education","lineage":["https://openalex.org/I17974374"]},{"id":"https://openalex.org/I33213144","display_name":"University of Florida","ror":"https://ror.org/02y3ad647","country_code":"US","type":"education","lineage":["https://openalex.org/I33213144"]},{"id":"https://openalex.org/I58956616","display_name":"Case Western Reserve University","ror":"https://ror.org/051fd9666","country_code":"US","type":"education","lineage":["https://openalex.org/I58956616"]},{"id":"https://openalex.org/I88694374","display_name":"Marshall University","ror":"https://ror.org/02erqft81","country_code":"US","type":"education","lineage":["https://openalex.org/I88694374"]}],"countries":["BR","US"],"is_corresponding":false,"raw_author_name":"John R. Eyler","raw_affiliation_strings":["Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, Chemistry Department, Case Western Reserve University, Cleveland, Ohio 44106, Department of Chemistry, Marshall University, Huntington, West Virginia 25755, and Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP, Brazil, Caixa Postal 26077, CEP 05599-970"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, P.O. Box 117200, University of Florida, Gainesville, Florida 32611-7200, Chemistry Department, Case Western Reserve University, Cleveland, Ohio 44106, Department of Chemistry, Marshall University, Huntington, West Virginia 25755, and Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP, Brazil, Caixa Postal 26077, CEP 05599-970","institution_ids":["https://openalex.org/I17974374","https://openalex.org/I33213144","https://openalex.org/I58956616","https://openalex.org/I88694374"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":4,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":1.3596,"has_fulltext":false,"cited_by_count":17,"citation_normalized_percentile":{"value":0.77704857,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":96},"biblio":{"volume":"106","issue":"42","first_page":"9686","last_page":"9694"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10683","display_name":"Mass Spectrometry Techniques and Applications","score":0.9779999852180481,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10683","display_name":"Mass Spectrometry Techniques and Applications","score":0.9779999852180481,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.011900000274181366,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.0024999999441206455,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/blackbody-infrared-radiative-dissociation","display_name":"blackbody infrared radiative dissociation","score":0.8460000157356262},{"id":"https://openalex.org/keywords/ru-bpy-3-2","display_name":"Ru(bpy)3 2+","score":0.8960000276565552},{"id":"https://openalex.org/keywords/solvation-shell","display_name":"solvation shell","score":0.5820000171661377},{"id":"https://openalex.org/keywords/activation-energy","display_name":"activation energy","score":0.6110000014305115},{"id":"https://openalex.org/keywords/solvation-energy","display_name":"solvation energy","score":0.6919999718666077},{"id":"https://openalex.org/keywords/zindo-calculations","display_name":"ZINDO calculations","score":0.5770000219345093},{"id":"https://openalex.org/keywords/vibrational-frequencies","display_name":"vibrational frequencies","score":0.8299999833106995},{"id":"https://openalex.org/keywords/ruthenium-ii-complexes","display_name":"ruthenium(II) complexes","score":0.5569999814033508}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7776049375534058},{"id":"https://openalex.org/C102931765","wikidata":"https://www.wikidata.org/wiki/Q189673","display_name":"Dissociation (chemistry)","level":2,"score":0.6267867088317871},{"id":"https://openalex.org/C555196967","wikidata":"https://www.wikidata.org/wiki/Q1086","display_name":"Ruthenium","level":3,"score":0.6009954214096069},{"id":"https://openalex.org/C148093993","wikidata":"https://www.wikidata.org/wiki/Q739398","display_name":"Solvation","level":3,"score":0.5006015300750732},{"id":"https://openalex.org/C3896420","wikidata":"https://www.wikidata.org/wiki/Q3710339","display_name":"Infrared multiphoton dissociation","level":3,"score":0.4483633041381836},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.4480934739112854},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.3847362995147705},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.3723708391189575},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.3424297869205475},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.10244148969650269},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/jp025860b","doi":"https://doi.org/10.1021/jp025860b","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp025860b","pdf_url":null,"source":{"id":"https://openalex.org/S146709414","display_name":"The Journal of Physical Chemistry A","issn_l":"1089-5639","issn":["1089-5639","1520-5215"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry A","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":50,"referenced_works":["https://openalex.org/W1965529577","https://openalex.org/W1966182479","https://openalex.org/W1968512837","https://openalex.org/W1970393749","https://openalex.org/W1971983473","https://openalex.org/W1974689663","https://openalex.org/W1974732006","https://openalex.org/W1974788134","https://openalex.org/W1975508076","https://openalex.org/W1976305412","https://openalex.org/W1980687876","https://openalex.org/W1984530468","https://openalex.org/W1988195405","https://openalex.org/W1991647123","https://openalex.org/W1992355745","https://openalex.org/W1992576083","https://openalex.org/W2000758415","https://openalex.org/W2000821086","https://openalex.org/W2002599428","https://openalex.org/W2003347556","https://openalex.org/W2005695502","https://openalex.org/W2012216630","https://openalex.org/W2013914375","https://openalex.org/W2015826861","https://openalex.org/W2020017439","https://openalex.org/W2022402530","https://openalex.org/W2031498259","https://openalex.org/W2034376262","https://openalex.org/W2036163944","https://openalex.org/W2044490585","https://openalex.org/W2048345443","https://openalex.org/W2049599999","https://openalex.org/W2053223828","https://openalex.org/W2055569741","https://openalex.org/W2056683515","https://openalex.org/W2063055915","https://openalex.org/W2068617439","https://openalex.org/W2073292063","https://openalex.org/W2084135044","https://openalex.org/W2084834026","https://openalex.org/W2087152379","https://openalex.org/W2088460973","https://openalex.org/W2089457306","https://openalex.org/W2123987607","https://openalex.org/W2132905138","https://openalex.org/W2133192126","https://openalex.org/W2142516950","https://openalex.org/W2144142072","https://openalex.org/W2323174283","https://openalex.org/W2951470060"],"related_works":["https://openalex.org/W2027747223","https://openalex.org/W2016711004","https://openalex.org/W4388563694","https://openalex.org/W2031498259","https://openalex.org/W2049282183","https://openalex.org/W2470065749","https://openalex.org/W1990997378","https://openalex.org/W2007562444","https://openalex.org/W2543899860","https://openalex.org/W2064102505"],"abstract_inverted_index":{"Electrospray":[0],"ionization":[1],"Fourier":[2],"transform":[3],"ion":[4,175],"cyclotron":[5],"resonance":[6],"(ESI-FTICR)":[7],"mass":[8],"spectrometry":[9],"has":[10,94],"been":[11,95,206],"utilized":[12],"to":[13,58,62,104,108,145,184,208,245],"study":[14],"solvates":[15],"of":[16,20,41,88,112,126,138,156,158,163,171,236,242,261,269],"tris(2,2\u2018-bipyridine)ruthenium(II).":[17],"Spontaneous":[18],"dissociation":[19,84,93,113,128,192],"solvent":[21,262],"(acetonitrile,":[22],"acetone,":[23],"or":[24],"methyl":[25],"ethyl":[26],"ketone)":[27],"from":[28,101,150],"the":[29,44,79,86,116,124,127,154,161,164,172,177,189,230,243,246,253,265],"solvation":[30,267],"shell":[31,268],"occurs":[32],"when":[33],"these":[34,51],"ions":[35],"are":[36,53,182],"trapped":[37],"for":[38,72,215,225,259],"extended":[39],"periods":[40],"time":[42],"in":[43,50,115,252,264],"ICR":[45],"cell.":[46],"The":[47,119],"pressures":[48,99,132],"employed":[49],"experiments":[52],"low":[54],"enough":[55],"(10":[56],"-9":[57,103],"10":[59,102,105],"-8":[60,106],"mbar)":[61],"neglect":[63],"(or":[64],"partially":[65],"neglect)":[66],"collisional":[67],"activation":[68,148,180],"as":[69],"a":[70,110,168],"means":[71],"dissociation.":[73],"Therefore,":[74],"it":[75],"is":[76],"suggested":[77],"that":[78,133],"solvated":[80],"ruthenium":[81,173,247],"species":[82],"undergo":[83],"following":[85],"absorption":[87],"blackbody":[89],"infrared":[90],"radiation.":[91],"Solvent\u2212complex":[92],"studied":[96],"at":[97,131,167],"several":[98],"ranging":[100],"mbar":[107],"provide":[109,238],"range":[111,254],"data":[114],"low-pressure":[117],"regime.":[118],"results":[120],"reported":[121],"here":[122],"demonstrate":[123],"consistency":[125],"rate":[129,165],"constants":[130,166],"differ":[134],"by":[135],"an":[136],"order":[137],"magnitude.":[139],"Temperature":[140],"dependence":[141],"studies":[142],"were":[143,198,221,257],"performed":[144],"extract":[146],"zero-pressure":[147],"energies":[149,181,241,251],"Arrhenius":[151,179],"analyses.":[152],"Given":[153],"number":[155],"degrees":[157],"freedom":[159],"and":[160,202,212,229],"magnitude":[162],"given":[169],"temperature":[170],"complex":[174,248],"solvates,":[176],"experimental":[178,203],"likely":[183],"be":[185],"substantially":[186],"lower":[187],"than":[188],"true":[190],"bond":[191],"energies.":[193],"ZINDO":[194],"semiempirical":[195],"methods,":[196],"which":[197,237],"calibrated":[199],"against":[200],"DFT":[201],"values,":[204],"have":[205],"used":[207,223],"determine":[209],"optimized":[210],"structures":[211],"vibrational":[213],"frequencies":[214],"bipyridine-containing":[216],"ruthenium(II)":[217,271],"solvates.":[218],"These":[219],"parameters":[220],"then":[222],"both":[224],"master":[226],"equation":[227],"modeling":[228],"truncated":[231],"Boltzmann/modified":[232],"Tolman":[233],"approach,":[234],"each":[235],"calculated":[239],"binding":[240,260],"solvents":[244],"ion.":[249],"Solvation":[250],"15\u221220":[255],"kcal/mol":[256],"found":[258],"molecules":[263],"first":[266],"tris(2,2\u2018-bipyridine)":[270],"ions.":[272]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2013,"cited_by_count":1},{"year":2012,"cited_by_count":2}],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2016-06-24T00:00:00"}