{"id":"https://openalex.org/W2013803494","doi":"https://doi.org/10.1002/zaac.200400496","title":"3\u2010(Arylhydrazono)pentane\u20102, 4\u2010diones and their Complexes with Copper(II) and Nickel(II) \u2014 Synthesis and Crystal Structures","display_name":"3\u2010(Arylhydrazono)pentane\u20102, 4\u2010diones and their Complexes with Copper(II) and Nickel(II) \u2014 Synthesis and Crystal Structures","publication_year":2005,"publication_date":"2005-03-23","ids":{"openalex":"https://openalex.org/W2013803494","doi":"https://doi.org/10.1002/zaac.200400496","mag":"2013803494"},"language":"en","primary_location":{"id":"doi:10.1002/zaac.200400496","doi":"https://doi.org/10.1002/zaac.200400496","is_oa":false,"landing_page_url":"https://doi.org/10.1002/zaac.200400496","pdf_url":null,"source":{"id":"https://openalex.org/S171987449","display_name":"Zeitschrift f\u00fcr anorganische und allgemeine Chemie","issn_l":"0044-2313","issn":["0044-2313","0863-1778","1521-3749"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","jufo-1","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Zeitschrift f\u00fcr anorganische und allgemeine Chemie","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5006426685","display_name":"J. Marten","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I61893789","display_name":"TU Bergakademie Freiberg","ror":"https://ror.org/031vc2293","country_code":"DE","type":"education","lineage":["https://openalex.org/I61893789"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"J. Marten","raw_affiliation_strings":["Freiberg/Sachsen, Institut fu\u0308r Organische Chemie der TU Bergakademie Freiberg","Freiberg/Sachsen, Institut f\u00fcr Organische Chemie der TU Bergakademie Freiberg"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Freiberg/Sachsen, Institut fu\u0308r Organische Chemie der TU Bergakademie Freiberg","institution_ids":["https://openalex.org/I61893789"]},{"raw_affiliation_string":"Freiberg/Sachsen, Institut f\u00fcr Organische Chemie der TU Bergakademie Freiberg","institution_ids":["https://openalex.org/I61893789"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113617892","display_name":"Wilhelm Seichter","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I61893789","display_name":"TU Bergakademie Freiberg","ror":"https://ror.org/031vc2293","country_code":"DE","type":"education","lineage":["https://openalex.org/I61893789"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"W. Seichter","raw_affiliation_strings":["Freiberg/Sachsen, Institut fu\u0308r Organische Chemie der TU Bergakademie Freiberg","Freiberg/Sachsen, Institut f\u00fcr Organische Chemie der TU Bergakademie Freiberg"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Freiberg/Sachsen, Institut fu\u0308r Organische Chemie der TU Bergakademie Freiberg","institution_ids":["https://openalex.org/I61893789"]},{"raw_affiliation_string":"Freiberg/Sachsen, Institut f\u00fcr Organische Chemie der TU Bergakademie Freiberg","institution_ids":["https://openalex.org/I61893789"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5002580128","display_name":"Edwin Weber","orcid":"https://orcid.org/0000-0002-5896-1205","observed_orcids":["https://orcid.org/0000-0002-5896-1205"]},"institutions":[{"id":"https://openalex.org/I61893789","display_name":"TU Bergakademie Freiberg","ror":"https://ror.org/031vc2293","country_code":"DE","type":"education","lineage":["https://openalex.org/I61893789"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"E. Weber","raw_affiliation_strings":["Institut f\u00fcr Organische Chemie, TU Bergakademie Freiberg, Leipziger Str. 29, D\u201009596 Freiberg/Sachs. Fax: Int. Code 49\u2010(0)3731/393170"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie, TU Bergakademie Freiberg, Leipziger Str. 29, D\u201009596 Freiberg/Sachs. Fax: Int. Code 49\u2010(0)3731/393170","institution_ids":["https://openalex.org/I61893789"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I61893789"],"apc_list":{"value":3960,"currency":"USD","value_usd":3960},"apc_paid":null,"fwci":0.9238,"has_fulltext":false,"cited_by_count":47,"citation_normalized_percentile":{"value":0.73018116,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":99},"biblio":{"volume":"631","issue":"5","first_page":"869","last_page":"877"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.9442999958992004,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.9442999958992004,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.03240000084042549,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.009600000455975533,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/hydrazones","display_name":"hydrazones","score":0.7929999828338623},{"id":"https://openalex.org/keywords/cu-ii-complexes","display_name":"copper(II) complexes","score":0.953000009059906},{"id":"https://openalex.org/keywords/nickel-ii-complexes","display_name":"nickel(II) complexes","score":1.0},{"id":"https://openalex.org/keywords/diazonium-salts","display_name":"diazonium salts","score":0.859000027179718},{"id":"https://openalex.org/keywords/intramolecular-n-ho-hydrogen-bond","display_name":"intramolecular N-H\u22efO hydrogen bond","score":0.8640000224113464},{"id":"https://openalex.org/keywords/hydrazone-tautomerism","display_name":"hydrazone tautomerism","score":0.9380000233650208},{"id":"https://openalex.org/keywords/coordination-geometry","display_name":"coordination geometry","score":0.722000002861023},{"id":"https://openalex.org/keywords/crystal-packing","display_name":"crystal packing","score":0.7310000061988831},{"id":"https://openalex.org/keywords/supramolecular-networks","display_name":"supramolecular networks","score":0.9160000085830688}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7882809638977051},{"id":"https://openalex.org/C2777589835","wikidata":"https://www.wikidata.org/wiki/Q150429","display_name":"Pentane","level":2,"score":0.6725904941558838},{"id":"https://openalex.org/C2780349576","wikidata":"https://www.wikidata.org/wiki/Q416007","display_name":"Hydrazone","level":2,"score":0.6665321588516235},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.6602205038070679},{"id":"https://openalex.org/C111233374","wikidata":"https://www.wikidata.org/wiki/Q334640","display_name":"Tautomer","level":2,"score":0.6242237091064453},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.6203797459602356},{"id":"https://openalex.org/C504270822","wikidata":"https://www.wikidata.org/wiki/Q744","display_name":"Nickel","level":2,"score":0.6046164035797119},{"id":"https://openalex.org/C93275456","wikidata":"https://www.wikidata.org/wiki/Q756449","display_name":"Supramolecular chemistry","level":3,"score":0.5404006838798523},{"id":"https://openalex.org/C75079739","wikidata":"https://www.wikidata.org/wiki/Q1571801","display_name":"Intramolecular force","level":2,"score":0.5318405628204346},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.4854903519153595},{"id":"https://openalex.org/C544778455","wikidata":"https://www.wikidata.org/wiki/Q753","display_name":"Copper","level":2,"score":0.4843786656856537},{"id":"https://openalex.org/C194196696","wikidata":"https://www.wikidata.org/wiki/Q1753378","display_name":"Coordination geometry","level":4,"score":0.4457882344722748},{"id":"https://openalex.org/C198819137","wikidata":"https://www.wikidata.org/wiki/Q188884","display_name":"Octahedron","level":3,"score":0.418948769569397},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3634204864501953},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.2949292063713074},{"id":"https://openalex.org/C112887158","wikidata":"https://www.wikidata.org/wiki/Q169324","display_name":"Hydrogen bond","level":3,"score":0.12004303932189941},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1013512909412384},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/zaac.200400496","doi":"https://doi.org/10.1002/zaac.200400496","is_oa":false,"landing_page_url":"https://doi.org/10.1002/zaac.200400496","pdf_url":null,"source":{"id":"https://openalex.org/S171987449","display_name":"Zeitschrift f\u00fcr anorganische und allgemeine Chemie","issn_l":"0044-2313","issn":["0044-2313","0863-1778","1521-3749"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","jufo-1","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Zeitschrift f\u00fcr anorganische und allgemeine Chemie","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":23,"referenced_works":["https://openalex.org/W614573190","https://openalex.org/W1971657568","https://openalex.org/W1973642790","https://openalex.org/W1987565580","https://openalex.org/W2003035408","https://openalex.org/W2010416487","https://openalex.org/W2030200821","https://openalex.org/W2048631643","https://openalex.org/W2062794671","https://openalex.org/W2067200623","https://openalex.org/W2068046003","https://openalex.org/W2074596879","https://openalex.org/W2076075169","https://openalex.org/W2085493017","https://openalex.org/W2092270072","https://openalex.org/W2094682831","https://openalex.org/W2113701650","https://openalex.org/W2152157528","https://openalex.org/W2164120073","https://openalex.org/W2333579312","https://openalex.org/W2485291212","https://openalex.org/W4206386417","https://openalex.org/W4285719527"],"related_works":["https://openalex.org/W3002950110","https://openalex.org/W1990003107","https://openalex.org/W2056961360","https://openalex.org/W2115435351","https://openalex.org/W2086336063","https://openalex.org/W2966989641","https://openalex.org/W2049520971","https://openalex.org/W2333391059","https://openalex.org/W2058324979","https://openalex.org/W3016000571"],"abstract_inverted_index":{"Abstract":[0],"A":[1],"series":[2],"of":[3,15,21,37,47,54,63,80,93],"new":[4],"3\u2010(arylhydrazono)pentane\u20102,":[5],"4\u2010diones":[6],"(1\u20106)":[7],"synthesized":[8],"from":[9],"pentane\u20102,":[10],"4\u2010dione":[11],"and":[12,28,43,53,116,123,133,147,155],"diazonium":[13],"salts":[14,30],"respective":[16],"anilines":[17],"using":[18],"the":[19,55,64,81,86,108,114,117,129,143,151],"procedure":[20],"Japp\u2010Klingemann":[22],"are":[23,31,59,88,102],"described.":[24],"Complexes":[25],"with":[26],"CuII":[27,130],"NiII":[29,144],"prepared":[32],"(7\u201010,":[33],"respectively).":[34],"Spectroscopic":[35],"properties":[36],"these":[38],"compounds":[39],"have":[40],"been":[41],"studied":[42],"X\u2010ray":[44],"crystal":[45,152],"structures":[46,62,92],"selected":[48],"hydrazones":[49,66],"(3,":[50],"4,":[51],"6)":[52],"hydrazone":[56,82],"complexes":[57,87,131,145],"(7\u201010)":[58],"reported.":[60],"The":[61],"uncomplexed":[65],"feature":[67],"an":[68],"intramolecular":[69],"N\u2010H\u00b7\u00b7\u00b7O":[70],"interaction":[71],"to":[72],"yield":[73],"a":[74],"six\u2010membered":[75,94],"H\u2010bond":[76,157],"ring":[77],"reflecting":[78],"preference":[79],"tautomeric":[83],"structure.":[84],"All":[85],"mononuclear":[89],"2:1":[90],"(L:M)":[91],"chelate":[95],"type":[96],"involving":[97],"N2O2":[98],"binding":[99],"sites":[100],"that":[101],"quadratic":[103,124],"arranged":[104],"but":[105],"differ":[106],"in":[107,128,142],"entire":[109],"coordination":[110,126,140],"environment":[111],"dependent":[112],"on":[113],"metal":[115],"ligand":[118],"substitution":[119],"including":[120],"distorted":[121],"octahedral":[122],"pyramidal":[125],"geometries":[127],"7":[132],"8":[134],"or":[135],"nearly":[136],"regular":[137],"square":[138],"planar":[139],"geometry":[141],"9":[146],"10,":[148],"respectively.":[149],"In":[150],"packings,":[153],"strong":[154],"weak":[156],"interactions":[158],"cause":[159],"supramolecular":[160],"network":[161],"structures.":[162]},"counts_by_year":[{"year":2023,"cited_by_count":3},{"year":2022,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2018,"cited_by_count":2},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":2},{"year":2013,"cited_by_count":4},{"year":2012,"cited_by_count":7}],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2016-06-24T00:00:00"}