{"id":"https://openalex.org/W2013648404","doi":"https://doi.org/10.1039/dt9740001961","title":"Thermal decomposition of primary and secondary amine adducts of triethylaluminium and diethylaluminium halides","display_name":"Thermal decomposition of primary and secondary amine adducts of triethylaluminium and diethylaluminium halides","publication_year":1974,"publication_date":"1974-01-01","ids":{"openalex":"https://openalex.org/W2013648404","doi":"https://doi.org/10.1039/dt9740001961","mag":"2013648404"},"language":"en","primary_location":{"id":"doi:10.1039/dt9740001961","doi":"https://doi.org/10.1039/dt9740001961","is_oa":false,"landing_page_url":"https://doi.org/10.1039/dt9740001961","pdf_url":null,"source":{"id":"https://openalex.org/S4210210551","display_name":"Journal of the Chemical Society Dalton Transactions","issn_l":"1364-5447","issn":["1364-5447","1472-7773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Dalton Transactions","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5085447647","display_name":"Keith Gosling","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Keith Gosling","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":null,"display_name":"Richard E. Bowen","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Richard E. Bowen","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":1.0551,"has_fulltext":false,"cited_by_count":6,"citation_normalized_percentile":{"value":0.69308639,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":"18","first_page":"1961","last_page":"1961"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.37599998712539673,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.37599998712539673,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.29170000553131104,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.12630000710487366,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/thermal-decomposition","display_name":"thermal decomposition","score":0.9010000228881836},{"id":"https://openalex.org/keywords/amine-adducts","display_name":"amine adducts","score":0.847000002861023},{"id":"https://openalex.org/keywords/triethylaluminum","display_name":"triethylaluminum","score":0.9810000061988831},{"id":"https://openalex.org/keywords/adduct-stability","display_name":"adduct stability","score":0.8289999961853027},{"id":"https://openalex.org/keywords/negative-charge-density","display_name":"negative charge density","score":0.609000027179718},{"id":"https://openalex.org/keywords/zero-order-kinetics","display_name":"zero-order kinetics","score":0.9480000138282776},{"id":"https://openalex.org/keywords/surface-catalysis","display_name":"surface catalysis","score":0.8159999847412109},{"id":"https://openalex.org/keywords/halogen-substituent-effects","display_name":"halogen substituent effects","score":0.4740000069141388}],"concepts":[{"id":"https://openalex.org/C108204754","wikidata":"https://www.wikidata.org/wiki/Q353392","display_name":"Adduct","level":2,"score":0.825363039970398},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7480005025863647},{"id":"https://openalex.org/C160434732","wikidata":"https://www.wikidata.org/wiki/Q2611095","display_name":"Thermal decomposition","level":2,"score":0.7085825204849243},{"id":"https://openalex.org/C171560689","wikidata":"https://www.wikidata.org/wiki/Q193086","display_name":"Halide","level":2,"score":0.575900137424469},{"id":"https://openalex.org/C131779359","wikidata":"https://www.wikidata.org/wiki/Q471875","display_name":"Amine gas treating","level":2,"score":0.5314978957176208},{"id":"https://openalex.org/C124681953","wikidata":"https://www.wikidata.org/wiki/Q339062","display_name":"Decomposition","level":2,"score":0.4739170968532562},{"id":"https://openalex.org/C513153333","wikidata":"https://www.wikidata.org/wiki/Q663","display_name":"Aluminium","level":2,"score":0.45460671186447144},{"id":"https://openalex.org/C537208039","wikidata":"https://www.wikidata.org/wiki/Q627","display_name":"Nitrogen","level":2,"score":0.4503357708454132},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.4404032230377197},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.43547993898391724},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.38871026039123535},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.3674114942550659},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.22598430514335632},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/dt9740001961","doi":"https://doi.org/10.1039/dt9740001961","is_oa":false,"landing_page_url":"https://doi.org/10.1039/dt9740001961","pdf_url":null,"source":{"id":"https://openalex.org/S4210210551","display_name":"Journal of the Chemical Society Dalton Transactions","issn_l":"1364-5447","issn":["1364-5447","1472-7773"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the Chemical Society, Dalton Transactions","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2152625171","https://openalex.org/W1979143876","https://openalex.org/W2949878967","https://openalex.org/W1974084410","https://openalex.org/W2086543017","https://openalex.org/W2091499751","https://openalex.org/W1964340595","https://openalex.org/W1487661158","https://openalex.org/W2026980390","https://openalex.org/W2043225592"],"abstract_inverted_index":{"The":[0],"stabilities":[1],"of":[2,11,44,53,64,71,77,88,92],"the":[3,14,45,50,54,65,72,75,81,89,96],"adducts":[4],"Et2XAl\u2013NHMe2":[5],"and":[6,31,60],"Et2XAl\u2013NH2But":[7],"toward":[8],"thermal":[9,90],"elimination":[10],"ethane":[12],"follow":[13],"order":[15,26],"X":[16],"=":[17],"Et":[18],"<":[19,21,23],"Cl":[20],"Br":[22],"I.":[24],"This":[25],"is":[27,40,84,104],"correlated":[28],"with":[29],"i.r.":[30],"n.m.r.":[32],"spectral":[33],"data":[34],"to":[35,58],"show":[36],"that":[37,95,102],"adduct":[38],"stability":[39],"principally":[41],"a":[42,62],"function":[43,63],"negative":[46],"charge":[47],"density":[48,79],"on":[49],"\u03b1-carbon":[51],"atoms":[52],"ethyl":[55],"groups":[56],"bonded":[57],"aluminium,":[59],"not":[61],"nitrogen":[66],"proton":[67],"acidity.":[68],"A":[69,86],"discussion":[70],"factors":[73],"influencing":[74],"distribution":[76],"electron":[78],"in":[80],"Al\u2013C":[82],"bond":[83],"presented.":[85],"study":[87],"decomposition":[91],"Et2ClAl\u2013NHMe2":[93],"shows":[94],"reaction":[97],"follows":[98],"zero-order":[99],"kinetics,":[100],"indicating":[101],"it":[103],"predominantly":[105],"surface":[106],"catalysed.":[107]},"counts_by_year":[],"updated_date":"2026-09-27T08:07:27.782135","created_date":"2016-06-24T00:00:00"}