{"id":"https://openalex.org/W2013484596","doi":"https://doi.org/10.1021/om060491h","title":"Reactivity of Organolanthanide Derivatives Containing the o-Aminothiophenolate Ligand toward Carbodiimide","display_name":"Reactivity of Organolanthanide Derivatives Containing the o-Aminothiophenolate Ligand toward Carbodiimide","publication_year":2006,"publication_date":"2006-08-18","ids":{"openalex":"https://openalex.org/W2013484596","doi":"https://doi.org/10.1021/om060491h","mag":"2013484596"},"language":"en","primary_location":{"id":"doi:10.1021/om060491h","doi":"https://doi.org/10.1021/om060491h","is_oa":false,"landing_page_url":"https://doi.org/10.1021/om060491h","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5102148573","display_name":"Liping Ma","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I24943067","display_name":"Fudan University","ror":"https://ror.org/013q1eq08","country_code":"CN","type":"education","lineage":["https://openalex.org/I24943067"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Liping Ma","raw_affiliation_strings":["Department of Chemistry, Fudan University, Shanghai 200433, People's Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Fudan University, Shanghai 200433, People's Republic of China","institution_ids":["https://openalex.org/I24943067"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100436689","display_name":"Jie Zhang","orcid":"https://orcid.org/0000-0002-0584-6609","observed_orcids":["https://orcid.org/0000-0002-0584-6609"]},"institutions":[{"id":"https://openalex.org/I24943067","display_name":"Fudan University","ror":"https://ror.org/013q1eq08","country_code":"CN","type":"education","lineage":["https://openalex.org/I24943067"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Jie Zhang","raw_affiliation_strings":["Department of Chemistry, Fudan University, Shanghai 200433, People's Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Fudan University, Shanghai 200433, People's Republic of China","institution_ids":["https://openalex.org/I24943067"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5071598124","display_name":"Zhengxing Zhang","orcid":"https://orcid.org/0000-0002-3857-8583","observed_orcids":["https://orcid.org/0000-0002-3857-8583"]},"institutions":[{"id":"https://openalex.org/I24943067","display_name":"Fudan University","ror":"https://ror.org/013q1eq08","country_code":"CN","type":"education","lineage":["https://openalex.org/I24943067"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zhengxing Zhang","raw_affiliation_strings":["Department of Chemistry, Fudan University, Shanghai 200433, People's Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Fudan University, Shanghai 200433, People's Republic of China","institution_ids":["https://openalex.org/I24943067"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5115595506","display_name":"Ruifang Cai","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I24943067","display_name":"Fudan University","ror":"https://ror.org/013q1eq08","country_code":"CN","type":"education","lineage":["https://openalex.org/I24943067"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Ruifang Cai","raw_affiliation_strings":["Department of Chemistry, Fudan University, Shanghai 200433, People's Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Fudan University, Shanghai 200433, People's Republic of China","institution_ids":["https://openalex.org/I24943067"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5006830394","display_name":"Zhenxia Chen","orcid":"https://orcid.org/0000-0001-8307-4184","observed_orcids":["https://orcid.org/0000-0001-8307-4184"]},"institutions":[{"id":"https://openalex.org/I24943067","display_name":"Fudan University","ror":"https://ror.org/013q1eq08","country_code":"CN","type":"education","lineage":["https://openalex.org/I24943067"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zhenxia Chen","raw_affiliation_strings":["Department of Chemistry, Fudan University, Shanghai 200433, People's Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Fudan University, Shanghai 200433, People's Republic of China","institution_ids":["https://openalex.org/I24943067"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5072816186","display_name":"Xigeng Zhou","orcid":"https://orcid.org/0000-0003-2948-9930","observed_orcids":["https://orcid.org/0000-0003-2948-9930"]},"institutions":[{"id":"https://openalex.org/I24943067","display_name":"Fudan University","ror":"https://ror.org/013q1eq08","country_code":"CN","type":"education","lineage":["https://openalex.org/I24943067"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Xigeng Zhou","raw_affiliation_strings":["Department of Chemistry, Fudan University, Shanghai 200433, People's Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Fudan University, Shanghai 200433, People's Republic of China","institution_ids":["https://openalex.org/I24943067"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I24943067"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.6083,"has_fulltext":false,"cited_by_count":27,"citation_normalized_percentile":{"value":0.88976797,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"25","issue":"19","first_page":"4571","last_page":"4578"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9164999723434448,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9164999723434448,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.026599999517202377,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.026399999856948853,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/carbodiimides","display_name":"carbodiimides","score":0.8880000114440918},{"id":"https://openalex.org/keywords/n-n-diisopropylcarbodiimide","display_name":"N,N'-diisopropylcarbodiimide","score":0.9430000185966492},{"id":"https://openalex.org/keywords/lanthanum-complexes","display_name":"lanthanum complexes","score":0.6290000081062317},{"id":"https://openalex.org/keywords/ytterbium-complexes","display_name":"ytterbium complexes","score":0.953000009059906},{"id":"https://openalex.org/keywords/dysprosium-complexes","display_name":"dysprosium complexes","score":0.9929999709129333},{"id":"https://openalex.org/keywords/erbium-complexes","display_name":"erbium complexes","score":0.9169999957084656},{"id":"https://openalex.org/keywords/cyclopentadienyl-complexes","display_name":"cyclopentadienyl complexes","score":0.6919999718666077},{"id":"https://openalex.org/keywords/bridging-amide-ligands","display_name":"bridging amide ligands","score":0.4269999861717224},{"id":"https://openalex.org/keywords/protolysis","display_name":"protolysis","score":0.5170000195503235}],"concepts":[{"id":"https://openalex.org/C2775997276","wikidata":"https://www.wikidata.org/wiki/Q420241","display_name":"Carbodiimide","level":2,"score":0.9399933218955994},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9390649795532227},{"id":"https://openalex.org/C181458950","wikidata":"https://www.wikidata.org/wiki/Q2855060","display_name":"Cyclopentadienyl complex","level":3,"score":0.8462644815444946},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.7046313285827637},{"id":"https://openalex.org/C2779546866","wikidata":"https://www.wikidata.org/wiki/Q531306","display_name":"Dimer","level":2,"score":0.6686651706695557},{"id":"https://openalex.org/C2778142098","wikidata":"https://www.wikidata.org/wiki/Q15779","display_name":"Toluene","level":2,"score":0.6165332198143005},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.5563564896583557},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.5479745864868164},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.4305225908756256},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.22861412167549133},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.22554951906204224},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.21316438913345337},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/om060491h","doi":"https://doi.org/10.1021/om060491h","is_oa":false,"landing_page_url":"https://doi.org/10.1021/om060491h","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":54,"referenced_works":["https://openalex.org/W11455398","https://openalex.org/W1965556286","https://openalex.org/W1975650978","https://openalex.org/W1983196938","https://openalex.org/W1986775748","https://openalex.org/W1987968139","https://openalex.org/W1995444410","https://openalex.org/W1995606707","https://openalex.org/W1999133968","https://openalex.org/W2002248154","https://openalex.org/W2002467664","https://openalex.org/W2004822266","https://openalex.org/W2005906194","https://openalex.org/W2008793470","https://openalex.org/W2012271631","https://openalex.org/W2014926538","https://openalex.org/W2016191867","https://openalex.org/W2016659736","https://openalex.org/W2018101375","https://openalex.org/W2021627309","https://openalex.org/W2022842187","https://openalex.org/W2027270982","https://openalex.org/W2028111704","https://openalex.org/W2028692248","https://openalex.org/W2035424916","https://openalex.org/W2035578154","https://openalex.org/W2035871617","https://openalex.org/W2038431710","https://openalex.org/W2039280267","https://openalex.org/W2043068345","https://openalex.org/W2050687820","https://openalex.org/W2052780983","https://openalex.org/W2053226959","https://openalex.org/W2060553548","https://openalex.org/W2061896890","https://openalex.org/W2071231936","https://openalex.org/W2073016027","https://openalex.org/W2079498968","https://openalex.org/W2081190477","https://openalex.org/W2081973768","https://openalex.org/W2083846738","https://openalex.org/W2086717437","https://openalex.org/W2089697072","https://openalex.org/W2093575210","https://openalex.org/W2114395718","https://openalex.org/W2132391195","https://openalex.org/W2164076542","https://openalex.org/W2167464092","https://openalex.org/W2167590372","https://openalex.org/W2279897401","https://openalex.org/W2314029175","https://openalex.org/W2331733998","https://openalex.org/W2949920996","https://openalex.org/W4241614509"],"related_works":["https://openalex.org/W2117920582","https://openalex.org/W2004822266","https://openalex.org/W1974654465","https://openalex.org/W2028692248","https://openalex.org/W1995606707","https://openalex.org/W4408766280","https://openalex.org/W2028062161","https://openalex.org/W2089512620","https://openalex.org/W1995444410","https://openalex.org/W1986823251"],"abstract_inverted_index":{"A":[0],"series":[1],"of":[2,22,95,119,132,213,251,254,284,289,296,304,346,354,392,403,419,423],"lanthanocene":[3],"derivatives":[4],"containing":[5],"the":[6,82,90,146,271,280,317,361,390,393,398,404,411,416,420,424],"o":[7,37,106,124,189,217,297,347],"-aminothiophenolate":[8],"ligand":[9],"have":[10,18,427,438],"been":[11,19,428,440],"synthesized,":[12],"and":[13,97,191,209,230,299,349,415,433],"their":[14],"reactivities":[15],"toward":[16],"carbodiimide":[17,96,286,405],"investigated.":[20],"Reaction":[21,288],"N,":[23],"N":[24,30,70,92,136,161,197,240,258,282,308,358,400],"\u2018-diisopropylcarbodiimide":[25],"(":[26,54,77,180,227,247,334,364,380],"i":[27,31,72,74,133,137,163,165,194,198,242,244,255,259,305,309,329,355,359,365,377],"PrN":[28,134,195,256,306,356],"C":[29,49,91,135,196,257,281,307,357,399],"Pr)":[32,330,378],"with":[33,123,127,188,193,261,293,301,343,351],"[Cp":[34,103,214],"2":[35,39,45,76,78,85,104,108,114,128,176,178,215,219,225,246,252,274,294,302,331,333,344,367,379],"Yb(":[36],"-H":[38,107,218],"NC":[40,109,220],"6":[41,67,110,158,172,221,237,248,325,369,373],"H":[42,51,68,111,159,173,222,238,322,326,370,374],"4":[43,69,112,160,174,181,208,223,239,327,371,375],"S)]":[44,113,224],"\u00b72THF":[46,226],"(Cp":[47],"=":[48],"5":[50,52,228,321,323],")":[53,56,229,382],"1":[55,65,130,156,170,235,352],"yields":[57,316],"a":[58,210],"centrosymmetric":[59],"dimer,":[60],"[Cp(THF)Yb(\u03bc-":[61],"\u03b7":[62,64,153,155,167,169,232,234],"3:":[63,154,233],"-SC":[66,157,171,236],"C(NH":[71,162,241],"Pr)N":[73,164,243],"Pr)]":[75,245],"),":[79],"indicating":[80],"that":[81,389],"adjacent":[83,394],"NH":[84,175,273],"group":[86,100,149,275,396],"can":[87,383],"add":[88,278],"to":[89,144],"double":[93,401],"bonds":[94,283,402],"one":[98],"cyclopentadienyl":[99],"is":[101,407],"eliminated.":[102],"Dy(":[105,216],"\u00b73THF,":[115],"obtained":[116],"by":[117,410,430],"protolysis":[118],"Cp":[120,184,290,339],"3":[121,185,262,291,340],"Ln":[122],"-aminothiophenol,":[125,190,348],"reacts":[126,187,342],"or":[129],"equiv":[131,253,295,303,345,353],"Pr":[138,199,260,310],"in":[139,200,263,311],"THF":[140,264,312],"at":[141,202,313],"room":[142,203,314],"temperature":[143,267,315],"give":[145],"partial":[147],"amino":[148,395],"addition":[150,391],"product":[151,319],"CpDy(THF)[\u03bc-":[152],"Pr)](\u03bc-":[166],"2:":[168],")DyCp":[177],"\u00b7THF":[179],").":[182,249,336],"When":[183],"Dy":[186],"subsequently":[192,300,350],"toluene":[201],"temperature,":[204],"we":[205],"isolated":[206],"complex":[207],"small":[211],"amount":[212],"[Cp(THF)Dy(\u03bc-":[231],"Treatment":[250],"under":[265],"reflux":[266],"also":[268,439],"gave":[269],"4;":[270],"residual":[272],"cannot":[276],"continuously":[277],"into":[279,397],"other":[285],"molecules.":[287],"Er":[292,341],"-aminothiophenol":[298],"bis-addition":[318],"(C":[320],")Er[SC":[324],"NC(NH":[328,376],"]":[332],"7":[335],"However,":[337],"when":[338],"Pr,":[360],"organic":[362],"disulfide":[363],"PrHN)":[366],"CNC":[368],"SSC":[372],"8":[381],"be":[384],"isolated.":[385],"These":[386],"results":[387],"indicate":[388],"molecule":[406],"strongly":[408],"affected":[409],"metal":[412],"ion":[413],"character":[414],"steric":[417],"hindrance":[418],"ligands.":[421],"All":[422],"new":[425],"compounds":[426],"characterized":[429],"elemental":[431],"analysis":[432],"spectroscopic":[434],"properties.":[435],"Their":[436],"structures":[437],"determined":[441],"through":[442],"X-ray":[443],"single-crystal":[444],"diffraction":[445],"analysis.":[446]},"counts_by_year":[{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2016,"cited_by_count":2},{"year":2013,"cited_by_count":3}],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2016-06-24T00:00:00"}