{"id":"https://openalex.org/W2013469734","doi":"https://doi.org/10.1039/c3gc40215k","title":"Piperazine-functionalized ordered mesoporous polymer as highly active and reusable organocatalyst for water-medium organic synthesis","display_name":"Piperazine-functionalized ordered mesoporous polymer as highly active and reusable organocatalyst for water-medium organic synthesis","publication_year":2013,"publication_date":"2013-01-01","ids":{"openalex":"https://openalex.org/W2013469734","doi":"https://doi.org/10.1039/c3gc40215k","mag":"2013469734"},"language":"en","primary_location":{"id":"doi:10.1039/c3gc40215k","doi":"https://doi.org/10.1039/c3gc40215k","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c3gc40215k","pdf_url":null,"source":{"id":"https://openalex.org/S55009144","display_name":"Green Chemistry","issn_l":"1463-9262","issn":["1463-9262","1463-9270"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-3","ki-jl-1","norway-1","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Green Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5100367254","display_name":"Fang Zhang","orcid":"https://orcid.org/0000-0002-9656-8893","observed_orcids":["https://orcid.org/0000-0002-9656-8893"]},"institutions":[{"id":"https://openalex.org/I21945476","display_name":"Shanghai Normal University","ror":"https://ror.org/01cxqmw89","country_code":"CN","type":"education","lineage":["https://openalex.org/I21945476"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Fang Zhang","raw_affiliation_strings":["The Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"The Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, China","institution_ids":["https://openalex.org/I21945476"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5052118048","display_name":"Xushi Yang","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I21945476","display_name":"Shanghai Normal University","ror":"https://ror.org/01cxqmw89","country_code":"CN","type":"education","lineage":["https://openalex.org/I21945476"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Xushi Yang","raw_affiliation_strings":["The Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"The Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, China","institution_ids":["https://openalex.org/I21945476"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Lei Jiang","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Lei Jiang","raw_affiliation_strings":["Shanghai Haide Pharmaceutical Co. Ltd., Shanghai 201203, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Shanghai Haide Pharmaceutical Co. Ltd., Shanghai 201203, China","institution_ids":[]}]},{"author_position":"middle","author":{"id":null,"display_name":"Chao Liang","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I21945476","display_name":"Shanghai Normal University","ror":"https://ror.org/01cxqmw89","country_code":"CN","type":"education","lineage":["https://openalex.org/I21945476"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Chao Liang","raw_affiliation_strings":["The Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"The Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, China","institution_ids":["https://openalex.org/I21945476"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5037497398","display_name":"Ruixing Zhu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I21945476","display_name":"Shanghai Normal University","ror":"https://ror.org/01cxqmw89","country_code":"CN","type":"education","lineage":["https://openalex.org/I21945476"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Ruixing Zhu","raw_affiliation_strings":["The Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"The Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, China","institution_ids":["https://openalex.org/I21945476"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5108090523","display_name":"Hexing Li","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I21945476","display_name":"Shanghai Normal University","ror":"https://ror.org/01cxqmw89","country_code":"CN","type":"education","lineage":["https://openalex.org/I21945476"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Hexing Li","raw_affiliation_strings":["The Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"The Education Ministry Key Laboratory of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials, Shanghai Normal University, Shanghai 200234, China","institution_ids":["https://openalex.org/I21945476"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5100367254","https://openalex.org/A5108090523"],"corresponding_institution_ids":["https://openalex.org/I21945476"],"apc_list":null,"apc_paid":null,"fwci":1.3358,"has_fulltext":false,"cited_by_count":24,"citation_normalized_percentile":{"value":0.7834766,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"15","issue":"6","first_page":"1665","last_page":"1665"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10735","display_name":"Mesoporous Materials and Catalysis","score":0.9477999806404114,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10735","display_name":"Mesoporous Materials and Catalysis","score":0.9477999806404114,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11831","display_name":"Chemical Synthesis and Reactions","score":0.017000000923871994,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12038","display_name":"Covalent Organic Framework Applications","score":0.016699999570846558,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/organocatalysis","display_name":"organocatalysis","score":0.7749999761581421},{"id":"https://openalex.org/keywords/knoevenagel-condensation","display_name":"Knoevenagel condensation","score":0.9610000252723694},{"id":"https://openalex.org/keywords/3-3-cycloaddition","display_name":"[3+3] cycloaddition","score":0.9700000286102295},{"id":"https://openalex.org/keywords/catalyst-reusability","display_name":"catalyst reusability","score":0.7870000004768372},{"id":"https://openalex.org/keywords/active-site-dispersion","display_name":"active site dispersion","score":0.6740000247955322},{"id":"https://openalex.org/keywords/surface-hydrophobicity","display_name":"surface hydrophobicity","score":0.7990000247955322}],"concepts":[{"id":"https://openalex.org/C2776201271","wikidata":"https://www.wikidata.org/wiki/Q409292","display_name":"Piperazine","level":2,"score":0.8587946891784668},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7206467390060425},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6254106163978577},{"id":"https://openalex.org/C82776694","wikidata":"https://www.wikidata.org/wiki/Q380049","display_name":"Mesoporous material","level":3,"score":0.5867356061935425},{"id":"https://openalex.org/C168395250","wikidata":"https://www.wikidata.org/wiki/Q898972","display_name":"Knoevenagel condensation","level":3,"score":0.4621724486351013},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.453879714012146},{"id":"https://openalex.org/C118792377","wikidata":"https://www.wikidata.org/wiki/Q108584245","display_name":"Selectivity","level":3,"score":0.4284178912639618},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.4175903797149658},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.39804741740226746},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3728581666946411},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/c3gc40215k","doi":"https://doi.org/10.1039/c3gc40215k","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c3gc40215k","pdf_url":null,"source":{"id":"https://openalex.org/S55009144","display_name":"Green Chemistry","issn_l":"1463-9262","issn":["1463-9262","1463-9270"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-3","ki-jl-1","norway-1","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Green Chemistry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[{"id":"https://metadata.un.org/sdg/12","display_name":"Responsible consumption and production","score":0.807699978351593}],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":32,"referenced_works":["https://openalex.org/W1974166089","https://openalex.org/W1974306386","https://openalex.org/W1994630131","https://openalex.org/W1997116111","https://openalex.org/W2003976279","https://openalex.org/W2007868913","https://openalex.org/W2018709993","https://openalex.org/W2021010532","https://openalex.org/W2022624426","https://openalex.org/W2026605465","https://openalex.org/W2028995824","https://openalex.org/W2042602209","https://openalex.org/W2051118901","https://openalex.org/W2068257301","https://openalex.org/W2072750734","https://openalex.org/W2075285544","https://openalex.org/W2087961748","https://openalex.org/W2097829320","https://openalex.org/W2098024254","https://openalex.org/W2098430907","https://openalex.org/W2110260000","https://openalex.org/W2114651945","https://openalex.org/W2121636363","https://openalex.org/W2123888001","https://openalex.org/W2135559956","https://openalex.org/W2136569830","https://openalex.org/W2145120220","https://openalex.org/W2156215736","https://openalex.org/W4211250191","https://openalex.org/W4236051258","https://openalex.org/W4239014595","https://openalex.org/W4248401078"],"related_works":["https://openalex.org/W2950481232","https://openalex.org/W3216132838","https://openalex.org/W2365575351","https://openalex.org/W2028995824","https://openalex.org/W2144469537","https://openalex.org/W3200307670","https://openalex.org/W2065526163","https://openalex.org/W2951445720","https://openalex.org/W1972284339","https://openalex.org/W1969006720"],"abstract_inverted_index":{"A":[0],"piperazine-functionalized":[1],"mesoporous":[2,56],"polymer":[3],"(PP-MPs)":[4],"was":[5],"synthesized":[6],"through":[7],"a":[8],"one-step":[9],"surfactant-directed":[10],"phenol\u2013formaldehyde\u2013piperazinecarbaldehyde":[11],"oligomer":[12],"self-assembly":[13],"approach.":[14],"This":[15],"novel":[16],"PP-MP":[17],"catalyst":[18],"exhibited":[19],"highly":[20],"catalytic":[21],"reactivity":[22],"and":[23,35,54,64,101,115],"selectivity":[24],"for":[25,113],"water-medium":[26,29],"Knoevenagel":[27],"reaction,":[28],"[3":[30],"+":[31],"3]":[32],"cycloaddition":[33],"reaction":[34],"intermolecular":[36],"cross-conjugated":[37],"addition":[38],"reaction.":[39],"The":[40],"excellent":[41,106],"performance":[42],"could":[43,72,94],"be":[44],"attributed":[45],"to":[46],"its":[47,68],"high":[48],"dispersion":[49],"of":[50,98,111],"piperazine":[51,86],"active":[52,99],"sites":[53],"ordered":[55],"structure,":[57],"which":[58,76],"effectively":[59],"diminished":[60],"the":[61,91,96,105],"steric":[62],"hindrance":[63],"diffusion":[65],"limitation.":[66],"Moreover,":[67],"pure":[69],"organic":[70,78],"framework":[71,93],"enhance":[73],"surface":[74],"hydrophobicity,":[75],"promoted":[77],"reactant":[79],"molecule":[80],"adsorption,":[81],"especially":[82],"in":[83,90,104],"water.":[84],"Meanwhile,":[85],"functional":[87],"groups":[88],"embedded":[89],"polymeric":[92],"inhibit":[95],"leaching":[97],"species":[100],"thus":[102],"resulted":[103],"durability":[107],"without":[108],"significant":[109],"loss":[110],"activity":[112],"recovery":[114],"recycling":[116],"at":[117],"least":[118],"four":[119],"times.":[120]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2024,"cited_by_count":3},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":3},{"year":2020,"cited_by_count":3},{"year":2018,"cited_by_count":2},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":5},{"year":2014,"cited_by_count":3},{"year":2013,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}