{"id":"https://openalex.org/W2013449493","doi":"https://doi.org/10.1080/02773818508085187","title":"The Mechanism of Cleavage of B-Ether Bonds in Lignin Model Compounds By Reducing Sugars","display_name":"The Mechanism of Cleavage of B-Ether Bonds in Lignin Model Compounds By Reducing Sugars","publication_year":1985,"publication_date":"1985-01-01","ids":{"openalex":"https://openalex.org/W2013449493","doi":"https://doi.org/10.1080/02773818508085187","mag":"2013449493"},"language":"en","primary_location":{"id":"doi:10.1080/02773818508085187","doi":"https://doi.org/10.1080/02773818508085187","is_oa":false,"landing_page_url":"https://doi.org/10.1080/02773818508085187","pdf_url":null,"source":{"id":"https://openalex.org/S149325625","display_name":"Journal of Wood Chemistry and Technology","issn_l":"0277-3813","issn":["0277-3813","1532-2319"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-140","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Wood Chemistry and Technology","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5070512897","display_name":"Terry J. Fullerton","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I154136665","display_name":"Scion","ror":"https://ror.org/048r72142","country_code":"NZ","type":"facility","lineage":["https://openalex.org/I154136665","https://openalex.org/I4405260297"]}],"countries":["NZ"],"is_corresponding":false,"raw_author_name":"Terry J. Fullerton","raw_affiliation_strings":["New Zealand Forest Service, Forest Research Institute, Private Bag, Rotorua, New Zealand"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"New Zealand Forest Service, Forest Research Institute, Private Bag, Rotorua, New Zealand","institution_ids":["https://openalex.org/I154136665"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5109088498","display_name":"Alistair L. Wilkins","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I52179390","display_name":"University of Waikato","ror":"https://ror.org/013fsnh78","country_code":"NZ","type":"education","lineage":["https://openalex.org/I52179390"]}],"countries":["NZ"],"is_corresponding":false,"raw_author_name":"Alistair L. Wilkins","raw_affiliation_strings":["Chemistry Dept, University of Waikato, Hamilton, New Zealand","Chemistry Department, University of Waikato, Hamilton, New Zealand"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemistry Dept, University of Waikato, Hamilton, New Zealand","institution_ids":["https://openalex.org/I52179390"]},{"raw_affiliation_string":"Chemistry Department, University of Waikato, Hamilton, New Zealand","institution_ids":["https://openalex.org/I52179390"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":2.9251,"has_fulltext":false,"cited_by_count":17,"citation_normalized_percentile":{"value":0.88697318,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":93},"biblio":{"volume":"5","issue":"2","first_page":"189","last_page":"201"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11208","display_name":"Lignin and Wood Chemistry","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11208","display_name":"Lignin and Wood Chemistry","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10171","display_name":"Biofuel production and bioconversion","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2204","display_name":"Biomedical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10484","display_name":"Wood Treatment and Properties","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2215","display_name":"Building and Construction"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/lignin-model-compounds","display_name":"lignin model compounds","score":0.9819999933242798},{"id":"https://openalex.org/keywords/reducing-sugars","display_name":"reducing sugars","score":0.8370000123977661},{"id":"https://openalex.org/keywords/quinone-methides","display_name":"quinone methides","score":0.8420000076293945},{"id":"https://openalex.org/keywords/enediols","display_name":"enediols","score":0.7210000157356262},{"id":"https://openalex.org/keywords/vitamin-c","display_name":"vitamin C","score":0.9229999780654907},{"id":"https://openalex.org/keywords/guaiacol","display_name":"guaiacol","score":0.8489999771118164},{"id":"https://openalex.org/keywords/stereoisomers","display_name":"stereoisomers","score":0.7179999947547913},{"id":"https://openalex.org/keywords/lignin-carbohydrate-complexes","display_name":"lignin-carbohydrate complexes","score":0.8130000233650208},{"id":"https://openalex.org/keywords/alkaline-cleavage","display_name":"alkaline cleavage","score":0.6919999718666077}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9707953333854675},{"id":"https://openalex.org/C2986274086","wikidata":"https://www.wikidata.org/wiki/Q199678","display_name":"Ascorbic acid","level":2,"score":0.7685360908508301},{"id":"https://openalex.org/C2781052789","wikidata":"https://www.wikidata.org/wiki/Q184817","display_name":"Lignin","level":2,"score":0.7618038654327393},{"id":"https://openalex.org/C2778407918","wikidata":"https://www.wikidata.org/wiki/Q7272333","display_name":"Quinone methide","level":3,"score":0.7438438534736633},{"id":"https://openalex.org/C2780199054","wikidata":"https://www.wikidata.org/wiki/Q412403","display_name":"Guaiacol","level":3,"score":0.7402989864349365},{"id":"https://openalex.org/C2780407432","wikidata":"https://www.wikidata.org/wiki/Q103230","display_name":"Ether","level":2,"score":0.6698758602142334},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.6183871030807495},{"id":"https://openalex.org/C140205800","wikidata":"https://www.wikidata.org/wiki/Q5860","display_name":"Carbon fibers","level":3,"score":0.4997432231903076},{"id":"https://openalex.org/C2780643102","wikidata":"https://www.wikidata.org/wiki/Q412382","display_name":"Quinone","level":2,"score":0.3692058026790619},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.17406883835792542},{"id":"https://openalex.org/C104779481","wikidata":"https://www.wikidata.org/wiki/Q50707","display_name":"Composite number","level":2,"score":0.0},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.0},{"id":"https://openalex.org/C31903555","wikidata":"https://www.wikidata.org/wiki/Q1637030","display_name":"Food science","level":1,"score":0.0},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1080/02773818508085187","doi":"https://doi.org/10.1080/02773818508085187","is_oa":false,"landing_page_url":"https://doi.org/10.1080/02773818508085187","pdf_url":null,"source":{"id":"https://openalex.org/S149325625","display_name":"Journal of Wood Chemistry and Technology","issn_l":"0277-3813","issn":["0277-3813","1532-2319"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-140","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Wood Chemistry and Technology","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":9,"referenced_works":["https://openalex.org/W211194999","https://openalex.org/W1992588717","https://openalex.org/W1998221419","https://openalex.org/W2013001754","https://openalex.org/W2022464151","https://openalex.org/W2080842740","https://openalex.org/W2081513722","https://openalex.org/W2137941082","https://openalex.org/W2571138275"],"related_works":["https://openalex.org/W1989754151","https://openalex.org/W2089180200","https://openalex.org/W2035105407","https://openalex.org/W2034912755","https://openalex.org/W2083233083","https://openalex.org/W2257071245","https://openalex.org/W2065835095","https://openalex.org/W4233773256","https://openalex.org/W2244611969","https://openalex.org/W2132998042"],"abstract_inverted_index":{"The":[0,103,129],"alkaline":[1,78,101],"cleavage":[2],"of":[3,6,22,26,35,39,47,57,61,69,114,131,140,149],"\u03b2-ether":[4,92],"bonds":[5],"phenolic":[7],"lignin":[8,28,152],"model":[9,29],"compounds":[10],"by":[11,19,55],"reducing":[12,98],"sugars":[13,99],"has":[14],"been":[15],"shown":[16],"to":[17,80,111,137],"occur":[18],"the":[20,23,27,36,45,58,62,67,70,84,91,119,132,138,147],"reaction":[21,56,133],"quinone":[24,37,71],"methide":[25,38],"with":[30,41,66,94],"a":[31,50,109],"sugar-derived":[32],"enediol.":[33],"Reaction":[34],"1-(4-hydroxy-3-methoxyphenyl)-2-(2-methoxyphenoxy)ethanol":[40],"L-ascorbic":[42],"acid":[43,64,96],"in":[44],"absence":[46],"base":[48],"gives":[49],"carbon-carbon":[51,150],"bonded":[52,151],"intermediate":[53,74,105],"formed":[54,156],"C-2":[59],"carbon":[60],"ascorbic":[63,95],"enediol":[65],"\u03b1-carbon":[68],"methide.":[72],"This":[73],"then":[75],"fragments":[76],"under":[77,100],"conditions":[79],"guaiacol":[81],"and":[82,134,146],"vinylguaiacol,":[83],"same":[85],"products":[86],"as":[87,108],"obtained":[88,107],"from":[89,122],"heating":[90],"itself":[93],"or":[97],"conditions.":[102],"isolated":[104],"was":[106,126],"one":[110,112,124],"mixture":[113],"two":[115],"stereoisomers,":[116],"isomeric":[117],"at":[118],"benzylic":[120],"carbon,":[121],"which":[123],"isomer":[125],"selectively":[127],"crystallised.":[128],"generality":[130],"its":[135],"relevance":[136],"development":[139],"alternative":[141],"pulping":[142],"processes":[143],"is":[144,159],"discussed":[145],"possibility":[148],"carbohydrate":[153],"complexes":[154],"being":[155],"via":[157],"enediols":[158],"suggested.":[160]},"counts_by_year":[{"year":2021,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2014,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}