{"id":"https://openalex.org/W2013314569","doi":"https://doi.org/10.1039/p29750001614","title":"The kinetics and mechanism of the electrophilic substitution of heteroaromatic compounds. Part XLII. The nitration of thiazoles and thiazolones","display_name":"The kinetics and mechanism of the electrophilic substitution of heteroaromatic compounds. Part XLII. The nitration of thiazoles and thiazolones","publication_year":1975,"publication_date":"1975-01-01","ids":{"openalex":"https://openalex.org/W2013314569","doi":"https://doi.org/10.1039/p29750001614","mag":"2013314569"},"language":"en","primary_location":{"id":"doi:10.1039/p29750001614","doi":"https://doi.org/10.1039/p29750001614","is_oa":false,"landing_page_url":"https://doi.org/10.1039/p29750001614","pdf_url":null,"source":{"id":"https://openalex.org/S4210187049","display_name":"Journal of the Chemical Society Perkin Transactions 2","issn_l":"0300-9580","issn":["0300-9580","1364-5471","1472-779X","2050-8239"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"J. Chem. Soc., Perkin Trans. 2","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5082158198","display_name":"ALAN ROY KATRITZKY","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Alan R. Katritzky","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5007307052","display_name":"Cemi\u0307l \u00d6\u011fret\u0131r","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Cemil \u00d6gretir","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5016467431","display_name":"H. Okan Tarhan","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"H. Okan Tarhan","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5009648801","display_name":"Henri Dou","orcid":"https://orcid.org/0000-0002-2990-5589","observed_orcids":["https://orcid.org/0000-0002-2990-5589"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Henri M. Dou","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5111899375","display_name":"Jacques V. Metzger","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Jacques V. Metzger","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.6435,"has_fulltext":false,"cited_by_count":16,"citation_normalized_percentile":{"value":0.6255004,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":93},"biblio":{"volume":null,"issue":"14","first_page":"1614","last_page":"1620"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.9833999872207642,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12191","display_name":"Physical Organic Chemistry and Reaction Kinetics","score":0.9833999872207642,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12410","display_name":"Structural and Chemical Analysis of Organic and Inorganic Compounds","score":0.005499999970197678,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T14068","display_name":"Organic and Inorganic Chemical Reactions","score":0.003800000064074993,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/electrophilic-substitution","display_name":"electrophilic substitution","score":0.8379999995231628},{"id":"https://openalex.org/keywords/nitration","display_name":"nitration","score":0.8769999742507935},{"id":"https://openalex.org/keywords/thiazole","display_name":"thiazole","score":0.9829999804496765},{"id":"https://openalex.org/keywords/thiazolones","display_name":"thiazolones","score":0.9779999852180481},{"id":"https://openalex.org/keywords/reaction-kinetics","display_name":"reaction kinetics","score":0.8960000276565552},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.9269999861717224},{"id":"https://openalex.org/keywords/protonated-forms","display_name":"protonated forms","score":0.5889999866485596},{"id":"https://openalex.org/keywords/acidity-effects","display_name":"acidity effects","score":0.7689999938011169},{"id":"https://openalex.org/keywords/standard-rate-constant","display_name":"standard rate constant","score":0.4959999918937683}],"concepts":[{"id":"https://openalex.org/C2775856698","wikidata":"https://www.wikidata.org/wiki/Q909607","display_name":"Nitration","level":2,"score":0.9709792137145996},{"id":"https://openalex.org/C2777965246","wikidata":"https://www.wikidata.org/wiki/Q899587","display_name":"Electrophilic substitution","level":2,"score":0.9087874889373779},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8964259624481201},{"id":"https://openalex.org/C30095370","wikidata":"https://www.wikidata.org/wiki/Q899488","display_name":"Protonation","level":3,"score":0.8190701603889465},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.6870819330215454},{"id":"https://openalex.org/C50027330","wikidata":"https://www.wikidata.org/wiki/Q908086","display_name":"Electrophile","level":3,"score":0.6185650825500488},{"id":"https://openalex.org/C122085161","wikidata":"https://www.wikidata.org/wiki/Q597833","display_name":"Electrophilic aromatic substitution","level":2,"score":0.5911266207695007},{"id":"https://openalex.org/C116858620","wikidata":"https://www.wikidata.org/wiki/Q280190","display_name":"Free base","level":3,"score":0.5619006752967834},{"id":"https://openalex.org/C89611455","wikidata":"https://www.wikidata.org/wiki/Q6804646","display_name":"Mechanism (biology)","level":2,"score":0.49591121077537537},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.46111607551574707},{"id":"https://openalex.org/C42058472","wikidata":"https://www.wikidata.org/wiki/Q810214","display_name":"Base (topology)","level":2,"score":0.43861377239227295},{"id":"https://openalex.org/C2778220771","wikidata":"https://www.wikidata.org/wiki/Q1522579","display_name":"Substitution (logic)","level":2,"score":0.4139145612716675},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.38203808665275574},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3665204346179962},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.32086142897605896},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.05246588587760925},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.0398617684841156},{"id":"https://openalex.org/C199360897","wikidata":"https://www.wikidata.org/wiki/Q9143","display_name":"Programming language","level":1,"score":0.0},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.0},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C2776371256","wikidata":"https://www.wikidata.org/wiki/Q12370","display_name":"Salt (chemistry)","level":2,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C138885662","wikidata":"https://www.wikidata.org/wiki/Q5891","display_name":"Philosophy","level":0,"score":0.0},{"id":"https://openalex.org/C134306372","wikidata":"https://www.wikidata.org/wiki/Q7754","display_name":"Mathematical analysis","level":1,"score":0.0},{"id":"https://openalex.org/C111472728","wikidata":"https://www.wikidata.org/wiki/Q9471","display_name":"Epistemology","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1039/p29750001614","doi":"https://doi.org/10.1039/p29750001614","is_oa":false,"landing_page_url":"https://doi.org/10.1039/p29750001614","pdf_url":null,"source":{"id":"https://openalex.org/S4210187049","display_name":"Journal of the Chemical Society Perkin Transactions 2","issn_l":"0300-9580","issn":["0300-9580","1364-5471","1472-779X","2050-8239"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"J. Chem. Soc., Perkin Trans. 2","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2059989968","https://openalex.org/W2042463562","https://openalex.org/W2076914934","https://openalex.org/W2040685094","https://openalex.org/W2151035712","https://openalex.org/W2061955607","https://openalex.org/W1984731491","https://openalex.org/W1998333631","https://openalex.org/W7048005533","https://openalex.org/W3007634920"],"abstract_inverted_index":{"Kinetic":[0],"investigations":[1],"show":[2],"that":[3],"whereas":[4],"2,4-":[5],"and":[6,44],"2,5-dialkylthiazoles":[7],"undergo":[8],"nitration":[9],"as":[10],"their":[11],"protonated":[12],"forms":[13],"at":[14,26,28],"all":[15],"acidities":[16],"studied,":[17],"2-thiazolones":[18],"are":[19,34],"nitrated":[20],"via":[21],"a":[22],"free":[23],"base":[24],"mechanism":[25],"least":[27],"the":[29],"lower":[30],"acidities.":[31],"The":[32],"reactivities":[33],"discussed":[35],"in":[36],"terms":[37],"of":[38],"standard":[39],"rates":[40],"extrapolated":[41],"to":[42],"25\u00b0":[43],"Ho\u20136.6.":[45]},"counts_by_year":[{"year":2018,"cited_by_count":1},{"year":2016,"cited_by_count":1},{"year":2014,"cited_by_count":1}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}