{"id":"https://openalex.org/W2013259490","doi":"https://doi.org/10.1080/10426509608037963","title":"UNEXPECTED FORMATION AND MOLECULAR STRUCTURE OF 2,2,6,6-TETRA-t-BUTYL-4,8-DIMETHYL-1,5,9-TRIOXA-4,8-DISILA-2,6-DISTANNABICYCLO[3.3.1]NONANE","display_name":"UNEXPECTED FORMATION AND MOLECULAR STRUCTURE OF 2,2,6,6-TETRA-t-BUTYL-4,8-DIMETHYL-1,5,9-TRIOXA-4,8-DISILA-2,6-DISTANNABICYCLO[3.3.1]NONANE","publication_year":1996,"publication_date":"1996-08-01","ids":{"openalex":"https://openalex.org/W2013259490","doi":"https://doi.org/10.1080/10426509608037963","mag":"2013259490"},"language":"en","primary_location":{"id":"doi:10.1080/10426509608037963","doi":"https://doi.org/10.1080/10426509608037963","is_oa":false,"landing_page_url":"https://doi.org/10.1080/10426509608037963","pdf_url":null,"source":{"id":"https://openalex.org/S70121411","display_name":"Phosphorus, sulfur, and silicon and the related elements","issn_l":"1026-7719","issn":["1026-7719","1042-6507","1563-5325"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Phosphorus, Sulfur, and Silicon and the Related Elements","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5070555642","display_name":"Klaus Jurkschat","orcid":"https://orcid.org/0000-0001-9930-858X","observed_orcids":["https://orcid.org/0000-0001-9930-858X"]},"institutions":[{"id":"https://openalex.org/I200332995","display_name":"TU Dortmund University","ror":"https://ror.org/01k97gp34","country_code":"DE","type":"education","lineage":["https://openalex.org/I200332995"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Klaus Jurkschat","raw_affiliation_strings":["a  Fachbereich Chemie der Universit\u00e4t Dortmund, Lehrstuhl f\u00fcr Anorganische Chemie II , D-4421, Dortmund,  Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"a  Fachbereich Chemie der Universit\u00e4t Dortmund, Lehrstuhl f\u00fcr Anorganische Chemie II , D-4421, Dortmund,  Germany","institution_ids":["https://openalex.org/I200332995"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5058391718","display_name":"Fred Rosche","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I200332995","display_name":"TU Dortmund University","ror":"https://ror.org/01k97gp34","country_code":"DE","type":"education","lineage":["https://openalex.org/I200332995"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Fred Rosche","raw_affiliation_strings":["a  Fachbereich Chemie der Universit\u00e4t Dortmund, Lehrstuhl f\u00fcr Anorganische Chemie II , D-4421, Dortmund,  Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"a  Fachbereich Chemie der Universit\u00e4t Dortmund, Lehrstuhl f\u00fcr Anorganische Chemie II , D-4421, Dortmund,  Germany","institution_ids":["https://openalex.org/I200332995"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5111449929","display_name":"Markus Sch\u00fcrmann","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I200332995","display_name":"TU Dortmund University","ror":"https://ror.org/01k97gp34","country_code":"DE","type":"education","lineage":["https://openalex.org/I200332995"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Markus Schurmann","raw_affiliation_strings":["a  Fachbereich Chemie der Universit\u00e4t Dortmund, Lehrstuhl f\u00fcr Anorganische Chemie II , D-4421, Dortmund,  Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"a  Fachbereich Chemie der Universit\u00e4t Dortmund, Lehrstuhl f\u00fcr Anorganische Chemie II , D-4421, Dortmund,  Germany","institution_ids":["https://openalex.org/I200332995"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I200332995"],"apc_list":null,"apc_paid":null,"fwci":0.8929,"has_fulltext":false,"cited_by_count":8,"citation_normalized_percentile":{"value":0.65446707,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":93},"biblio":{"volume":"115","issue":"1","first_page":"161","last_page":"167"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.9032999873161316,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.9032999873161316,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12458","display_name":"Organometallic Compounds Synthesis and Characterization","score":0.07100000232458115,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.008899999782443047,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/organotin-compounds","display_name":"organotin compounds","score":0.6449999809265137},{"id":"https://openalex.org/keywords/organosilicon-compounds","display_name":"organosilicon compounds","score":0.8119999766349792},{"id":"https://openalex.org/keywords/bicyclo-3-3-1-nonane","display_name":"bicyclo[3.3.1]nonane","score":0.9599999785423279},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.6700000166893005},{"id":"https://openalex.org/keywords/molecular-structure","display_name":"molecular structure","score":0.42100000381469727}],"concepts":[{"id":"https://openalex.org/C2778265757","wikidata":"https://www.wikidata.org/wiki/Q150694","display_name":"Nonane","level":2,"score":0.9685823917388916},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9219670295715332},{"id":"https://openalex.org/C61276311","wikidata":"https://www.wikidata.org/wiki/Q624543","display_name":"Monoclinic crystal system","level":3,"score":0.8655388355255127},{"id":"https://openalex.org/C2777873363","wikidata":"https://www.wikidata.org/wiki/Q13533436","display_name":"Tetra","level":2,"score":0.7883865833282471},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.5011579990386963},{"id":"https://openalex.org/C24961977","wikidata":"https://www.wikidata.org/wiki/Q225972","display_name":"Bicyclic molecule","level":2,"score":0.484982967376709},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.4781854450702667},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.45186737179756165},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.44035598635673523},{"id":"https://openalex.org/C122637931","wikidata":"https://www.wikidata.org/wiki/Q118084","display_name":"Unit (ring theory)","level":2,"score":0.42618608474731445},{"id":"https://openalex.org/C2781311116","wikidata":"https://www.wikidata.org/wiki/Q83306","display_name":"Group (periodic table)","level":2,"score":0.4193446636199951},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1264445185661316},{"id":"https://openalex.org/C145420912","wikidata":"https://www.wikidata.org/wiki/Q853077","display_name":"Mathematics education","level":1,"score":0.0},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1080/10426509608037963","doi":"https://doi.org/10.1080/10426509608037963","is_oa":false,"landing_page_url":"https://doi.org/10.1080/10426509608037963","pdf_url":null,"source":{"id":"https://openalex.org/S70121411","display_name":"Phosphorus, sulfur, and silicon and the related elements","issn_l":"1026-7719","issn":["1026-7719","1042-6507","1563-5325"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Phosphorus, Sulfur, and Silicon and the Related Elements","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":14,"referenced_works":["https://openalex.org/W1594096339","https://openalex.org/W1595263782","https://openalex.org/W1964049823","https://openalex.org/W1980439105","https://openalex.org/W1982219720","https://openalex.org/W1991139785","https://openalex.org/W1997212718","https://openalex.org/W2006233202","https://openalex.org/W2038139391","https://openalex.org/W2065547080","https://openalex.org/W2067772821","https://openalex.org/W2315130211","https://openalex.org/W2952176378","https://openalex.org/W4403733501"],"related_works":["https://openalex.org/W2071195646","https://openalex.org/W1982195437","https://openalex.org/W2053893390","https://openalex.org/W2073542565","https://openalex.org/W2031686688","https://openalex.org/W2344558391","https://openalex.org/W2015617435","https://openalex.org/W2084830829","https://openalex.org/W2374319337","https://openalex.org/W1998403086"],"abstract_inverted_index":{"The":[0,52],"title":[1],"compound":[2],"2":[3,21,25],"has":[4],"been":[5],"prepared":[6],"by":[7],"treatment":[8],"of":[9,61],"(i-PrO)2MeSiCH2(t-Bu)2SnCl":[10],"1":[11],"with":[12,33],"potassium":[13],"fluoride/water.":[14],"Multinuclear":[15],"NMR":[16],"and":[17],"X-ray":[18],"studies":[19],"reveal":[20],"adopts":[22],"bicyclo[3.3.1]nonane":[23],"structure.":[24],"crystallizes":[26],"in":[27],"the":[28],"monoclinic":[29],"space":[30],"group":[31],"P2(1)/n":[32],"unit":[34],"cell":[35],"dimensions":[36],"a":[37,57],"=":[38,41,44,50],"12.880(3),":[39],"b":[40],"16.949(4),":[42],"c":[43],"13.472(4)":[45],"\u00c5,":[46],"\u03b2":[47],"93.04(2)\u00b0,":[48],"Z":[49],"4.":[51],"structure":[53],"was":[54],"refined":[55],"to":[56],"final":[58],"R":[59],"value":[60],"0.065.":[62]},"counts_by_year":[{"year":2022,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2015,"cited_by_count":1},{"year":2013,"cited_by_count":1}],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2016-06-24T00:00:00"}