{"id":"https://openalex.org/W2013151920","doi":"https://doi.org/10.1039/c3dt33010a","title":"Synthesis of functionalised N-heterocyclic carbene ligands bearing a long spacer and their use in olefin metathesis","display_name":"Synthesis of functionalised N-heterocyclic carbene ligands bearing a long spacer and their use in olefin metathesis","publication_year":2013,"publication_date":"2013-01-01","ids":{"openalex":"https://openalex.org/W2013151920","doi":"https://doi.org/10.1039/c3dt33010a","mag":"2013151920","pmid":"https://pubmed.ncbi.nlm.nih.gov/23463014"},"language":"en","primary_location":{"id":"doi:10.1039/c3dt33010a","doi":"https://doi.org/10.1039/c3dt33010a","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c3dt33010a","pdf_url":null,"source":{"id":"https://openalex.org/S166159787","display_name":"Dalton Transactions","issn_l":"1477-9226","issn":["1477-9226","1477-9234"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton Transactions","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5036678232","display_name":"Wioletta Ko\u015bnik","orcid":"https://orcid.org/0000-0002-3889-7744","observed_orcids":["https://orcid.org/0000-0002-3889-7744"]},"institutions":[{"id":"https://openalex.org/I4654613","display_name":"University of Warsaw","ror":"https://ror.org/039bjqg32","country_code":"PL","type":"education","lineage":["https://openalex.org/I4654613"]}],"countries":["PL"],"is_corresponding":false,"raw_author_name":"Wioletta Ko\u015bnik","raw_affiliation_strings":["Department of Chemistry, Warsaw University, Zwirki i Wigury Street 101, 02-089 Warsaw, Poland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Warsaw University, Zwirki i Wigury Street 101, 02-089 Warsaw, Poland","institution_ids":["https://openalex.org/I4654613"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5039822744","display_name":"Karol Grela","orcid":"https://orcid.org/0000-0001-9193-3305","observed_orcids":["https://orcid.org/0000-0001-9193-3305"]},"institutions":[{"id":"https://openalex.org/I4654613","display_name":"University of Warsaw","ror":"https://ror.org/039bjqg32","country_code":"PL","type":"education","lineage":["https://openalex.org/I4654613"]}],"countries":["PL"],"is_corresponding":true,"raw_author_name":"Karol Grela","raw_affiliation_strings":["Department of Chemistry, Warsaw University, Zwirki i Wigury Street 101, 02-089 Warsaw, Poland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Warsaw University, Zwirki i Wigury Street 101, 02-089 Warsaw, Poland","institution_ids":["https://openalex.org/I4654613"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5039822744"],"corresponding_institution_ids":["https://openalex.org/I4654613"],"apc_list":null,"apc_paid":null,"fwci":1.5113,"has_fulltext":false,"cited_by_count":23,"citation_normalized_percentile":{"value":0.79230795,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":98},"biblio":{"volume":"42","issue":"20","first_page":"7463","last_page":"7463"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.9276999831199646,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.9276999831199646,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11549","display_name":"Synthetic Organic Chemistry Methods","score":0.05139999836683273,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11281","display_name":"Asymmetric Hydrogenation and Catalysis","score":0.012299999594688416,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/n-heterocyclic-carbenes","display_name":"N-heterocyclic carbenes","score":0.9679999947547913},{"id":"https://openalex.org/keywords/imidazolinium-salts","display_name":"imidazolinium salts","score":0.9240000247955322},{"id":"https://openalex.org/keywords/olefin-metathesis","display_name":"olefin metathesis","score":0.9430000185966492},{"id":"https://openalex.org/keywords/quaternary-ammonium-groups","display_name":"quaternary ammonium groups","score":0.8519999980926514},{"id":"https://openalex.org/keywords/homogeneous-catalysis","display_name":"homogeneous catalysis","score":0.7839999794960022},{"id":"https://openalex.org/keywords/ligand-synthesis","display_name":"ligand synthesis","score":0.6029999852180481}],"concepts":[{"id":"https://openalex.org/C2777164566","wikidata":"https://www.wikidata.org/wiki/Q419257","display_name":"Carbene","level":3,"score":0.9109565615653992},{"id":"https://openalex.org/C2994504213","wikidata":"https://www.wikidata.org/wiki/Q898959","display_name":"Olefin metathesis","level":5,"score":0.855961799621582},{"id":"https://openalex.org/C153914509","wikidata":"https://www.wikidata.org/wiki/Q191090","display_name":"Metathesis","level":4,"score":0.6962976455688477},{"id":"https://openalex.org/C51886252","wikidata":"https://www.wikidata.org/wiki/Q4118667","display_name":"Olefin fiber","level":3,"score":0.6828348636627197},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6797430515289307},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.6737205982208252},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6707424521446228},{"id":"https://openalex.org/C2779870022","wikidata":"https://www.wikidata.org/wiki/Q190901","display_name":"Ammonium","level":2,"score":0.5451348423957825},{"id":"https://openalex.org/C66882249","wikidata":"https://www.wikidata.org/wiki/Q169336","display_name":"Homogeneous","level":2,"score":0.5264987349510193},{"id":"https://openalex.org/C44138296","wikidata":"https://www.wikidata.org/wiki/Q13533728","display_name":"Salt metathesis reaction","level":5,"score":0.506869375705719},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.4559827446937561},{"id":"https://openalex.org/C109474758","wikidata":"https://www.wikidata.org/wiki/Q1411716","display_name":"Homogeneous catalysis","level":3,"score":0.4389582872390747},{"id":"https://openalex.org/C2780227895","wikidata":"https://www.wikidata.org/wiki/Q2660966","display_name":"ROMP","level":5,"score":0.43646135926246643},{"id":"https://openalex.org/C2779532046","wikidata":"https://www.wikidata.org/wiki/Q308976","display_name":"Silica gel","level":2,"score":0.43241772055625916},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.4293302893638611},{"id":"https://openalex.org/C174499055","wikidata":"https://www.wikidata.org/wiki/Q4250538","display_name":"Ring-opening metathesis polymerisation","level":5,"score":0.4216483533382416},{"id":"https://openalex.org/C193363816","wikidata":"https://www.wikidata.org/wiki/Q1617865","display_name":"Size-exclusion chromatography","level":3,"score":0.4117738902568817},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.3969353437423706},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.28062155842781067},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.0},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C181199279","wikidata":"https://www.wikidata.org/wiki/Q8047","display_name":"Enzyme","level":2,"score":0.0},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1039/c3dt33010a","doi":"https://doi.org/10.1039/c3dt33010a","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c3dt33010a","pdf_url":null,"source":{"id":"https://openalex.org/S166159787","display_name":"Dalton Transactions","issn_l":"1477-9226","issn":["1477-9226","1477-9234"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","ki-jl-1","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton Transactions","raw_type":"journal-article"},{"id":"pmid:23463014","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/23463014","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Dalton transactions (Cambridge, England : 2003)","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":35,"referenced_works":["https://openalex.org/W1967253297","https://openalex.org/W1967294104","https://openalex.org/W1975451501","https://openalex.org/W1982153282","https://openalex.org/W1992402368","https://openalex.org/W1994126330","https://openalex.org/W1997440217","https://openalex.org/W2005227604","https://openalex.org/W2005264507","https://openalex.org/W2010535838","https://openalex.org/W2017414089","https://openalex.org/W2019130521","https://openalex.org/W2027895673","https://openalex.org/W2038092103","https://openalex.org/W2038729811","https://openalex.org/W2042389194","https://openalex.org/W2042787152","https://openalex.org/W2043935388","https://openalex.org/W2045665986","https://openalex.org/W2046898906","https://openalex.org/W2058367938","https://openalex.org/W2066635731","https://openalex.org/W2106679607","https://openalex.org/W2123818211","https://openalex.org/W2124648084","https://openalex.org/W2126640916","https://openalex.org/W2133080465","https://openalex.org/W2133142785","https://openalex.org/W2138136066","https://openalex.org/W2150990441","https://openalex.org/W2155802665","https://openalex.org/W2156888755","https://openalex.org/W2160336331","https://openalex.org/W2315081263","https://openalex.org/W2949350526"],"related_works":["https://openalex.org/W2041942749","https://openalex.org/W2808716599","https://openalex.org/W2124878237","https://openalex.org/W2031377360","https://openalex.org/W2052407816","https://openalex.org/W2043529795","https://openalex.org/W3196355788","https://openalex.org/W4282835310","https://openalex.org/W2009633167","https://openalex.org/W7149013449"],"abstract_inverted_index":{"A":[0],"synthetic":[1],"route":[2],"to":[3,20],"backbone":[4],"functionalised":[5],"imidazolinium":[6],"salts-NHC":[7],"ligand":[8],"precursors":[9],"has":[10],"been":[11],"developed.":[12],"These":[13],"tagged":[14],"NHC":[15],"ligands":[16],"can":[17,46],"be":[18,47],"used":[19],"obtain":[21],"a":[22,28,33,59],"homogeneous":[23],"Hoveyda-type":[24],"catalyst":[25],"(19)":[26],"containing":[27],"quaternary":[29],"ammonium":[30],"group":[31],"on":[32],"C-8":[34],"long":[35],"spacer.":[36],"Products":[37],"of":[38,54,62],"olefin":[39],"metathesis":[40],"reactions":[41],"promoted":[42],"by":[43,52],"complex":[44],"19":[45],"readily":[48],"purified":[49],"from":[50],"Ru-residues":[51],"filtration":[53],"the":[55],"reaction":[56],"mixture":[57],"through":[58],"small":[60],"amount":[61],"silica":[63],"gel.":[64]},"counts_by_year":[{"year":2023,"cited_by_count":1},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":1},{"year":2018,"cited_by_count":5},{"year":2017,"cited_by_count":3},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":3},{"year":2014,"cited_by_count":6}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}