{"id":"https://openalex.org/W2012804317","doi":"https://doi.org/10.1002/ejic.201101054","title":"Synthesis and Characterization of New Pentacoordinate Iron\u2010Based Aryloxide Complexes","display_name":"Synthesis and Characterization of New Pentacoordinate Iron\u2010Based Aryloxide Complexes","publication_year":2012,"publication_date":"2012-01-24","ids":{"openalex":"https://openalex.org/W2012804317","doi":"https://doi.org/10.1002/ejic.201101054","mag":"2012804317"},"language":"en","primary_location":{"id":"doi:10.1002/ejic.201101054","doi":"https://doi.org/10.1002/ejic.201101054","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ejic.201101054","pdf_url":null,"source":{"id":"https://openalex.org/S16435181","display_name":"European Journal of Inorganic Chemistry","issn_l":"1099-0682","issn":["1099-0682","1434-1948"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"European Journal of Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5028324714","display_name":"Yvens Ch\u00e9r\u00e9mond","orcid":"https://orcid.org/0000-0001-8508-9654","observed_orcids":["https://orcid.org/0000-0001-8508-9654"]},"institutions":[{"id":"https://openalex.org/I154338468","display_name":"University of Fribourg","ror":"https://ror.org/022fs9h90","country_code":"CH","type":"education","lineage":["https://openalex.org/I154338468"]}],"countries":["CH"],"is_corresponding":false,"raw_author_name":"Yvens Ch\u00e9r\u00e9mond","raw_affiliation_strings":["Department of Chemistry, Fribourg Center for Nanomaterials FriMat, University of Fribourg, Chemin du Muse\u0301e 9, 1700 Fribourg, Switzerland,","Department of Chemistry, Fribourg Center for Nanomaterials FriMat, University of Fribourg, Chemin du Mus\u00e9e 9, 1700 Fribourg, Switzerland, Fax: +41-26-3009738"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Fribourg Center for Nanomaterials FriMat, University of Fribourg, Chemin du Muse\u0301e 9, 1700 Fribourg, Switzerland,","institution_ids":["https://openalex.org/I154338468"]},{"raw_affiliation_string":"Department of Chemistry, Fribourg Center for Nanomaterials FriMat, University of Fribourg, Chemin du Mus\u00e9e 9, 1700 Fribourg, Switzerland, Fax: +41-26-3009738","institution_ids":["https://openalex.org/I154338468"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5000099476","display_name":"Aur\u00e9lien Crochet","orcid":"https://orcid.org/0000-0002-4763-2764","observed_orcids":["https://orcid.org/0000-0002-4763-2764"]},"institutions":[{"id":"https://openalex.org/I154338468","display_name":"University of Fribourg","ror":"https://ror.org/022fs9h90","country_code":"CH","type":"education","lineage":["https://openalex.org/I154338468"]}],"countries":["CH"],"is_corresponding":false,"raw_author_name":"Aur\u00e9lien Crochet","raw_affiliation_strings":["Department of Chemistry, Fribourg Center for Nanomaterials FriMat, University of Fribourg, Chemin du Muse\u0301e 9, 1700 Fribourg, Switzerland,","Department of Chemistry, Fribourg Center for Nanomaterials FriMat, University of Fribourg, Chemin du Mus\u00e9e 9, 1700 Fribourg, Switzerland, Fax: +41-26-3009738"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Fribourg Center for Nanomaterials FriMat, University of Fribourg, Chemin du Muse\u0301e 9, 1700 Fribourg, Switzerland,","institution_ids":["https://openalex.org/I154338468"]},{"raw_affiliation_string":"Department of Chemistry, Fribourg Center for Nanomaterials FriMat, University of Fribourg, Chemin du Mus\u00e9e 9, 1700 Fribourg, Switzerland, Fax: +41-26-3009738","institution_ids":["https://openalex.org/I154338468"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5040427898","display_name":"Katharina M. Fromm","orcid":"https://orcid.org/0000-0002-1168-0123","observed_orcids":["https://orcid.org/0000-0002-1168-0123"]},"institutions":[{"id":"https://openalex.org/I154338468","display_name":"University of Fribourg","ror":"https://ror.org/022fs9h90","country_code":"CH","type":"education","lineage":["https://openalex.org/I154338468"]}],"countries":["CH"],"is_corresponding":false,"raw_author_name":"Katharina M. Fromm","raw_affiliation_strings":["Department of Chemistry, Fribourg Center for Nanomaterials FriMat, University of Fribourg, Chemin du Muse\u0301e 9, 1700 Fribourg, Switzerland,","Department of Chemistry, Fribourg Center for Nanomaterials FriMat, University of Fribourg, Chemin du Mus\u00e9e 9, 1700 Fribourg, Switzerland, Fax: +41-26-3009738"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Fribourg Center for Nanomaterials FriMat, University of Fribourg, Chemin du Muse\u0301e 9, 1700 Fribourg, Switzerland,","institution_ids":["https://openalex.org/I154338468"]},{"raw_affiliation_string":"Department of Chemistry, Fribourg Center for Nanomaterials FriMat, University of Fribourg, Chemin du Mus\u00e9e 9, 1700 Fribourg, Switzerland, Fax: +41-26-3009738","institution_ids":["https://openalex.org/I154338468"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I154338468"],"apc_list":{"value":4050,"currency":"USD","value_usd":4050},"apc_paid":null,"fwci":0.4957,"has_fulltext":false,"cited_by_count":3,"citation_normalized_percentile":{"value":0.64164437,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":95},"biblio":{"volume":"2012","issue":"16","first_page":"2725","last_page":"2730"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.4203999936580658,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.4203999936580658,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12228","display_name":"Coordination Chemistry and Organometallics","score":0.2847000062465668,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.14669999480247498,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/aryloxide-ligands","display_name":"aryloxide ligands","score":0.8140000104904175},{"id":"https://openalex.org/keywords/trigonal-bipyramidal-coordination","display_name":"trigonal bipyramidal coordination","score":0.8360000252723694},{"id":"https://openalex.org/keywords/oxidative-substitution","display_name":"oxidative substitution","score":0.7950000166893005},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.5860000252723694}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9714845418930054},{"id":"https://openalex.org/C111592845","wikidata":"https://www.wikidata.org/wiki/Q2867924","display_name":"Trigonal bipyramidal molecular geometry","level":3,"score":0.7042922377586365},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.7025139331817627},{"id":"https://openalex.org/C2777713698","wikidata":"https://www.wikidata.org/wiki/Q282440","display_name":"Catechol","level":2,"score":0.6056001782417297},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.5245937705039978},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.512141227722168},{"id":"https://openalex.org/C2778541603","wikidata":"https://www.wikidata.org/wiki/Q152763","display_name":"Lithium (medication)","level":2,"score":0.5043212175369263},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.48588627576828003},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.4845565855503082},{"id":"https://openalex.org/C68913812","wikidata":"https://www.wikidata.org/wiki/Q238156","display_name":"Coordination complex","level":3,"score":0.44691333174705505},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.44584667682647705},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.43954646587371826},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.38365960121154785},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.37275269627571106},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.3652322292327881},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.16091367602348328},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C134018914","wikidata":"https://www.wikidata.org/wiki/Q162606","display_name":"Endocrinology","level":1,"score":0.0},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1002/ejic.201101054","doi":"https://doi.org/10.1002/ejic.201101054","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ejic.201101054","pdf_url":null,"source":{"id":"https://openalex.org/S16435181","display_name":"European Journal of Inorganic Chemistry","issn_l":"1099-0682","issn":["1099-0682","1434-1948"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"European Journal of Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmh:oai:doc.rero.ch:20120508100739-RQ","doi":null,"is_oa":false,"landing_page_url":"http://doc.rero.ch/record/29101/files/fro_scn.pdf","pdf_url":"http://doc.rero.ch/record/29101/files/fro_scn.pdf","source":{"id":"https://openalex.org/S4306400148","display_name":"reroDoc Digital Library","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I67311998","host_organization_name":"European Organization for Nuclear Research","host_organization_lineage":["https://openalex.org/I67311998"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":null}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320320924","display_name":"Schweizerischer Nationalfonds zur F\u00f6rderung der Wissenschaftlichen Forschung","ror":"https://ror.org/00yjd3n13"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":59,"referenced_works":["https://openalex.org/W574641230","https://openalex.org/W594010138","https://openalex.org/W1710565104","https://openalex.org/W1952948855","https://openalex.org/W1963955777","https://openalex.org/W1967532850","https://openalex.org/W1971957257","https://openalex.org/W1972103896","https://openalex.org/W1973697113","https://openalex.org/W1989849227","https://openalex.org/W1997676894","https://openalex.org/W1997921153","https://openalex.org/W1999799556","https://openalex.org/W2000291104","https://openalex.org/W2004750952","https://openalex.org/W2013299343","https://openalex.org/W2014675750","https://openalex.org/W2022115712","https://openalex.org/W2023703725","https://openalex.org/W2025715997","https://openalex.org/W2025838163","https://openalex.org/W2032383437","https://openalex.org/W2033890502","https://openalex.org/W2034730508","https://openalex.org/W2036913915","https://openalex.org/W2044434077","https://openalex.org/W2050061697","https://openalex.org/W2050915803","https://openalex.org/W2053724703","https://openalex.org/W2058610310","https://openalex.org/W2059767716","https://openalex.org/W2067514442","https://openalex.org/W2068160927","https://openalex.org/W2070984899","https://openalex.org/W2071633715","https://openalex.org/W2074019256","https://openalex.org/W2074044473","https://openalex.org/W2080136773","https://openalex.org/W2081443484","https://openalex.org/W2086704859","https://openalex.org/W2088051201","https://openalex.org/W2089239938","https://openalex.org/W2093881840","https://openalex.org/W2105249240","https://openalex.org/W2121752895","https://openalex.org/W2124440245","https://openalex.org/W2128914100","https://openalex.org/W2129516624","https://openalex.org/W2134973605","https://openalex.org/W2145045185","https://openalex.org/W2145538332","https://openalex.org/W2146912163","https://openalex.org/W2159696105","https://openalex.org/W2320353005","https://openalex.org/W2322084313","https://openalex.org/W2943612633","https://openalex.org/W2949129112","https://openalex.org/W2950944005","https://openalex.org/W2950971113"],"related_works":["https://openalex.org/W1986537063","https://openalex.org/W4386122811","https://openalex.org/W3011512898","https://openalex.org/W2952463593","https://openalex.org/W1480764659","https://openalex.org/W1982001873","https://openalex.org/W2008394019","https://openalex.org/W2015148817","https://openalex.org/W2152592530","https://openalex.org/W2052026390"],"abstract_inverted_index":{"Abstract":[0],"Heterobimetallic":[1],"lithium\u2013iron":[2],"coordination":[3,132],"compounds":[4,64,85,121],"are":[5,38,86],"interesting":[6],"targets":[7],"for":[8,17,23,25],"several":[9],"reasons:":[10],"they":[11],"can":[12],"be":[13],"used":[14],"as":[15,21,112],"precursors":[16],"mixed":[18],"metal":[19],"oxides,":[20],"catalysts,":[22],"example,":[24],"ring\u2010opening":[26],"polymerization":[27],"reactions":[28],"or":[29],"to":[30,102,118],"study":[31],"oxidation/reduction":[32],"processes.":[33],"Finally":[34],"their":[35],"magnetic":[36],"properties":[37],"also":[39],"of":[40,110],"interest.":[41],"New":[42],"heterobimetallic":[43],"aryloxide":[44],"complexes,":[45],"namely":[46],"[(thf)4Li3Fe(OPh)3(O2C6H4)Cl]2":[47],"(1),":[48],"[{(thf)3Li3Fe(OPh)5Cl}3]n":[49],"(2),":[50],"and":[51,57,66],"[(thf)3Li3Fe(OPh)6]2":[52],"(3),":[53],"have":[54],"been":[55],"synthesized":[56,69],"characterized":[58],"by":[59,70,88],"single\u2010crystal":[60],"X\u2010ray":[61],"diffraction.":[62],"While":[63],"1":[65,111],"3":[67],"were":[68],"an":[71],"oxidative":[72],"substitution":[73],"reaction,":[74],"compound":[75,94],"2":[76],"was":[77,99,105],"directly":[78],"obtained":[79],"from":[80],"the":[81,96,108,123],"FeIII":[82,124],"salt.":[83],"These":[84],"accessible":[87],"both":[89],"synthetic":[90],"pathways.":[91],"Additionally,":[92],"in":[93],"1,":[95],"phenoxy":[97],"ligand":[98,114],"catalytically":[100],"oxidized":[101],"ortho\u2010catechol,":[103],"which":[104],"incorporated":[106],"into":[107],"structure":[109],"a":[113,127],"that":[115],"coordinates":[116],"strongly":[117],"iron.":[119],"All":[120],"feature":[122],"ion":[125],"with":[126,131],"trigonal,":[128],"bipyramidal":[129],"environment,":[130],"number":[133],"5.":[134]},"counts_by_year":[{"year":2013,"cited_by_count":2},{"year":2012,"cited_by_count":1}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}