{"id":"https://openalex.org/W2012696136","doi":"https://doi.org/10.1073/pnas.1118348109","title":"Mimicking the electron transfer chain in photosystem II with a molecular triad thermodynamically capable of water oxidation","display_name":"Mimicking the electron transfer chain in photosystem II with a molecular triad thermodynamically capable of water oxidation","publication_year":2012,"publication_date":"2012-05-07","ids":{"openalex":"https://openalex.org/W2012696136","doi":"https://doi.org/10.1073/pnas.1118348109","mag":"2012696136","pmid":"https://pubmed.ncbi.nlm.nih.gov/22566659","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/3465380"},"language":"en","primary_location":{"id":"doi:10.1073/pnas.1118348109","doi":"https://doi.org/10.1073/pnas.1118348109","is_oa":true,"landing_page_url":"https://doi.org/10.1073/pnas.1118348109","pdf_url":"https://www.pnas.org/content/pnas/109/39/15578.full.pdf","source":{"id":"https://openalex.org/S125754415","display_name":"Proceedings of the National Academy of Sciences","issn_l":"0027-8424","issn":["0027-8424","1091-6490"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-a","doyens","erih-plus","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320052","host_organization_name":"National Academy of Sciences","host_organization_lineage":["https://openalex.org/P4310320052"],"host_organization_lineage_names":["National Academy of Sciences"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Proceedings of the National Academy of Sciences","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"bronze","oa_url":"https://www.pnas.org/content/pnas/109/39/15578.full.pdf","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5085347002","display_name":"Jackson Dirceu Megiatto Junior","orcid":"https://orcid.org/0000-0002-1258-4678","observed_orcids":["https://orcid.org/0000-0002-1258-4678"]},"institutions":[{"id":"https://openalex.org/I55732556","display_name":"Arizona State University","ror":"https://ror.org/03efmqc40","country_code":"US","type":"education","lineage":["https://openalex.org/I55732556"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jackson D. Megiatto","raw_affiliation_strings":["Center for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and","institution_ids":["https://openalex.org/I55732556"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5041998496","display_name":"Antaeres Antoniuk-Pablant","orcid":"https://orcid.org/0009-0003-2750-1040","observed_orcids":["https://orcid.org/0009-0003-2750-1040"]},"institutions":[{"id":"https://openalex.org/I55732556","display_name":"Arizona State University","ror":"https://ror.org/03efmqc40","country_code":"US","type":"education","lineage":["https://openalex.org/I55732556"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Antaeres Antoniuk-Pablant","raw_affiliation_strings":["Center for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and","institution_ids":["https://openalex.org/I55732556"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5008096609","display_name":"Benjamin D. Sherman","orcid":"https://orcid.org/0000-0001-9571-5065","observed_orcids":["https://orcid.org/0000-0001-9571-5065"]},"institutions":[{"id":"https://openalex.org/I55732556","display_name":"Arizona State University","ror":"https://ror.org/03efmqc40","country_code":"US","type":"education","lineage":["https://openalex.org/I55732556"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Benjamin D. Sherman","raw_affiliation_strings":["Center for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and","institution_ids":["https://openalex.org/I55732556"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5032994717","display_name":"Gerdenis Kodis","orcid":"https://orcid.org/0000-0003-4998-7005","observed_orcids":["https://orcid.org/0000-0003-4998-7005"]},"institutions":[{"id":"https://openalex.org/I55732556","display_name":"Arizona State University","ror":"https://ror.org/03efmqc40","country_code":"US","type":"education","lineage":["https://openalex.org/I55732556"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Gerdenis Kodis","raw_affiliation_strings":["Center for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and","aCenter for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and","institution_ids":["https://openalex.org/I55732556"]},{"raw_affiliation_string":"aCenter for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and","institution_ids":["https://openalex.org/I55732556"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5046801499","display_name":"Miguel Gervaldo","orcid":"https://orcid.org/0000-0001-9287-5872","observed_orcids":["https://orcid.org/0000-0001-9287-5872"]},"institutions":[{"id":"https://openalex.org/I15366983","display_name":"Universidad Nacional de R\u00edo Cuarto","ror":"https://ror.org/0002pcv65","country_code":"AR","type":"education","lineage":["https://openalex.org/I15366983"]}],"countries":["AR"],"is_corresponding":false,"raw_author_name":"Miguel Gervaldo","raw_affiliation_strings":["Departamento de Qu\u00edmica, Universidad Nacional de R\u00edo Cuarto, Agencia Postal, 3, 5800 R\u00edo Cuarto, Argentina"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departamento de Qu\u00edmica, Universidad Nacional de R\u00edo Cuarto, Agencia Postal, 3, 5800 R\u00edo Cuarto, Argentina","institution_ids":["https://openalex.org/I15366983"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5006939009","display_name":"Thomas A. Moore","orcid":"https://orcid.org/0000-0002-1577-7117","observed_orcids":["https://orcid.org/0000-0002-1577-7117"]},"institutions":[{"id":"https://openalex.org/I55732556","display_name":"Arizona State University","ror":"https://ror.org/03efmqc40","country_code":"US","type":"education","lineage":["https://openalex.org/I55732556"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Thomas A. Moore","raw_affiliation_strings":["Center for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and","aCenter for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and","institution_ids":["https://openalex.org/I55732556"]},{"raw_affiliation_string":"aCenter for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and","institution_ids":["https://openalex.org/I55732556"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5019828593","display_name":"Ana L. Moore","orcid":"https://orcid.org/0000-0002-6653-9506","observed_orcids":["https://orcid.org/0000-0002-6653-9506"]},"institutions":[{"id":"https://openalex.org/I55732556","display_name":"Arizona State University","ror":"https://ror.org/03efmqc40","country_code":"US","type":"education","lineage":["https://openalex.org/I55732556"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Ana L. Moore","raw_affiliation_strings":["Center for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and","aCenter for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and","institution_ids":["https://openalex.org/I55732556"]},{"raw_affiliation_string":"aCenter for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and","institution_ids":["https://openalex.org/I55732556"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5082113971","display_name":"Devens Gust","orcid":"https://orcid.org/0000-0003-0550-8498","observed_orcids":["https://orcid.org/0000-0003-0550-8498"]},"institutions":[{"id":"https://openalex.org/I55732556","display_name":"Arizona State University","ror":"https://ror.org/03efmqc40","country_code":"US","type":"education","lineage":["https://openalex.org/I55732556"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Devens Gust","raw_affiliation_strings":["Center for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Bio-Inspired Solar Fuel Production, Department of Chemistry and Biochemistry, Arizona State University, Tempe, AZ 85287; and","institution_ids":["https://openalex.org/I55732556"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":5.1366,"has_fulltext":true,"cited_by_count":128,"citation_normalized_percentile":{"value":0.96711671,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":95,"max":100},"biblio":{"volume":"109","issue":"39","first_page":"15578","last_page":"15583"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":0.47609999775886536,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":0.47609999775886536,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10303","display_name":"Photosynthetic Processes and Mechanisms","score":0.2556000053882599,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.2290000021457672,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/photosystem-ii","display_name":"photosystem II","score":0.9710000157356262},{"id":"https://openalex.org/keywords/electron-transport-chain","display_name":"electron transport chain","score":0.8370000123977661},{"id":"https://openalex.org/keywords/molecular-triad","display_name":"molecular triad","score":0.8080000281333923},{"id":"https://openalex.org/keywords/water-oxidation","display_name":"water oxidation","score":0.8370000123977661},{"id":"https://openalex.org/keywords/oxygen-evolving-complex","display_name":"oxygen-evolving complex","score":0.800000011920929},{"id":"https://openalex.org/keywords/proton-coupled-electron-transfer","display_name":"proton-coupled electron transfer","score":0.9679999947547913},{"id":"https://openalex.org/keywords/pentafluorophenyl-porphyrin","display_name":"pentafluorophenyl porphyrin","score":0.8949999809265137},{"id":"https://openalex.org/keywords/charge-separated-states","display_name":"charge-separated states","score":0.6470000147819519},{"id":"https://openalex.org/keywords/artificial-photosynthesis","display_name":"artificial photosynthesis","score":0.8240000009536743}],"concepts":[{"id":"https://openalex.org/C177499756","wikidata":"https://www.wikidata.org/wiki/Q7117940","display_name":"P680","level":5,"score":0.8936334848403931},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7758803367614746},{"id":"https://openalex.org/C123669783","wikidata":"https://www.wikidata.org/wiki/Q902898","display_name":"Electron transfer","level":2,"score":0.7404625415802002},{"id":"https://openalex.org/C110010208","wikidata":"https://www.wikidata.org/wiki/Q7252048","display_name":"Proton-coupled electron transfer","level":3,"score":0.6842283606529236},{"id":"https://openalex.org/C80298142","wikidata":"https://www.wikidata.org/wiki/Q22327014","display_name":"Photosystem II","level":3,"score":0.6722286939620972},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.6653094291687012},{"id":"https://openalex.org/C56990077","wikidata":"https://www.wikidata.org/wiki/Q2628457","display_name":"Oxygen-evolving complex","level":4,"score":0.6007111668586731},{"id":"https://openalex.org/C188231169","wikidata":"https://www.wikidata.org/wiki/Q418676","display_name":"Photosynthetic reaction centre","level":3,"score":0.5398385524749756},{"id":"https://openalex.org/C89389743","wikidata":"https://www.wikidata.org/wiki/Q13444837","display_name":"P700","level":5,"score":0.49434733390808105},{"id":"https://openalex.org/C2900893","wikidata":"https://www.wikidata.org/wiki/Q1231592","display_name":"Electron acceptor","level":2,"score":0.4744214415550232},{"id":"https://openalex.org/C2778148179","wikidata":"https://www.wikidata.org/wiki/Q911571","display_name":"Electron donor","level":3,"score":0.4585196375846863},{"id":"https://openalex.org/C55904794","wikidata":"https://www.wikidata.org/wiki/Q82682","display_name":"Redox","level":2,"score":0.4404154419898987},{"id":"https://openalex.org/C206865886","wikidata":"https://www.wikidata.org/wiki/Q22327806","display_name":"Photosystem","level":4,"score":0.42352625727653503},{"id":"https://openalex.org/C2778460671","wikidata":"https://www.wikidata.org/wiki/Q485277","display_name":"Histidine","level":3,"score":0.41453471779823303},{"id":"https://openalex.org/C154828652","wikidata":"https://www.wikidata.org/wiki/Q4339518","display_name":"Photosystem I","level":4,"score":0.2767302393913269},{"id":"https://openalex.org/C183688256","wikidata":"https://www.wikidata.org/wiki/Q11982","display_name":"Photosynthesis","level":2,"score":0.16176339983940125},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.15680760145187378},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.12372457981109619},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.08935397863388062},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C181199279","wikidata":"https://www.wikidata.org/wiki/Q8047","display_name":"Enzyme","level":2,"score":0.0}],"mesh":[{"descriptor_ui":"D002734","descriptor_name":"Chlorophyll","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D004579","descriptor_name":"Electron Transport","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008956","descriptor_name":"Models, Chemical","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true},{"descriptor_ui":"D010084","descriptor_name":"Oxidation-Reduction","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D011522","descriptor_name":"Protons","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true},{"descriptor_ui":"D014867","descriptor_name":"Water","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D045332","descriptor_name":"Photosystem II Protein Complex","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true}],"locations_count":5,"locations":[{"id":"doi:10.1073/pnas.1118348109","doi":"https://doi.org/10.1073/pnas.1118348109","is_oa":true,"landing_page_url":"https://doi.org/10.1073/pnas.1118348109","pdf_url":"https://www.pnas.org/content/pnas/109/39/15578.full.pdf","source":{"id":"https://openalex.org/S125754415","display_name":"Proceedings of the National Academy of Sciences","issn_l":"0027-8424","issn":["0027-8424","1091-6490"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-a","doyens","erih-plus","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320052","host_organization_name":"National Academy of Sciences","host_organization_lineage":["https://openalex.org/P4310320052"],"host_organization_lineage_names":["National Academy of Sciences"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Proceedings of the National Academy of Sciences","raw_type":"journal-article"},{"id":"pmh:oai:europepmc.org:2603182","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/3465380","pdf_url":null,"source":{"id":"https://openalex.org/S4306400806","display_name":"Europe PMC (PubMed Central)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1303153112","host_organization_name":"European Bioinformatics Institute","host_organization_lineage":["https://openalex.org/I1303153112"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":null,"raw_type":"Text"},{"id":"pmh:oai:pubmedcentral.nih.gov:3465380","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/3465380","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Proc Natl Acad Sci U S A","raw_type":"Text"},{"id":"pmid:22566659","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/22566659","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Proceedings of the National Academy of Sciences of the United States of America","raw_type":"Journal Article"},{"id":"pmh:oai:ri.conicet.gov.ar:11336/194735","doi":null,"is_oa":true,"landing_page_url":"http://hdl.handle.net/11336/194735","pdf_url":null,"source":{"id":"https://openalex.org/S4306402455","display_name":"CONICET Digital (CONICET)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4210148385","host_organization_name":"Biomedicine Research Institute of Buenos Aires - CONICET - Partner Institute of the Max Planck Society","host_organization_lineage":["https://openalex.org/I4210148385"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-sa","license_id":"https://openalex.org/licenses/cc-by-nc-sa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":{"id":"doi:10.1073/pnas.1118348109","doi":"https://doi.org/10.1073/pnas.1118348109","is_oa":true,"landing_page_url":"https://doi.org/10.1073/pnas.1118348109","pdf_url":"https://www.pnas.org/content/pnas/109/39/15578.full.pdf","source":{"id":"https://openalex.org/S125754415","display_name":"Proceedings of the National Academy of Sciences","issn_l":"0027-8424","issn":["0027-8424","1091-6490"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-a","doyens","erih-plus","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320052","host_organization_name":"National Academy of Sciences","host_organization_lineage":["https://openalex.org/P4310320052"],"host_organization_lineage_names":["National Academy of Sciences"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Proceedings of the National Academy of Sciences","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G3228151500","display_name":"TAS::89 0227::TAS RECOVERY; NEW: RECOVERY ACT -  EFRC CENTER FOR BIO-INSPIRED SOLAR FUEL PRODUCTION -- EFRC; J. DEVENS GUST","funder_award_id":"DESC0001016","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"},{"id":"https://openalex.org/G5728457517","display_name":null,"funder_award_id":"DE-SC0001016","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G753167560","display_name":"TAS::89 0227::TAS RECOVERY; NEW: RECOVERY ACT -  EFRC CENTER FOR BIO-INSPIRED SOLAR FUEL PRODUCTION -- EFRC; J. DEVENS GUST","funder_award_id":"DESC0001016","funder_id":"https://openalex.org/F4320332359","funder_display_name":"Office of Science"}],"funders":[{"id":"https://openalex.org/F4320306084","display_name":"U.S. Department of Energy","ror":"https://ror.org/01bj3aw27"},{"id":"https://openalex.org/F4320332359","display_name":"Office of Science","ror":"https://ror.org/00mmn6b08"},{"id":"https://openalex.org/F4320337480","display_name":"Basic Energy Sciences","ror":"https://ror.org/05mg91w61"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2012696136.pdf","grobid_xml":"https://content.openalex.org/works/W2012696136.grobid-xml"},"referenced_works_count":35,"referenced_works":["https://openalex.org/W1531102271","https://openalex.org/W1559674465","https://openalex.org/W1679387364","https://openalex.org/W1981849326","https://openalex.org/W2011655890","https://openalex.org/W2016018644","https://openalex.org/W2032521268","https://openalex.org/W2033033156","https://openalex.org/W2040079634","https://openalex.org/W2048694717","https://openalex.org/W2048867659","https://openalex.org/W2049745418","https://openalex.org/W2052315960","https://openalex.org/W2056735473","https://openalex.org/W2057223641","https://openalex.org/W2057863409","https://openalex.org/W2058925597","https://openalex.org/W2063780436","https://openalex.org/W2071705887","https://openalex.org/W2075567202","https://openalex.org/W2076388181","https://openalex.org/W2076950836","https://openalex.org/W2078171630","https://openalex.org/W2082305750","https://openalex.org/W2083907491","https://openalex.org/W2091481003","https://openalex.org/W2106531886","https://openalex.org/W2122608953","https://openalex.org/W2126285505","https://openalex.org/W2130271590","https://openalex.org/W2130280236","https://openalex.org/W2150310416","https://openalex.org/W2165896332","https://openalex.org/W2169791789","https://openalex.org/W2171093931"],"related_works":["https://openalex.org/W2026389394","https://openalex.org/W2039620058","https://openalex.org/W7058273804","https://openalex.org/W2078171630","https://openalex.org/W4241731065","https://openalex.org/W4246570913","https://openalex.org/W7131067807","https://openalex.org/W4416216480","https://openalex.org/W2754017752","https://openalex.org/W2076950836"],"abstract_inverted_index":{"In":[0],"the":[1,9,16,35,44,48,55,59,148,171,175,195],"photosynthetic":[2,212],"photosystem":[3],"II,":[4],"electrons":[5],"are":[6],"transferred":[7],"from":[8,34],"manganese-containing":[10],"oxygen":[11],"evolving":[12],"complex":[13],"(OEC)":[14],"to":[15,39,108,126,204],"oxidized":[17],"primary":[18],"electron-donor":[19,95],"chlorophyll":[20],"P680(\u2022+)":[21,53],"by":[22,104,118],"a":[23,29,40,66,78,86,92,140,160],"proton-coupled":[24],"electron":[25,72,88,120,131,172],"transfer":[26,33,107,121,132],"process":[27],"involving":[28,174],"tyrosine-histidine":[30,176],"pair.":[31],"Proton":[32],"tyrosine":[36,49],"phenolic":[37,149],"group":[38],"histidine":[41],"nitrogen":[42],"positions":[43],"redox":[45],"potential":[46],"of":[47,52,65,77,98,163,187,197],"between":[50],"those":[51],"and":[54,61,91,190],"OEC.":[56],"We":[57],"report":[58],"synthesis":[60],"time-resolved":[62],"spectroscopic":[63],"study":[64],"molecular":[67],"triad":[68,75,167],"that":[69],"models":[70],"this":[71,202],"transfer.":[73],"The":[74,166,180],"consists":[76],"high-potential":[79],"porphyrin":[80],"bearing":[81],"two":[82],"pentafluorophenyl":[83],"groups":[84],"(PF(10)),":[85],"tetracyanoporphyrin":[87],"acceptor":[89],"(TCNP),":[90],"benzimidazole-phenol":[93],"secondary":[94],"(Bi-PhOH).":[96],"Excitation":[97],"PF(10)":[99],"in":[100,146,178,210],"benzonitrile":[101],"is":[102,184],"followed":[103],"singlet":[105],"energy":[106],"TCNP":[109],"(\u03c4":[110,122,135],"=":[111,123],"41":[112],"ps),":[113,138],"whose":[114],"excited":[115],"state":[116,142,157,183],"decays":[117,158],"photoinduced":[119],"830":[124],"ps)":[125],"yield":[127],"Bi-PhOH-PF(10)(\u2022+)-TCNP(\u2022-).":[128],"A":[129],"second":[130],"reaction":[133],"follows":[134],"<":[136],"12":[137],"giving":[139],"final":[141,156,181],"postulated":[143],"as":[144,201],"BiH(+)-PhO(\u2022)-PF(10)-TCNP(\u2022-),":[145],"which":[147],"proton":[150],"now":[151],"resides":[152],"on":[153],"benzimidazole.":[154],"This":[155],"with":[159],"time":[161],"constant":[162],"3.8":[164],"\u03bcs.":[165],"thus":[168],"functionally":[169],"mimics":[170],"transfers":[173],"pair":[177],"PSII.":[179],"charge-separated":[182],"thermodynamically":[185],"capable":[186],"water":[188,205],"oxidation,":[189],"its":[191],"long":[192],"lifetime":[193],"suggests":[194],"possibility":[196],"coupling":[198],"systems":[199],"such":[200],"system":[203],"oxidation":[206],"catalysts":[207],"for":[208],"use":[209],"artificial":[211],"fuel":[213],"production.":[214]},"counts_by_year":[{"year":2026,"cited_by_count":3},{"year":2025,"cited_by_count":5},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":3},{"year":2022,"cited_by_count":4},{"year":2021,"cited_by_count":10},{"year":2020,"cited_by_count":12},{"year":2019,"cited_by_count":13},{"year":2018,"cited_by_count":10},{"year":2017,"cited_by_count":14},{"year":2016,"cited_by_count":14},{"year":2015,"cited_by_count":10},{"year":2014,"cited_by_count":13},{"year":2013,"cited_by_count":11},{"year":2012,"cited_by_count":3}],"updated_date":"2026-11-03T10:50:19.383937","created_date":"2016-06-24T00:00:00"}