{"id":"https://openalex.org/W2012194705","doi":"https://doi.org/10.1021/ic0605928","title":"Microwave-Assisted Synthesis of 3,1,2- and 2,1,8-Re(I) and 99mTc(I)\u2212Metallocarborane Complexes","display_name":"Microwave-Assisted Synthesis of 3,1,2- and 2,1,8-Re(I) and 99mTc(I)\u2212Metallocarborane Complexes","publication_year":2006,"publication_date":"2006-06-22","ids":{"openalex":"https://openalex.org/W2012194705","doi":"https://doi.org/10.1021/ic0605928","mag":"2012194705","pmid":"https://pubmed.ncbi.nlm.nih.gov/16841972"},"language":"en","primary_location":{"id":"doi:10.1021/ic0605928","doi":"https://doi.org/10.1021/ic0605928","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic0605928","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5049955003","display_name":"Andrew E. C. Green","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I98251732","display_name":"McMaster University","ror":"https://ror.org/02fa3aq29","country_code":"CA","type":"education","lineage":["https://openalex.org/I98251732"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Andrew E. C. Green","raw_affiliation_strings":["Departments of Chemistry and Medical Physics & Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4M1","Departments of Chemistry and Medical Physics and Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada, L8S 4M1"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departments of Chemistry and Medical Physics & Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4M1","institution_ids":["https://openalex.org/I98251732"]},{"raw_affiliation_string":"Departments of Chemistry and Medical Physics and Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada, L8S 4M1","institution_ids":["https://openalex.org/I98251732"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5082200026","display_name":"Patrick W. Causey","orcid":"https://orcid.org/0000-0002-7606-2836","observed_orcids":["https://orcid.org/0000-0002-7606-2836"]},"institutions":[{"id":"https://openalex.org/I98251732","display_name":"McMaster University","ror":"https://ror.org/02fa3aq29","country_code":"CA","type":"education","lineage":["https://openalex.org/I98251732"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Patrick W. Causey","raw_affiliation_strings":["Departments of Chemistry and Medical Physics & Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4M1","Departments of Chemistry and Medical Physics and Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada, L8S 4M1"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departments of Chemistry and Medical Physics & Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4M1","institution_ids":["https://openalex.org/I98251732"]},{"raw_affiliation_string":"Departments of Chemistry and Medical Physics and Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada, L8S 4M1","institution_ids":["https://openalex.org/I98251732"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5035414469","display_name":"Anika S. Louie","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I98251732","display_name":"McMaster University","ror":"https://ror.org/02fa3aq29","country_code":"CA","type":"education","lineage":["https://openalex.org/I98251732"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Anika S. Louie","raw_affiliation_strings":["Departments of Chemistry and Medical Physics & Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4M1","Departments of Chemistry and Medical Physics and Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada, L8S 4M1"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departments of Chemistry and Medical Physics & Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4M1","institution_ids":["https://openalex.org/I98251732"]},{"raw_affiliation_string":"Departments of Chemistry and Medical Physics and Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada, L8S 4M1","institution_ids":["https://openalex.org/I98251732"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5001670444","display_name":"Andrea Florence Armstrong","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I98251732","display_name":"McMaster University","ror":"https://ror.org/02fa3aq29","country_code":"CA","type":"education","lineage":["https://openalex.org/I98251732"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Andrea F. Armstrong","raw_affiliation_strings":["Departments of Chemistry and Medical Physics & Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4M1","Departments of Chemistry and Medical Physics and Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada, L8S 4M1"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departments of Chemistry and Medical Physics & Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4M1","institution_ids":["https://openalex.org/I98251732"]},{"raw_affiliation_string":"Departments of Chemistry and Medical Physics and Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada, L8S 4M1","institution_ids":["https://openalex.org/I98251732"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5010378779","display_name":"L.E. Harrington","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I98251732","display_name":"McMaster University","ror":"https://ror.org/02fa3aq29","country_code":"CA","type":"education","lineage":["https://openalex.org/I98251732"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Laura E. Harrington","raw_affiliation_strings":["Departments of Chemistry and Medical Physics & Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4M1","Departments of Chemistry and Medical Physics and Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada, L8S 4M1"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departments of Chemistry and Medical Physics & Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4M1","institution_ids":["https://openalex.org/I98251732"]},{"raw_affiliation_string":"Departments of Chemistry and Medical Physics and Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada, L8S 4M1","institution_ids":["https://openalex.org/I98251732"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5026175733","display_name":"John F. Valliant","orcid":"https://orcid.org/0000-0002-1461-552X","observed_orcids":["https://orcid.org/0000-0002-1461-552X"]},"institutions":[{"id":"https://openalex.org/I98251732","display_name":"McMaster University","ror":"https://ror.org/02fa3aq29","country_code":"CA","type":"education","lineage":["https://openalex.org/I98251732"]}],"countries":["CA"],"is_corresponding":true,"raw_author_name":"John F. Valliant","raw_affiliation_strings":["Departments of Chemistry and Medical Physics & Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4M1","Departments of Chemistry and Medical Physics and Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada, L8S 4M1"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departments of Chemistry and Medical Physics & Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada L8S 4M1","institution_ids":["https://openalex.org/I98251732"]},{"raw_affiliation_string":"Departments of Chemistry and Medical Physics and Applied Radiation Sciences, McMaster University, 1280 Main Street West, Hamilton, Ontario, Canada, L8S 4M1","institution_ids":["https://openalex.org/I98251732"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5026175733"],"corresponding_institution_ids":["https://openalex.org/I98251732"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":3.2358,"has_fulltext":false,"cited_by_count":50,"citation_normalized_percentile":{"value":0.90951372,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"45","issue":"15","first_page":"5727","last_page":"5729"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12055","display_name":"Boron Compounds in Chemistry","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/2741","display_name":"Radiology, Nuclear Medicine and Imaging"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},"topics":[{"id":"https://openalex.org/T12055","display_name":"Boron Compounds in Chemistry","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/2741","display_name":"Radiology, Nuclear Medicine and Imaging"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},{"id":"https://openalex.org/T11395","display_name":"Radiopharmaceutical Chemistry and Applications","score":0.0003000000142492354,"subfield":{"id":"https://openalex.org/subfields/2741","display_name":"Radiology, Nuclear Medicine and Imaging"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},{"id":"https://openalex.org/T12270","display_name":"Microwave-Assisted Synthesis and Applications","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/microwave-assisted-synthesis","display_name":"microwave-assisted synthesis","score":0.9670000076293945},{"id":"https://openalex.org/keywords/technetium-99m","display_name":"technetium-99m","score":0.9010000228881836},{"id":"https://openalex.org/keywords/99mtc-complexes","display_name":"99mTc complexes","score":0.6660000085830688},{"id":"https://openalex.org/keywords/aqueous-reaction-medium","display_name":"aqueous reaction media","score":0.6959999799728394},{"id":"https://openalex.org/keywords/molecular-imaging-agents","display_name":"molecular imaging agents","score":0.8899999856948853},{"id":"https://openalex.org/keywords/metallacarboranes","display_name":"metallacarboranes","score":0.597000002861023}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9666807651519775},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.3290398120880127}],"mesh":[{"descriptor_ui":"D002244","descriptor_name":"Carbon","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D002621","descriptor_name":"Chemistry","qualifier_ui":"Q000379","qualifier_name":"methods","is_major_topic":true},{"descriptor_ui":"D008670","descriptor_name":"Metals","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D008872","descriptor_name":"Microwaves","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true},{"descriptor_ui":"D008956","descriptor_name":"Models, Chemical","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008968","descriptor_name":"Molecular Conformation","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D012211","descriptor_name":"Rhenium","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D013667","descriptor_name":"Technetium","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D015609","descriptor_name":"Organotechnetium Compounds","qualifier_ui":"Q000138","qualifier_name":"chemical synthesis","is_major_topic":true},{"descriptor_ui":"D015609","descriptor_name":"Organotechnetium Compounds","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D019275","descriptor_name":"Radiopharmaceuticals","qualifier_ui":"Q000138","qualifier_name":"chemical synthesis","is_major_topic":true},{"descriptor_ui":"D019275","descriptor_name":"Radiopharmaceuticals","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false}],"locations_count":2,"locations":[{"id":"doi:10.1021/ic0605928","doi":"https://doi.org/10.1021/ic0605928","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic0605928","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmid:16841972","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/16841972","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":16,"referenced_works":["https://openalex.org/W2015409638","https://openalex.org/W2016793379","https://openalex.org/W2023611473","https://openalex.org/W2040689444","https://openalex.org/W2045258833","https://openalex.org/W2049368719","https://openalex.org/W2080789660","https://openalex.org/W2081630250","https://openalex.org/W2082769748","https://openalex.org/W2083952090","https://openalex.org/W2092440972","https://openalex.org/W2101754594","https://openalex.org/W2321244670","https://openalex.org/W2329331412","https://openalex.org/W2950660977","https://openalex.org/W4230278501"],"related_works":["https://openalex.org/W1991483158","https://openalex.org/W1988489692","https://openalex.org/W2037682320","https://openalex.org/W1987693874","https://openalex.org/W2023763122","https://openalex.org/W3124801851","https://openalex.org/W2327785546","https://openalex.org/W2059670634","https://openalex.org/W2138560519","https://openalex.org/W1998538691"],"abstract_inverted_index":{"Microwave":[0,32],"heating":[1,33],"was":[2,34],"used":[3],"to":[4,25,45],"prepare":[5],"eta5-rhenium":[6],"carborane":[7],"complexes":[8],"in":[9],"aqueous":[10],"reaction":[11],"media.":[12],"For":[13],"carboranes":[14],"bearing":[15],"sterically":[16],"demanding":[17],"substituents,":[18],"isomerization":[19],"of":[20,49],"the":[21,38],"cage":[22],"from":[23],"3,1,2":[24],"2,1,8":[26],"derivatives":[27],"occurred":[28],"concomitantly":[29],"with":[30],"complexation.":[31],"equally":[35],"effective":[36],"at":[37],"tracer":[39],"level":[40],"using":[41],"technetium-99m,":[42],"affording":[43],"access":[44],"a":[46],"new":[47],"class":[48],"synthons":[50],"for":[51],"designing":[52],"novel":[53],"molecular":[54],"imaging":[55],"agents.":[56]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":1},{"year":2022,"cited_by_count":3},{"year":2021,"cited_by_count":5},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":2},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":3},{"year":2013,"cited_by_count":3},{"year":2012,"cited_by_count":8}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}