{"id":"https://openalex.org/W2012180862","doi":"https://doi.org/10.1021/jp306172k","title":"Electrochemical CO 2 and CO Reduction on Metal-Functionalized Porphyrin-like Graphene","display_name":"Electrochemical CO 2 and CO Reduction on Metal-Functionalized Porphyrin-like Graphene","publication_year":2013,"publication_date":"2013-04-10","ids":{"openalex":"https://openalex.org/W2012180862","doi":"https://doi.org/10.1021/jp306172k","mag":"2012180862"},"language":"en","primary_location":{"id":"doi:10.1021/jp306172k","doi":"https://doi.org/10.1021/jp306172k","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp306172k","pdf_url":null,"source":{"id":"https://openalex.org/S95739953","display_name":"The Journal of Physical Chemistry C","issn_l":"1932-7447","issn":["1932-7447","1932-7455"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry C","raw_type":"journal-article"},"parent_works":[],"lineage":["https://openalex.org/W2012180862"],"child_works_count":0,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5058555695","display_name":"Vladimir Tripkovi\u0107","orcid":"https://orcid.org/0000-0003-4629-043X","observed_orcids":["https://orcid.org/0000-0003-4629-043X"]},"institutions":[{"id":"https://openalex.org/I96673099","display_name":"Technical University of Denmark","ror":"https://ror.org/04qtj9h94","country_code":"DK","type":"education","lineage":["https://openalex.org/I96673099"]}],"countries":["DK"],"is_corresponding":false,"raw_author_name":"Vladimir Tripkovic","raw_affiliation_strings":["Center for Atomic-scale Materials\rDesign, Department\rof Physics, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Atomic-scale Materials\rDesign, Department\rof Physics, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark","institution_ids":["https://openalex.org/I96673099"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5088301225","display_name":"Marco Vanin","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I96673099","display_name":"Technical University of Denmark","ror":"https://ror.org/04qtj9h94","country_code":"DK","type":"education","lineage":["https://openalex.org/I96673099"]}],"countries":["DK"],"is_corresponding":false,"raw_author_name":"Marco Vanin","raw_affiliation_strings":["Center for Atomic-scale Materials\rDesign, Department\rof Physics, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Atomic-scale Materials\rDesign, Department\rof Physics, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark","institution_ids":["https://openalex.org/I96673099"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5088118708","display_name":"Mohammedreza Karamad","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I96673099","display_name":"Technical University of Denmark","ror":"https://ror.org/04qtj9h94","country_code":"DK","type":"education","lineage":["https://openalex.org/I96673099"]}],"countries":["DK"],"is_corresponding":false,"raw_author_name":"Mohammedreza Karamad","raw_affiliation_strings":["Center for Atomic-scale Materials\rDesign, Department\rof Physics, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Atomic-scale Materials\rDesign, Department\rof Physics, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark","institution_ids":["https://openalex.org/I96673099"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5041220928","display_name":"M\u00e5rten E. Bj\u00f6rketun","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I96673099","display_name":"Technical University of Denmark","ror":"https://ror.org/04qtj9h94","country_code":"DK","type":"education","lineage":["https://openalex.org/I96673099"]}],"countries":["DK"],"is_corresponding":false,"raw_author_name":"M\u00e5rten E. Bj\u00f6rketun","raw_affiliation_strings":["Center for Atomic-scale Materials\rDesign, Department\rof Physics, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Atomic-scale Materials\rDesign, Department\rof Physics, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark","institution_ids":["https://openalex.org/I96673099"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5079996682","display_name":"Karsten W. Jacobsen","orcid":"https://orcid.org/0000-0002-1121-2979","observed_orcids":["https://orcid.org/0000-0002-1121-2979"]},"institutions":[{"id":"https://openalex.org/I96673099","display_name":"Technical University of Denmark","ror":"https://ror.org/04qtj9h94","country_code":"DK","type":"education","lineage":["https://openalex.org/I96673099"]}],"countries":["DK"],"is_corresponding":false,"raw_author_name":"Karsten W. Jacobsen","raw_affiliation_strings":["Center for Atomic-scale Materials\rDesign, Department\rof Physics, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Atomic-scale Materials\rDesign, Department\rof Physics, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark","institution_ids":["https://openalex.org/I96673099"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5067980873","display_name":"Kristian Sommer Thygesen","orcid":"https://orcid.org/0000-0001-5197-214X","observed_orcids":["https://orcid.org/0000-0001-5197-214X"]},"institutions":[{"id":"https://openalex.org/I96673099","display_name":"Technical University of Denmark","ror":"https://ror.org/04qtj9h94","country_code":"DK","type":"education","lineage":["https://openalex.org/I96673099"]}],"countries":["DK"],"is_corresponding":false,"raw_author_name":"Kristian S. Thygesen","raw_affiliation_strings":["Center for Atomic-scale Materials\rDesign, Department\rof Physics, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Atomic-scale Materials\rDesign, Department\rof Physics, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark","institution_ids":["https://openalex.org/I96673099"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5083668074","display_name":"Jan Rossmeisl","orcid":"https://orcid.org/0000-0001-7749-6567","observed_orcids":["https://orcid.org/0000-0001-7749-6567"]},"institutions":[{"id":"https://openalex.org/I96673099","display_name":"Technical University of Denmark","ror":"https://ror.org/04qtj9h94","country_code":"DK","type":"education","lineage":["https://openalex.org/I96673099"]}],"countries":["DK"],"is_corresponding":true,"raw_author_name":"Jan Rossmeisl","raw_affiliation_strings":["Center for Atomic-scale Materials\rDesign, Department\rof Physics, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center for Atomic-scale Materials\rDesign, Department\rof Physics, Technical University of Denmark, DK-2800 Kongens Lyngby, Denmark","institution_ids":["https://openalex.org/I96673099"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5083668074"],"corresponding_institution_ids":["https://openalex.org/I96673099"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":6.5002,"has_fulltext":false,"cited_by_count":307,"citation_normalized_percentile":{"value":0.974188,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":93,"max":100},"biblio":{"volume":"117","issue":"18","first_page":"9187","last_page":"9195"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11784","display_name":"CO2 Reduction Techniques and Catalysts","score":0.9761000275611877,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11784","display_name":"CO2 Reduction Techniques and Catalysts","score":0.9761000275611877,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10030","display_name":"Electrocatalysts for Energy Conversion","score":0.014600000344216824,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10495","display_name":"Catalysts for Methane Reforming","score":0.007699999958276749,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/electrochemical-co2-reduction","display_name":"electrochemical CO2 reduction","score":0.8450000286102295},{"id":"https://openalex.org/keywords/electrochemical-co-reduction","display_name":"CO electroreduction","score":0.9629999995231628},{"id":"https://openalex.org/keywords/methanol-synthesis","display_name":"methanol synthesis","score":0.6769999861717224},{"id":"https://openalex.org/keywords/methane-synthesis","display_name":"methane synthesis","score":0.8379999995231628},{"id":"https://openalex.org/keywords/rhodium-catalysts","display_name":"rhodium catalysts","score":0.6430000066757202},{"id":"https://openalex.org/keywords/late-transition-metals","display_name":"late transition metals","score":0.8450000286102295},{"id":"https://openalex.org/keywords/hydrogen-evolution-reaction","display_name":"hydrogen evolution reaction","score":0.42100000381469727},{"id":"https://openalex.org/keywords/hydrogen-oxidation-reaction","display_name":"hydrogen oxidation","score":0.9229999780654907},{"id":"https://openalex.org/keywords/volcano-plot","display_name":"volcano plot","score":0.8510000109672546},{"id":"https://openalex.org/keywords/overpotential","display_name":"overpotential","score":0.7319999933242798},{"id":"https://openalex.org/keywords/reaction-intermediates","display_name":"reaction intermediates","score":0.6759999990463257},{"id":"https://openalex.org/keywords/active-site-electronic-structure","display_name":"active site electronic structure","score":0.6299999952316284}],"concepts":[{"id":"https://openalex.org/C2779480358","wikidata":"https://www.wikidata.org/wiki/Q422926","display_name":"Porphyrin","level":2,"score":0.863098680973053},{"id":"https://openalex.org/C30080830","wikidata":"https://www.wikidata.org/wiki/Q169917","display_name":"Graphene","level":2,"score":0.8464902639389038},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.7708101868629456},{"id":"https://openalex.org/C111335779","wikidata":"https://www.wikidata.org/wiki/Q3454686","display_name":"Reduction (mathematics)","level":2,"score":0.5538285970687866},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.5130530595779419},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.5011096000671387},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.3814195990562439},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.3408154845237732},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.3372178375720978},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.28415584564208984},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.20820868015289307},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.15003088116645813},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.08450445532798767},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.05703192949295044},{"id":"https://openalex.org/C2524010","wikidata":"https://www.wikidata.org/wiki/Q8087","display_name":"Geometry","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/jp306172k","doi":"https://doi.org/10.1021/jp306172k","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp306172k","pdf_url":null,"source":{"id":"https://openalex.org/S95739953","display_name":"The Journal of Physical Chemistry C","issn_l":"1932-7447","issn":["1932-7447","1932-7455"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry C","raw_type":"journal-article"},{"id":"pmh:oai:pure.atira.dk:publications/262e6c33-162b-4ee4-9a3f-648eb10115d0","doi":null,"is_oa":false,"landing_page_url":"https://orbit.dtu.dk/en/publications/262e6c33-162b-4ee4-9a3f-648eb10115d0","pdf_url":null,"source":{"id":"https://openalex.org/S4306400705","display_name":"Technical University of Denmark, DTU Orbit (Technical University of Denmark, DTU)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I96673099","host_organization_name":"Technical University of Denmark","host_organization_lineage":["https://openalex.org/I96673099"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Tripkovic , V , Vanin , M , Karamad , M , Bj\u00f6rketun , M , Jacobsen , K W , Thygesen , K S & Rossmeisl , J 2013 , ' Electrochemical CO 2 and CO reduction on metal-functionalized porphyrin-like graphene ' , The Journal of Physical Chemistry Part C , vol. 117 , no. 18 , pp. 9187-9195 . https://doi.org/10.1021/jp306172k","raw_type":"article"}],"best_oa_location":null,"sustainable_development_goals":[{"score":0.41499999165534973,"display_name":"Affordable and clean energy","id":"https://metadata.un.org/sdg/7"}],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":62,"referenced_works":["https://openalex.org/W1599536855","https://openalex.org/W1966335846","https://openalex.org/W1967131314","https://openalex.org/W1967853451","https://openalex.org/W1973634181","https://openalex.org/W1978526482","https://openalex.org/W1981626052","https://openalex.org/W1982153238","https://openalex.org/W1985235311","https://openalex.org/W1986829915","https://openalex.org/W1991071828","https://openalex.org/W1991149034","https://openalex.org/W2000935529","https://openalex.org/W2001617371","https://openalex.org/W2001652951","https://openalex.org/W2007923221","https://openalex.org/W2010505630","https://openalex.org/W2015698502","https://openalex.org/W2016585341","https://openalex.org/W2019248842","https://openalex.org/W2021250876","https://openalex.org/W2024805067","https://openalex.org/W2026301653","https://openalex.org/W2026533180","https://openalex.org/W2027033107","https://openalex.org/W2032541787","https://openalex.org/W2032749248","https://openalex.org/W2034291571","https://openalex.org/W2035784231","https://openalex.org/W2040913860","https://openalex.org/W2041511900","https://openalex.org/W2041698310","https://openalex.org/W2048451151","https://openalex.org/W2049282733","https://openalex.org/W2052515101","https://openalex.org/W2059835590","https://openalex.org/W2060023027","https://openalex.org/W2066753574","https://openalex.org/W2070161787","https://openalex.org/W2073545820","https://openalex.org/W2074207002","https://openalex.org/W2074527904","https://openalex.org/W2076346814","https://openalex.org/W2076702902","https://openalex.org/W2079097674","https://openalex.org/W2091459675","https://openalex.org/W2091775405","https://openalex.org/W2095004068","https://openalex.org/W2102807619","https://openalex.org/W2109066403","https://openalex.org/W2119989570","https://openalex.org/W2126048094","https://openalex.org/W2126688530","https://openalex.org/W2153118102","https://openalex.org/W2160488576","https://openalex.org/W2167035995","https://openalex.org/W2312964985","https://openalex.org/W2314642759","https://openalex.org/W2319865050","https://openalex.org/W2323309348","https://openalex.org/W2326264304","https://openalex.org/W2332399007"],"related_works":["https://openalex.org/W2743033577","https://openalex.org/W2743843268","https://openalex.org/W4395683595","https://openalex.org/W7212218486","https://openalex.org/W2513531240","https://openalex.org/W3215543482","https://openalex.org/W2922405197","https://openalex.org/W2591681540","https://openalex.org/W4234619132","https://openalex.org/W4214761870"],"abstract_inverted_index":{"Porphyrin-like":[0],"metal-functionalized":[1],"graphene":[2,134],"structures":[3],"have":[4,155],"been":[5],"investigated":[6],"as":[7,137],"possible":[8,91],"catalysts":[9],"for":[10,142],"CO":[11,14,99,102],"2":[12,103],"and":[13,36,42,118,161,164],"reduction":[15],"to":[16,60,67,78,93,97,172],"methane":[17],"or":[18],"methanol.":[19],"The":[20,76,131],"late":[21],"transition":[22],"metals":[23,45],"(Cu,":[24],"Ag,":[25],"Au,":[26],"Ni,":[27],"Pd,":[28],"Pt,":[29],"Co,":[30],"Rh,":[31],"Ir,":[32],"Fe,":[33],"Ru,":[34],"Os)":[35],"some":[37],"p":[38],"(B,":[39],"Al,":[40],"Ga)":[41],"s":[43],"(Mg)":[44],"comprised":[46],"the":[47,50,73,87,110,122,126,138,158,174],"center":[48],"of":[49,72,101,112,115,150,180],"porphyrin":[51],"ring.":[52],"A":[53,90],"clear":[54],"difference":[55],"in":[56,86,165],"catalytic":[57],"properties":[58],"compared":[59],"extended":[61],"metal":[62],"surfaces":[63],"was":[64,135],"observed":[65],"owing":[66],"a":[68,83],"different":[69],"electronic":[70],"nature":[71],"active":[74,140],"site.":[75],"preference":[77],"bind":[79],"hydrogen,":[80],"however,":[81],"becomes":[82],"major":[84],"obstacle":[85],"reaction":[88,116,123],"path.":[89],"solution":[92],"this":[94],"problem":[95],"is":[96],"reduce":[98],"instead":[100],".":[104],"Volcano":[105],"plots":[106,121],"were":[107,129],"constructed":[108],"on":[109],"basis":[111],"scaling":[113],"relations":[114],"intermediates,":[117],"from":[119,145],"these":[120],"steps":[124],"with":[125,177],"highest":[127],"overpotentials":[128],"deduced.":[130],"Rh\u2013porphyrin-like":[132],"functionalized":[133],"identified":[136],"most":[139],"catalyst":[141,176],"producing":[143],"methanol":[144],"CO,":[146],"featuring":[147],"an":[148,178],"overpotential":[149,179],"0.22":[151],"V.":[152,182],"Additionally,":[153],"we":[154],"also":[156],"examined":[157],"hydrogen":[159],"evolution":[160],"oxidation":[162],"reaction,":[163],"their":[166],"case,":[167],"too,":[168],"Rh\u2013porphyrin":[169],"turned":[170],"out":[171],"be":[173],"best":[175],"0.15":[181]},"counts_by_year":[{"year":2026,"cited_by_count":9},{"year":2025,"cited_by_count":17},{"year":2024,"cited_by_count":22},{"year":2023,"cited_by_count":25},{"year":2022,"cited_by_count":19},{"year":2021,"cited_by_count":37},{"year":2020,"cited_by_count":38},{"year":2019,"cited_by_count":30},{"year":2018,"cited_by_count":33},{"year":2017,"cited_by_count":25},{"year":2016,"cited_by_count":18},{"year":2015,"cited_by_count":23},{"year":2014,"cited_by_count":9},{"year":2013,"cited_by_count":2}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}