{"id":"https://openalex.org/W2012114092","doi":"https://doi.org/10.1002/bbpc.19920960802","title":"Thermodynamics of liquid cesium\u2010cesium hydride mixtures at high pressures and temperatures","display_name":"Thermodynamics of liquid cesium\u2010cesium hydride mixtures at high pressures and temperatures","publication_year":1992,"publication_date":"1992-08-01","ids":{"openalex":"https://openalex.org/W2012114092","doi":"https://doi.org/10.1002/bbpc.19920960802","mag":"2012114092"},"language":"en","primary_location":{"id":"doi:10.1002/bbpc.19920960802","doi":"https://doi.org/10.1002/bbpc.19920960802","is_oa":false,"landing_page_url":"https://doi.org/10.1002/bbpc.19920960802","pdf_url":null,"source":{"id":"https://openalex.org/S4306504167","display_name":"Berichte der Bunsengesellschaft f\u00fcr physikalische Chemie","issn_l":"0005-9021","issn":["0005-9021"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Berichte der Bunsengesellschaft f\u00fcr physikalische Chemie","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5045343205","display_name":"A. W. Szafra\u0144ski","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I102335020","display_name":"Karlsruhe Institute of Technology","ror":"https://ror.org/04t3en479","country_code":"DE","type":"education","lineage":["https://openalex.org/I102335020","https://openalex.org/I1305996414"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"A. W. Szafranski","raw_affiliation_strings":["Institut fu\u0308r Physikalische Chemie und Elektrochemie, Universita\u0308t Karlsruhe, Kaiserstra\u00dfe 12, D-7500 Karlsruhe, Germany","Institut f\u00fcr Physikalische Chemie und Elektrochemie, Universit\u00e4t Karlsruhe, Kaiserstra\u00dfe 12, D\u20107500 Karlsruhe, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut fu\u0308r Physikalische Chemie und Elektrochemie, Universita\u0308t Karlsruhe, Kaiserstra\u00dfe 12, D-7500 Karlsruhe, Germany","institution_ids":["https://openalex.org/I102335020"]},{"raw_affiliation_string":"Institut f\u00fcr Physikalische Chemie und Elektrochemie, Universit\u00e4t Karlsruhe, Kaiserstra\u00dfe 12, D\u20107500 Karlsruhe, Germany","institution_ids":["https://openalex.org/I102335020"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5039069523","display_name":"E.E.O. Keller","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I102335020","display_name":"Karlsruhe Institute of Technology","ror":"https://ror.org/04t3en479","country_code":"DE","type":"education","lineage":["https://openalex.org/I102335020","https://openalex.org/I1305996414"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"E. Keller","raw_affiliation_strings":["Institut fu\u0308r Physikalische Chemie und Elektrochemie, Universita\u0308t Karlsruhe, Kaiserstra\u00dfe 12, D-7500 Karlsruhe, Germany","Institut f\u00fcr Physikalische Chemie und Elektrochemie, Universit\u00e4t Karlsruhe, Kaiserstra\u00dfe 12, D\u20107500 Karlsruhe, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut fu\u0308r Physikalische Chemie und Elektrochemie, Universita\u0308t Karlsruhe, Kaiserstra\u00dfe 12, D-7500 Karlsruhe, Germany","institution_ids":["https://openalex.org/I102335020"]},{"raw_affiliation_string":"Institut f\u00fcr Physikalische Chemie und Elektrochemie, Universit\u00e4t Karlsruhe, Kaiserstra\u00dfe 12, D\u20107500 Karlsruhe, Germany","institution_ids":["https://openalex.org/I102335020"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5110073231","display_name":"E. Ulrich Franck","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I102335020","display_name":"Karlsruhe Institute of Technology","ror":"https://ror.org/04t3en479","country_code":"DE","type":"education","lineage":["https://openalex.org/I102335020","https://openalex.org/I1305996414"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"E. U. Franck","raw_affiliation_strings":["Institut fu\u0308r Physikalische Chemie und Elektrochemie, Universita\u0308t Karlsruhe, Kaiserstra\u00dfe 12, D-7500 Karlsruhe, Germany","Institut f\u00fcr Physikalische Chemie und Elektrochemie, Universit\u00e4t Karlsruhe, Kaiserstra\u00dfe 12, D\u20107500 Karlsruhe, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut fu\u0308r Physikalische Chemie und Elektrochemie, Universita\u0308t Karlsruhe, Kaiserstra\u00dfe 12, D-7500 Karlsruhe, Germany","institution_ids":["https://openalex.org/I102335020"]},{"raw_affiliation_string":"Institut f\u00fcr Physikalische Chemie und Elektrochemie, Universit\u00e4t Karlsruhe, Kaiserstra\u00dfe 12, D\u20107500 Karlsruhe, Germany","institution_ids":["https://openalex.org/I102335020"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5110073231"],"corresponding_institution_ids":["https://openalex.org/I102335020"],"apc_list":null,"apc_paid":null,"fwci":1.0864,"has_fulltext":false,"cited_by_count":7,"citation_normalized_percentile":{"value":0.78126671,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":94},"biblio":{"volume":"96","issue":"8","first_page":"955","last_page":"962"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13645","display_name":"Thermodynamic and Structural Properties of Metals and Alloys","score":0.9672999978065491,"subfield":{"id":"https://openalex.org/subfields/2210","display_name":"Mechanical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13645","display_name":"Thermodynamic and Structural Properties of Metals and Alloys","score":0.9672999978065491,"subfield":{"id":"https://openalex.org/subfields/2210","display_name":"Mechanical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10402","display_name":"Phase Equilibria and Thermodynamics","score":0.01489999983459711,"subfield":{"id":"https://openalex.org/subfields/2204","display_name":"Biomedical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10811","display_name":"Hydrogen Storage and Materials","score":0.005799999926239252,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/liquid-phase-equilibria","display_name":"liquid phase equilibria","score":0.7289999723434448},{"id":"https://openalex.org/keywords/hydrogen-pressure","display_name":"hydrogen pressure","score":0.7630000114440918},{"id":"https://openalex.org/keywords/metal-nonmetal-transition","display_name":"metal-nonmetal transition","score":0.9169999957084656},{"id":"https://openalex.org/keywords/critical-solution-point","display_name":"critical solution point","score":0.9549999833106995},{"id":"https://openalex.org/keywords/two-phase-coexistence","display_name":"two-phase coexistence","score":0.6890000104904175},{"id":"https://openalex.org/keywords/melting-point","display_name":"melting point","score":0.6840000152587891},{"id":"https://openalex.org/keywords/critical-exponents","display_name":"critical exponents","score":0.8159999847412109},{"id":"https://openalex.org/keywords/activity-coefficients","display_name":"activity coefficients","score":0.8790000081062317},{"id":"https://openalex.org/keywords/excess-gibbs-energy","display_name":"excess Gibbs energy","score":0.9079999923706055},{"id":"https://openalex.org/keywords/heat-of-mixing","display_name":"excess enthalpy","score":0.9089999794960022},{"id":"https://openalex.org/keywords/excess-entropy","display_name":"excess entropy","score":0.9869999885559082},{"id":"https://openalex.org/keywords/high-pressure","display_name":"high pressure","score":0.6610000133514404},{"id":"https://openalex.org/keywords/high-temperature","display_name":"high temperature","score":0.7059999704360962}],"concepts":[{"id":"https://openalex.org/C2777961443","wikidata":"https://www.wikidata.org/wiki/Q106520","display_name":"Hydride","level":3,"score":0.7544267177581787},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.7415099143981934},{"id":"https://openalex.org/C519659679","wikidata":"https://www.wikidata.org/wiki/Q1108","display_name":"Caesium","level":2,"score":0.6804559230804443},{"id":"https://openalex.org/C36591836","wikidata":"https://www.wikidata.org/wiki/Q125264","display_name":"Mole fraction","level":2,"score":0.6736547946929932},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6416804790496826},{"id":"https://openalex.org/C196298200","wikidata":"https://www.wikidata.org/wiki/Q577705","display_name":"Critical point (mathematics)","level":2,"score":0.5669717192649841},{"id":"https://openalex.org/C3288061","wikidata":"https://www.wikidata.org/wiki/Q161064","display_name":"Enthalpy","level":2,"score":0.5215268731117249},{"id":"https://openalex.org/C85906118","wikidata":"https://www.wikidata.org/wiki/Q186693","display_name":"Phase diagram","level":3,"score":0.5093010663986206},{"id":"https://openalex.org/C512968161","wikidata":"https://www.wikidata.org/wiki/Q556","display_name":"Hydrogen","level":2,"score":0.502898633480072},{"id":"https://openalex.org/C118419359","wikidata":"https://www.wikidata.org/wiki/Q682585","display_name":"Supercritical fluid","level":2,"score":0.4957753121852875},{"id":"https://openalex.org/C13530604","wikidata":"https://www.wikidata.org/wiki/Q15318","display_name":"Melting point","level":2,"score":0.4610890746116638},{"id":"https://openalex.org/C19184958","wikidata":"https://www.wikidata.org/wiki/Q2661322","display_name":"Vapor pressure","level":2,"score":0.4109003245830536},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.30381491780281067},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.20258349180221558},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.18695372343063354},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C134306372","wikidata":"https://www.wikidata.org/wiki/Q7754","display_name":"Mathematical analysis","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/bbpc.19920960802","doi":"https://doi.org/10.1002/bbpc.19920960802","is_oa":false,"landing_page_url":"https://doi.org/10.1002/bbpc.19920960802","pdf_url":null,"source":{"id":"https://openalex.org/S4306504167","display_name":"Berichte der Bunsengesellschaft f\u00fcr physikalische Chemie","issn_l":"0005-9021","issn":["0005-9021"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Berichte der Bunsengesellschaft f\u00fcr physikalische Chemie","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":10,"referenced_works":["https://openalex.org/W1998561593","https://openalex.org/W1999744994","https://openalex.org/W2004506198","https://openalex.org/W2046266692","https://openalex.org/W2053776375","https://openalex.org/W2057169303","https://openalex.org/W2068280144","https://openalex.org/W2325816630","https://openalex.org/W2950788186","https://openalex.org/W3149701544"],"related_works":["https://openalex.org/W7223266775","https://openalex.org/W2325816630","https://openalex.org/W1966391776","https://openalex.org/W2044998511","https://openalex.org/W1983859305","https://openalex.org/W4239775490","https://openalex.org/W2010556062","https://openalex.org/W2951132502","https://openalex.org/W3004333734","https://openalex.org/W1986531625"],"abstract_inverted_index":{"Abstract":[0],"The":[1,28,104,126],"hydrogen":[2,59,88],"pressure":[3,89],"in":[4,36,90,133],"equilibrium":[5,164],"with":[6,50,57],"liquid":[7,82],"phases":[8,83],"of":[9,33,87,92,107,128,135,143,160,175,184],"the":[10,31,129,161,173],"system":[11],"cesium\u2010cesium":[12,93],"hydride":[13,94,110],"has":[14,111],"been":[15,43,97,112],"measured":[16],"between":[17,23],"575":[18],"and":[19,25,40,53,71,101,181,188],"750\u00b0C":[20],"at":[21,67,99,116,124],"pressures":[22],"30":[24,118],"600":[26],"bar.":[27,119],"results":[29],"support":[30],"discussion":[32],"metal\u2010nonmetal":[34,177],"transition":[35],"this":[37,79,171],"system.":[38],"Apparatus":[39],"procedure":[41],"have":[42,96],"described":[44],"earlier.":[45],"An":[46],"autoclave":[47],"was":[48,65],"used":[49],"an":[51,54],"outer":[52],"inner":[55],"compartment":[56],"equilibrated":[58],"pressures.":[60],"A":[61,120,154],"critical":[62,149],"solution":[63],"point":[64,122],"found":[66],"665\u00b0C,":[68],"157":[69],"bar":[70],"a":[72,141,147,158],"mole":[73,136],"fraction":[74,137],"x(CsH)":[75,168],"=":[76,152,169],"0.68.":[77],"Below":[78],"temperature":[80,106,145],"two":[81,130,162],"coexist.":[84],"Nine":[85],"isotherms":[86],"dependence":[91],"composition":[95],"determined":[98],"sub\u2010":[100],"supercritical":[102],"temperatures.":[103],"melting":[105],"pure":[108],"cesium":[109],"redetermined":[113],"to":[114],"522\u00b0C":[115],"nearly":[117],"monotectic":[121],"exists":[123],"519\u00b0C.":[125],"width":[127],"phase":[131,163],"region":[132,174],"terms":[134],"difference,":[138],"\u0394x,":[139],"as":[140],"function":[142],"subcritical":[144],"gives":[146],"\u201cclassical\u201d":[148],"exponent":[150],"\u03b2":[151],"0.5.":[153],"careful":[155],"calculation":[156],"suggests":[157],"\u201cbulge\u201d":[159],"boundary":[165],"curve":[166],"near":[167],"0.85;":[170],"is":[172],"prominent":[176],"transition.":[178],"Activity":[179],"coefficients":[180],"excess":[182],"functions":[183],"Gibbs":[185],"energy,":[186],"enthalpy":[187],"entropy":[189],"are":[190],"presented.":[191]},"counts_by_year":[{"year":2024,"cited_by_count":1}],"updated_date":"2026-10-01T08:54:57.152042","created_date":"2016-06-24T00:00:00"}