{"id":"https://openalex.org/W2012055027","doi":"https://doi.org/10.1021/ic040109y","title":"Reaction Systems Related to Dissimilatory Nitrate Reductase: Nitrate Reduction Mediated by Bis(dithiolene)tungsten Complexes","display_name":"Reaction Systems Related to Dissimilatory Nitrate Reductase: Nitrate Reduction Mediated by Bis(dithiolene)tungsten Complexes","publication_year":2005,"publication_date":"2005-01-28","ids":{"openalex":"https://openalex.org/W2012055027","doi":"https://doi.org/10.1021/ic040109y","mag":"2012055027","pmid":"https://pubmed.ncbi.nlm.nih.gov/15859288"},"language":"en","primary_location":{"id":"doi:10.1021/ic040109y","doi":"https://doi.org/10.1021/ic040109y","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic040109y","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5110635617","display_name":"Jianfeng Jiang","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I136199984","display_name":"Harvard University","ror":"https://ror.org/03vek6s52","country_code":"US","type":"education","lineage":["https://openalex.org/I136199984"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jianfeng Jiang","raw_affiliation_strings":["Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138","Department of Chemistry and Chemical Biology Harvard University Cambridge Massachusetts 02138 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138","institution_ids":["https://openalex.org/I136199984"]},{"raw_affiliation_string":"Department of Chemistry and Chemical Biology Harvard University Cambridge Massachusetts 02138 USA","institution_ids":["https://openalex.org/I136199984"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5052881048","display_name":"R. H. Holm","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I136199984","display_name":"Harvard University","ror":"https://ror.org/03vek6s52","country_code":"US","type":"education","lineage":["https://openalex.org/I136199984"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"R. H. Holm","raw_affiliation_strings":["Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138","institution_ids":["https://openalex.org/I136199984"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I136199984"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.9788,"has_fulltext":false,"cited_by_count":57,"citation_normalized_percentile":{"value":0.8410104,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"44","issue":"4","first_page":"1068","last_page":"1072"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11626","display_name":"Metalloenzymes and iron-sulfur proteins","score":0.6689000129699707,"subfield":{"id":"https://openalex.org/subfields/1303","display_name":"Biochemistry"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},"topics":[{"id":"https://openalex.org/T11626","display_name":"Metalloenzymes and iron-sulfur proteins","score":0.6689000129699707,"subfield":{"id":"https://openalex.org/subfields/1303","display_name":"Biochemistry"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.17880000174045563,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.06430000066757202,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/dissimilatory-nitrate-reductase","display_name":"dissimilatory nitrate reductase","score":0.9710000157356262},{"id":"https://openalex.org/keywords/nitrate-reduction","display_name":"nitrate reduction","score":0.7699999809265137},{"id":"https://openalex.org/keywords/oxygen-atom-transfer","display_name":"oxygen atom transfer","score":0.7720000147819519},{"id":"https://openalex.org/keywords/molybdenum-complexes","display_name":"molybdenum complexes","score":0.7329999804496765},{"id":"https://openalex.org/keywords/reaction-kinetics","display_name":"reaction kinetics","score":0.4490000009536743},{"id":"https://openalex.org/keywords/steric-effects","display_name":"steric effects","score":0.6489999890327454},{"id":"https://openalex.org/keywords/nitrite","display_name":"nitrite","score":0.35899999737739563},{"id":"https://openalex.org/keywords/sulfur-oxides","display_name":"sulfur oxides","score":0.46299999952316284},{"id":"https://openalex.org/keywords/enzyme-mimics","display_name":"enzyme mimics","score":0.4869999885559082},{"id":"https://openalex.org/keywords/square-pyramidal-complexes","display_name":"square pyramidal complexes","score":0.6140000224113464}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9586232304573059},{"id":"https://openalex.org/C201194858","wikidata":"https://www.wikidata.org/wiki/Q898238","display_name":"Steric effects","level":2,"score":0.8158840537071228},{"id":"https://openalex.org/C549387045","wikidata":"https://www.wikidata.org/wiki/Q1053","display_name":"Molybdenum","level":2,"score":0.5821382403373718},{"id":"https://openalex.org/C2777463227","wikidata":"https://www.wikidata.org/wiki/Q408047","display_name":"Acetonitrile","level":2,"score":0.5709697008132935},{"id":"https://openalex.org/C2778710519","wikidata":"https://www.wikidata.org/wiki/Q420896","display_name":"Nitrate reductase","level":3,"score":0.5567669868469238},{"id":"https://openalex.org/C2776384668","wikidata":"https://www.wikidata.org/wiki/Q182168","display_name":"Nitrate","level":2,"score":0.5376120805740356},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.47868138551712036},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.4364510476589203},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.4260086119174957},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.4100510776042938},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.3328084945678711},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.12698590755462646},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0}],"mesh":[{"descriptor_ui":"D001665","descriptor_name":"Binding Sites","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D007700","descriptor_name":"Kinetics","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008024","descriptor_name":"Ligands","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008956","descriptor_name":"Models, Chemical","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008982","descriptor_name":"Molybdenum","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D009565","descriptor_name":"Nitrate Reductases","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D009566","descriptor_name":"Nitrates","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D009942","descriptor_name":"Organometallic Compounds","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D010084","descriptor_name":"Oxidation-Reduction","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D010100","descriptor_name":"Oxygen","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D013056","descriptor_name":"Spectrophotometry, Ultraviolet","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D019800","descriptor_name":"Phenol","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D050901","descriptor_name":"Nitrate Reductase","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false}],"locations_count":2,"locations":[{"id":"doi:10.1021/ic040109y","doi":"https://doi.org/10.1021/ic040109y","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic040109y","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmid:15859288","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/15859288","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Comparative Study"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":8,"referenced_works":["https://openalex.org/W2002578376","https://openalex.org/W2006243394","https://openalex.org/W2015646183","https://openalex.org/W2024127963","https://openalex.org/W2046738998","https://openalex.org/W2073276776","https://openalex.org/W2089292984","https://openalex.org/W4245399940"],"related_works":["https://openalex.org/W1989813523","https://openalex.org/W1985745681","https://openalex.org/W2607656360","https://openalex.org/W2152258331","https://openalex.org/W2086910210","https://openalex.org/W2023707273","https://openalex.org/W2005288391","https://openalex.org/W2076236925","https://openalex.org/W2004240849","https://openalex.org/W2554413794"],"abstract_inverted_index":{"Kinetics":[0],"of":[1,58,62,92,96,124,155,205,223,229,244],"the":[2,59,68,97,156,182,197,203,224],"oxygen":[3],"atom":[4,74,211],"transfer":[5,212],"reactions":[6,109],"[M(IV)(QC6H2-2,4,6-Pr(i)3)(S2C2Me2)2]1-":[7],"+":[8,12],"XO":[9,18],"-->":[10],"[M(VI)O(QC6H2-2,4,6-Pr(i)3)(S2C2Me2)2]1-":[11],"X":[13],"in":[14,67,180],"acetonitrile":[15],"with":[16,31,41,88,110,115,130,185,196,215],"substrates":[17,112,236],"=":[19,33,43,145,151,162],"NO3-":[20],"and":[21,36,80,127,164,169,219,234,237],"(CH2)4SO":[22,148,170],"have":[23],"been":[24],"determined.":[25],"The":[26,52,191],"reactants":[27],"are":[28,113,227],"bis(dithiolene)":[29],"complexes":[30,90],"M":[32,126],"Mo,":[34],"W":[35],"sterically":[37],"encumbered":[38],"axial":[39,217],"ligands":[40,79],"Q":[42],"O,":[44],"S":[45],"to":[46,139,175],"stabilize":[47],"mononuclear":[48],"square":[49],"pyramidal":[50],"structures.":[51],"complex":[53],"[MoIV(SC6H2-2,4,6-Pr(i)3)(S2C2Me2)2]1-":[54],"is":[55,193],"an":[56,153],"analogue":[57,241],"active":[60],"site":[61],"dissimilatory":[63],"nitrate":[64,168,207,235],"reductase":[65],"which":[66],"reduced":[69],"state":[70,184],"contains":[71],"a":[72,81,105],"molybdenum":[73,98],"bound":[75],"by":[76,104,209],"two":[77],"pyranopterindithiolene":[78],"cysteinate":[82],"residue.":[83],"Nitrate":[84],"reduction":[85,149,208],"was":[86,102],"studied":[87],"tungsten":[89],"because":[91],"unfavorable":[93],"stability":[94],"properties":[95],"complexes.":[99],"Product":[100],"nitrite":[101],"detected":[103],"colorimetric":[106],"method.":[107],"All":[108],"both":[111,216],"second-order":[114],"associative":[116],"transition":[117,183],"states":[118],"(deltaS":[119],"approximately":[120,165],"-20":[121],"eu).":[122],"Variation":[123],"atoms":[125],"Q,":[128],"together":[129],"data":[131],"from":[132],"prior":[133],"work,":[134],"allows":[135],"certain":[136],"kinetics":[137],"comparisons":[138],"be":[140],"made.":[141],"Among":[142],"them,":[143],"k2W/k2Mo":[144],"25":[146],"for":[147,167],"(Q":[150],"S),":[152],"expression":[154],"kinetic":[157],"metal":[158],"effect.":[159],"Further,":[160],"k2S/k2O":[161],"28":[163],"10(4)":[166],"reduction,":[171],"respectively,":[172],"effects":[173],"attributed":[174],"relatively":[176],"more":[177,194],"steric":[178],"congestion":[179],"achieving":[181],"hindered":[186],"phenolate":[187,220],"vs":[188],"thiolate":[189,218],"ligands.":[190,221],"effect":[192],"pronounced":[195],"larger":[198],"substrate.":[199],"These":[200],"results":[201],"demonstrate":[202],"feasibility":[204],"tungsten-mediated":[206],"direct":[210],"using":[213],"molecules":[214],"Complexes":[222],"type":[225],"[M(IV)(OR)(S2C2Me2)2]":[226],"capable":[228],"reducing":[230],"biological":[231],"N-oxide,":[232],"S-oxide,":[233],"thus":[238],"constitute":[239],"functional":[240],"reaction":[242],"systems":[243],"enzymic":[245],"transformations.":[246]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":5},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":3},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":3},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":2},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":3},{"year":2013,"cited_by_count":1},{"year":2012,"cited_by_count":2}],"updated_date":"2026-11-02T09:45:03.842371","created_date":"2016-06-24T00:00:00"}
