{"id":"https://openalex.org/W2011820587","doi":"https://doi.org/10.1021/ic801685v","title":"Lanthanide(III) and Actinide(III) Complexes [M(BH4)2(THF)5][BPh4] and [M(BH4)2(18-crown-6)][BPh4] (M = Nd, Ce, U): Synthesis, Crystal Structure, and Density Functional Theory Investigation of the Covalent Contribution to Metal-Borohydride Bonding","display_name":"Lanthanide(III) and Actinide(III) Complexes [M(BH4)2(THF)5][BPh4] and [M(BH4)2(18-crown-6)][BPh4] (M = Nd, Ce, U): Synthesis, Crystal Structure, and Density Functional Theory Investigation of the Covalent Contribution to Metal-Borohydride Bonding","publication_year":2008,"publication_date":"2008-11-19","ids":{"openalex":"https://openalex.org/W2011820587","doi":"https://doi.org/10.1021/ic801685v","mag":"2011820587","pmid":"https://pubmed.ncbi.nlm.nih.gov/19053334"},"language":"en","primary_location":{"id":"doi:10.1021/ic801685v","doi":"https://doi.org/10.1021/ic801685v","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic801685v","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5109159730","display_name":"Th\u00e9r\u00e8se Arliguie","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I125485651","display_name":"University Fr\u00e8res Mentouri Constantine 1","ror":"https://ror.org/017wv6808","country_code":"DZ","type":"education","lineage":["https://openalex.org/I125485651"]},{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I2738703131","display_name":"Commissariat \u00e0 l'\u00c9nergie Atomique et aux \u00c9nergies Alternatives","ror":"https://ror.org/00jjx8s55","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131"]},{"id":"https://openalex.org/I4210090783","display_name":"Institut des Sciences Chimiques de Rennes","ror":"https://ror.org/00adwkx90","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I28221208","https://openalex.org/I4210090783","https://openalex.org/I4210115835","https://openalex.org/I4210128300","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I4210128565","display_name":"CEA Paris-Saclay","ror":"https://ror.org/03n15ch10","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131","https://openalex.org/I277688954","https://openalex.org/I4210128565"]},{"id":"https://openalex.org/I4405258264","display_name":"Universit\u00e9 Rennes 1","ror":"https://ror.org/00crteh33","country_code":"FR","type":"education","lineage":["https://openalex.org/I4405258264","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I56067802","display_name":"Universit\u00e9 de Rennes","ror":"https://ror.org/015m7wh34","country_code":"FR","type":"education","lineage":["https://openalex.org/I56067802"]}],"countries":["DZ","FR"],"is_corresponding":false,"raw_author_name":"Th\u00e9r\u00e8se Arliguie","raw_affiliation_strings":["CEA, IRAMIS, Service de Chimie Mol\u00e9culaire, CNRS URA 331, CEA/Saclay, 91191 Gif-sur-Yvette, France, Laboratoire de Chimie Mol\u00e9culaire (LACMOM), D\u00e9partement de Chimie, Facult\u00e9 des Sciences, Universit\u00e9 Mentouri de Constantine, BP 325, Route de l\u2019A\u00e9roport Ain El Bey, 25017 Constantine, Algeria, and UMR CNRS 6226 Sciences Chimiques de Rennes, Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CEA, IRAMIS, Service de Chimie Mol\u00e9culaire, CNRS URA 331, CEA/Saclay, 91191 Gif-sur-Yvette, France, Laboratoire de Chimie Mol\u00e9culaire (LACMOM), D\u00e9partement de Chimie, Facult\u00e9 des Sciences, Universit\u00e9 Mentouri de Constantine, BP 325, Route de l\u2019A\u00e9roport Ain El Bey, 25017 Constantine, Algeria, and UMR CNRS 6226 Sciences Chimiques de Rennes, Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes, France","institution_ids":["https://openalex.org/I125485651","https://openalex.org/I1294671590","https://openalex.org/I2738703131","https://openalex.org/I4210090783","https://openalex.org/I4210128565","https://openalex.org/I4405258264","https://openalex.org/I56067802"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5017853159","display_name":"Lotfi Belkh\u0131r\u0131","orcid":"https://orcid.org/0000-0002-6093-6965","observed_orcids":["https://orcid.org/0000-0002-6093-6965"]},"institutions":[{"id":"https://openalex.org/I125485651","display_name":"University Fr\u00e8res Mentouri Constantine 1","ror":"https://ror.org/017wv6808","country_code":"DZ","type":"education","lineage":["https://openalex.org/I125485651"]},{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I2738703131","display_name":"Commissariat \u00e0 l'\u00c9nergie Atomique et aux \u00c9nergies Alternatives","ror":"https://ror.org/00jjx8s55","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131"]},{"id":"https://openalex.org/I4210090783","display_name":"Institut des Sciences Chimiques de Rennes","ror":"https://ror.org/00adwkx90","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I28221208","https://openalex.org/I4210090783","https://openalex.org/I4210115835","https://openalex.org/I4210128300","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I4210128565","display_name":"CEA Paris-Saclay","ror":"https://ror.org/03n15ch10","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131","https://openalex.org/I277688954","https://openalex.org/I4210128565"]},{"id":"https://openalex.org/I4405258264","display_name":"Universit\u00e9 Rennes 1","ror":"https://ror.org/00crteh33","country_code":"FR","type":"education","lineage":["https://openalex.org/I4405258264","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I56067802","display_name":"Universit\u00e9 de Rennes","ror":"https://ror.org/015m7wh34","country_code":"FR","type":"education","lineage":["https://openalex.org/I56067802"]}],"countries":["DZ","FR"],"is_corresponding":false,"raw_author_name":"Lotfi Belkhiri","raw_affiliation_strings":["CEA, IRAMIS, Service de Chimie Mol\u00e9culaire, CNRS URA 331, CEA/Saclay, 91191 Gif-sur-Yvette, France, Laboratoire de Chimie Mol\u00e9culaire (LACMOM), D\u00e9partement de Chimie, Facult\u00e9 des Sciences, Universit\u00e9 Mentouri de Constantine, BP 325, Route de l\u2019A\u00e9roport Ain El Bey, 25017 Constantine, Algeria, and UMR CNRS 6226 Sciences Chimiques de Rennes, Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CEA, IRAMIS, Service de Chimie Mol\u00e9culaire, CNRS URA 331, CEA/Saclay, 91191 Gif-sur-Yvette, France, Laboratoire de Chimie Mol\u00e9culaire (LACMOM), D\u00e9partement de Chimie, Facult\u00e9 des Sciences, Universit\u00e9 Mentouri de Constantine, BP 325, Route de l\u2019A\u00e9roport Ain El Bey, 25017 Constantine, Algeria, and UMR CNRS 6226 Sciences Chimiques de Rennes, Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes, France","institution_ids":["https://openalex.org/I125485651","https://openalex.org/I1294671590","https://openalex.org/I2738703131","https://openalex.org/I4210090783","https://openalex.org/I4210128565","https://openalex.org/I4405258264","https://openalex.org/I56067802"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5109078401","display_name":"Salah\u2010Eddine Bouaoud","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I125485651","display_name":"University Fr\u00e8res Mentouri Constantine 1","ror":"https://ror.org/017wv6808","country_code":"DZ","type":"education","lineage":["https://openalex.org/I125485651"]},{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I2738703131","display_name":"Commissariat \u00e0 l'\u00c9nergie Atomique et aux \u00c9nergies Alternatives","ror":"https://ror.org/00jjx8s55","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131"]},{"id":"https://openalex.org/I4210090783","display_name":"Institut des Sciences Chimiques de Rennes","ror":"https://ror.org/00adwkx90","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I28221208","https://openalex.org/I4210090783","https://openalex.org/I4210115835","https://openalex.org/I4210128300","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I4210128565","display_name":"CEA Paris-Saclay","ror":"https://ror.org/03n15ch10","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131","https://openalex.org/I277688954","https://openalex.org/I4210128565"]},{"id":"https://openalex.org/I4405258264","display_name":"Universit\u00e9 Rennes 1","ror":"https://ror.org/00crteh33","country_code":"FR","type":"education","lineage":["https://openalex.org/I4405258264","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I56067802","display_name":"Universit\u00e9 de Rennes","ror":"https://ror.org/015m7wh34","country_code":"FR","type":"education","lineage":["https://openalex.org/I56067802"]}],"countries":["DZ","FR"],"is_corresponding":false,"raw_author_name":"Salah-Eddine Bouaoud","raw_affiliation_strings":["CEA, IRAMIS, Service de Chimie Mol\u00e9culaire, CNRS URA 331, CEA/Saclay, 91191 Gif-sur-Yvette, France, Laboratoire de Chimie Mol\u00e9culaire (LACMOM), D\u00e9partement de Chimie, Facult\u00e9 des Sciences, Universit\u00e9 Mentouri de Constantine, BP 325, Route de l\u2019A\u00e9roport Ain El Bey, 25017 Constantine, Algeria, and UMR CNRS 6226 Sciences Chimiques de Rennes, Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CEA, IRAMIS, Service de Chimie Mol\u00e9culaire, CNRS URA 331, CEA/Saclay, 91191 Gif-sur-Yvette, France, Laboratoire de Chimie Mol\u00e9culaire (LACMOM), D\u00e9partement de Chimie, Facult\u00e9 des Sciences, Universit\u00e9 Mentouri de Constantine, BP 325, Route de l\u2019A\u00e9roport Ain El Bey, 25017 Constantine, Algeria, and UMR CNRS 6226 Sciences Chimiques de Rennes, Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes, France","institution_ids":["https://openalex.org/I125485651","https://openalex.org/I1294671590","https://openalex.org/I2738703131","https://openalex.org/I4210090783","https://openalex.org/I4210128565","https://openalex.org/I4405258264","https://openalex.org/I56067802"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5063941923","display_name":"P. Thu\u00e9ry","orcid":"https://orcid.org/0000-0003-1683-570X","observed_orcids":["https://orcid.org/0000-0003-1683-570X"]},"institutions":[{"id":"https://openalex.org/I125485651","display_name":"University Fr\u00e8res Mentouri Constantine 1","ror":"https://ror.org/017wv6808","country_code":"DZ","type":"education","lineage":["https://openalex.org/I125485651"]},{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I2738703131","display_name":"Commissariat \u00e0 l'\u00c9nergie Atomique et aux \u00c9nergies Alternatives","ror":"https://ror.org/00jjx8s55","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131"]},{"id":"https://openalex.org/I4210090783","display_name":"Institut des Sciences Chimiques de Rennes","ror":"https://ror.org/00adwkx90","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I28221208","https://openalex.org/I4210090783","https://openalex.org/I4210115835","https://openalex.org/I4210128300","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I4210128565","display_name":"CEA Paris-Saclay","ror":"https://ror.org/03n15ch10","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131","https://openalex.org/I277688954","https://openalex.org/I4210128565"]},{"id":"https://openalex.org/I4405258264","display_name":"Universit\u00e9 Rennes 1","ror":"https://ror.org/00crteh33","country_code":"FR","type":"education","lineage":["https://openalex.org/I4405258264","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I56067802","display_name":"Universit\u00e9 de Rennes","ror":"https://ror.org/015m7wh34","country_code":"FR","type":"education","lineage":["https://openalex.org/I56067802"]}],"countries":["DZ","FR"],"is_corresponding":false,"raw_author_name":"Pierre Thu\u00e9ry","raw_affiliation_strings":["CEA, IRAMIS, Service de Chimie Mol\u00e9culaire, CNRS URA 331, CEA/Saclay, 91191 Gif-sur-Yvette, France, Laboratoire de Chimie Mol\u00e9culaire (LACMOM), D\u00e9partement de Chimie, Facult\u00e9 des Sciences, Universit\u00e9 Mentouri de Constantine, BP 325, Route de l\u2019A\u00e9roport Ain El Bey, 25017 Constantine, Algeria, and UMR CNRS 6226 Sciences Chimiques de Rennes, Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CEA, IRAMIS, Service de Chimie Mol\u00e9culaire, CNRS URA 331, CEA/Saclay, 91191 Gif-sur-Yvette, France, Laboratoire de Chimie Mol\u00e9culaire (LACMOM), D\u00e9partement de Chimie, Facult\u00e9 des Sciences, Universit\u00e9 Mentouri de Constantine, BP 325, Route de l\u2019A\u00e9roport Ain El Bey, 25017 Constantine, Algeria, and UMR CNRS 6226 Sciences Chimiques de Rennes, Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes, France","institution_ids":["https://openalex.org/I125485651","https://openalex.org/I1294671590","https://openalex.org/I2738703131","https://openalex.org/I4210090783","https://openalex.org/I4210128565","https://openalex.org/I4405258264","https://openalex.org/I56067802"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5020839524","display_name":"Claude Villiers","orcid":"https://orcid.org/0000-0002-5891-9373","observed_orcids":["https://orcid.org/0000-0002-5891-9373"]},"institutions":[{"id":"https://openalex.org/I125485651","display_name":"University Fr\u00e8res Mentouri Constantine 1","ror":"https://ror.org/017wv6808","country_code":"DZ","type":"education","lineage":["https://openalex.org/I125485651"]},{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I2738703131","display_name":"Commissariat \u00e0 l'\u00c9nergie Atomique et aux \u00c9nergies Alternatives","ror":"https://ror.org/00jjx8s55","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131"]},{"id":"https://openalex.org/I4210090783","display_name":"Institut des Sciences Chimiques de Rennes","ror":"https://ror.org/00adwkx90","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I28221208","https://openalex.org/I4210090783","https://openalex.org/I4210115835","https://openalex.org/I4210128300","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I4210128565","display_name":"CEA Paris-Saclay","ror":"https://ror.org/03n15ch10","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131","https://openalex.org/I277688954","https://openalex.org/I4210128565"]},{"id":"https://openalex.org/I4405258264","display_name":"Universit\u00e9 Rennes 1","ror":"https://ror.org/00crteh33","country_code":"FR","type":"education","lineage":["https://openalex.org/I4405258264","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I56067802","display_name":"Universit\u00e9 de Rennes","ror":"https://ror.org/015m7wh34","country_code":"FR","type":"education","lineage":["https://openalex.org/I56067802"]}],"countries":["DZ","FR"],"is_corresponding":false,"raw_author_name":"Claude Villiers","raw_affiliation_strings":["CEA, IRAMIS, Service de Chimie Mol\u00e9culaire, CNRS URA 331, CEA/Saclay, 91191 Gif-sur-Yvette, France, Laboratoire de Chimie Mol\u00e9culaire (LACMOM), D\u00e9partement de Chimie, Facult\u00e9 des Sciences, Universit\u00e9 Mentouri de Constantine, BP 325, Route de l\u2019A\u00e9roport Ain El Bey, 25017 Constantine, Algeria, and UMR CNRS 6226 Sciences Chimiques de Rennes, Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CEA, IRAMIS, Service de Chimie Mol\u00e9culaire, CNRS URA 331, CEA/Saclay, 91191 Gif-sur-Yvette, France, Laboratoire de Chimie Mol\u00e9culaire (LACMOM), D\u00e9partement de Chimie, Facult\u00e9 des Sciences, Universit\u00e9 Mentouri de Constantine, BP 325, Route de l\u2019A\u00e9roport Ain El Bey, 25017 Constantine, Algeria, and UMR CNRS 6226 Sciences Chimiques de Rennes, Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes, France","institution_ids":["https://openalex.org/I125485651","https://openalex.org/I1294671590","https://openalex.org/I2738703131","https://openalex.org/I4210090783","https://openalex.org/I4210128565","https://openalex.org/I4405258264","https://openalex.org/I56067802"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5037130710","display_name":"Abdou Boucekkine","orcid":"https://orcid.org/0000-0002-3714-7191","observed_orcids":["https://orcid.org/0000-0002-3714-7191"]},"institutions":[{"id":"https://openalex.org/I125485651","display_name":"University Fr\u00e8res Mentouri Constantine 1","ror":"https://ror.org/017wv6808","country_code":"DZ","type":"education","lineage":["https://openalex.org/I125485651"]},{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I2738703131","display_name":"Commissariat \u00e0 l'\u00c9nergie Atomique et aux \u00c9nergies Alternatives","ror":"https://ror.org/00jjx8s55","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131"]},{"id":"https://openalex.org/I4210090783","display_name":"Institut des Sciences Chimiques de Rennes","ror":"https://ror.org/00adwkx90","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I28221208","https://openalex.org/I4210090783","https://openalex.org/I4210115835","https://openalex.org/I4210128300","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I4210128565","display_name":"CEA Paris-Saclay","ror":"https://ror.org/03n15ch10","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131","https://openalex.org/I277688954","https://openalex.org/I4210128565"]},{"id":"https://openalex.org/I4405258264","display_name":"Universit\u00e9 Rennes 1","ror":"https://ror.org/00crteh33","country_code":"FR","type":"education","lineage":["https://openalex.org/I4405258264","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I56067802","display_name":"Universit\u00e9 de Rennes","ror":"https://ror.org/015m7wh34","country_code":"FR","type":"education","lineage":["https://openalex.org/I56067802"]}],"countries":["DZ","FR"],"is_corresponding":true,"raw_author_name":"Abdou Boucekkine","raw_affiliation_strings":["CEA, IRAMIS, Service de Chimie Mol\u00e9culaire, CNRS URA 331, CEA/Saclay, 91191 Gif-sur-Yvette, France, Laboratoire de Chimie Mol\u00e9culaire (LACMOM), D\u00e9partement de Chimie, Facult\u00e9 des Sciences, Universit\u00e9 Mentouri de Constantine, BP 325, Route de l\u2019A\u00e9roport Ain El Bey, 25017 Constantine, Algeria, and UMR CNRS 6226 Sciences Chimiques de Rennes, Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CEA, IRAMIS, Service de Chimie Mol\u00e9culaire, CNRS URA 331, CEA/Saclay, 91191 Gif-sur-Yvette, France, Laboratoire de Chimie Mol\u00e9culaire (LACMOM), D\u00e9partement de Chimie, Facult\u00e9 des Sciences, Universit\u00e9 Mentouri de Constantine, BP 325, Route de l\u2019A\u00e9roport Ain El Bey, 25017 Constantine, Algeria, and UMR CNRS 6226 Sciences Chimiques de Rennes, Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes, France","institution_ids":["https://openalex.org/I125485651","https://openalex.org/I1294671590","https://openalex.org/I2738703131","https://openalex.org/I4210090783","https://openalex.org/I4210128565","https://openalex.org/I4405258264","https://openalex.org/I56067802"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5022761172","display_name":"M. Ephritikhine","orcid":"https://orcid.org/0000-0001-6775-5721","observed_orcids":["https://orcid.org/0000-0001-6775-5721"]},"institutions":[{"id":"https://openalex.org/I125485651","display_name":"University Fr\u00e8res Mentouri Constantine 1","ror":"https://ror.org/017wv6808","country_code":"DZ","type":"education","lineage":["https://openalex.org/I125485651"]},{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I2738703131","display_name":"Commissariat \u00e0 l'\u00c9nergie Atomique et aux \u00c9nergies Alternatives","ror":"https://ror.org/00jjx8s55","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131"]},{"id":"https://openalex.org/I4210090783","display_name":"Institut des Sciences Chimiques de Rennes","ror":"https://ror.org/00adwkx90","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I28221208","https://openalex.org/I4210090783","https://openalex.org/I4210115835","https://openalex.org/I4210128300","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I4210128565","display_name":"CEA Paris-Saclay","ror":"https://ror.org/03n15ch10","country_code":"FR","type":"government","lineage":["https://openalex.org/I2738703131","https://openalex.org/I277688954","https://openalex.org/I4210128565"]},{"id":"https://openalex.org/I4405258264","display_name":"Universit\u00e9 Rennes 1","ror":"https://ror.org/00crteh33","country_code":"FR","type":"education","lineage":["https://openalex.org/I4405258264","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I56067802","display_name":"Universit\u00e9 de Rennes","ror":"https://ror.org/015m7wh34","country_code":"FR","type":"education","lineage":["https://openalex.org/I56067802"]}],"countries":["DZ","FR"],"is_corresponding":true,"raw_author_name":"Michel Ephritikhine","raw_affiliation_strings":["CEA, IRAMIS, Service de Chimie Mol\u00e9culaire, CNRS URA 331, CEA/Saclay, 91191 Gif-sur-Yvette, France, Laboratoire de Chimie Mol\u00e9culaire (LACMOM), D\u00e9partement de Chimie, Facult\u00e9 des Sciences, Universit\u00e9 Mentouri de Constantine, BP 325, Route de l\u2019A\u00e9roport Ain El Bey, 25017 Constantine, Algeria, and UMR CNRS 6226 Sciences Chimiques de Rennes, Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"CEA, IRAMIS, Service de Chimie Mol\u00e9culaire, CNRS URA 331, CEA/Saclay, 91191 Gif-sur-Yvette, France, Laboratoire de Chimie Mol\u00e9culaire (LACMOM), D\u00e9partement de Chimie, Facult\u00e9 des Sciences, Universit\u00e9 Mentouri de Constantine, BP 325, Route de l\u2019A\u00e9roport Ain El Bey, 25017 Constantine, Algeria, and UMR CNRS 6226 Sciences Chimiques de Rennes, Universit\u00e9 de Rennes 1, Campus de Beaulieu, 35042 Rennes, France","institution_ids":["https://openalex.org/I125485651","https://openalex.org/I1294671590","https://openalex.org/I2738703131","https://openalex.org/I4210090783","https://openalex.org/I4210128565","https://openalex.org/I4405258264","https://openalex.org/I56067802"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":7,"corresponding_author_ids":["https://openalex.org/A5022761172","https://openalex.org/A5037130710"],"corresponding_institution_ids":["https://openalex.org/I125485651","https://openalex.org/I1294671590","https://openalex.org/I2738703131","https://openalex.org/I4210090783","https://openalex.org/I4210128565","https://openalex.org/I4405258264","https://openalex.org/I56067802"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.1211,"has_fulltext":false,"cited_by_count":79,"citation_normalized_percentile":{"value":0.86557624,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":99},"biblio":{"volume":"48","issue":"1","first_page":"221","last_page":"230"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10973","display_name":"Radioactive element chemistry and processing","score":0.6718999743461609,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10973","display_name":"Radioactive element chemistry and processing","score":0.6718999743461609,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.08009999990463257,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.07919999957084656,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/uranium-iii-complexes","display_name":"uranium(III) complexes","score":0.6990000009536743},{"id":"https://openalex.org/keywords/neodymium-iii-complexes","display_name":"neodymium(III) complexes","score":0.9409999847412109},{"id":"https://openalex.org/keywords/cerium-iii-complexes","display_name":"cerium(III) complexes","score":1.0},{"id":"https://openalex.org/keywords/tetrafluoroborate-salts","display_name":"tetrafluoroborate salts","score":0.6309999823570251},{"id":"https://openalex.org/keywords/18-crown-6","display_name":"18-crown-6","score":0.9390000104904175},{"id":"https://openalex.org/keywords/lewis-acid-base-interactions","display_name":"Lewis acid-base interactions","score":0.48500001430511475},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.5059999823570251},{"id":"https://openalex.org/keywords/mulliken-population-analysis","display_name":"Mulliken population analysis","score":0.8989999890327454},{"id":"https://openalex.org/keywords/nbo-analysis","display_name":"natural bond orbital analysis","score":0.9490000009536743}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9367238283157349},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.7103316783905029},{"id":"https://openalex.org/C2780477052","wikidata":"https://www.wikidata.org/wiki/Q412118","display_name":"Tetrahydrothiophene","level":2,"score":0.6037153005599976},{"id":"https://openalex.org/C201770740","wikidata":"https://www.wikidata.org/wiki/Q19569","display_name":"Lanthanide","level":3,"score":0.601791501045227},{"id":"https://openalex.org/C155860418","wikidata":"https://www.wikidata.org/wiki/Q863695","display_name":"Bond length","level":3,"score":0.5454869270324707},{"id":"https://openalex.org/C135788738","wikidata":"https://www.wikidata.org/wiki/Q19577","display_name":"Actinide","level":2,"score":0.4876450300216675},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.47743090987205505},{"id":"https://openalex.org/C7167053","wikidata":"https://www.wikidata.org/wiki/Q2076140","display_name":"Bipyramid","level":3,"score":0.4746939539909363},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.46594512462615967},{"id":"https://openalex.org/C152365726","wikidata":"https://www.wikidata.org/wiki/Q1048589","display_name":"Density functional theory","level":2,"score":0.4479682445526123},{"id":"https://openalex.org/C7214806","wikidata":"https://www.wikidata.org/wiki/Q2957735","display_name":"Mulliken population analysis","level":3,"score":0.41501691937446594},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3502661883831024},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.23587912321090698},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.23469945788383484},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1021/ic801685v","doi":"https://doi.org/10.1021/ic801685v","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic801685v","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmid:19053334","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/19053334","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"},{"id":"pmh:oai:HAL:hal-00861212v1","doi":null,"is_oa":false,"landing_page_url":"https://hal.science/hal-00861212","pdf_url":null,"source":{"id":"https://openalex.org/S4306402512","display_name":"HAL","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4405252976","host_organization_name":"Centre pour la Communication Scientifique Directe","host_organization_lineage":["https://openalex.org/I4405252976"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Inorganic Chemistry, 2009, 48 (1), pp.221-30. ⟨10.1021/ic801685v⟩","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":98,"referenced_works":["https://openalex.org/W1499338250","https://openalex.org/W1526468834","https://openalex.org/W1539796472","https://openalex.org/W1970034545","https://openalex.org/W1970368702","https://openalex.org/W1971178956","https://openalex.org/W1971384712","https://openalex.org/W1971481081","https://openalex.org/W1974407288","https://openalex.org/W1975444655","https://openalex.org/W1979495834","https://openalex.org/W1981898910","https://openalex.org/W1989260521","https://openalex.org/W1989709574","https://openalex.org/W1992402961","https://openalex.org/W1992512936","https://openalex.org/W1993774897","https://openalex.org/W1994016426","https://openalex.org/W1994426561","https://openalex.org/W1995514696","https://openalex.org/W1996931461","https://openalex.org/W1998022199","https://openalex.org/W1998477536","https://openalex.org/W2000651267","https://openalex.org/W2000959729","https://openalex.org/W2002417684","https://openalex.org/W2003975054","https://openalex.org/W2005782480","https://openalex.org/W2007437266","https://openalex.org/W2007991829","https://openalex.org/W2011270458","https://openalex.org/W2011872626","https://openalex.org/W2016602994","https://openalex.org/W2018053998","https://openalex.org/W2018547691","https://openalex.org/W2019971348","https://openalex.org/W2020114693","https://openalex.org/W2022527241","https://openalex.org/W2022679749","https://openalex.org/W2026041572","https://openalex.org/W2030687437","https://openalex.org/W2031475294","https://openalex.org/W2031782178","https://openalex.org/W2032486973","https://openalex.org/W2033670552","https://openalex.org/W2035698483","https://openalex.org/W2036765845","https://openalex.org/W2037429053","https://openalex.org/W2038767330","https://openalex.org/W2039092272","https://openalex.org/W2039919004","https://openalex.org/W2040447059","https://openalex.org/W2040891489","https://openalex.org/W2041545700","https://openalex.org/W2045288206","https://openalex.org/W2045838062","https://openalex.org/W2045893454","https://openalex.org/W2046381522","https://openalex.org/W2055230539","https://openalex.org/W2055620247","https://openalex.org/W2055770627","https://openalex.org/W2057376844","https://openalex.org/W2057519065","https://openalex.org/W2057674761","https://openalex.org/W2060384712","https://openalex.org/W2060385754","https://openalex.org/W2061070806","https://openalex.org/W2064277663","https://openalex.org/W2069729269","https://openalex.org/W2070513934","https://openalex.org/W2073242536","https://openalex.org/W2076546523","https://openalex.org/W2080195775","https://openalex.org/W2080521678","https://openalex.org/W2086957099","https://openalex.org/W2087214367","https://openalex.org/W2090759468","https://openalex.org/W2108446403","https://openalex.org/W2108834666","https://openalex.org/W2110985514","https://openalex.org/W2122346121","https://openalex.org/W2129920267","https://openalex.org/W2131350133","https://openalex.org/W2141127077","https://openalex.org/W2148667170","https://openalex.org/W2150345533","https://openalex.org/W2166689829","https://openalex.org/W2167590372","https://openalex.org/W2218206206","https://openalex.org/W2301716907","https://openalex.org/W2890252021","https://openalex.org/W2951713955","https://openalex.org/W2952770477","https://openalex.org/W3004460910","https://openalex.org/W3036723969","https://openalex.org/W3139008845","https://openalex.org/W4235046024","https://openalex.org/W4242405084"],"related_works":["https://openalex.org/W2039092272","https://openalex.org/W2061070806","https://openalex.org/W2949969975","https://openalex.org/W64417796","https://openalex.org/W4386505898","https://openalex.org/W2780633757","https://openalex.org/W2485180504","https://openalex.org/W2002694972","https://openalex.org/W6995988009","https://openalex.org/W2073253652"],"abstract_inverted_index":{"Treatment":[0],"of":[1,36,78,107,114,145,149,164,171,180,217,239,290],"[M(BH4)3(THF)3]":[2],"with":[3,63,92,152,267,286],"NEt3HBPh4":[4],"in":[5,33,46,69,75,81,101,276],"THF":[6],"afforded":[7],"the":[8,34,64,72,76,86,150,155,165,172,181,189,196,214,218,227,232,240,248,256,263,277,291],"cationic":[9],"complexes":[10],"[M(BH4)2(THF)5][BPh4]":[11],"[M":[12,25],"=":[13,26,133,176,204,209],"U":[14,27,205],"(1),":[15],"Nd":[16,29],"(2),":[17],"Ce":[18,31],"(3)]":[19],"which":[20,158],"were":[21],"transformed":[22],"into":[23],"[M(BH4)2(18-crown-6)][BPh4]":[24],"(4),":[28],"(5),":[30],"(6)]":[32],"presence":[35],"18-crown-6;":[37],"[U(BH4)2(18-thiacrown-6)][BPh4]":[38],"(7)":[39],"was":[40,245],"obtained":[41,129],"from":[42],"1":[43],"and":[44,53,85,168,188,231,262,270],"18-thiacrown-6":[45],"tetrahydro-thiophene.":[47],"Compounds":[48],"1,":[49],"3.C4H8S,":[50],"4.THF,":[51],"5,":[52],"6.THF":[54],"exhibit":[55,280],"a":[56,89,146,162,223,281],"penta-":[57],"or":[58],"hexagonal":[59],"bipyramidal":[60],"crystal":[61,105],"structure":[62],"two":[65,93],"terdentate":[66],"borohydride":[67],"ligands":[68],"apical":[70],"positions;":[71],"BH4":[73,197],"groups":[74],"crystals":[77],"7.C4H8S":[79],"are":[80,143],"relative":[82],"cis":[83],"positions,":[84],"thiacrown-ether":[87],"presents":[88],"saddle":[90],"shape,":[91],"diametrically":[94],"opposite":[95],"sulfur":[96],"atoms":[97,266],"bound":[98],"to":[99,154],"uranium":[100,228],"trans":[102],"positions.":[103],"The":[104,126,184,235],"structures":[106],"these":[108],"complexes,":[109],"as":[110,112,211,213],"well":[111,212],"those":[113],"previously":[115],"reported":[116],"[M(BH4)2(THF)5]+":[117],"cations,":[118],"do":[119],"not":[120],"reveal":[121],"any":[122],"clear-cut":[123],"lanthanide(III)/actinide(III)":[124],"differentiation.":[125],"structural":[127],"data":[128],"for":[130,202,207],"[M(BH4)2(18-crown-6)]+":[131],"(M":[132],"U,":[134],"Ce)":[135],"by":[136,161,247],"relativistic":[137],"density":[138],"functional":[139],"theory":[140],"(DFT)":[141],"calculations":[142],"indicative":[144],"small":[147],"shortening":[148],"U...B":[151],"respect":[153],"Ce...B":[156],"distance,":[157],"is":[159,200],"accompanied":[160],"lengthening":[163],"U-Hb":[166],"bonds":[167],"an":[169],"opening":[170],"Hb-B-Hb":[173],"angle":[174],"(Hb":[175],"bridging":[177],"hydrogen":[178],"atom":[179],"eta3-BH4":[182],"ligand).":[183],"Mulliken":[185],"population":[186,216],"analysis":[187,193],"natural":[190],"bond":[191,244],"orbital":[192,250,272],"indicate":[194],"that":[195],"-->M(III)":[198],"donation":[199],"greater":[201],"M":[203,208],"than":[206],"Ce,":[210],"overlap":[215],"M-Hb":[219],"bond,":[220],"thus":[221],"showing":[222],"better":[224],"interaction":[225],"between":[226,260],"5f":[229,271],"orbitals":[230],"Hb":[233,265],"atoms.":[234],"more":[236],"covalent":[237],"character":[238],"B-H-U":[241],"three-center":[242],"two-electron":[243],"confirmed":[246],"molecular":[249],"(MO)":[251],"analysis.":[252],"Three":[253],"MOs":[254,275],"represent":[255],"pi":[257],"bonding":[258],"interactions":[259],"U(III)":[261],"three":[264],"significant":[268],"6d":[269],"contributions.":[273],"These":[274],"cerium(III)":[278],"complex":[279],"much":[282],"lesser":[283],"metallic":[284],"weight":[285],"practically":[287],"no":[288],"participation":[289],"4f":[292],"orbitals.":[293]},"counts_by_year":[{"year":2026,"cited_by_count":5},{"year":2025,"cited_by_count":3},{"year":2024,"cited_by_count":7},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":3},{"year":2021,"cited_by_count":4},{"year":2020,"cited_by_count":3},{"year":2019,"cited_by_count":5},{"year":2018,"cited_by_count":8},{"year":2017,"cited_by_count":3},{"year":2016,"cited_by_count":4},{"year":2015,"cited_by_count":2},{"year":2014,"cited_by_count":8},{"year":2013,"cited_by_count":4},{"year":2012,"cited_by_count":6}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}