{"id":"https://openalex.org/W2011645832","doi":"https://doi.org/10.1021/ma035387f","title":"Architectural Effects of Poly(\u03b5-caprolactone)s on the Crystallization Kinetics","display_name":"Architectural Effects of Poly(\u03b5-caprolactone)s on the Crystallization Kinetics","publication_year":2004,"publication_date":"2004-04-15","ids":{"openalex":"https://openalex.org/W2011645832","doi":"https://doi.org/10.1021/ma035387f","mag":"2011645832"},"language":"en","primary_location":{"id":"doi:10.1021/ma035387f","doi":"https://doi.org/10.1021/ma035387f","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ma035387f","pdf_url":null,"source":{"id":"https://openalex.org/S177196338","display_name":"Macromolecules","issn_l":"0024-9297","issn":["0024-9297","1520-5835"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecules","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5111556720","display_name":"Jeongsoo Choi","orcid":"https://orcid.org/0000-0002-5554-3657","observed_orcids":["https://orcid.org/0000-0002-5554-3657"]},"institutions":[{"id":"https://openalex.org/I139264467","display_name":"Seoul National University","ror":"https://ror.org/04h9pn542","country_code":"KR","type":"education","lineage":["https://openalex.org/I139264467"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Jeongsoo Choi","raw_affiliation_strings":["Research Institute of Advanced Materials (RIAM), and School of Materials Science and Engineering, Seoul National University, San 56-1, Shinlim-dong, Kwanak-ku, Seoul 151-744, Korea, and Hyperstructured Organic Materials Research Center (HOMRC), and School of Materials Science and Engineering, Seoul National University, San 56-1, Shinlim-dong, Kwanak-ku, Seoul 151-744, Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Research Institute of Advanced Materials (RIAM), and School of Materials Science and Engineering, Seoul National University, San 56-1, Shinlim-dong, Kwanak-ku, Seoul 151-744, Korea, and Hyperstructured Organic Materials Research Center (HOMRC), and School of Materials Science and Engineering, Seoul National University, San 56-1, Shinlim-dong, Kwanak-ku, Seoul 151-744, Korea","institution_ids":["https://openalex.org/I139264467"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5024271305","display_name":"Seung\u2010Yeop Kwak","orcid":"https://orcid.org/0000-0002-8903-4287","observed_orcids":["https://orcid.org/0000-0002-8903-4287"]},"institutions":[{"id":"https://openalex.org/I139264467","display_name":"Seoul National University","ror":"https://ror.org/04h9pn542","country_code":"KR","type":"education","lineage":["https://openalex.org/I139264467"]}],"countries":["KR"],"is_corresponding":true,"raw_author_name":"Seung-Yeop Kwak","raw_affiliation_strings":["Research Institute of Advanced Materials (RIAM), and School of Materials Science and Engineering, Seoul National University, San 56-1, Shinlim-dong, Kwanak-ku, Seoul 151-744, Korea, and Hyperstructured Organic Materials Research Center (HOMRC), and School of Materials Science and Engineering, Seoul National University, San 56-1, Shinlim-dong, Kwanak-ku, Seoul 151-744, Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Research Institute of Advanced Materials (RIAM), and School of Materials Science and Engineering, Seoul National University, San 56-1, Shinlim-dong, Kwanak-ku, Seoul 151-744, Korea, and Hyperstructured Organic Materials Research Center (HOMRC), and School of Materials Science and Engineering, Seoul National University, San 56-1, Shinlim-dong, Kwanak-ku, Seoul 151-744, Korea","institution_ids":["https://openalex.org/I139264467"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5024271305"],"corresponding_institution_ids":["https://openalex.org/I139264467"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":3.7425,"has_fulltext":false,"cited_by_count":35,"citation_normalized_percentile":{"value":0.91979227,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":98},"biblio":{"volume":"37","issue":"10","first_page":"3745","last_page":"3754"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10389","display_name":"Polymer crystallization and properties","score":0.8687000274658203,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10389","display_name":"Polymer crystallization and properties","score":0.8687000274658203,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11686","display_name":"Dendrimers and Hyperbranched Polymers","score":0.05169999971985817,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10661","display_name":"biodegradable polymer synthesis and properties","score":0.04820000007748604,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/polycaprolactone","display_name":"polycaprolactone","score":0.9380000233650208},{"id":"https://openalex.org/keywords/hyperbranched-polymers","display_name":"hyperbranched polymers","score":0.9860000014305115},{"id":"https://openalex.org/keywords/molecular-architecture","display_name":"molecular architecture","score":0.7239999771118164},{"id":"https://openalex.org/keywords/crystallization-kinetics","display_name":"crystallization kinetics","score":0.9589999914169312},{"id":"https://openalex.org/keywords/non-isothermal-crystallization","display_name":"non-isothermal crystallization","score":0.8479999899864197},{"id":"https://openalex.org/keywords/avrami-exponent","display_name":"Avrami exponent","score":0.9089999794960022},{"id":"https://openalex.org/keywords/nucleation-and-growth","display_name":"nucleation and growth","score":0.8769999742507935},{"id":"https://openalex.org/keywords/branch-points","display_name":"branch points","score":0.7250000238418579},{"id":"https://openalex.org/keywords/spherulites","display_name":"spherulites","score":0.7559999823570251},{"id":"https://openalex.org/keywords/radial-growth-rate","display_name":"radial growth rate","score":0.8769999742507935},{"id":"https://openalex.org/keywords/flow-activation-energy","display_name":"flow activation energy","score":0.9020000100135803},{"id":"https://openalex.org/keywords/chain-mobility","display_name":"chain mobility","score":0.6100000143051147},{"id":"https://openalex.org/keywords/melt-crystallization","display_name":"melt crystallization","score":0.5730000138282776}],"concepts":[{"id":"https://openalex.org/C206175624","wikidata":"https://www.wikidata.org/wiki/Q595731","display_name":"Branching (polymer chemistry)","level":2,"score":0.888622522354126},{"id":"https://openalex.org/C203036418","wikidata":"https://www.wikidata.org/wiki/Q284256","display_name":"Crystallization","level":2,"score":0.8376142978668213},{"id":"https://openalex.org/C61048295","wikidata":"https://www.wikidata.org/wiki/Q909022","display_name":"Nucleation","level":2,"score":0.7413374781608582},{"id":"https://openalex.org/C2781111393","wikidata":"https://www.wikidata.org/wiki/Q288104","display_name":"Caprolactone","level":4,"score":0.5623009204864502},{"id":"https://openalex.org/C148898269","wikidata":"https://www.wikidata.org/wiki/Q1108792","display_name":"Kinetics","level":2,"score":0.5601236820220947},{"id":"https://openalex.org/C166940927","wikidata":"https://www.wikidata.org/wiki/Q178827","display_name":"Monomer","level":3,"score":0.48232170939445496},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.4515515863895416},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.4476713240146637},{"id":"https://openalex.org/C204774569","wikidata":"https://www.wikidata.org/wiki/Q902606","display_name":"Avrami equation","level":4,"score":0.43541640043258667},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.4147256910800934},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.413469523191452},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.3085191249847412},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.20677074790000916},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.1376659870147705},{"id":"https://openalex.org/C110530677","wikidata":"https://www.wikidata.org/wiki/Q1789148","display_name":"Crystallization of polymers","level":3,"score":0.07526305317878723},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/ma035387f","doi":"https://doi.org/10.1021/ma035387f","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ma035387f","pdf_url":null,"source":{"id":"https://openalex.org/S177196338","display_name":"Macromolecules","issn_l":"0024-9297","issn":["0024-9297","1520-5835"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecules","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":40,"referenced_works":["https://openalex.org/W402639177","https://openalex.org/W1579563536","https://openalex.org/W1971386451","https://openalex.org/W1973413775","https://openalex.org/W1974872221","https://openalex.org/W1975590279","https://openalex.org/W1977595301","https://openalex.org/W1984507949","https://openalex.org/W1992779470","https://openalex.org/W1994899665","https://openalex.org/W1997769170","https://openalex.org/W1997947135","https://openalex.org/W2004566397","https://openalex.org/W2015564295","https://openalex.org/W2020699551","https://openalex.org/W2022373667","https://openalex.org/W2022462472","https://openalex.org/W2024364297","https://openalex.org/W2024908520","https://openalex.org/W2027160862","https://openalex.org/W2031814691","https://openalex.org/W2040552744","https://openalex.org/W2047712090","https://openalex.org/W2049173846","https://openalex.org/W2050110843","https://openalex.org/W2054463121","https://openalex.org/W2056320034","https://openalex.org/W2057080478","https://openalex.org/W2060785268","https://openalex.org/W2066515797","https://openalex.org/W2082407062","https://openalex.org/W2086996410","https://openalex.org/W2090260002","https://openalex.org/W2092512936","https://openalex.org/W2144206679","https://openalex.org/W2172187890","https://openalex.org/W2312647854","https://openalex.org/W2951076761","https://openalex.org/W3180929528","https://openalex.org/W4251659088"],"related_works":["https://openalex.org/W2026869536","https://openalex.org/W2161617439","https://openalex.org/W1133503441","https://openalex.org/W2913786645","https://openalex.org/W4231914312","https://openalex.org/W2049803581","https://openalex.org/W4312106520","https://openalex.org/W2112650492","https://openalex.org/W2144679434","https://openalex.org/W2044694356"],"abstract_inverted_index":{"A":[0,282],"series":[1],"of":[2,18,24,46,64,87,102,119,137,235,247,258,280,284,305,316],"hyperbranched":[3],"poly(":[4,60],"\u03b5":[5,29,61],"-caprolactone)s":[6],"(HPCLs)":[7],"with":[8,197,231,249,261,313],"molecular":[9,56,71,85,158],"architectural":[10],"variation,":[11],"which":[12],"refers":[13],"to":[14,35,79,128,152,265,310],"the":[15,19,43,55,65,76,114,120,122,132,138,144,147,157,161,170,177,183,205,232,240,245,255,266,291,301,314,325],"different":[16,44],"lengths":[17],"linear":[20,59,77,199,251],"backbone":[21,246],"segments":[22,200],"consisting":[23],"5,":[25],"10,":[26],"and":[27,39,42,58,69,104,110,134,175,189,201,216,300,321],"20":[28],"-caprolactone":[30],"monomer":[31],"units":[32],"(thereby":[33],"referred":[34],"as":[36,75,169,182,275],"HPCL-5,":[37],"HPCL-10,":[38],"HPCL-20,":[40,217],"respectively)":[41],"numbers":[45],"branching":[47,237],"points,":[48,238],"were":[49,90,106,293,308],"synthesized":[50],"without":[51],"significant":[52],"variation":[53],"in":[54,244,271],"weights,":[57],"-caprolactone)":[62],"(LPCL)":[63],"same":[66],"chemical":[67],"structure":[68],"similar":[70],"weight":[72],"was":[73,150,229,263],"used":[74],"counterpart":[78],"HPCLs":[80,103,196,248],"for":[81,295],"comparison.":[82],"The":[83,98,226],"specific":[84],"architectures":[86],"these":[88,306],"samples":[89,139,297],"characterized":[91],"by":[92,108,113,156,277,298],"1":[93],"H":[94],"NMR":[95],"end-group":[96],"analyses.":[97,328],"nonisothermal":[99,326],"crystallization":[100,148,190,212,228,257,327],"exotherms":[101,167],"LPCL":[105,209,223,262],"measured":[107],"DSC":[109,166],"further":[111],"analyzed":[112],"modified":[115,178],"Avrami":[116,123,179],"method.":[117],"Regardless":[118],"samples,":[121],"exponents":[124],"ranged":[125],"from":[126,165,176,290,324],"2.4":[127],"3.3,":[129],"indicating":[130],"that":[131,195],"nucleation":[133],"growth":[135,303],"mechanisms":[136],"are":[140],"apparently":[141],"identical.":[142],"On":[143],"other":[145],"hand,":[146],"kinetics":[149],"found":[151],"be":[153],"fairly":[154],"affected":[155],"architectures.":[159],"All":[160],"kinetic":[162],"parameters":[163],"estimated":[164],"such":[168,181],"initial":[171],"slope,":[172],"S":[173,317],"i,":[174,318],"analyses":[180],"corrected":[184],"rate":[185,213],"constant,":[186],"K":[187,319],"c,":[188,320],"half-time,":[191],"t":[192,322],"1/2,":[193],"indicated":[194],"longer":[198],"fewer":[202],"branches":[203],"showed":[204],"faster":[206,256],"crystallization,":[207],"whereas":[208],"exhibited":[210],"intermediate":[211],"between":[214],"HPCL-10":[215,221],"i.e.,":[218],"HPCL-5":[219],"<":[220,222,224],"HPCL-20.":[225],"slower":[227],"linked":[230],"frequent":[233],"presence":[234],"heterogeneous":[236],"hindering":[239],"regular":[241],"chain":[242,269],"packing,":[243],"shorter":[250],"segments.":[252],"In":[253],"addition,":[254],"HPCL-20":[259],"compared":[260],"attributed":[264],"higher":[267],"cooperative":[268],"mobility":[270],"their":[272],"melt":[273,292],"state":[274],"evaluated":[276,309],"activation":[278],"energy":[279],"flow.":[281],"number":[283],"spherulites":[285,307],"developed":[286],"during":[287],"isothermal":[288],"process":[289],"observed":[294],"all":[296],"POM,":[299],"radial":[302],"rates":[304],"correspond":[311],"well":[312],"results":[315],"1/2":[323]},"counts_by_year":[{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":2},{"year":2018,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2015,"cited_by_count":4},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":2},{"year":2012,"cited_by_count":3}],"updated_date":"2026-09-29T14:09:16.559479","created_date":"2016-06-24T00:00:00"}
