{"id":"https://openalex.org/W2011491406","doi":"https://doi.org/10.1002/(sici)1521-3765(19980807)4:8<1428::aid-chem1428>3.0.co;2-7","title":"Structure and Bonding of Low-Valent (Fischer-Type) and High-Valent (Schrock-Type) Transition Metal Carbene Complexes","display_name":"Structure and Bonding of Low-Valent (Fischer-Type) and High-Valent (Schrock-Type) Transition Metal Carbene Complexes","publication_year":1998,"publication_date":"1998-08-07","ids":{"openalex":"https://openalex.org/W2011491406","doi":"https://doi.org/10.1002/(sici)1521-3765(19980807)4:8<1428::aid-chem1428>3.0.co;2-7","mag":"2011491406"},"language":"en","primary_location":{"id":"doi:10.1002/(sici)1521-3765(19980807)4:8<1428::aid-chem1428>3.0.co;2-7","doi":"https://doi.org/10.1002/(sici)1521-3765(19980807)4:8<1428::aid-chem1428>3.0.co;2-7","is_oa":true,"landing_page_url":"https://doi.org/10.1002/(sici)1521-3765(19980807)4:8<1428::aid-chem1428>3.0.co;2-7","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/%28SICI%291521-3765%2819980807%294%3A8%3C1428%3A%3AAID-CHEM1428%3E3.0.CO%3B2-7","source":{"id":"https://openalex.org/S68911691","display_name":"Chemistry - A European Journal","issn_l":"0947-6539","issn":["0947-6539","1521-3765"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry - A European Journal","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"bronze","oa_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/%28SICI%291521-3765%2819980807%294%3A8%3C1428%3A%3AAID-CHEM1428%3E3.0.CO%3B2-7","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5070490233","display_name":"Sergei F. Vyboishchikov","orcid":"https://orcid.org/0000-0003-1338-3437","observed_orcids":["https://orcid.org/0000-0003-1338-3437"]},"institutions":[{"id":"https://openalex.org/I161103922","display_name":"Philipps University of Marburg","ror":"https://ror.org/01rdrb571","country_code":"DE","type":"education","lineage":["https://openalex.org/I161103922"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Sergei F. Vyboishchikov","raw_affiliation_strings":["Fachbereich Chemie, Philipps-Universita\u0308t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg (Germany),","Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg (Germany), Fax: (+49)\u20096421-282189"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Fachbereich Chemie, Philipps-Universita\u0308t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg (Germany),","institution_ids":["https://openalex.org/I161103922"]},{"raw_affiliation_string":"Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg (Germany), Fax: (+49)\u20096421-282189","institution_ids":["https://openalex.org/I161103922"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5033413160","display_name":"Gernot Frenking","orcid":"https://orcid.org/0000-0003-1689-1197","observed_orcids":["https://orcid.org/0000-0003-1689-1197"]},"institutions":[{"id":"https://openalex.org/I161103922","display_name":"Philipps University of Marburg","ror":"https://ror.org/01rdrb571","country_code":"DE","type":"education","lineage":["https://openalex.org/I161103922"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Gernot Frenking","raw_affiliation_strings":["Fachbereich Chemie, Philipps-Universita\u0308t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg (Germany),","Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg (Germany), Fax: (+49)\u20096421-282189"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Fachbereich Chemie, Philipps-Universita\u0308t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg (Germany),","institution_ids":["https://openalex.org/I161103922"]},{"raw_affiliation_string":"Fachbereich Chemie, Philipps-Universit\u00e4t Marburg, Hans-Meerwein-Strasse, D-35032 Marburg (Germany), Fax: (+49)\u20096421-282189","institution_ids":["https://openalex.org/I161103922"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I161103922"],"apc_list":{"value":4640,"currency":"USD","value_usd":4640},"apc_paid":null,"fwci":7.7942,"has_fulltext":true,"cited_by_count":157,"citation_normalized_percentile":{"value":0.98593468,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"4","issue":"8","first_page":"1428","last_page":"1438"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.7910000085830688,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.7910000085830688,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.10679999738931656,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.053599998354911804,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/fischer-carbene-complexes","display_name":"Fischer carbene complexes","score":0.7480000257492065},{"id":"https://openalex.org/keywords/tungsten-carbene-complexes","display_name":"tungsten carbene complexes","score":0.925000011920929},{"id":"https://openalex.org/keywords/bond-dissociation-energy","display_name":"bond dissociation energy","score":0.8939999938011169},{"id":"https://openalex.org/keywords/transition-metal-carbene-complexes","display_name":"transition metal carbene complexes","score":0.6759999990463257},{"id":"https://openalex.org/keywords/molecular-geometry","display_name":"molecular geometry","score":0.4009999930858612}],"concepts":[{"id":"https://openalex.org/C2777164566","wikidata":"https://www.wikidata.org/wiki/Q419257","display_name":"Carbene","level":3,"score":0.9667841792106628},{"id":"https://openalex.org/C542268612","wikidata":"https://www.wikidata.org/wiki/Q743","display_name":"Tungsten","level":2,"score":0.6903283596038818},{"id":"https://openalex.org/C102931765","wikidata":"https://www.wikidata.org/wiki/Q189673","display_name":"Dissociation (chemistry)","level":2,"score":0.6252962350845337},{"id":"https://openalex.org/C106773901","wikidata":"https://www.wikidata.org/wiki/Q19588","display_name":"Transition metal","level":3,"score":0.5866003036499023},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5423740744590759},{"id":"https://openalex.org/C2781442258","wikidata":"https://www.wikidata.org/wiki/Q46310","display_name":"Ab initio","level":2,"score":0.5327496528625488},{"id":"https://openalex.org/C86914705","wikidata":"https://www.wikidata.org/wiki/Q414293","display_name":"Transition metal carbene complex","level":4,"score":0.5247160196304321},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.5149003267288208},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.49934887886047363},{"id":"https://openalex.org/C62396407","wikidata":"https://www.wikidata.org/wiki/Q863696","display_name":"Bond-dissociation energy","level":3,"score":0.48952803015708923},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.432685524225235},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.2528829872608185},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.19242656230926514},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.15786534547805786},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1002/(sici)1521-3765(19980807)4:8<1428::aid-chem1428>3.0.co;2-7","doi":"https://doi.org/10.1002/(sici)1521-3765(19980807)4:8<1428::aid-chem1428>3.0.co;2-7","is_oa":true,"landing_page_url":"https://doi.org/10.1002/(sici)1521-3765(19980807)4:8<1428::aid-chem1428>3.0.co;2-7","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/%28SICI%291521-3765%2819980807%294%3A8%3C1428%3A%3AAID-CHEM1428%3E3.0.CO%3B2-7","source":{"id":"https://openalex.org/S68911691","display_name":"Chemistry - A European Journal","issn_l":"0947-6539","issn":["0947-6539","1521-3765"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry - A European Journal","raw_type":"journal-article"},{"id":"doi:10.1002/(sici)1521-3765(19980807)4:8<1428::aid-chem1428>3.3.co;2-z","doi":"https://doi.org/10.1002/(sici)1521-3765(19980807)4:8<1428::aid-chem1428>3.3.co;2-z","is_oa":false,"landing_page_url":"https://doi.org/10.1002/(sici)1521-3765(19980807)4:8<1428::aid-chem1428>3.3.co;2-z","pdf_url":null,"source":{"id":"https://openalex.org/S68911691","display_name":"Chemistry - A European Journal","issn_l":"0947-6539","issn":["0947-6539","1521-3765"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry - A European Journal","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1002/(sici)1521-3765(19980807)4:8<1428::aid-chem1428>3.0.co;2-7","doi":"https://doi.org/10.1002/(sici)1521-3765(19980807)4:8<1428::aid-chem1428>3.0.co;2-7","is_oa":true,"landing_page_url":"https://doi.org/10.1002/(sici)1521-3765(19980807)4:8<1428::aid-chem1428>3.0.co;2-7","pdf_url":"https://onlinelibrary.wiley.com/doi/pdfdirect/10.1002/%28SICI%291521-3765%2819980807%294%3A8%3C1428%3A%3AAID-CHEM1428%3E3.0.CO%3B2-7","source":{"id":"https://openalex.org/S68911691","display_name":"Chemistry - A European Journal","issn_l":"0947-6539","issn":["0947-6539","1521-3765"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry - A European Journal","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320310905","display_name":"Philipps-Universit\u00e4t Marburg","ror":"https://ror.org/01rdrb571"},{"id":"https://openalex.org/F4320320875","display_name":"Deutscher Akademischer Austauschdienst","ror":"https://ror.org/039djdh30"},{"id":"https://openalex.org/F4320320879","display_name":"Deutsche Forschungsgemeinschaft","ror":"https://ror.org/018mejw64"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2011491406.pdf","grobid_xml":"https://content.openalex.org/works/W2011491406.grobid-xml"},"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W4239047777","https://openalex.org/W2156165214","https://openalex.org/W2030556374","https://openalex.org/W2114314801","https://openalex.org/W2912467207","https://openalex.org/W2627058539","https://openalex.org/W4231262337","https://openalex.org/W2031751987","https://openalex.org/W2001498174","https://openalex.org/W3180379284"],"abstract_inverted_index":{"The":[0,27],"nature":[1],"and":[2,12,22,29,46],"reactivity":[3],"of":[4,8,18,38,49],"the":[5,43],"metal\u2013carbene":[6],"bond":[7,31],"12":[9],"Fischer-":[10],"(1)":[11],"Schrock-":[13],"(2)":[14],"type":[15],"carbene":[16],"complexes":[17],"tungsten,":[19],"both":[20],"neutral":[21],"negatively":[23],"charged,":[24],"is":[25],"investigated.":[26],"geometries":[28],"tungsten\u2013carbene":[30],"dissociation":[32],"energies":[33],"were":[34],"calculated":[35],"by":[36],"use":[37],"ab":[39],"initio":[40],"methods":[41],"at":[42],"HF,":[44],"MP2,":[45],"CCSD(T)":[47],"level":[48],"theory.":[50]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2024,"cited_by_count":6},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":5},{"year":2021,"cited_by_count":6},{"year":2020,"cited_by_count":8},{"year":2019,"cited_by_count":4},{"year":2018,"cited_by_count":10},{"year":2017,"cited_by_count":9},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":8},{"year":2014,"cited_by_count":4},{"year":2013,"cited_by_count":5},{"year":2012,"cited_by_count":2}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}