{"id":"https://openalex.org/W2011477643","doi":"https://doi.org/10.1002/ejoc.200400132","title":"Synthesis and Radical Polymerization of Various 2\u2010Cyclopropylacrylates","display_name":"Synthesis and Radical Polymerization of Various 2\u2010Cyclopropylacrylates","publication_year":2004,"publication_date":"2004-08-17","ids":{"openalex":"https://openalex.org/W2011477643","doi":"https://doi.org/10.1002/ejoc.200400132","mag":"2011477643"},"language":"en","primary_location":{"id":"doi:10.1002/ejoc.200400132","doi":"https://doi.org/10.1002/ejoc.200400132","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ejoc.200400132","pdf_url":null,"source":{"id":"https://openalex.org/S21317199","display_name":"European Journal of Organic Chemistry","issn_l":"1099-0690","issn":["1099-0690","1434-193X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"European Journal of Organic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://resolver.sub.uni-goettingen.de/purl?gro-2/47710","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5056358838","display_name":"Armin de Meijere","orcid":"https://orcid.org/0000-0002-5140-0720","observed_orcids":["https://orcid.org/0000-0002-5140-0720"]},"institutions":[{"id":"https://openalex.org/I74656192","display_name":"University of G\u00f6ttingen","ror":"https://ror.org/01y9bpm73","country_code":"DE","type":"education","lineage":["https://openalex.org/I74656192"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Armin\u00a0de Meijere","raw_affiliation_strings":["Institut fu\u0308r Organische Chemie der Georg-August-Universita\u0308t Go\u0308ttingen, Tammannstrasse 2, 37077 Go\u0308ttingen, Germany,","Institut f\u00fcr Organische Chemie der Georg\u2010August\u2010Universit\u00e4t G\u00f6ttingen, Tammannstrasse 2, 37077 G\u00f6ttingen, Germany, Fax: (internat.) + 49\u2010551/399475"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut fu\u0308r Organische Chemie der Georg-August-Universita\u0308t Go\u0308ttingen, Tammannstrasse 2, 37077 Go\u0308ttingen, Germany,","institution_ids":["https://openalex.org/I74656192"]},{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie der Georg\u2010August\u2010Universit\u00e4t G\u00f6ttingen, Tammannstrasse 2, 37077 G\u00f6ttingen, Germany, Fax: (internat.) + 49\u2010551/399475","institution_ids":["https://openalex.org/I74656192"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5024908194","display_name":"Viktor Bagutski","orcid":"https://orcid.org/0000-0002-7514-2455","observed_orcids":["https://orcid.org/0000-0002-7514-2455"]},"institutions":[{"id":"https://openalex.org/I74656192","display_name":"University of G\u00f6ttingen","ror":"https://ror.org/01y9bpm73","country_code":"DE","type":"education","lineage":["https://openalex.org/I74656192"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Viktor Bagutski","raw_affiliation_strings":["Institut fu\u0308r Organische Chemie der Georg-August-Universita\u0308t Go\u0308ttingen, Tammannstrasse 2, 37077 Go\u0308ttingen, Germany,","Institut f\u00fcr Organische Chemie der Georg\u2010August\u2010Universit\u00e4t G\u00f6ttingen, Tammannstrasse 2, 37077 G\u00f6ttingen, Germany, Fax: (internat.) + 49\u2010551/399475"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut fu\u0308r Organische Chemie der Georg-August-Universita\u0308t Go\u0308ttingen, Tammannstrasse 2, 37077 Go\u0308ttingen, Germany,","institution_ids":["https://openalex.org/I74656192"]},{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie der Georg\u2010August\u2010Universit\u00e4t G\u00f6ttingen, Tammannstrasse 2, 37077 G\u00f6ttingen, Germany, Fax: (internat.) + 49\u2010551/399475","institution_ids":["https://openalex.org/I74656192"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5081808206","display_name":"Frank Zeuner","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210086727","display_name":"Ivoclar Vivadent (Liechtenstein)","ror":"https://ror.org/001tmkc70","country_code":"LI","type":"company","lineage":["https://openalex.org/I4210086727"]}],"countries":["LI"],"is_corresponding":false,"raw_author_name":"Frank Zeuner","raw_affiliation_strings":["Ivoclar Vivadent AG, Bendererstrasse 2, 9494 Schaan, Liechtenstein,","Ivoclar Vivadent AG, Bendererstrasse 2, 9494 Schaan, Liechtenstein, Fax: (internat.) + 423-2331279"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Ivoclar Vivadent AG, Bendererstrasse 2, 9494 Schaan, Liechtenstein,","institution_ids":["https://openalex.org/I4210086727"]},{"raw_affiliation_string":"Ivoclar Vivadent AG, Bendererstrasse 2, 9494 Schaan, Liechtenstein, Fax: (internat.) + 423-2331279","institution_ids":["https://openalex.org/I4210086727"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5014332078","display_name":"Urs Karl Fischer","orcid":"https://orcid.org/0000-0003-3642-6065","observed_orcids":["https://orcid.org/0000-0003-3642-6065"]},"institutions":[{"id":"https://openalex.org/I4210086727","display_name":"Ivoclar Vivadent (Liechtenstein)","ror":"https://ror.org/001tmkc70","country_code":"LI","type":"company","lineage":["https://openalex.org/I4210086727"]}],"countries":["LI"],"is_corresponding":false,"raw_author_name":"Urs\u00a0Karl Fischer","raw_affiliation_strings":["Ivoclar Vivadent AG, Bendererstrasse 2, 9494 Schaan, Liechtenstein,","Ivoclar Vivadent AG, Bendererstrasse 2, 9494 Schaan, Liechtenstein, Fax: (internat.) + 423-2331279"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Ivoclar Vivadent AG, Bendererstrasse 2, 9494 Schaan, Liechtenstein,","institution_ids":["https://openalex.org/I4210086727"]},{"raw_affiliation_string":"Ivoclar Vivadent AG, Bendererstrasse 2, 9494 Schaan, Liechtenstein, Fax: (internat.) + 423-2331279","institution_ids":["https://openalex.org/I4210086727"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111849647","display_name":"Volker M. Rheinberger","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210086727","display_name":"Ivoclar Vivadent (Liechtenstein)","ror":"https://ror.org/001tmkc70","country_code":"LI","type":"company","lineage":["https://openalex.org/I4210086727"]}],"countries":["LI"],"is_corresponding":false,"raw_author_name":"Volker Rheinberger","raw_affiliation_strings":["Ivoclar Vivadent AG, Bendererstrasse 2, 9494 Schaan, Liechtenstein,","Ivoclar Vivadent AG, Bendererstrasse 2, 9494 Schaan, Liechtenstein, Fax: (internat.) + 423-2331279"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Ivoclar Vivadent AG, Bendererstrasse 2, 9494 Schaan, Liechtenstein,","institution_ids":["https://openalex.org/I4210086727"]},{"raw_affiliation_string":"Ivoclar Vivadent AG, Bendererstrasse 2, 9494 Schaan, Liechtenstein, Fax: (internat.) + 423-2331279","institution_ids":["https://openalex.org/I4210086727"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5071136918","display_name":"Norbert Moszner","orcid":"https://orcid.org/0000-0002-9854-1838","observed_orcids":["https://orcid.org/0000-0002-9854-1838"]},"institutions":[{"id":"https://openalex.org/I4210086727","display_name":"Ivoclar Vivadent (Liechtenstein)","ror":"https://ror.org/001tmkc70","country_code":"LI","type":"company","lineage":["https://openalex.org/I4210086727"]}],"countries":["LI"],"is_corresponding":false,"raw_author_name":"Norbert Moszner","raw_affiliation_strings":["Ivoclar Vivadent AG, Bendererstrasse 2, 9494 Schaan, Liechtenstein,","Ivoclar Vivadent AG, Bendererstrasse 2, 9494 Schaan, Liechtenstein, Fax: (internat.) + 423-2331279"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Ivoclar Vivadent AG, Bendererstrasse 2, 9494 Schaan, Liechtenstein,","institution_ids":["https://openalex.org/I4210086727"]},{"raw_affiliation_string":"Ivoclar Vivadent AG, Bendererstrasse 2, 9494 Schaan, Liechtenstein, Fax: (internat.) + 423-2331279","institution_ids":["https://openalex.org/I4210086727"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4330,"currency":"USD","value_usd":4330},"apc_paid":null,"fwci":1.0124,"has_fulltext":false,"cited_by_count":24,"citation_normalized_percentile":{"value":0.6998068,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"2004","issue":"17","first_page":"3669","last_page":"3678"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.8310999870300293,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.8310999870300293,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11611","display_name":"Cyclopropane Reaction Mechanisms","score":0.14980000257492065,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T14303","display_name":"Polymer Synthesis and Characterization","score":0.008100000210106373,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/free-radical-polymerization","display_name":"radical polymerization","score":0.8569999933242798},{"id":"https://openalex.org/keywords/free-radical-copolymerization","display_name":"radical copolymerization","score":0.8130000233650208},{"id":"https://openalex.org/keywords/cyclopropanation","display_name":"cyclopropanation","score":0.6990000009536743},{"id":"https://openalex.org/keywords/aibn-initiator","display_name":"AIBN initiator","score":0.6330000162124634},{"id":"https://openalex.org/keywords/glass-transition-temperature","display_name":"glass transition temperature","score":0.8640000224113464},{"id":"https://openalex.org/keywords/monomer-reactivity","display_name":"monomer reactivity","score":0.7630000114440918},{"id":"https://openalex.org/keywords/methyl-methacrylate-copolymers","display_name":"methyl methacrylate copolymers","score":0.6899999976158142}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9302182197570801},{"id":"https://openalex.org/C166940927","wikidata":"https://www.wikidata.org/wiki/Q178827","display_name":"Monomer","level":3,"score":0.7330589890480042},{"id":"https://openalex.org/C2777935641","wikidata":"https://www.wikidata.org/wiki/Q382897","display_name":"Methyl methacrylate","level":4,"score":0.5568959712982178},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.5546186566352844},{"id":"https://openalex.org/C2778910044","wikidata":"https://www.wikidata.org/wiki/Q416814","display_name":"Cyanohydrin","level":3,"score":0.552531898021698},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.5201259255409241},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.45388585329055786},{"id":"https://openalex.org/C2776041390","wikidata":"https://www.wikidata.org/wiki/Q407768","display_name":"Chlorobenzene","level":3,"score":0.4452621638774872},{"id":"https://openalex.org/C122865956","wikidata":"https://www.wikidata.org/wiki/Q825643","display_name":"Glass transition","level":3,"score":0.4300924241542816},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.403706431388855},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.39776432514190674},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.35921621322631836}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1002/ejoc.200400132","doi":"https://doi.org/10.1002/ejoc.200400132","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ejoc.200400132","pdf_url":null,"source":{"id":"https://openalex.org/S21317199","display_name":"European Journal of Organic Chemistry","issn_l":"1099-0690","issn":["1099-0690","1434-193X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"European Journal of Organic Chemistry","raw_type":"journal-article"},{"id":"pmh:oai:publications.goettingen-research-online.de:2/47710","doi":null,"is_oa":true,"landing_page_url":"https://resolver.sub.uni-goettingen.de/purl?gro-2/47710","pdf_url":null,"source":{"id":"https://openalex.org/S7407055187","display_name":"GRO","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":{"id":"pmh:oai:publications.goettingen-research-online.de:2/47710","doi":null,"is_oa":true,"landing_page_url":"https://resolver.sub.uni-goettingen.de/purl?gro-2/47710","pdf_url":null,"source":{"id":"https://openalex.org/S7407055187","display_name":"GRO","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"info:eu-repo/semantics/article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":24,"referenced_works":["https://openalex.org/W1968328348","https://openalex.org/W1975473529","https://openalex.org/W1980452088","https://openalex.org/W1989124898","https://openalex.org/W1991728005","https://openalex.org/W1993088738","https://openalex.org/W2007536998","https://openalex.org/W2009963188","https://openalex.org/W2010165243","https://openalex.org/W2015351496","https://openalex.org/W2026729566","https://openalex.org/W2038605383","https://openalex.org/W2054972365","https://openalex.org/W2058576479","https://openalex.org/W2060858889","https://openalex.org/W2066465366","https://openalex.org/W2078441485","https://openalex.org/W2093173434","https://openalex.org/W2161167654","https://openalex.org/W2949704023","https://openalex.org/W2950562800","https://openalex.org/W2951802150","https://openalex.org/W2951972607","https://openalex.org/W2952047653"],"related_works":["https://openalex.org/W2046188852","https://openalex.org/W2066465366","https://openalex.org/W2044418445","https://openalex.org/W2074675759","https://openalex.org/W2076415137","https://openalex.org/W2125595737","https://openalex.org/W2304995922","https://openalex.org/W2945750166","https://openalex.org/W2027728278","https://openalex.org/W4253621656"],"abstract_inverted_index":{"Abstract":[0],"Fourteen":[1],"new":[2,48],"alkyl":[3],"2\u2010cyclopropylacrylates":[4],"1a\u2212n":[5,85,102],"with":[6,75,106,136,216],"various":[7],"substituents":[8],"R1\u2212R5":[9],"were":[10,65,86,103,120,169],"synthesized":[11],"from":[12,24,43,134,178],"readily":[13],"available":[14],"precursors":[15],"by":[16,67,88],"applying":[17],"standard":[18],"transformations":[19],"such":[20],"as":[21,109,184],"cyanohydrin":[22],"formation":[23],"an":[25,29,37,137],"aldehyde,":[26],"alcoholysis":[27],"to":[28,45,56,221],"\u03b1\u2010hydroxycarboxylic":[30],"ester,":[31],"oxidation":[32],"and":[33,95,127,131,148,155,158,166,205],"Wittig":[34],"methylenation":[35],"of":[36,53,72,101,125,146,164,195],"\u03b1\u2010oxocarboxylic":[38],"ester.":[39],"Overall":[40],"yields":[41,119,153],"ranged":[42],"33":[44],"54%.":[46],"A":[47],"method":[49],"for":[50,175,187],"the":[51,57,123,144,151,159,176,188,192,197,213],"hydrolysis":[52],"dimethyl":[54],"cyclopropanedicarboxylates":[55],"corresponding":[58],"half\u2010esters":[59],"was":[60,182],"developed.":[61],"The":[62,83,98,116,201],"\u03b1\u2010oxocarboxylates":[63],"7g\u2212n":[64],"prepared":[66],"dirhodium":[68],"tetraacetate":[69],"catalyzed":[70],"cyclopropanation":[71],"alkenes":[73],"8g\u2212n":[74],"methyl":[76,217],"or":[77,129,140],"ethyl":[78],"diazopyruvate":[79],"in":[80,111,122,191,212],"32\u221258%":[81],"yield.":[82],"monomers":[84,135,203],"characterized":[87],"1H,":[89],"13C":[90],"NMR":[91],"spectroscopy,":[92],"mass":[93],"spectrometry":[94],"elemental":[96],"analysis.":[97],"radical":[99,193,214],"homopolymerizations":[100],"carried":[104],"out":[105],"2,2\u2032\u2010azabisisobutyronitrile":[107],"(AIBN)":[108],"initiator":[110],"chlorobenzene":[112],"at":[113],"65":[114],"\u00b0C.":[115],"highest":[117],"polymer":[118,152,177],"obtained":[121],"polymerizations":[124,194],"1f":[126],"1h":[128,147,204],"1k":[130,206],"1l,":[132],"i.e.":[133],"annelated":[138],"five\u2010":[139],"six\u2010membered":[141],"ring.":[142],"In":[143],"case":[145],"1k,":[149],"both":[150],"(99":[154],"98%,":[156],"respectively)":[157],"glass":[160],"transition":[161],"temperatures":[162],"(Tg)":[163],"57":[165],"93":[167],"\u00b0C":[168],"significantly":[170],"higher":[171],"than":[172],"those":[173],"observed":[174],"1,1\u2010bis(ethoxycarbonyl)\u20102\u2010vinylcyclopropane":[179],"(DECVCP),":[180],"which":[181],"used":[183],"a":[185],"benchmark":[186],"monomer":[189],"reactivities":[190,211],"all":[196],"vinylcyclopropane":[198],"derivatives":[199],"1a\u2212n.":[200],"bicyclic":[202],"also":[207],"demonstrated":[208],"drastically":[209],"improved":[210],"copolymerization":[215],"methacrylate":[218],"when":[219],"compared":[220],"DECVCP.":[222],"(\u00a9":[223],"Wiley\u2010VCH":[224],"Verlag":[225],"GmbH":[226],"&":[227],"Co.":[228],"KGaA,":[229],"69451":[230],"Weinheim,":[231],"Germany,":[232],"2004)":[233]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":2},{"year":2019,"cited_by_count":1},{"year":2017,"cited_by_count":1},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":3},{"year":2013,"cited_by_count":4},{"year":2012,"cited_by_count":1}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}