{"id":"https://openalex.org/W2010600545","doi":"https://doi.org/10.1002/anie.198406211","title":"Structure of a \u201cY\u2010Conjugated\u201d Dilithium Salt of an \u03b1,\u03b1\u2032\u2010Keto Dianion: 1,3\u2010Dilithiodibenzyl Ketone\u2010(Me2NCH2CH2NMe2)2","display_name":"Structure of a \u201cY\u2010Conjugated\u201d Dilithium Salt of an \u03b1,\u03b1\u2032\u2010Keto Dianion: 1,3\u2010Dilithiodibenzyl Ketone\u2010(Me2NCH2CH2NMe2)2","publication_year":1984,"publication_date":"1984-08-01","ids":{"openalex":"https://openalex.org/W2010600545","doi":"https://doi.org/10.1002/anie.198406211","mag":"2010600545"},"language":"en","primary_location":{"id":"doi:10.1002/anie.198406211","doi":"https://doi.org/10.1002/anie.198406211","is_oa":false,"landing_page_url":"https://doi.org/10.1002/anie.198406211","pdf_url":null,"source":{"id":"https://openalex.org/S4394735490","display_name":"Angewandte Chemie International Edition in English","issn_l":"0570-0833","issn":["0570-0833"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition in English","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5108420989","display_name":"Hans Dietrich","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I2800875726","display_name":"Fritz Haber Institute of the Max Planck Society","ror":"https://ror.org/03k9qs827","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I2800875726"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Hans Dietrich","raw_affiliation_strings":["Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4\u20146, 1 Berlin 33"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4\u20146, 1 Berlin 33","institution_ids":["https://openalex.org/I2800875726"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110151148","display_name":"Waruno Mahdi","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I2800875726","display_name":"Fritz Haber Institute of the Max Planck Society","ror":"https://ror.org/03k9qs827","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I2800875726"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Waruno Mahdi","raw_affiliation_strings":["Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4\u20146, 1 Berlin 33"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4\u20146, 1 Berlin 33","institution_ids":["https://openalex.org/I2800875726"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5042517338","display_name":"Dieter Wilhelm","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I181369854","display_name":"Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg","ror":"https://ror.org/00f7hpc57","country_code":"DE","type":"education","lineage":["https://openalex.org/I181369854"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Dieter Wilhelm","raw_affiliation_strings":["Institut fu\u0308r Organische Chemie der Universita\u0308t Erlangen-Nu\u0308rnberg, Henkestrasse 42, D-8520 Erlangen (FRG)","Institut f\u00fcr Organische Chemie der Universit\u00e4t Erlangen\u2010Nurnberg, Henkestrasse 42, D\u20108520 Erlangen (FRG)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut fu\u0308r Organische Chemie der Universita\u0308t Erlangen-Nu\u0308rnberg, Henkestrasse 42, D-8520 Erlangen (FRG)","institution_ids":["https://openalex.org/I181369854"]},{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie der Universit\u00e4t Erlangen\u2010Nurnberg, Henkestrasse 42, D\u20108520 Erlangen (FRG)","institution_ids":["https://openalex.org/I181369854"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5017203543","display_name":"Timothy Clark","orcid":"https://orcid.org/0000-0001-7931-4659","observed_orcids":["https://orcid.org/0000-0001-7931-4659"]},"institutions":[{"id":"https://openalex.org/I181369854","display_name":"Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg","ror":"https://ror.org/00f7hpc57","country_code":"DE","type":"education","lineage":["https://openalex.org/I181369854"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Timothy Clark","raw_affiliation_strings":["Institut fu\u0308r Organische Chemie der Universita\u0308t Erlangen-Nu\u0308rnberg, Henkestrasse 42, D-8520 Erlangen (FRG)","Institut f\u00fcr Organische Chemie der Universit\u00e4t Erlangen\u2010Nurnberg, Henkestrasse 42, D\u20108520 Erlangen (FRG)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut fu\u0308r Organische Chemie der Universita\u0308t Erlangen-Nu\u0308rnberg, Henkestrasse 42, D-8520 Erlangen (FRG)","institution_ids":["https://openalex.org/I181369854"]},{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie der Universit\u00e4t Erlangen\u2010Nurnberg, Henkestrasse 42, D\u20108520 Erlangen (FRG)","institution_ids":["https://openalex.org/I181369854"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5109987002","display_name":"Paul von Ragu\u00e9 Schleyer","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I181369854","display_name":"Friedrich-Alexander-Universit\u00e4t Erlangen-N\u00fcrnberg","ror":"https://ror.org/00f7hpc57","country_code":"DE","type":"education","lineage":["https://openalex.org/I181369854"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Paul von Ragu\u00e9 Schleyer","raw_affiliation_strings":["Institut fu\u0308r Organische Chemie der Universita\u0308t Erlangen-Nu\u0308rnberg, Henkestrasse 42, D-8520 Erlangen (FRG)","Institut f\u00fcr Organische Chemie der Universit\u00e4t Erlangen\u2010Nurnberg, Henkestrasse 42, D\u20108520 Erlangen (FRG)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institut fu\u0308r Organische Chemie der Universita\u0308t Erlangen-Nu\u0308rnberg, Henkestrasse 42, D-8520 Erlangen (FRG)","institution_ids":["https://openalex.org/I181369854"]},{"raw_affiliation_string":"Institut f\u00fcr Organische Chemie der Universit\u00e4t Erlangen\u2010Nurnberg, Henkestrasse 42, D\u20108520 Erlangen (FRG)","institution_ids":["https://openalex.org/I181369854"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5108420989"],"corresponding_institution_ids":["https://openalex.org/I2800875726"],"apc_list":null,"apc_paid":null,"fwci":3.9199,"has_fulltext":false,"cited_by_count":14,"citation_normalized_percentile":{"value":0.93516997,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":null,"biblio":{"volume":"23","issue":"8","first_page":"621","last_page":"622"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12228","display_name":"Coordination Chemistry and Organometallics","score":0.9901999831199646,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12228","display_name":"Coordination Chemistry and Organometallics","score":0.9901999831199646,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.0034000000450760126,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.0013000000035390258,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/dilithium-salt","display_name":"dilithium salt","score":0.9279999732971191},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.628000020980835},{"id":"https://openalex.org/keywords/first-principles-calculations","display_name":"first-principles calculations","score":0.7160000205039978},{"id":"https://openalex.org/keywords/organolithium-reagents","display_name":"organolithium reagents","score":0.6570000052452087}],"concepts":[{"id":"https://openalex.org/C2775951159","wikidata":"https://www.wikidata.org/wiki/Q1189242","display_name":"Dilithium","level":4,"score":0.9281494617462158},{"id":"https://openalex.org/C2778153843","wikidata":"https://www.wikidata.org/wiki/Q6716898","display_name":"MNDO","level":3,"score":0.8958301544189453},{"id":"https://openalex.org/C2777738585","wikidata":"https://www.wikidata.org/wiki/Q170744","display_name":"Ketone","level":2,"score":0.6277952194213867},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5431848764419556},{"id":"https://openalex.org/C2781442258","wikidata":"https://www.wikidata.org/wiki/Q46310","display_name":"Ab initio","level":2,"score":0.5409679412841797},{"id":"https://openalex.org/C166940927","wikidata":"https://www.wikidata.org/wiki/Q178827","display_name":"Monomer","level":3,"score":0.4832797348499298},{"id":"https://openalex.org/C2776371256","wikidata":"https://www.wikidata.org/wiki/Q12370","display_name":"Salt (chemistry)","level":2,"score":0.47828373312950134},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.47369953989982605},{"id":"https://openalex.org/C183971685","wikidata":"https://www.wikidata.org/wiki/Q547605","display_name":"Ab initio quantum chemistry methods","level":3,"score":0.41082483530044556},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.348816454410553},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.23989617824554443},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.22864660620689392},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.11228284239768982},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.10755348205566406},{"id":"https://openalex.org/C118629725","wikidata":"https://www.wikidata.org/wiki/Q2686738","display_name":"Deprotonation","level":3,"score":0.0},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/anie.198406211","doi":"https://doi.org/10.1002/anie.198406211","is_oa":false,"landing_page_url":"https://doi.org/10.1002/anie.198406211","pdf_url":null,"source":{"id":"https://openalex.org/S4394735490","display_name":"Angewandte Chemie International Edition in English","issn_l":"0570-0833","issn":["0570-0833"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie International Edition in English","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":10,"referenced_works":["https://openalex.org/W1965157030","https://openalex.org/W1971434300","https://openalex.org/W1976106600","https://openalex.org/W2016664886","https://openalex.org/W2065591703","https://openalex.org/W2071467252","https://openalex.org/W2074656443","https://openalex.org/W2134767505","https://openalex.org/W3005068429","https://openalex.org/W4236225826"],"related_works":["https://openalex.org/W2050508983","https://openalex.org/W2134767505","https://openalex.org/W2047295871","https://openalex.org/W3005309592","https://openalex.org/W2059149507","https://openalex.org/W1995215486","https://openalex.org/W1969473166","https://openalex.org/W1998388054","https://openalex.org/W2102371678","https://openalex.org/W2030142860"],"abstract_inverted_index":{"The":[0],"first":[1],"X\u2010ray":[2],"structure":[3,35],"analysis":[4],"of":[5,31],"a":[6],"monomeric":[7],"dilithium":[8],"salt":[9],"with":[10,36],"an":[11,52],"\u03b1,\u03b1\u2032\u2010keto":[12],"dianion":[13],"was":[14],"successfully":[15],"carried":[16],"out":[17],"on":[18],"the":[19,32],"TMEDA":[20],"complex":[21],"1.":[22],"With":[23],"approximate":[24],"C2":[25],"symmetry,":[26],"1":[27],"is":[28],"chiral.":[29],"Comparison":[30],"experimentally":[33],"determined":[34],"that":[37],"calculated":[38],"semiempirically":[39],"(MNDO)":[40],"reveals":[41],"good":[42],"overall":[43],"agreement.":[44],"According":[45],"to":[46],"ab":[47],"initio":[48],"calculations,":[49],"2":[50],"has":[51],"analogous":[53],"structure.":[54],"equation":[55],"image":[56]},"counts_by_year":[],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}