{"id":"https://openalex.org/W2010398740","doi":"https://doi.org/10.1021/ja00771a058","title":"Decomposition of azo compounds via cationic intermediates. Elucidation of the mechanism of ionization and nitrogen elimination","display_name":"Decomposition of azo compounds via cationic intermediates. Elucidation of the mechanism of ionization and nitrogen elimination","publication_year":1972,"publication_date":"1972-08-01","ids":{"openalex":"https://openalex.org/W2010398740","doi":"https://doi.org/10.1021/ja00771a058","mag":"2010398740"},"language":"en","primary_location":{"id":"doi:10.1021/ja00771a058","doi":"https://doi.org/10.1021/ja00771a058","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja00771a058","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5018213765","display_name":"Evan L. Allred","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Evan L. Allred","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":null,"display_name":"Charles R. Flynn","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Charles R. Flynn","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.3304,"has_fulltext":false,"cited_by_count":2,"citation_normalized_percentile":{"value":0.73947935,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":"94","issue":"16","first_page":"5891","last_page":"5893"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12191","display_name":"Chemical Reaction Mechanisms","score":0.9384999871253967,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12191","display_name":"Chemical Reaction Mechanisms","score":0.9384999871253967,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13253","display_name":"Chemical Reactions and Mechanisms","score":0.04280000180006027,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T14068","display_name":"Organic and Inorganic Chemical Reactions","score":0.006000000052154064,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/azo-compounds","display_name":"azo compounds","score":0.9990000128746033},{"id":"https://openalex.org/keywords/cationic-intermediates","display_name":"cationic intermediates","score":0.8709999918937683},{"id":"https://openalex.org/keywords/decomposition-mechanism","display_name":"decomposition mechanism","score":0.7879999876022339},{"id":"https://openalex.org/keywords/ionization-processes","display_name":"ionization mechanisms","score":0.8059999942779541},{"id":"https://openalex.org/keywords/nitrogen-removal","display_name":"nitrogen removal","score":0.9810000061988831},{"id":"https://openalex.org/keywords/azo-bond-cleavage","display_name":"azo bond cleavage","score":0.5889999866485596},{"id":"https://openalex.org/keywords/reaction-kinetics","display_name":"reaction kinetics","score":0.3619999885559082}],"concepts":[{"id":"https://openalex.org/C2778805511","wikidata":"https://www.wikidata.org/wiki/Q1713","display_name":"Citation","level":2,"score":0.626996636390686},{"id":"https://openalex.org/C183882617","wikidata":"https://www.wikidata.org/wiki/Q3046749","display_name":"Cationic polymerization","level":2,"score":0.6258372664451599},{"id":"https://openalex.org/C124681953","wikidata":"https://www.wikidata.org/wiki/Q339062","display_name":"Decomposition","level":2,"score":0.5263458490371704},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.5042246580123901},{"id":"https://openalex.org/C89611455","wikidata":"https://www.wikidata.org/wiki/Q6804646","display_name":"Mechanism (biology)","level":2,"score":0.4542331397533417},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.419716477394104},{"id":"https://openalex.org/C23123220","wikidata":"https://www.wikidata.org/wiki/Q816826","display_name":"Information retrieval","level":1,"score":0.3818384110927582},{"id":"https://openalex.org/C161191863","wikidata":"https://www.wikidata.org/wiki/Q199655","display_name":"Library science","level":1,"score":0.360757976770401},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.14958837628364563},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.12767678499221802},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/ja00771a058","doi":"https://doi.org/10.1021/ja00771a058","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja00771a058","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2020002343","https://openalex.org/W2949302460","https://openalex.org/W3005443560","https://openalex.org/W1536233480","https://openalex.org/W1972761774","https://openalex.org/W2320691895","https://openalex.org/W2319247654","https://openalex.org/W4412490321","https://openalex.org/W4238827537","https://openalex.org/W1968772816"],"abstract_inverted_index":{"ADVERTISEMENT":[0],"RETURN":[1],"TO":[2],"ISSUEPREVArticleNEXTDecomposition":[3],"of":[4,11,14,59,94,120],"azo":[5],"compounds":[6],"via":[7],"cationic":[8],"intermediates.":[9],"Elucidation":[10],"the":[12,56,87,92,121,132,145,148,153,160,166],"mechanism":[13],"ionization":[15],"and":[16,21,69,74,103,147,164,180,182],"nitrogen":[17],"eliminationEvan":[18],"L.":[19],"Allred":[20],"Charles":[22],"R.":[23],"FlynnCite":[24],"this:":[25],"J.":[26],"Am.":[27],"Chem.":[28],"Soc.":[29],"1972,":[30],"94,":[31],"16,":[32],"5891\u20135893Publication":[33],"Date":[34],"(Print):August":[35],"1,":[36],"1972Publication":[37],"History":[38],"Published":[39],"online1":[40],"May":[41],"2002Published":[42],"inissue":[43],"1":[44],"August":[45],"1972https://pubs.acs.org/doi/10.1021/ja00771a058https://doi.org/10.1021/ja00771a058research-articleACS":[46],"PublicationsRequest":[47],"reuse":[48],"permissionsArticle":[49],"Views41Altmetric-Citations2LEARN":[50],"ABOUT":[51],"THESE":[52],"METRICSArticle":[53],"Views":[54],"are":[55,78,91],"COUNTER-compliant":[57],"sum":[58],"full":[60],"text":[61],"article":[62,126],"downloads":[63],"since":[64],"November":[65],"2008":[66],"(both":[67],"PDF":[68],"HTML)":[70],"across":[71],"all":[72],"institutions":[73],"individuals.":[75],"These":[76],"metrics":[77],"regularly":[79],"updated":[80,104],"to":[81,86],"reflect":[82],"usage":[83],"leading":[84],"up":[85],"last":[88],"few":[89],"days.Citations":[90],"number":[93],"other":[95],"articles":[96],"citing":[97],"this":[98],"article,":[99],"calculated":[100],"by":[101],"Crossref":[102,110],"daily.":[105],"Find":[106,156],"more":[107,157],"information":[108,158],"about":[109,144],"citation":[111],"counts.The":[112],"Altmetric":[113,161],"Attention":[114,162],"Score":[115,163],"is":[116,168],"a":[117,124,137],"quantitative":[118],"measure":[119],"attention":[122],"that":[123],"research":[125],"has":[127],"received":[128],"online.":[129],"Clicking":[130],"on":[131,159],"donut":[133],"icon":[134],"will":[135],"load":[136],"page":[138],"at":[139],"altmetric.com":[140],"with":[141,176],"additional":[142],"details":[143],"score":[146,167],"social":[149],"media":[150],"presence":[151],"for":[152],"given":[154],"article.":[155],"how":[165],"calculated.":[169],"Share":[170,185],"Add":[171],"toView":[172],"InAdd":[173],"Full":[174],"Text":[175],"ReferenceAdd":[177],"Description":[178],"ExportRISCitationCitation":[179],"abstractCitation":[181],"referencesMore":[183],"Options":[184],"onFacebookTwitterWechatLinked":[186],"InRedditEmail":[187],"Other":[188],"access":[189],"optionsGet":[190],"e-Alertsclose":[191],"Get":[192],"e-Alerts":[193]},"counts_by_year":[],"updated_date":"2026-09-29T14:09:16.559479","created_date":"2016-06-24T00:00:00"}