{"id":"https://openalex.org/W2010189574","doi":"https://doi.org/10.1021/ic060796o","title":"Highly Phosphorescent Iridium Complexes Containing Both Tridentate Bis(benzimidazolyl)-benzene or -pyridine and Bidentate Phenylpyridine: Synthesis, Photophysical Properties, and Theoretical Study of Ir-Bis(benzimidazolyl)benzene Complex","display_name":"Highly Phosphorescent Iridium Complexes Containing Both Tridentate Bis(benzimidazolyl)-benzene or -pyridine and Bidentate Phenylpyridine: Synthesis, Photophysical Properties, and Theoretical Study of Ir-Bis(benzimidazolyl)benzene Complex","publication_year":2006,"publication_date":"2006-09-29","ids":{"openalex":"https://openalex.org/W2010189574","doi":"https://doi.org/10.1021/ic060796o","mag":"2010189574","pmid":"https://pubmed.ncbi.nlm.nih.gov/17054350"},"language":"en","primary_location":{"id":"doi:10.1021/ic060796o","doi":"https://doi.org/10.1021/ic060796o","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic060796o","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5025301315","display_name":"Shinya Obara","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210087728","display_name":"Idemitsu Kosan (Japan)","ror":"https://ror.org/002v59719","country_code":"JP","type":"company","lineage":["https://openalex.org/I4210087728"]},{"id":"https://openalex.org/I96679780","display_name":"Chuo University","ror":"https://ror.org/03qvqb743","country_code":"JP","type":"education","lineage":["https://openalex.org/I96679780"]},{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Shinya Obara","raw_affiliation_strings":["Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan, Department of Chemistry, Graduate School of Science, Osaka University, 1-16, Machikaneyama, Toyonaka, Osaka 560-0043, Japan, and Central Research Laboratories, Idemitsu Kosan Co., Ltd., 1280 Kami-Izumi, Sodegaura, Chiba 299-293, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan, Department of Chemistry, Graduate School of Science, Osaka University, 1-16, Machikaneyama, Toyonaka, Osaka 560-0043, Japan, and Central Research Laboratories, Idemitsu Kosan Co., Ltd., 1280 Kami-Izumi, Sodegaura, Chiba 299-293, Japan","institution_ids":["https://openalex.org/I4210087728","https://openalex.org/I96679780","https://openalex.org/I98285908"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5005381913","display_name":"Masumi Itabashi","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210087728","display_name":"Idemitsu Kosan (Japan)","ror":"https://ror.org/002v59719","country_code":"JP","type":"company","lineage":["https://openalex.org/I4210087728"]},{"id":"https://openalex.org/I96679780","display_name":"Chuo University","ror":"https://ror.org/03qvqb743","country_code":"JP","type":"education","lineage":["https://openalex.org/I96679780"]},{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Masumi Itabashi","raw_affiliation_strings":["Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan, Department of Chemistry, Graduate School of Science, Osaka University, 1-16, Machikaneyama, Toyonaka, Osaka 560-0043, Japan, and Central Research Laboratories, Idemitsu Kosan Co., Ltd., 1280 Kami-Izumi, Sodegaura, Chiba 299-293, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan, Department of Chemistry, Graduate School of Science, Osaka University, 1-16, Machikaneyama, Toyonaka, Osaka 560-0043, Japan, and Central Research Laboratories, Idemitsu Kosan Co., Ltd., 1280 Kami-Izumi, Sodegaura, Chiba 299-293, Japan","institution_ids":["https://openalex.org/I4210087728","https://openalex.org/I96679780","https://openalex.org/I98285908"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5008514391","display_name":"Fumio Okuda","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210087728","display_name":"Idemitsu Kosan (Japan)","ror":"https://ror.org/002v59719","country_code":"JP","type":"company","lineage":["https://openalex.org/I4210087728"]},{"id":"https://openalex.org/I96679780","display_name":"Chuo University","ror":"https://ror.org/03qvqb743","country_code":"JP","type":"education","lineage":["https://openalex.org/I96679780"]},{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Fumio Okuda","raw_affiliation_strings":["Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan, Department of Chemistry, Graduate School of Science, Osaka University, 1-16, Machikaneyama, Toyonaka, Osaka 560-0043, Japan, and Central Research Laboratories, Idemitsu Kosan Co., Ltd., 1280 Kami-Izumi, Sodegaura, Chiba 299-293, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan, Department of Chemistry, Graduate School of Science, Osaka University, 1-16, Machikaneyama, Toyonaka, Osaka 560-0043, Japan, and Central Research Laboratories, Idemitsu Kosan Co., Ltd., 1280 Kami-Izumi, Sodegaura, Chiba 299-293, Japan","institution_ids":["https://openalex.org/I4210087728","https://openalex.org/I96679780","https://openalex.org/I98285908"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5039479435","display_name":"Satoru Tamaki","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210087728","display_name":"Idemitsu Kosan (Japan)","ror":"https://ror.org/002v59719","country_code":"JP","type":"company","lineage":["https://openalex.org/I4210087728"]},{"id":"https://openalex.org/I96679780","display_name":"Chuo University","ror":"https://ror.org/03qvqb743","country_code":"JP","type":"education","lineage":["https://openalex.org/I96679780"]},{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Satoru Tamaki","raw_affiliation_strings":["Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan, Department of Chemistry, Graduate School of Science, Osaka University, 1-16, Machikaneyama, Toyonaka, Osaka 560-0043, Japan, and Central Research Laboratories, Idemitsu Kosan Co., Ltd., 1280 Kami-Izumi, Sodegaura, Chiba 299-293, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan, Department of Chemistry, Graduate School of Science, Osaka University, 1-16, Machikaneyama, Toyonaka, Osaka 560-0043, Japan, and Central Research Laboratories, Idemitsu Kosan Co., Ltd., 1280 Kami-Izumi, Sodegaura, Chiba 299-293, Japan","institution_ids":["https://openalex.org/I4210087728","https://openalex.org/I96679780","https://openalex.org/I98285908"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5042344549","display_name":"Yoshiaki Tanabe","orcid":"https://orcid.org/0000-0001-5858-7834","observed_orcids":["https://orcid.org/0000-0001-5858-7834"]},"institutions":[{"id":"https://openalex.org/I4210087728","display_name":"Idemitsu Kosan (Japan)","ror":"https://ror.org/002v59719","country_code":"JP","type":"company","lineage":["https://openalex.org/I4210087728"]},{"id":"https://openalex.org/I96679780","display_name":"Chuo University","ror":"https://ror.org/03qvqb743","country_code":"JP","type":"education","lineage":["https://openalex.org/I96679780"]},{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Yoshiaki Tanabe","raw_affiliation_strings":["Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan, Department of Chemistry, Graduate School of Science, Osaka University, 1-16, Machikaneyama, Toyonaka, Osaka 560-0043, Japan, and Central Research Laboratories, Idemitsu Kosan Co., Ltd., 1280 Kami-Izumi, Sodegaura, Chiba 299-293, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan, Department of Chemistry, Graduate School of Science, Osaka University, 1-16, Machikaneyama, Toyonaka, Osaka 560-0043, Japan, and Central Research Laboratories, Idemitsu Kosan Co., Ltd., 1280 Kami-Izumi, Sodegaura, Chiba 299-293, Japan","institution_ids":["https://openalex.org/I4210087728","https://openalex.org/I96679780","https://openalex.org/I98285908"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036717014","display_name":"Youichi Ishii","orcid":"https://orcid.org/0000-0002-1914-7147","observed_orcids":["https://orcid.org/0000-0002-1914-7147"]},"institutions":[{"id":"https://openalex.org/I4210087728","display_name":"Idemitsu Kosan (Japan)","ror":"https://ror.org/002v59719","country_code":"JP","type":"company","lineage":["https://openalex.org/I4210087728"]},{"id":"https://openalex.org/I96679780","display_name":"Chuo University","ror":"https://ror.org/03qvqb743","country_code":"JP","type":"education","lineage":["https://openalex.org/I96679780"]},{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Youichi Ishii","raw_affiliation_strings":["Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan, Department of Chemistry, Graduate School of Science, Osaka University, 1-16, Machikaneyama, Toyonaka, Osaka 560-0043, Japan, and Central Research Laboratories, Idemitsu Kosan Co., Ltd., 1280 Kami-Izumi, Sodegaura, Chiba 299-293, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan, Department of Chemistry, Graduate School of Science, Osaka University, 1-16, Machikaneyama, Toyonaka, Osaka 560-0043, Japan, and Central Research Laboratories, Idemitsu Kosan Co., Ltd., 1280 Kami-Izumi, Sodegaura, Chiba 299-293, Japan","institution_ids":["https://openalex.org/I4210087728","https://openalex.org/I96679780","https://openalex.org/I98285908"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5081419516","display_name":"Koichi Nozaki","orcid":"https://orcid.org/0000-0003-4164-3697","observed_orcids":["https://orcid.org/0000-0003-4164-3697"]},"institutions":[{"id":"https://openalex.org/I4210087728","display_name":"Idemitsu Kosan (Japan)","ror":"https://ror.org/002v59719","country_code":"JP","type":"company","lineage":["https://openalex.org/I4210087728"]},{"id":"https://openalex.org/I96679780","display_name":"Chuo University","ror":"https://ror.org/03qvqb743","country_code":"JP","type":"education","lineage":["https://openalex.org/I96679780"]},{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Koichi Nozaki","raw_affiliation_strings":["Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan, Department of Chemistry, Graduate School of Science, Osaka University, 1-16, Machikaneyama, Toyonaka, Osaka 560-0043, Japan, and Central Research Laboratories, Idemitsu Kosan Co., Ltd., 1280 Kami-Izumi, Sodegaura, Chiba 299-293, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan, Department of Chemistry, Graduate School of Science, Osaka University, 1-16, Machikaneyama, Toyonaka, Osaka 560-0043, Japan, and Central Research Laboratories, Idemitsu Kosan Co., Ltd., 1280 Kami-Izumi, Sodegaura, Chiba 299-293, Japan","institution_ids":["https://openalex.org/I4210087728","https://openalex.org/I96679780","https://openalex.org/I98285908"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5053601852","display_name":"Masa\u2010aki Haga","orcid":"https://orcid.org/0000-0002-1230-3848","observed_orcids":["https://orcid.org/0000-0002-1230-3848"]},"institutions":[{"id":"https://openalex.org/I4210087728","display_name":"Idemitsu Kosan (Japan)","ror":"https://ror.org/002v59719","country_code":"JP","type":"company","lineage":["https://openalex.org/I4210087728"]},{"id":"https://openalex.org/I96679780","display_name":"Chuo University","ror":"https://ror.org/03qvqb743","country_code":"JP","type":"education","lineage":["https://openalex.org/I96679780"]},{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Masa-aki Haga","raw_affiliation_strings":["Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan, Department of Chemistry, Graduate School of Science, Osaka University, 1-16, Machikaneyama, Toyonaka, Osaka 560-0043, Japan, and Central Research Laboratories, Idemitsu Kosan Co., Ltd., 1280 Kami-Izumi, Sodegaura, Chiba 299-293, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Applied Chemistry, Faculty of Science and Engineering, Chuo University, 1-13-27, Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan, Department of Chemistry, Graduate School of Science, Osaka University, 1-16, Machikaneyama, Toyonaka, Osaka 560-0043, Japan, and Central Research Laboratories, Idemitsu Kosan Co., Ltd., 1280 Kami-Izumi, Sodegaura, Chiba 299-293, Japan","institution_ids":["https://openalex.org/I4210087728","https://openalex.org/I96679780","https://openalex.org/I98285908"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5053601852","https://openalex.org/A5081419516"],"corresponding_institution_ids":["https://openalex.org/I4210087728","https://openalex.org/I96679780","https://openalex.org/I98285908"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":9.8431,"has_fulltext":false,"cited_by_count":213,"citation_normalized_percentile":{"value":0.98343111,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":95,"max":100},"biblio":{"volume":"45","issue":"22","first_page":"8907","last_page":"8921"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10611","display_name":"Organic Light-Emitting Diodes Research","score":0.9878000020980835,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10611","display_name":"Organic Light-Emitting Diodes Research","score":0.9878000020980835,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11279","display_name":"Lanthanide and Transition Metal Complexes","score":0.004100000020116568,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11240","display_name":"Luminescence and Fluorescent Materials","score":0.0034000000450760126,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/iridium-iii-complexes","display_name":"iridium(III) complexes","score":0.9539999961853027},{"id":"https://openalex.org/keywords/phosphorescence","display_name":"phosphorescence","score":0.8980000019073486},{"id":"https://openalex.org/keywords/mixed-ligand-complexes","display_name":"mixed-ligand complexes","score":0.7919999957084656},{"id":"https://openalex.org/keywords/phenylpyridine","display_name":"phenylpyridine","score":0.8740000128746033},{"id":"https://openalex.org/keywords/oxidation-potential","display_name":"oxidation potential","score":0.628000020980835},{"id":"https://openalex.org/keywords/redox-potential","display_name":"redox potential","score":0.8980000019073486},{"id":"https://openalex.org/keywords/metal-to-ligand-charge-transfer","display_name":"metal-to-ligand charge transfer","score":0.9340000152587891},{"id":"https://openalex.org/keywords/triplet-state","display_name":"triplet state","score":0.5979999899864197},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.6100000143051147},{"id":"https://openalex.org/keywords/photophysical-properties","display_name":"photophysical properties","score":0.5389999747276306}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9170952439308167},{"id":"https://openalex.org/C528581852","wikidata":"https://www.wikidata.org/wiki/Q877","display_name":"Iridium","level":3,"score":0.8351069688796997},{"id":"https://openalex.org/C2779485729","wikidata":"https://www.wikidata.org/wiki/Q210385","display_name":"Pyridine","level":2,"score":0.7413239479064941},{"id":"https://openalex.org/C181817918","wikidata":"https://www.wikidata.org/wiki/Q192275","display_name":"Phosphorescence","level":3,"score":0.7385320663452148},{"id":"https://openalex.org/C2777691172","wikidata":"https://www.wikidata.org/wiki/Q2270","display_name":"Benzene","level":2,"score":0.6437541246414185},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.6115967631340027},{"id":"https://openalex.org/C178516000","wikidata":"https://www.wikidata.org/wiki/Q3023362","display_name":"Denticity","level":3,"score":0.605093240737915},{"id":"https://openalex.org/C153642686","wikidata":"https://www.wikidata.org/wiki/Q70906","display_name":"Infrared spectroscopy","level":2,"score":0.49356329441070557},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.4528133273124695},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.4464518129825592},{"id":"https://openalex.org/C2780591471","wikidata":"https://www.wikidata.org/wiki/Q410915","display_name":"Biphenyl","level":2,"score":0.44161728024482727},{"id":"https://openalex.org/C33062035","wikidata":"https://www.wikidata.org/wiki/Q3296863","display_name":"Singlet state","level":3,"score":0.41633865237236023},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.38222837448120117},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.32306742668151855},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.11502060294151306},{"id":"https://openalex.org/C91881484","wikidata":"https://www.wikidata.org/wiki/Q191807","display_name":"Fluorescence","level":2,"score":0.10223543643951416},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.06738635897636414},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C185544564","wikidata":"https://www.wikidata.org/wiki/Q81197","display_name":"Nuclear physics","level":1,"score":0.0},{"id":"https://openalex.org/C181500209","wikidata":"https://www.wikidata.org/wiki/Q215328","display_name":"Excited state","level":2,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/ic060796o","doi":"https://doi.org/10.1021/ic060796o","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ic060796o","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmid:17054350","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/17054350","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":60,"referenced_works":["https://openalex.org/W28217284","https://openalex.org/W212929038","https://openalex.org/W244463721","https://openalex.org/W261663411","https://openalex.org/W271008867","https://openalex.org/W1487348743","https://openalex.org/W1512388082","https://openalex.org/W1668566020","https://openalex.org/W1965632157","https://openalex.org/W1967210431","https://openalex.org/W1976387749","https://openalex.org/W1981258792","https://openalex.org/W1981988181","https://openalex.org/W1982490750","https://openalex.org/W1987741147","https://openalex.org/W1988111430","https://openalex.org/W1993953045","https://openalex.org/W1996005246","https://openalex.org/W1998062380","https://openalex.org/W2000614287","https://openalex.org/W2010459093","https://openalex.org/W2014279890","https://openalex.org/W2015496655","https://openalex.org/W2015982828","https://openalex.org/W2018626355","https://openalex.org/W2020114693","https://openalex.org/W2020933326","https://openalex.org/W2022573775","https://openalex.org/W2029634804","https://openalex.org/W2030687437","https://openalex.org/W2033419889","https://openalex.org/W2035042188","https://openalex.org/W2038533471","https://openalex.org/W2041391739","https://openalex.org/W2044349973","https://openalex.org/W2052212603","https://openalex.org/W2052329392","https://openalex.org/W2052623480","https://openalex.org/W2054355767","https://openalex.org/W2066774243","https://openalex.org/W2066877229","https://openalex.org/W2068617439","https://openalex.org/W2076060557","https://openalex.org/W2090833337","https://openalex.org/W2095374362","https://openalex.org/W2108446403","https://openalex.org/W2117894566","https://openalex.org/W2123195204","https://openalex.org/W2123491942","https://openalex.org/W2126952850","https://openalex.org/W2132570683","https://openalex.org/W2143981217","https://openalex.org/W2151256381","https://openalex.org/W2152745328","https://openalex.org/W2154776619","https://openalex.org/W2158422033","https://openalex.org/W2166052839","https://openalex.org/W2176103595","https://openalex.org/W4293208197","https://openalex.org/W4388155256"],"related_works":["https://openalex.org/W2005707910","https://openalex.org/W2080871064","https://openalex.org/W2014279890","https://openalex.org/W2385926390","https://openalex.org/W4211220644","https://openalex.org/W2051475491","https://openalex.org/W2061806680","https://openalex.org/W3214790921","https://openalex.org/W4200420391","https://openalex.org/W1996209464"],"abstract_inverted_index":{"Novel":[0],"mixed-ligand":[1],"Ir(III)":[2],"complexes,":[3,102,303],"[Ir(L)(NwedgeC)X]n+":[4],"(L":[5,169,305],"=":[6,11,20,28,35,40,53,170,219,235,242,251,272,306],"N/\\C/\\N":[7],"or":[8,17,22,74,308],"N/\\N/\\N;":[9],"X":[10,146,234,241],"Cl,":[12],"Br,":[13],"I,":[14],"CN,":[15],"CH3CN,":[16],"-CCPh;":[18],"n":[19],"0":[21],"1),":[23],"were":[24,104],"synthesized,":[25],"where":[26],"N/\\CwedgeN":[27],"bis(N-methylbenzimidazolyl)benzene":[29],"(Mebib)":[30],"and":[31,38,50,145,172,174,196,237,298,315,345,376],"bis(N-phenylbenzimidazolyl)benzene":[32],"(Phbib),":[33],"N/\\N/\\N":[34],"bis(N-methylbenzimidazolyl)pyridine":[36],"(Mebip),":[37],"N/\\C":[39],"phenylpyridine":[41],"(ppy)":[42],"derivatives.":[43],"The":[44,111,179,224,331,350],"X-ray":[45],"crystal":[46],"structures":[47],"of":[48,60,87,113,124,135,142,182,217,226,270,283,294,365,369],"[Ir(Phbib)(ppy)Cl]":[49,258],"[Ir(Mebib)(mppy)Cl]":[51],"[mppy":[52],"5-methyl-2-(2'-pyridyl)phenyl]":[54],"indicate":[55],"that":[56,337],"the":[57,61,68,77,84,100,132,140,150,153,245,260,290,295,300,363,366],"nitrogen":[58],"atom":[59,71,80],"ppy":[62,82],"ligand":[63],"is":[64,275,359],"located":[65],"trans":[66,85],"to":[67,149,164,281,289,326],"coordinating":[69,78],"carbon":[70,79],"in":[72,81,117,127,357],"Me-":[73,307],"Phbib,":[75],"while":[76,99],"occupies":[83],"position":[86],"Cl.":[88],"[Ir(Mebip)(ppy)Cl]+":[89,207],"showed":[90],"a":[91,120,128,185,197,213,266,353,377],"quasireversible":[92],"Ir(III/IV)":[93],"oxidation":[94,133,151],"wave":[95],"at":[96,106,162,202,209,221,230,255,262],"+1.05":[97],"V,":[98],"Ir":[101,302,339],"[Ir(Mebib)(ppy)Cl],":[103],"oxidized":[105],"+0.42":[107],"V":[108,126,166,176],"versus":[109],"Fc/Fc+.":[110],"introduction":[112],"an":[114,158,276],"Ir-C":[115],"bond":[116],"[Ir(Mebib)(ppy)Cl]":[118],"induces":[119],"large":[121,316],"potential":[122,134,156],"shift":[123],"0.63":[125],"negative":[129],"direction.":[130],"Further,":[131],"[Ir(Mebib)(Rppy)X]":[136],"was":[137,228],"altered":[138],"by":[139],"substitution":[141],"R,":[143],"R',":[144],"groups.":[147],"Compared":[148,288],"potential,":[152],"first":[154],"reduction":[155],"revealed":[157],"almost":[159],"constant":[160],"value":[161,279],"-2.36":[163],"-2.46":[165],"for":[167,177,233,240,352],"[Ir(L)(ppy)Cl]":[168],"Mebib":[171],"Phbib)":[173],"-1.52":[175],"[Ir(Mebip)(ppy)Cl.":[178],"UV-vis":[180],"spectra":[181],"[Ir(Mebib)(R-ppy)X]":[183],"show":[184],"clear":[186],"singlet":[187],"metal-to-ligand":[188,199,343],"charge-transfer":[189,200,344,347],"transition":[190,201],"around":[191],"407":[192],"approximately":[193,204,253],"425":[194],"nm":[195,211,232,239,264],"triplet":[198],"498":[203],"523":[205],"nm.":[206],"emits":[208],"610":[210],"with":[212,244,265],"luminescent":[214,247,267,291],"quantum":[215,248,268,292,313],"yield":[216,269,356],"Phi":[218,250,271],"0.16":[220],"room":[222,256],"temperature.":[223,257],"phosphorescence":[225,355],"[Ir(Mebib)(ppy)X]":[227],"observed":[229],"526":[231],"CN":[236],"555":[238],"Cl":[243],"high":[246,278,312,354],"yields,":[249],"0.77":[252],"0.86,":[254],"shows":[259],"emission":[261],"559":[263],"0.95,":[273],"which":[274],"unprecedentedly":[277],"compared":[280],"those":[282],"other":[284],"emissive":[285],"metal":[286],"complexes.":[287],"yields":[293,314],"Ir(ppy)2(L)":[296],"derivatives":[297],"[Ir(Mebip)(ppy)Cl]+,":[299],"neutral":[301],"[Ir(L)(R-ppy)X]":[304],"Phbib),":[309],"reveal":[310],"very":[311],"radiative":[317,370],"rate":[318,371],"constants":[319,372],"(kr)":[320],"ranging":[321],"from":[322,362],"3.4":[323],"x":[324,328],"10(5)":[325,329],"5.5":[327],"s(-1).":[330],"density":[332],"functional":[333],"theory":[334,375],"calculation":[335],"suggests":[336],"these":[338],"complexes":[340],"possess":[341],"dominantly":[342],"halide-to-ligand":[346],"excited":[348],"states.":[349],"mechanism":[351],"[Ir(bib)(ppy)X]":[358],"discussed":[360],"herein":[361],"perspective":[364],"theoretical":[367],"consideration":[368],"using":[373],"perturbation":[374],"one-center":[378],"spin-orbit":[379],"coupling":[380],"approximation.":[381]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":3},{"year":2024,"cited_by_count":5},{"year":2023,"cited_by_count":8},{"year":2022,"cited_by_count":4},{"year":2021,"cited_by_count":9},{"year":2020,"cited_by_count":12},{"year":2019,"cited_by_count":9},{"year":2018,"cited_by_count":14},{"year":2017,"cited_by_count":19},{"year":2016,"cited_by_count":15},{"year":2015,"cited_by_count":16},{"year":2014,"cited_by_count":11},{"year":2013,"cited_by_count":14},{"year":2012,"cited_by_count":13}],"updated_date":"2026-11-12T12:28:57.059296","created_date":"2016-06-24T00:00:00"}