{"id":"https://openalex.org/W2010047136","doi":"https://doi.org/10.1021/bi000965v","title":"Resonance Raman Studies of the Stoichiometric Catalytic Turnover of a Substrate\u2212Stearoyl-Acyl Carrier Protein \u03949 Desaturase Complex","display_name":"Resonance Raman Studies of the Stoichiometric Catalytic Turnover of a Substrate\u2212Stearoyl-Acyl Carrier Protein \u03949 Desaturase Complex","publication_year":2000,"publication_date":"2000-08-01","ids":{"openalex":"https://openalex.org/W2010047136","doi":"https://doi.org/10.1021/bi000965v","mag":"2010047136","pmid":"https://pubmed.ncbi.nlm.nih.gov/10956041"},"language":"en","primary_location":{"id":"doi:10.1021/bi000965v","doi":"https://doi.org/10.1021/bi000965v","is_oa":false,"landing_page_url":"https://doi.org/10.1021/bi000965v","pdf_url":null,"source":{"id":"https://openalex.org/S104038378","display_name":"Biochemistry","issn_l":"0006-2960","issn":["0006-2960","1520-4995","1943-295X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","doyens","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Biochemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5112529946","display_name":"Karen S. Lyle","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1304256225","display_name":"University of Wisconsin System","ror":"https://ror.org/03ydkyb10","country_code":"US","type":"education","lineage":["https://openalex.org/I1304256225"]},{"id":"https://openalex.org/I135310074","display_name":"University of Wisconsin\u2013Madison","ror":"https://ror.org/01y2jtd41","country_code":"US","type":"education","lineage":["https://openalex.org/I135310074"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Karen S. Lyle","raw_affiliation_strings":["Department of Biochemistry, College of Agricultural and Life Sciences, University of Wisconsin, Madison, Wisconsin 53706-1544, and Department of Biochemistry and Molecular Biology, Oregon Graduate Institute of Science and Technology, Beaverton, Oregon 97006-8921"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Biochemistry, College of Agricultural and Life Sciences, University of Wisconsin, Madison, Wisconsin 53706-1544, and Department of Biochemistry and Molecular Biology, Oregon Graduate Institute of Science and Technology, Beaverton, Oregon 97006-8921","institution_ids":["https://openalex.org/I1304256225","https://openalex.org/I135310074"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5079246484","display_name":"Pierre Mo\u00ebnne\u2010Loccoz","orcid":"https://orcid.org/0000-0002-7684-7617","observed_orcids":["https://orcid.org/0000-0002-7684-7617"]},"institutions":[{"id":"https://openalex.org/I1304256225","display_name":"University of Wisconsin System","ror":"https://ror.org/03ydkyb10","country_code":"US","type":"education","lineage":["https://openalex.org/I1304256225"]},{"id":"https://openalex.org/I135310074","display_name":"University of Wisconsin\u2013Madison","ror":"https://ror.org/01y2jtd41","country_code":"US","type":"education","lineage":["https://openalex.org/I135310074"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Pierre M\u00f6enne-Loccoz","raw_affiliation_strings":["Department of Biochemistry, College of Agricultural and Life Sciences, University of Wisconsin, Madison, Wisconsin 53706-1544, and Department of Biochemistry and Molecular Biology, Oregon Graduate Institute of Science and Technology, Beaverton, Oregon 97006-8921"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Biochemistry, College of Agricultural and Life Sciences, University of Wisconsin, Madison, Wisconsin 53706-1544, and Department of Biochemistry and Molecular Biology, Oregon Graduate Institute of Science and Technology, Beaverton, Oregon 97006-8921","institution_ids":["https://openalex.org/I1304256225","https://openalex.org/I135310074"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5112470378","display_name":"Jingyuan Ai","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1304256225","display_name":"University of Wisconsin System","ror":"https://ror.org/03ydkyb10","country_code":"US","type":"education","lineage":["https://openalex.org/I1304256225"]},{"id":"https://openalex.org/I135310074","display_name":"University of Wisconsin\u2013Madison","ror":"https://ror.org/01y2jtd41","country_code":"US","type":"education","lineage":["https://openalex.org/I135310074"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jingyuan Ai","raw_affiliation_strings":["Department of Biochemistry, College of Agricultural and Life Sciences, University of Wisconsin, Madison, Wisconsin 53706-1544, and Department of Biochemistry and Molecular Biology, Oregon Graduate Institute of Science and Technology, Beaverton, Oregon 97006-8921"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Biochemistry, College of Agricultural and Life Sciences, University of Wisconsin, Madison, Wisconsin 53706-1544, and Department of Biochemistry and Molecular Biology, Oregon Graduate Institute of Science and Technology, Beaverton, Oregon 97006-8921","institution_ids":["https://openalex.org/I1304256225","https://openalex.org/I135310074"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5105934278","display_name":"Joann Sanders\u2013Loehr","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1304256225","display_name":"University of Wisconsin System","ror":"https://ror.org/03ydkyb10","country_code":"US","type":"education","lineage":["https://openalex.org/I1304256225"]},{"id":"https://openalex.org/I135310074","display_name":"University of Wisconsin\u2013Madison","ror":"https://ror.org/01y2jtd41","country_code":"US","type":"education","lineage":["https://openalex.org/I135310074"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Joann Sanders-Loehr","raw_affiliation_strings":["Department of Biochemistry, College of Agricultural and Life Sciences, University of Wisconsin, Madison, Wisconsin 53706-1544, and Department of Biochemistry and Molecular Biology, Oregon Graduate Institute of Science and Technology, Beaverton, Oregon 97006-8921"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Biochemistry, College of Agricultural and Life Sciences, University of Wisconsin, Madison, Wisconsin 53706-1544, and Department of Biochemistry and Molecular Biology, Oregon Graduate Institute of Science and Technology, Beaverton, Oregon 97006-8921","institution_ids":["https://openalex.org/I1304256225","https://openalex.org/I135310074"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111884687","display_name":"Thomas M. Loehr","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1304256225","display_name":"University of Wisconsin System","ror":"https://ror.org/03ydkyb10","country_code":"US","type":"education","lineage":["https://openalex.org/I1304256225"]},{"id":"https://openalex.org/I135310074","display_name":"University of Wisconsin\u2013Madison","ror":"https://ror.org/01y2jtd41","country_code":"US","type":"education","lineage":["https://openalex.org/I135310074"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Thomas M. Loehr","raw_affiliation_strings":["Department of Biochemistry, College of Agricultural and Life Sciences, University of Wisconsin, Madison, Wisconsin 53706-1544, and Department of Biochemistry and Molecular Biology, Oregon Graduate Institute of Science and Technology, Beaverton, Oregon 97006-8921"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Biochemistry, College of Agricultural and Life Sciences, University of Wisconsin, Madison, Wisconsin 53706-1544, and Department of Biochemistry and Molecular Biology, Oregon Graduate Institute of Science and Technology, Beaverton, Oregon 97006-8921","institution_ids":["https://openalex.org/I1304256225","https://openalex.org/I135310074"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5027461170","display_name":"Brian G. Fox","orcid":"https://orcid.org/0000-0001-9027-5371","observed_orcids":["https://orcid.org/0000-0001-9027-5371"]},"institutions":[{"id":"https://openalex.org/I1304256225","display_name":"University of Wisconsin System","ror":"https://ror.org/03ydkyb10","country_code":"US","type":"education","lineage":["https://openalex.org/I1304256225"]},{"id":"https://openalex.org/I135310074","display_name":"University of Wisconsin\u2013Madison","ror":"https://ror.org/01y2jtd41","country_code":"US","type":"education","lineage":["https://openalex.org/I135310074"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Brian G. Fox","raw_affiliation_strings":["Department of Biochemistry, College of Agricultural and Life Sciences, University of Wisconsin, Madison, Wisconsin 53706-1544, and Department of Biochemistry and Molecular Biology, Oregon Graduate Institute of Science and Technology, Beaverton, Oregon 97006-8921"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Biochemistry, College of Agricultural and Life Sciences, University of Wisconsin, Madison, Wisconsin 53706-1544, and Department of Biochemistry and Molecular Biology, Oregon Graduate Institute of Science and Technology, Beaverton, Oregon 97006-8921","institution_ids":["https://openalex.org/I1304256225","https://openalex.org/I135310074"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5027461170"],"corresponding_institution_ids":["https://openalex.org/I1304256225","https://openalex.org/I135310074"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.519,"has_fulltext":false,"cited_by_count":10,"citation_normalized_percentile":{"value":0.55928209,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":93},"biblio":{"volume":"39","issue":"34","first_page":"10507","last_page":"10513"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.9672999978065491,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.9672999978065491,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11626","display_name":"Metalloenzymes and iron-sulfur proteins","score":0.012900000438094139,"subfield":{"id":"https://openalex.org/subfields/1303","display_name":"Biochemistry"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T11324","display_name":"Spectroscopy Techniques in Biomedical and Chemical Research","score":0.0038999998942017555,"subfield":{"id":"https://openalex.org/subfields/1304","display_name":"Biophysics"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/delta9-desaturase","display_name":"delta-9 desaturase","score":0.7979999780654907},{"id":"https://openalex.org/keywords/ricinus-communis","display_name":"Ricinus communis","score":0.9049999713897705},{"id":"https://openalex.org/keywords/mu-oxo-bridge","display_name":"\u03bc-oxo bridge","score":0.6570000052452087},{"id":"https://openalex.org/keywords/fe-o-fe-bond-angle","display_name":"Fe-O-Fe bond angle","score":0.8299999833106995},{"id":"https://openalex.org/keywords/substrate-binding","display_name":"substrate binding","score":0.6269999742507935},{"id":"https://openalex.org/keywords/catalytic-turnover","display_name":"catalytic turnover","score":0.7860000133514404},{"id":"https://openalex.org/keywords/oxygen-incorporation","display_name":"oxygen incorporation","score":0.6359999775886536},{"id":"https://openalex.org/keywords/o-o-bond-cleavage","display_name":"O-O bond cleavage","score":0.8500000238418579},{"id":"https://openalex.org/keywords/18o-labeling","display_name":"18O labeling","score":0.6019999980926514},{"id":"https://openalex.org/keywords/enzyme-substrate-complex","display_name":"enzyme-substrate complex","score":0.4620000123977661}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6685893535614014},{"id":"https://openalex.org/C2781340169","wikidata":"https://www.wikidata.org/wiki/Q7315737","display_name":"Resonance Raman spectroscopy","level":3,"score":0.5602113008499146},{"id":"https://openalex.org/C144082473","wikidata":"https://www.wikidata.org/wiki/Q213185","display_name":"Stoichiometry","level":2,"score":0.5563120245933533},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.5538052916526794},{"id":"https://openalex.org/C2777289219","wikidata":"https://www.wikidata.org/wiki/Q7632154","display_name":"Substrate (aquarium)","level":2,"score":0.5515694618225098},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.5050624012947083},{"id":"https://openalex.org/C139210041","wikidata":"https://www.wikidata.org/wiki/Q2145840","display_name":"Resonance (particle physics)","level":2,"score":0.5026183128356934},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.4527287483215332},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.44163820147514343},{"id":"https://openalex.org/C40003534","wikidata":"https://www.wikidata.org/wiki/Q862228","display_name":"Raman spectroscopy","level":2,"score":0.4221239984035492},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.10099267959594727},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.09915545582771301},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.09221500158309937},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0},{"id":"https://openalex.org/C127313418","wikidata":"https://www.wikidata.org/wiki/Q1069","display_name":"Geology","level":0,"score":0.0},{"id":"https://openalex.org/C109214941","wikidata":"https://www.wikidata.org/wiki/Q18334","display_name":"Particle physics","level":1,"score":0.0},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C111368507","wikidata":"https://www.wikidata.org/wiki/Q43518","display_name":"Oceanography","level":1,"score":0.0}],"mesh":[{"descriptor_ui":"D000213","descriptor_name":"Acyl Carrier Protein","qualifier_ui":"Q000378","qualifier_name":"metabolism","is_major_topic":false},{"descriptor_ui":"D000213","descriptor_name":"Acyl Carrier Protein","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D006899","descriptor_name":"Mixed Function Oxygenases","qualifier_ui":"Q000378","qualifier_name":"metabolism","is_major_topic":true},{"descriptor_ui":"D006899","descriptor_name":"Mixed Function Oxygenases","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D007700","descriptor_name":"Kinetics","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008956","descriptor_name":"Models, Chemical","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D010947","descriptor_name":"Plants, Toxic","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D011994","descriptor_name":"Recombinant Proteins","qualifier_ui":"Q000378","qualifier_name":"metabolism","is_major_topic":false},{"descriptor_ui":"D011994","descriptor_name":"Recombinant Proteins","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D012278","descriptor_name":"Ricinus","qualifier_ui":"Q000201","qualifier_name":"enzymology","is_major_topic":false},{"descriptor_ui":"D013059","descriptor_name":"Spectrum Analysis, Raman","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D013379","descriptor_name":"Substrate Specificity","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false}],"locations_count":2,"locations":[{"id":"doi:10.1021/bi000965v","doi":"https://doi.org/10.1021/bi000965v","is_oa":false,"landing_page_url":"https://doi.org/10.1021/bi000965v","pdf_url":null,"source":{"id":"https://openalex.org/S104038378","display_name":"Biochemistry","issn_l":"0006-2960","issn":["0006-2960","1520-4995","1943-295X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","doyens","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Biochemistry","raw_type":"journal-article"},{"id":"pmid:10956041","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/10956041","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Biochemistry","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G3418816781","display_name":"Role of Iron-Oxo Clusters in Fatty Acid Desaturation","funder_award_id":"R01GM050853","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"},{"id":"https://openalex.org/G676989493","display_name":"Graduate Training in Molecular Biosciences","funder_award_id":"T32GM007215","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"}],"funders":[{"id":"https://openalex.org/F4320337354","display_name":"National Institute of General Medical Sciences","ror":"https://ror.org/04q48ey07"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":16,"referenced_works":["https://openalex.org/W166029275","https://openalex.org/W600684647","https://openalex.org/W1490899105","https://openalex.org/W1585683041","https://openalex.org/W1590302505","https://openalex.org/W1834249524","https://openalex.org/W1981696939","https://openalex.org/W1983845336","https://openalex.org/W1987003538","https://openalex.org/W2002276655","https://openalex.org/W2006370393","https://openalex.org/W2055283831","https://openalex.org/W2069951569","https://openalex.org/W2103908409","https://openalex.org/W2321004355","https://openalex.org/W2899862539"],"related_works":["https://openalex.org/W2087027286","https://openalex.org/W2080189994","https://openalex.org/W2079353388","https://openalex.org/W2060690458","https://openalex.org/W2149859312","https://openalex.org/W1988315750","https://openalex.org/W2019504581","https://openalex.org/W2050604610","https://openalex.org/W2165462415","https://openalex.org/W2000732917"],"abstract_inverted_index":{"Resonance":[0],"Raman":[1],"spectroscopy":[2],"has":[3,97],"been":[4],"used":[5,121],"to":[6,63,122],"study":[7],"the":[8,18,36,47,55,60,72,76,137,143,156,167,184,190,207,211,222,228],"effects":[9],"of":[10,21,38,59,71,75,85,112,116,136,148,152,158,162,189,201,210,218,230],"substrate":[11],"binding":[12],"(stearoyl-acyl":[13],"carrier":[14],"protein,":[15],"18:0-ACP)":[16],"on":[17],"diferric":[19,57,69,108,140,213],"centers":[20,58,70,96,141],"Ricinus":[22],"communis":[23],"18:0-ACP":[24,86,102,117,176],"Delta(9)":[25,177],"desaturase.":[26],"These":[27],"studies":[28],"show":[29],"that":[30,90,181],"complex":[31,115],"formation":[32,147,187],"produces":[33],"changes":[34],"in":[35,46,54,67,78,155],"frequencies":[37],"nu(s)(Fe-O-Fe)":[39,79],"and":[40,80,118,227],"nu(as)(Fe-O-Fe)":[41,81],"consistent":[42],"with":[43,175,199],"a":[44,83,98,113,133],"decrease":[45],"Fe-O-Fe":[48],"angle":[49],"from":[50,127,180,204],"approximately":[51,64,149],"123":[52],"degrees":[53,66],"oxo-bridged":[56,68],"as-isolated":[61],"enzyme":[62,192],"120":[65],"complex.":[73],"Analysis":[74],"shifts":[77],"as":[82],"function":[84],"concentration":[87],"also":[88],"suggests":[89],"4e(-)-reduced":[91],"Delta9D":[92,105,119,234],"containing":[93,106],"two":[94,107],"diferrous":[95],"higher":[99],"affinity":[100],"for":[101,221],"than":[103],"resting":[104,212],"centers.":[109],"Catalytic":[110],"turnover":[111],"stoichiometric":[114],"was":[120,171],"investigate":[123],"whether":[124],"an":[125,163,202],"O-atom":[126,203],"O(2)":[128,205],"would":[129],"be":[130],"incorporated":[131],"into":[132,166,206],"bridging":[134],"position":[135,170],"resultant":[138],"mu-oxo-bridged":[139],"during":[142,183,233],"desaturation":[144],"reaction.":[145],"Upon":[146],"70%":[150],"yield":[151],"18:1-ACP":[153],"product":[154],"presence":[157],"(18)O(2),":[159],"no":[160],"incorporation":[161,200],"(18)O":[164],"atom":[165],"mu-oxo":[168,208],"bridge":[169,209],"detected.":[172],"The":[173,215],"result":[174],"desaturase":[178],"differs":[179],"obtained":[182],"tyrosyl":[185],"radical":[186],"reaction":[188,226],"diiron":[191],"ribonucleotide":[193],"reductase":[194],"R2":[195],"component,":[196],"which":[197],"proceeds":[198],"site.":[214],"possible":[216],"implications":[217],"these":[219],"results":[220],"O-O":[223],"bond":[224],"cleavage":[225],"nature":[229],"intermediates":[231],"formed":[232],"catalysis":[235],"are":[236],"discussed.":[237]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2016,"cited_by_count":1}],"updated_date":"2026-11-06T12:05:46.655746","created_date":"2016-06-24T00:00:00"}
