{"id":"https://openalex.org/W2009941596","doi":"https://doi.org/10.1002/9783527620777.ch5d","title":"New Reactions of Stable Silylenes","display_name":"New Reactions of Stable Silylenes","publication_year":2005,"publication_date":"2005-07-26","ids":{"openalex":"https://openalex.org/W2009941596","doi":"https://doi.org/10.1002/9783527620777.ch5d","mag":"2009941596"},"language":"en","primary_location":{"id":"doi:10.1002/9783527620777.ch5d","doi":"https://doi.org/10.1002/9783527620777.ch5d","is_oa":false,"landing_page_url":"https://doi.org/10.1002/9783527620777.ch5d","pdf_url":null,"source":{"id":"https://openalex.org/S4306464293","display_name":"Wiley eBooks","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"ebook platform"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organosilicon Chemistry Set","raw_type":"other"},"volume":{"id":"https://openalex.org/W2486162272","display_name":"Organosilicon Chemistry Set"},"type":"book-chapter","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":null,"display_name":"Robert West","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I135310074","display_name":"University of Wisconsin\u2013Madison","ror":"https://ror.org/01y2jtd41","country_code":"US","type":"education","lineage":["https://openalex.org/I135310074"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Robert West","raw_affiliation_strings":["Organosilicon Research Center, University of Wisconsin-Madison 1101 University Ave., Madison, WI53706\u20131396, USA","Organosilicon Research Center, University of Wisconsin\u2010Madison 1101 University Ave., Madison, WI53706\u20131396, USA Fax: +1 608 262 6143"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Organosilicon Research Center, University of Wisconsin-Madison 1101 University Ave., Madison, WI53706\u20131396, USA","institution_ids":["https://openalex.org/I135310074"]},{"raw_affiliation_string":"Organosilicon Research Center, University of Wisconsin\u2010Madison 1101 University Ave., Madison, WI53706\u20131396, USA Fax: +1 608 262 6143","institution_ids":["https://openalex.org/I135310074"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5063781313","display_name":"Daniel F. Moser","orcid":"https://orcid.org/0000-0003-0648-4491","observed_orcids":["https://orcid.org/0000-0003-0648-4491"]},"institutions":[{"id":"https://openalex.org/I135310074","display_name":"University of Wisconsin\u2013Madison","ror":"https://ror.org/01y2jtd41","country_code":"US","type":"education","lineage":["https://openalex.org/I135310074"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Daniel F. Moser","raw_affiliation_strings":["Organosilicon Research Center, University of Wisconsin-Madison 1101 University Ave., Madison, WI53706\u20131396, USA","Organosilicon Research Center, University of Wisconsin\u2010Madison 1101 University Ave., Madison, WI53706\u20131396, USA Fax: +1 608 262 6143"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Organosilicon Research Center, University of Wisconsin-Madison 1101 University Ave., Madison, WI53706\u20131396, USA","institution_ids":["https://openalex.org/I135310074"]},{"raw_affiliation_string":"Organosilicon Research Center, University of Wisconsin\u2010Madison 1101 University Ave., Madison, WI53706\u20131396, USA Fax: +1 608 262 6143","institution_ids":["https://openalex.org/I135310074"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5003457106","display_name":"Michael Haaf","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I135310074","display_name":"University of Wisconsin\u2013Madison","ror":"https://ror.org/01y2jtd41","country_code":"US","type":"education","lineage":["https://openalex.org/I135310074"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Michael Haaf","raw_affiliation_strings":["Organosilicon Research Center, University of Wisconsin-Madison 1101 University Ave., Madison, WI53706\u20131396, USA","Organosilicon Research Center, University of Wisconsin\u2010Madison 1101 University Ave., Madison, WI53706\u20131396, USA Fax: +1 608 262 6143"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Organosilicon Research Center, University of Wisconsin-Madison 1101 University Ave., Madison, WI53706\u20131396, USA","institution_ids":["https://openalex.org/I135310074"]},{"raw_affiliation_string":"Organosilicon Research Center, University of Wisconsin\u2010Madison 1101 University Ave., Madison, WI53706\u20131396, USA Fax: +1 608 262 6143","institution_ids":["https://openalex.org/I135310074"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5007159906","display_name":"Thomas A. Schmedake","orcid":"https://orcid.org/0000-0002-5695-7376","observed_orcids":["https://orcid.org/0000-0002-5695-7376"]},"institutions":[{"id":"https://openalex.org/I135310074","display_name":"University of Wisconsin\u2013Madison","ror":"https://ror.org/01y2jtd41","country_code":"US","type":"education","lineage":["https://openalex.org/I135310074"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Thomas A. Schmedake","raw_affiliation_strings":["Organosilicon Research Center, University of Wisconsin-Madison 1101 University Ave., Madison, WI53706\u20131396, USA","Organosilicon Research Center, University of Wisconsin\u2010Madison 1101 University Ave., Madison, WI53706\u20131396, USA Fax: +1 608 262 6143"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Organosilicon Research Center, University of Wisconsin-Madison 1101 University Ave., Madison, WI53706\u20131396, USA","institution_ids":["https://openalex.org/I135310074"]},{"raw_affiliation_string":"Organosilicon Research Center, University of Wisconsin\u2010Madison 1101 University Ave., Madison, WI53706\u20131396, USA Fax: +1 608 262 6143","institution_ids":["https://openalex.org/I135310074"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5040701048","display_name":"Ilia A. Guzei","orcid":"https://orcid.org/0000-0003-1976-7386","observed_orcids":["https://orcid.org/0000-0003-1976-7386"]},"institutions":[{"id":"https://openalex.org/I135310074","display_name":"University of Wisconsin\u2013Madison","ror":"https://ror.org/01y2jtd41","country_code":"US","type":"education","lineage":["https://openalex.org/I135310074"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Ilia Guzei","raw_affiliation_strings":["Organosilicon Research Center, University of Wisconsin-Madison 1101 University Ave., Madison, WI53706\u20131396, USA","Organosilicon Research Center, University of Wisconsin\u2010Madison 1101 University Ave., Madison, WI53706\u20131396, USA Fax: +1 608 262 6143"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Organosilicon Research Center, University of Wisconsin-Madison 1101 University Ave., Madison, WI53706\u20131396, USA","institution_ids":["https://openalex.org/I135310074"]},{"raw_affiliation_string":"Organosilicon Research Center, University of Wisconsin\u2010Madison 1101 University Ave., Madison, WI53706\u20131396, USA Fax: +1 608 262 6143","institution_ids":["https://openalex.org/I135310074"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I135310074"],"apc_list":null,"apc_paid":null,"fwci":2.796,"has_fulltext":false,"cited_by_count":1,"citation_normalized_percentile":{"value":0.92996604,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":"19","last_page":"26"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.9765999913215637,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.9765999913215637,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.013799999840557575,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.00800000037997961,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/silylene-complexes","display_name":"silylene complexes","score":0.7379999756813049},{"id":"https://openalex.org/keywords/transition-metal-carbonyls","display_name":"transition metal carbonyls","score":0.8830000162124634},{"id":"https://openalex.org/keywords/co-displacement","display_name":"CO displacement","score":0.8119999766349792},{"id":"https://openalex.org/keywords/si-si-bond-formation","display_name":"Si-Si bond formation","score":0.9229999780654907},{"id":"https://openalex.org/keywords/olefin-polymerization","display_name":"olefin polymerization","score":0.746999979019165},{"id":"https://openalex.org/keywords/alkyne-polymerization","display_name":"alkyne polymerization","score":0.8360000252723694},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.8349999785423279},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.8420000076293945}],"concepts":[{"id":"https://openalex.org/C2776758007","wikidata":"https://www.wikidata.org/wiki/Q7517196","display_name":"Silylene","level":3,"score":0.9944757223129272},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7244238257408142},{"id":"https://openalex.org/C2780055204","wikidata":"https://www.wikidata.org/wiki/Q387914","display_name":"Halocarbon","level":2,"score":0.6458247900009155},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.5716280937194824},{"id":"https://openalex.org/C196099240","wikidata":"https://www.wikidata.org/wiki/Q177033","display_name":"Triple bond","level":3,"score":0.5062798261642456},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.46490442752838135},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.45864301919937134},{"id":"https://openalex.org/C68381374","wikidata":"https://www.wikidata.org/wiki/Q258652","display_name":"Double bond","level":2,"score":0.4145599603652954},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3296157121658325},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3016781806945801},{"id":"https://openalex.org/C544956773","wikidata":"https://www.wikidata.org/wiki/Q670","display_name":"Silicon","level":2,"score":0.23349717259407043},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2252817451953888},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.15019500255584717},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/9783527620777.ch5d","doi":"https://doi.org/10.1002/9783527620777.ch5d","is_oa":false,"landing_page_url":"https://doi.org/10.1002/9783527620777.ch5d","pdf_url":null,"source":{"id":"https://openalex.org/S4306464293","display_name":"Wiley eBooks","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"ebook platform"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organosilicon Chemistry Set","raw_type":"other"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":11,"referenced_works":["https://openalex.org/W1972206365","https://openalex.org/W1973105379","https://openalex.org/W1973446797","https://openalex.org/W1974337796","https://openalex.org/W2005150540","https://openalex.org/W2087266904","https://openalex.org/W2089395684","https://openalex.org/W2115135661","https://openalex.org/W2119993306","https://openalex.org/W2120770658","https://openalex.org/W4255131163"],"related_works":["https://openalex.org/W2153290837","https://openalex.org/W2770056263","https://openalex.org/W4240678811","https://openalex.org/W7100045142","https://openalex.org/W1977431288","https://openalex.org/W1984045924","https://openalex.org/W2951552568","https://openalex.org/W4241730286","https://openalex.org/W2089321325","https://openalex.org/W2074046408"],"abstract_inverted_index":{"Some":[0],"recent":[1],"chemistry":[2],"of":[3,19,40,59,69,94,110],"the":[4,70,74,87,92,111],"stable":[5],"silylenes,":[6],"(CHNtBu)2Si:":[7],"(1)":[8],"and":[9,35,42,50,55,61],"(CH2NtBu)2Si:":[10],"(2)":[11],"is":[12],"reported":[13],"[1].":[14],"The":[15],"X-ray":[16],"crystal":[17],"structure":[18],"1":[20,41,60,90],"has":[21],"finally":[22],"been":[23,53],"determined.":[24],"Both":[25],"silylenes":[26],"react":[27],"with":[28,44,63],"transition":[29],"metal":[30],"carbonyls":[31],"to":[32,73],"displace":[33],"CO":[34],"form":[36],"silylene":[37],"complexes.":[38],"Complexes":[39],"2":[43,62],"Cr,":[45],"Mo,":[46],"W,":[47],"Fe,":[48],"Ru,":[49],"Ni":[51],"have":[52],"prepared":[54],"studied":[56],"structurally.":[57],"Reactions":[58],"halocarbons":[64],"yield":[65],"either":[66],"simple":[67],"addition":[68],"C-X":[71],"bond":[72],"silylene,":[75],"or":[76,101],"2:1":[77],"silylene:":[78],"halocarbon":[79],"products":[80],"containing":[81,98],"a":[82],"Si-Si":[83],"bond,":[84],"depending":[85],"on":[86],"halocarbon.":[88],"Silylene":[89],"catalyzes":[91],"polymerization":[93],"nearly":[95],"all":[96],"compounds":[97],"carbon-carbon":[99],"double":[100],"triple":[102],"bonds.":[103],"Possible":[104],"mechanisms":[105],"are":[106],"proposed":[107],"for":[108],"several":[109],"reactions":[112],"described":[113],"above.":[114]},"counts_by_year":[],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2016-06-24T00:00:00"}
