{"id":"https://openalex.org/W2008681886","doi":"https://doi.org/10.1139/v80-110","title":"Dianions of glyoxylic acid thioketals: conventent \u03b1-keto acid equivalents","display_name":"Dianions of glyoxylic acid thioketals: conventent \u03b1-keto acid equivalents","publication_year":1980,"publication_date":"1980-04-01","ids":{"openalex":"https://openalex.org/W2008681886","doi":"https://doi.org/10.1139/v80-110","mag":"2008681886"},"language":"en","primary_location":{"id":"doi:10.1139/v80-110","doi":"https://doi.org/10.1139/v80-110","is_oa":true,"landing_page_url":"https://doi.org/10.1139/v80-110","pdf_url":"https://cdnsciencepub.com/doi/pdf/10.1139/v80-110","source":{"id":"https://openalex.org/S9189650","display_name":"Canadian Journal of Chemistry","issn_l":"0008-4042","issn":["0008-4042","1480-3291"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310312929","host_organization_name":"Canadian Science Publishing","host_organization_lineage":["https://openalex.org/P4310312929"],"host_organization_lineage_names":["Canadian Science Publishing"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Canadian Journal of Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"bronze","oa_url":"https://cdnsciencepub.com/doi/pdf/10.1139/v80-110","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5114004938","display_name":"Gordon S. Bates","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I141945490","display_name":"University of British Columbia","ror":"https://ror.org/03rmrcq20","country_code":"CA","type":"education","lineage":["https://openalex.org/I141945490"]},{"id":"https://openalex.org/I4210159778","display_name":"National Research Council Canada","ror":"https://ror.org/04mte1k06","country_code":"CA","type":"government","lineage":["https://openalex.org/I4210159778"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"Gordon S. Bates","raw_affiliation_strings":["Department of Chetnistry, Uni~ersity of British Columbia, Vancou~er, B.C., Canada V6T I Y6","National Research Council of Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chetnistry, Uni~ersity of British Columbia, Vancou~er, B.C., Canada V6T I Y6","institution_ids":["https://openalex.org/I141945490"]},{"raw_affiliation_string":"National Research Council of Canada","institution_ids":["https://openalex.org/I4210159778"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5015165737","display_name":"S. Ramaswamy","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I141945490","display_name":"University of British Columbia","ror":"https://ror.org/03rmrcq20","country_code":"CA","type":"education","lineage":["https://openalex.org/I141945490"]},{"id":"https://openalex.org/I4210159778","display_name":"National Research Council Canada","ror":"https://ror.org/04mte1k06","country_code":"CA","type":"government","lineage":["https://openalex.org/I4210159778"]}],"countries":["CA"],"is_corresponding":false,"raw_author_name":"S. Ramaswamy","raw_affiliation_strings":["Department of Chetnistry, Uni~ersity of British Columbia, Vancou~er, B.C., Canada V6T I Y6","National Research Council of Canada"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chetnistry, Uni~ersity of British Columbia, Vancou~er, B.C., Canada V6T I Y6","institution_ids":["https://openalex.org/I141945490"]},{"raw_affiliation_string":"National Research Council of Canada","institution_ids":["https://openalex.org/I4210159778"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":1.1079,"has_fulltext":true,"cited_by_count":26,"citation_normalized_percentile":{"value":0.69437247,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":93},"biblio":{"volume":"58","issue":"7","first_page":"716","last_page":"722"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12228","display_name":"Coordination Chemistry and Organometallics","score":0.6445000171661377,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12228","display_name":"Coordination Chemistry and Organometallics","score":0.6445000171661377,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13859","display_name":"Organic Chemistry Synthesis Methods","score":0.093299999833107,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13649","display_name":"Advanced Synthetic Organic Chemistry","score":0.07029999792575836,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/dianion","display_name":"dianion","score":0.9300000071525574},{"id":"https://openalex.org/keywords/alkylation","display_name":"alkylation","score":0.8339999914169312},{"id":"https://openalex.org/keywords/tetrahydrofuran-solubility","display_name":"tetrahydrofuran solubility","score":0.7519999742507935},{"id":"https://openalex.org/keywords/alkyl-halides","display_name":"alkyl halides","score":0.9390000104904175},{"id":"https://openalex.org/keywords/tosylate","display_name":"tosylate","score":0.9729999899864197},{"id":"https://openalex.org/keywords/epoxides","display_name":"epoxides","score":0.9829999804496765},{"id":"https://openalex.org/keywords/alpha-keto-acids","display_name":"\u03b1-keto acids","score":0.828000009059906}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9677796959877014},{"id":"https://openalex.org/C164361826","wikidata":"https://www.wikidata.org/wiki/Q177604","display_name":"Alkylation","level":3,"score":0.9400545358657837},{"id":"https://openalex.org/C2779489543","wikidata":"https://www.wikidata.org/wiki/Q413552","display_name":"Glyoxylic acid","level":2,"score":0.8160408735275269},{"id":"https://openalex.org/C171560689","wikidata":"https://www.wikidata.org/wiki/Q193086","display_name":"Halide","level":2,"score":0.6712950468063354},{"id":"https://openalex.org/C2779193700","wikidata":"https://www.wikidata.org/wiki/Q413421","display_name":"Dimethyl sulfate","level":2,"score":0.6138364672660828},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.5896741151809692},{"id":"https://openalex.org/C2776701986","wikidata":"https://www.wikidata.org/wiki/Q278332","display_name":"Tetrahydrofuran","level":3,"score":0.58009934425354},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.5365275144577026},{"id":"https://openalex.org/C2776673659","wikidata":"https://www.wikidata.org/wiki/Q47512","display_name":"Acetic acid","level":2,"score":0.534930944442749},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.5251992344856262},{"id":"https://openalex.org/C517785266","wikidata":"https://www.wikidata.org/wiki/Q703","display_name":"Potassium","level":2,"score":0.5098947286605835},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.13211655616760254}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1139/v80-110","doi":"https://doi.org/10.1139/v80-110","is_oa":true,"landing_page_url":"https://doi.org/10.1139/v80-110","pdf_url":"https://cdnsciencepub.com/doi/pdf/10.1139/v80-110","source":{"id":"https://openalex.org/S9189650","display_name":"Canadian Journal of Chemistry","issn_l":"0008-4042","issn":["0008-4042","1480-3291"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310312929","host_organization_name":"Canadian Science Publishing","host_organization_lineage":["https://openalex.org/P4310312929"],"host_organization_lineage_names":["Canadian Science Publishing"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Canadian Journal of Chemistry","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1139/v80-110","doi":"https://doi.org/10.1139/v80-110","is_oa":true,"landing_page_url":"https://doi.org/10.1139/v80-110","pdf_url":"https://cdnsciencepub.com/doi/pdf/10.1139/v80-110","source":{"id":"https://openalex.org/S9189650","display_name":"Canadian Journal of Chemistry","issn_l":"0008-4042","issn":["0008-4042","1480-3291"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310312929","host_organization_name":"Canadian Science Publishing","host_organization_lineage":["https://openalex.org/P4310312929"],"host_organization_lineage_names":["Canadian Science Publishing"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Canadian Journal of Chemistry","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2008681886.pdf","grobid_xml":"https://content.openalex.org/works/W2008681886.grobid-xml"},"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2038381764","https://openalex.org/W3042812593","https://openalex.org/W2951813610","https://openalex.org/W2013097511","https://openalex.org/W2064847445","https://openalex.org/W2059373941","https://openalex.org/W4249119517","https://openalex.org/W634184560","https://openalex.org/W2041547246","https://openalex.org/W4251871197"],"abstract_inverted_index":{"By":[0],"varying":[1],"the":[2,14,17,32,73],"solvent,":[3],"reaction":[4],"temperature,":[5],"and":[6,24,51],"bases":[7],"(i.e.,":[8],"gegenions":[9],"present),":[10],"optimum":[11],"conditions":[12],"for":[13],"alkylation":[15,56],"of":[16,19,40],"dianions":[18],"glyoxylic":[20],"acid":[21,42],"derivatives":[22],"8":[23],"9":[25],"were":[26],"established.":[27],"It":[28],"was":[29,43],"found":[30],"that":[31],"easily":[33],"prepared,":[34],"thermally":[35],"stable,":[36],"tetrahydrofuran-soluble":[37],"potassium":[38],"dianion":[39],"bis(ethylthio)acetic":[41],"readily":[44,70],"alkylated":[45,66],"by":[46],"alkyl":[47],"halides,":[48],"tosylates,":[49],"epoxides,":[50],"N-tosyl":[52],"aziridines.":[53],"The":[54],"latter":[55],"is":[57],"being":[58],"used":[59],"to":[60],"develop":[61],"a":[62],"possible":[63],"cytochalasin":[64],"synthesis.The":[65],"products":[67],"may":[68],"be":[69],"converted":[71],"into":[72],"corresponding":[74],"\u03b1-keto":[75],"acids":[76],"or":[77],"methyl":[78],"2,2-bismethoxycarboxylates.":[79]},"counts_by_year":[{"year":2020,"cited_by_count":1},{"year":2018,"cited_by_count":1},{"year":2014,"cited_by_count":1}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}
