{"id":"https://openalex.org/W2008339658","doi":"https://doi.org/10.1039/c4cc04905e","title":"Silver-catalyzed cyclization of 2-pyridyl alkynyl carbinols with isocyanides: divergent synthesis of indolizines and pyrroles","display_name":"Silver-catalyzed cyclization of 2-pyridyl alkynyl carbinols with isocyanides: divergent synthesis of indolizines and pyrroles","publication_year":2014,"publication_date":"2014-01-01","ids":{"openalex":"https://openalex.org/W2008339658","doi":"https://doi.org/10.1039/c4cc04905e","mag":"2008339658","pmid":"https://pubmed.ncbi.nlm.nih.gov/25145403"},"language":"en","primary_location":{"id":"doi:10.1039/c4cc04905e","doi":"https://doi.org/10.1039/c4cc04905e","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c4cc04905e","pdf_url":null,"source":{"id":"https://openalex.org/S152760256","display_name":"Chemical Communications","issn_l":"1359-7345","issn":["1359-7345","1364-548X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chem. Commun.","raw_type":"journal-article"},"parent_works":[],"lineage":["https://openalex.org/W2008339658"],"child_works_count":0,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5101927372","display_name":"Xianyu Meng","orcid":"https://orcid.org/0009-0004-0188-1425","observed_orcids":["https://orcid.org/0009-0004-0188-1425"]},"institutions":[{"id":"https://openalex.org/I184983240","display_name":"Northeast Normal University","ror":"https://ror.org/02rkvz144","country_code":"CN","type":"education","lineage":["https://openalex.org/I184983240"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Xianyu Meng","raw_affiliation_strings":["Changchun 130024, China","Department of Chemistry","Northeast Normal University","Department of Chemistry, Northeast Normal University, Changchun 130024, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Changchun 130024, China","institution_ids":[]},{"raw_affiliation_string":"Department of Chemistry","institution_ids":[]},{"raw_affiliation_string":"Northeast Normal University","institution_ids":["https://openalex.org/I184983240"]},{"raw_affiliation_string":"Department of Chemistry, Northeast Normal University, Changchun 130024, China","institution_ids":["https://openalex.org/I184983240"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5061247509","display_name":"Peiqiu Liao","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I184983240","display_name":"Northeast Normal University","ror":"https://ror.org/02rkvz144","country_code":"CN","type":"education","lineage":["https://openalex.org/I184983240"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Peiqiu Liao","raw_affiliation_strings":["Changchun 130024, China","Department of Chemistry","Northeast Normal University","Department of Chemistry, Northeast Normal University, Changchun 130024, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Changchun 130024, China","institution_ids":[]},{"raw_affiliation_string":"Department of Chemistry","institution_ids":[]},{"raw_affiliation_string":"Northeast Normal University","institution_ids":["https://openalex.org/I184983240"]},{"raw_affiliation_string":"Department of Chemistry, Northeast Normal University, Changchun 130024, China","institution_ids":["https://openalex.org/I184983240"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101615204","display_name":"Jian\u2010Quan Liu","orcid":"https://orcid.org/0000-0002-5533-2075","observed_orcids":["https://orcid.org/0000-0002-5533-2075"]},"institutions":[{"id":"https://openalex.org/I184983240","display_name":"Northeast Normal University","ror":"https://ror.org/02rkvz144","country_code":"CN","type":"education","lineage":["https://openalex.org/I184983240"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Jianquan Liu","raw_affiliation_strings":["Changchun 130024, China","Department of Chemistry","Northeast Normal University","Department of Chemistry, Northeast Normal University, Changchun 130024, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Changchun 130024, China","institution_ids":[]},{"raw_affiliation_string":"Department of Chemistry","institution_ids":[]},{"raw_affiliation_string":"Northeast Normal University","institution_ids":["https://openalex.org/I184983240"]},{"raw_affiliation_string":"Department of Chemistry, Northeast Normal University, Changchun 130024, China","institution_ids":["https://openalex.org/I184983240"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5026672159","display_name":"Xihe Bi","orcid":"https://orcid.org/0000-0002-6694-6742","observed_orcids":["https://orcid.org/0000-0002-6694-6742"]},"institutions":[{"id":"https://openalex.org/I184983240","display_name":"Northeast Normal University","ror":"https://ror.org/02rkvz144","country_code":"CN","type":"education","lineage":["https://openalex.org/I184983240"]},{"id":"https://openalex.org/I4391768085","display_name":"State Key Laboratory of Elemental Organic Chemistry","ror":"https://ror.org/027j6ra75","country_code":"CN","type":"facility","lineage":["https://openalex.org/I205237279","https://openalex.org/I4391768085"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Xihe Bi","raw_affiliation_strings":["Changchun 130024, China","Department of Chemistry","Northeast Normal University","State Key Laboratory and Institute of Elemento-Organic Chemistry","Tianjin 300071, China","Department of Chemistry, Northeast Normal University, Changchun 130024, China","State Key Laboratory and Institute of Elemento-Organic Chemistry, Tianjin 300071, China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Changchun 130024, China","institution_ids":[]},{"raw_affiliation_string":"Department of Chemistry","institution_ids":[]},{"raw_affiliation_string":"Northeast Normal University","institution_ids":["https://openalex.org/I184983240"]},{"raw_affiliation_string":"State Key Laboratory and Institute of Elemento-Organic Chemistry","institution_ids":[]},{"raw_affiliation_string":"Tianjin 300071, China","institution_ids":[]},{"raw_affiliation_string":"Department of Chemistry, Northeast Normal University, Changchun 130024, China","institution_ids":["https://openalex.org/I184983240"]},{"raw_affiliation_string":"State Key Laboratory and Institute of Elemento-Organic Chemistry, Tianjin 300071, China","institution_ids":["https://openalex.org/I4391768085"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5026672159"],"corresponding_institution_ids":["https://openalex.org/I184983240","https://openalex.org/I4391768085"],"apc_list":null,"apc_paid":null,"fwci":6.1478,"has_fulltext":false,"cited_by_count":91,"citation_normalized_percentile":{"value":0.97397745,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":87,"max":100},"biblio":{"volume":"50","issue":"80","first_page":"11837","last_page":"11839"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10871","display_name":"Catalytic Alkyne Reactions","score":0.39719998836517334,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10871","display_name":"Catalytic Alkyne Reactions","score":0.39719998836517334,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13230","display_name":"Synthesis and Reactivity of Heterocycles","score":0.263700008392334,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12562","display_name":"Synthesis and Characterization of Pyrroles","score":0.17440000176429749,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/silver-catalysis","display_name":"silver catalysis","score":0.9890000224113464},{"id":"https://openalex.org/keywords/isocyanides","display_name":"isocyanides","score":0.9919999837875366},{"id":"https://openalex.org/keywords/indolizines","display_name":"indolizines","score":0.9549999833106995},{"id":"https://openalex.org/keywords/divergent-synthesis","display_name":"divergent synthesis","score":0.7879999876022339},{"id":"https://openalex.org/keywords/3-2-cycloaddition","display_name":"[3+2] cycloaddition","score":0.949999988079071},{"id":"https://openalex.org/keywords/terminal-alkynes","display_name":"terminal alkynes","score":0.8460000157356262},{"id":"https://openalex.org/keywords/regioselectivity","display_name":"regioselectivity","score":0.9300000071525574},{"id":"https://openalex.org/keywords/cyclization","display_name":"cyclization","score":0.5740000009536743}],"concepts":[{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7919559478759766},{"id":"https://openalex.org/C197865113","wikidata":"https://www.wikidata.org/wiki/Q2566866","display_name":"Divergent synthesis","level":3,"score":0.6334924101829529},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.6191391944885254},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.5365602374076843},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.38912278413772583},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.31301581859588623}],"mesh":[{"descriptor_ui":"D000432","descriptor_name":"Methanol","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D000480","descriptor_name":"Alkynes","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D002384","descriptor_name":"Catalysis","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D003486","descriptor_name":"Cyanides","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D003500","descriptor_name":"Cyclization","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D007212","descriptor_name":"Indolizines","qualifier_ui":"Q000138","qualifier_name":"chemical synthesis","is_major_topic":true},{"descriptor_ui":"D008958","descriptor_name":"Models, Molecular","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D011758","descriptor_name":"Pyrroles","qualifier_ui":"Q000138","qualifier_name":"chemical synthesis","is_major_topic":true},{"descriptor_ui":"D012834","descriptor_name":"Silver","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D013237","descriptor_name":"Stereoisomerism","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D061565","descriptor_name":"Cycloaddition Reaction","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false}],"locations_count":2,"locations":[{"id":"doi:10.1039/c4cc04905e","doi":"https://doi.org/10.1039/c4cc04905e","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c4cc04905e","pdf_url":null,"source":{"id":"https://openalex.org/S152760256","display_name":"Chemical Communications","issn_l":"1359-7345","issn":["1359-7345","1364-548X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-2","ki-jl-1","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chem. Commun.","raw_type":"journal-article"},{"id":"pmid:25145403","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/25145403","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemical communications (Cambridge, England)","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":37,"referenced_works":["https://openalex.org/W1529224957","https://openalex.org/W1973565571","https://openalex.org/W1996920733","https://openalex.org/W2000158533","https://openalex.org/W2001722190","https://openalex.org/W2002808866","https://openalex.org/W2011077957","https://openalex.org/W2011665918","https://openalex.org/W2015150429","https://openalex.org/W2022205556","https://openalex.org/W2025784332","https://openalex.org/W2030148632","https://openalex.org/W2031054971","https://openalex.org/W2031644569","https://openalex.org/W2038392568","https://openalex.org/W2039102203","https://openalex.org/W2043001394","https://openalex.org/W2047352933","https://openalex.org/W2054143434","https://openalex.org/W2077578474","https://openalex.org/W2078813757","https://openalex.org/W2082313839","https://openalex.org/W2086457719","https://openalex.org/W2088537550","https://openalex.org/W2104479320","https://openalex.org/W2108154096","https://openalex.org/W2114860602","https://openalex.org/W2121713387","https://openalex.org/W2142556071","https://openalex.org/W2148002316","https://openalex.org/W2165742515","https://openalex.org/W2170402672","https://openalex.org/W2320113454","https://openalex.org/W2950955710","https://openalex.org/W2951475440","https://openalex.org/W4211259730","https://openalex.org/W4297632299"],"related_works":["https://openalex.org/W2951273536","https://openalex.org/W2581271125","https://openalex.org/W2298981893","https://openalex.org/W2804993961","https://openalex.org/W2148002316","https://openalex.org/W2951441375","https://openalex.org/W2947172086","https://openalex.org/W2527023742","https://openalex.org/W7118144240","https://openalex.org/W3199609072"],"abstract_inverted_index":{"Divergent":[0],"syntheses":[1],"of":[2,11,48],"indolizines":[3,28],"and":[4,29],"2,4-disubstituted":[5,30,38],"pyrroles":[6,31,39],"by":[7,42],"the":[8],"silver-catalyzed":[9],"cyclization":[10],"2-pyridyl":[12],"alkynyl":[13],"carbinols":[14],"with":[15,51],"isocyanides":[16],"are":[17,40],"reported.":[18],"These":[19],"methods":[20],"provide":[21],"an":[22,43],"effective":[23],"route":[24],"to":[25,34],"highly":[26],"functionalized":[27],"in":[32],"good":[33],"excellent":[35],"yields.":[36],"The":[37],"synthesized":[41],"unprecedented":[44],"regioselective":[45],"[3+2]":[46],"cycloaddition":[47],"terminal":[49],"alkynes":[50],"isocyanides.":[52]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":3},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":5},{"year":2021,"cited_by_count":7},{"year":2020,"cited_by_count":10},{"year":2019,"cited_by_count":8},{"year":2018,"cited_by_count":4},{"year":2017,"cited_by_count":12},{"year":2016,"cited_by_count":11},{"year":2015,"cited_by_count":22},{"year":2014,"cited_by_count":1},{"year":2013,"cited_by_count":1},{"year":2012,"cited_by_count":1}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}